CN103445972A - Mild shampoo containing sulfonated alkyl glucoside - Google Patents
Mild shampoo containing sulfonated alkyl glucoside Download PDFInfo
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- CN103445972A CN103445972A CN2013103763109A CN201310376310A CN103445972A CN 103445972 A CN103445972 A CN 103445972A CN 2013103763109 A CN2013103763109 A CN 2013103763109A CN 201310376310 A CN201310376310 A CN 201310376310A CN 103445972 A CN103445972 A CN 103445972A
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- glucoside
- shampoo
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- mild shampoo
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Abstract
The invention relates to a mild shampoo containing sulfonated alkyl glucoside. Except water, the mild shampoo contains the following raw materials: (A) a main surfactant occupying 5.0-40% of the weight of the mild shampoo, which is the composition of sulfonated alkyl glucoside and sulfonated alkyl polyglycoside, (B) an ampholytic surfactant occupying 1.0-10.0% of the weight of the mild shampoo, which is amphoteric sodium coco-acetate or cocamidopropyl betaine, and (C) a cationic polymer occupying 0.05-1% of the weight of the mild shampoo, which is cationic guar gum. The shampoo is mild in nature, free from silicone oil, and good in foaming property.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of mild shampoo that contains the sulfonated alkyl glucoside.
Background technology
In the shampoo formula system, the effect of first type surface activating agent is extremely important as in foaming characteristic, spatter property, and the aspects such as the collaborative thickening of system all will play desirable effect.In the tradition shampoo formula, the first type surface activating agent has been continued to use the sulfate type anion surfactant as Laurel alkyl sulfate (sodium salt or ammonium salt) abbreviation K12 or K12A always, and Laurel alkyl ether sulfate (sodium salt or ammonium salt) is called for short AES or AESA.As shampoo first type surface activating agent, Laurel alkyl sulfate (sodium salt or ammonium salt) is called for short K12 or K12A, the collocation application technology (as foam, the clean thickening property etc. that reaches) that is called for short AES or AESA with Laurel alkyl ether sulfate (sodium salt or ammonium salt) is very ripe, and cost performance is also very high.
Yet, along with improving constantly of living standard, people are also more and more higher to demand and the requirement of hair washing product.People also turn to the product of the demands such as natural, green, environmental protection, gentleness to the demand of product from the product of traditional attractable point, and the product of natural demand also more and more is subject to pursuing of consumer.Therefore, be necessary to adopt technological means to start with and solve problem from the first type surface activating agent of existing shampoo product.Although the use of the sulfate type anion surface active used in traditional shampoo product is very ripe, yet from the science angle analysis, there is defat strong (therefore need to increase conditioning property with silicone oil) in the sulfate type anion surfactant, come from oil, contain oxirane EO etc., all these runs counter to natural, green, environmental protection and gentle demand.
How effectively to solve clean, the conditioning property that hair is good and cater to again natural and gentle actual demand? this practical problem that the present invention will solve just, substitutes with sulfonated alkyl glucoside (a kind of come from natural gentle anion surfactant) the sulfate type anion surfactant that traditional shampoo is used fully.
This special anion surfactant is exactly bonding hydroxypropyl azochlorosulfonate acid sodium and the novel product with anion surfactant feature of the natural origin that obtains on nonionic alkyl-glucoside or glycan molecule.The anion surfactant of this uniqueness provides gentleer cleaning effect can to hair and skin, and foam is abundant, its foaming properties and clean-up performance far surpass other non-ionic surface active agent be derived by APG, aspect spumescence and mildness and clean power, also are being better than traditional sulfate type anion surfactant.This new nonionic surfactant is when providing clean and nursing efficacy for hair and skin, glucosides in molecule can also reduce the zest of anion or other cationic polymer greatly, and there is good conditioning effect, therefore be used to gentle hair conditioning shampoo product.
Summary of the invention
The purpose of this invention is to provide a kind of mild shampoo containing the sulfonated alkyl glucoside.
This mild shampoo is except containing the acceptable component of shampoo, and this shampoo also contains:
(A) account for the first type surface activating agent of mild shampoo weight 5.0% to 40%, the compositions that this surfactant is sulfonated alkyl glucoside and the poly-alkyl-glucoside of sulfonation, and both ratios are weight ratio 1:2-2:1;
Wherein, sulfonated alkyl glucoside molecular structural formula following (I):
The molecular structure formula I
In formula I, R
1represent the alkyl that carbon number is 8 to 22, n represents the degree of polymerization, between 1-3;
The molecular structural formula following (II) of the poly-alkyl-glucoside of sulfonation
The molecular structure formula II
In formula II, R represents that carbon number is 8 to 22 alkyl, and n represents the degree of polymerization, is the integer between 4-6;
(B) account for the amphoteric surfactant of mild shampoo weight 1.0% to 10.0%, this amphoteric surfactant is cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine;
(C) account for the cation guar gum of mild shampoo weight 0.05% to 1%.
Mild shampoo of the present invention, R and R in the poly-alkyl-glucoside of sulfonated alkyl glucoside and sulfonation
1the alkyl mild shampoo of the present invention that to be respectively carbon number be 12, the wherein preferred cocamido propyl betaine of amphoteric surfactant.
Mild shampoo of the present invention, wherein said sulfonated alkyl glucoside is the lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium, the poly-alkyl-glucoside of sulfonation is poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium.
Mild shampoo of the present invention, also contain the pearlescent flake that accounts for composition weight 0.05% to 3.0%.
Mild shampoo of the present invention, do not contain silicone oil.
A kind of mild shampoo containing the sulfonated alkyl glucoside of the present invention, its component and content are:
| Component | The content % by weight |
| Lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium (40%) | 15.8 |
| Poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium (39.5%) | 15.9 |
| Cocamido propyl betaine | 5.0 |
| Cation guar gum | 0.2 |
| Pearlescent flake | 1.5 |
| Disodiumedetate | 0.1 |
| Citric acid, antiseptic, coloring agent, spice, sodium chloride | In right amount |
| Water | Add to 100% |
Compared with prior art, the present invention has the following advantages:
Mild shampoo of the present invention, the first type surface activating agent has adopted and has come from natural sulfonated alkyl glucoside (compositions of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium), and has substituted the sulfate type anion surfactant that traditional shampoo is used fully.Spumescence of the present invention and spatter property are superior, extremely low the stimulation, and containing EO, silicate-containing oil not, biological degradability is good, is genuine mild mild shampoo.
The specific embodiment
Below will be elaborated to compositional selecting of the present invention and effect.
Sulfonated alkyl glucoside in the present invention, the poly-alkyl-glucoside of sulfonation is that hydroxypropyl sulfonic acid reacts synthetic with the alkyl-glucoside of different carbon chain lengths.So gentle superior properties of product provide more range of application to the formula teacher.Pass through great many of experiments, the inventor finds, to be straight chain and carbon number put up the best performance aspect clean and conditioning effect at hair between the alkane of 10-12 long carbochain in the poly-alkyl-glucoside of sulfonated alkyl glucoside and sulfonation in alkyl polyglucoside, and the sulfonated alkyl glucoside gathers when two ratios according to weight ratio 1:2 to 2:1 of alkyl-glucoside are arranged in pairs or groups use and has synergy with sulfonation.
Mild shampoo of the present invention, the sulfonated alkyl glucoside comprises the lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium, ten alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, eight alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, cetyl glucoside hydroxypropyl azochlorosulfonate acid sodium, octadecyl glucoside hydroxypropyl azochlorosulfonate acid sodium etc.; Mild shampoo of the present invention, the poly-alkyl-glucoside of sulfonation comprises poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium, poly-ten alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, poly-eight alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, poly-cetyl glucoside hydroxypropyl azochlorosulfonate acid sodium, poly-octadecyl glucoside hydroxypropyl azochlorosulfonate acid sodium etc.
Mild shampoo of the present invention, the preferred lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium of sulfonated alkyl glucoside, the degree of polymerization is between 1-3, and further preferably 1.4.
Mild shampoo of the present invention, sulfonation gathers the preferred poly-dodecyl glucoside of alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodium, and the degree of polymerization is between the integer of 4-6.
The physicochemical property of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium of the present invention: active quantities (solid content): 40%, pH(10% solution) 7, color Gardner<1, the instant height of foam (1% active matter): 155.
The physicochemical property of poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium of the present invention: active quantities (solid content): 39.5%, pH(10% solution) 7, color Gardner<1, the instant height of foam (1% active matter): 150.
Wherein, sulfonated alkyl glucoside molecular structural formula following (I):
The molecular structure formula I
In formula I, R
1represent the alkyl that carbon number is 8 to 22, n represents the degree of polymerization, between 1-3, and more preferably 1.4.
The molecular structural formula following (II) of the poly-alkyl-glucoside of sulfonation
The molecular structure formula II
In formula II, R represents that carbon number is 8 to 22 alkyl, and n represents the degree of polymerization, is the integer between 4-6.
In mild shampoo of the present invention, the first type surface activating agent has replaced the aliphatic alcohol sulfate of traditional shampoo use and the compositions of fatty alcohol ether sulphate with sulfonated alkyl glucoside (lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium) and the form of poly-alkyl-glucoside (the poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium) compositions of sulfonation.
Mild shampoo of the present invention, contain the lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium that accounts for composition weight 5.0% to 40% and the compositions of poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium, the weight ratio of described lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium is 1:2-2:1.
The compositions that described traditional shampoo first type surface activating agent aliphatic alcohol sulfate and fatty alcohol ether sulphate are sulfated lauryl alcohol and lauryl alcohol sulfate.As polyoxyethylene lauryl ether ammonium sulfate is called for short AESA, its structural formula is RO (CH
2cH
2o)
nsO
3nH
4 +, R=C
12-C
18alkyl, n is 2-4, preferably average ethoxyquin degree is n=3.The active matter content of described polyoxyethylene lauryl ether ammonium sulfate commercially available prod has 25% and 70% two kind, the polyoxyethylene lauryl ether ammonium sulfate of 25% active matter content is the water white transparency thick liquid, the polyoxyethylene lauryl ether ammonium sulfate of 70% active matter content is white or faint yellow pastel, the polyoxyethylene lauryl ether ammonium sulfate that preferably active matter content is 70%.Described polyoxyethylene lauryl ether ammonium sulfate also has the characteristic of non-ionic surface active agent, still has dirt-removing power preferably in hard water.The composite use of described ammonium lauryl sulfate and lauryl alcohol polyoxy ether ammonium sulfate, can produce good cooperative effect, as: there is densification and abundant foam, gentle sensation, outstanding thickening properties etc.
In mild shampoo of the present invention, contain account for composition weight 1.0% to 10% amphoteric surfactant as cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine.Described cocoyl both sexes sodium acetate is colourless to micro-yellow transparent thick liquid, and the active matter content of its commercially available prod is under 30%, 25 ℃ of condition, its viscosity is 5000-10000, the pH that sodium chloride content is less than 9.0%, 1% aqueous solution is 6.0-8.0, and its structural formula is RN(CH2COONa)
2, the zest of described cocoyl both sexes sodium acetate is low, gentle especially to skin, eyes, match and can significantly reduce its zest with anion surfactant, and have good foaming power, foam enriches fine and closely woven, skinfeel is good, can significantly improve the foam state of formula system.Described cocamido propyl betaine is micro-yellow transparent liquid, and the active matter content of its commercially available prod is 30%, and sodium chloride content is less than 6.0%, and unhindered amina content is less than 0.10%, and the pH value of its 1% aqueous solution is 5.0-7.0, and its structural formula is RCONH (CH
2)
3n
+(CH
3)
2cH
2cOO
-.Described cocamido propyl betaine has good compatibility, and has good foaminess and significant thickening property, has good anti-hard water, antistatic behaviour and biological degradability.The preferred cocamido propyl betaine of amphoteric surfactant of the present invention.
Contain the cationic polymer that accounts for mild shampoo weight 0.05% to 1.0% in mild shampoo of the present invention, described cationic polymer is selected from: at least one in cationic cellulose polymer, cation melon xanthan polymer and cation modified alkyglycosides polymer
In the present invention, cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, according to the difference of cation substitution value, can be divided into: high-cation substitution value JR, middle-jiao yang, function of the spleen and stomach ionic replacement degree LR and tri-kinds of models of low cation substitution value LK, the cationic cellulose polymer of preferred high-cation substitution value, be Polyquaternium-10, other is suitable for cationic cellulose polymer of the present invention and also has copolymer of hydroxyethyl-cellulose and dialkyl dimethyl ammonium chloride etc.; Described cation melon glue is the product obtained after melon glue is quaternized, its key component is melon glue oxypropyl trimethyl ammonium chloride, can obtain a series of cation melon glue product according to the difference of substitution value, preferably substitution value is 0.1 to 0.2, for cation melon glue of the present invention, under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s.
Preferably use the cation melon glue that accounts for composition weight 0.05% to 1.0% in mild shampoo of the present invention.
Mild shampoo of the present invention also contains the pearlescent flake that accounts for composition weight 0.05% to 3.0%, and described pearlescent flake is ethylene glycol monostearate and Ethylene Glycol Distearate.Adding of described pearlescent flake, can give the pearl effect that shampoo is beautiful.
Shampoo composite of the present invention can also comprise other optional components, comprises viscosity-controlling agent, chelating agen, pH adjusting agent, antiseptic, pigment and spice etc.Described viscosity-controlling agent accounts for 0.1% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, cellulose derivative, acrylic copolymer etc.Described chelating agen accounts for 0.01% to 0.30% of composition weight, the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferably disodiumedetate; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., and optimization citric acid, the pH of regulation system is 5.0 to 8.0, and preferably 5.5 to 6.0; Choosing of described antiseptic, essence, pigment, meet the regulation of hygienic standards for cosmetics, selects safe raw material.
In mild shampoo of the present invention, except the above component, water is mended to aequum.
Preparation method
Mild shampoo of the present invention can by any known or other effectively be applicable to provide the technology preparation of shampoo composite, the method for preparing shampoo composite of the present invention comprises conventional preparation and hybrid technology.
Using method
Mild shampoo of the present invention is used in the clean and mode gentle hair of routine, mainly comprises following step:
(A) water is by the hair moistening;
(B) use the mild shampoo of the aforementioned any one claim of effective dose on described hair, the scope of described effective dose is generally 1 gram to 50 gram, preferably 2 to 20 grams;
(C) with the mild shampoo on the described hair of water rinse.
These steps can be as required repeatedly, to reach the effect of look for clean, conditioning, moisturizing and water retention.
Embodiment
It is below the non-limiting example of mild shampoo of the present invention.Providing of these embodiment is only for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, pigment etc., the selection of these a small amount of materials will be along with selected changing in order to the physics and chemistry characteristic for preparing special component of the present invention.
Preparation Example I-X V
Described in suitable Preparation Example I-X V, the method for mild shampoo is as follows: suitable quantity of water is joined in retort, under slowly stirring, add cationic polymer to be disperseed, slowly be stirred and heated to 60 ℃ to 80 ℃, then add respectively as required lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium, Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, cocos nucifera oil both sexes sodium acetate, cocamido propyl betaine, pearlescent flake, disodiumedetate (if using these materials), make these materials disperse rear cooling fully.When temperature is down to 45 ℃ of left and right, add again sodium chloride, citric acid, antiseptic, pigment, essence etc. to continue to stir, guarantee to obtain uniform mixture.After adding all components, can add as required viscosity modifier and pH adjusting agent, the viscosity and the pH that regulate product arrive suitable degree 5.5-6.0.Optionally finally can add a small amount of water to supply.
Embodiment I-V
Embodiment VI-X
The effect evaluation and test:
The foam height method of testing: adopt the method for testing of Roche (Ross--Miles) foamer meter to be tested, test respectively initial foam height, after 1 minute, foam height and foam height after 5 minutes, then average.From the embodiment of the present invention, can find out: in the situation that shampoo formula, the condition such as main and auxiliary surfactant and cationic polymer is approximate, shampoo of the present invention adopts take foam height that the compositions of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium is the formula of first type surface activating agent and all is greater than and take traditional aliphatic alcohol sulfate and fatty alcohol ether sulphate compositions as the foam height of first type surface active agent formulation, the results are shown in Table 1.
Mildness method of testing: adopt erythrocyte hemolysis experiment (Red blood cell test RBC) method, the method is one of Draize experiment alternative method, ultimate principle is to measure the damage of chemicals cell membrane and the change of the cell membrane permeability therefore caused, estimate the degree of injury of cell membrane by the amount of measuring the hemoglobin spilt from erythrocyte, this degree of injury has directly related property with the zest of product.The mainly eye irritation research for chemicals such as cosmetic product and raw materials by the RBC experiment in the world.Therefore the present invention passes through the mildness with erythrocyte hemolysis determination of experimental method formula, and forms contrast, test products mildness.Concrete grammar is: the absorbance of the red cell suspension after the effect of use spectrophotometry chemicals can calculate hemolysis rate and H
50value (even concentration value of the tested material of 50% erythrocyte generation haemolysis).H
50be worth littlely, add the sample of small amount just obvious haemolysis can occur, show that sample stimulus is large, mildness is poor.H
50value is large, shows that sample stimulus is little, and mildness increases.Shampoo of the present invention adopts take the H that the compositions of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium is the formula of first type surface activating agent
50value all is greater than take the H that traditional aliphatic alcohol sulfate and fatty alcohol ether sulphate compositions be the first type surface active agent formulation
50value, show the lifting of mildness, the results are shown in Table 1.
Table 1 foam height and H
50value (mildness)
Claims (7)
1. the mild shampoo containing the sulfonated alkyl glucoside, can accept component except containing shampoo, and this shampoo also contains:
(A) account for the first type surface activating agent of mild shampoo weight 5.0% to 40%, the compositions that this surfactant is sulfonated alkyl glucoside and the poly-alkyl-glucoside of sulfonation, and both ratios are weight ratio 1:2-2:1;
Wherein, sulfonated alkyl glucoside molecular structural formula following (I):
The molecular structure formula I
In formula I, R
1represent the alkyl that carbon number is 8 to 22, n represents the degree of polymerization, between 1-3;
The molecular structural formula following (II) of the poly-alkyl-glucoside of sulfonation
The molecular structure formula II
In formula II, R represents that carbon number is 8 to 22 alkyl, and n represents the degree of polymerization, is the integer between 4-6.
(B) account for the amphoteric surfactant of mild shampoo weight 1.0% to 10.0%, this amphoteric surfactant is cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine;
(C) account for the cation guar gum of mild shampoo weight 0.05% to 1%.
2. mild shampoo, wherein R and R according to claim 1
1be respectively the alkyl that carbon number is 12.
3. mild shampoo according to claim 1, in sulfonated alkyl glucoside molecular structural formula, polymerization degree n is preferably 1.4.
4. mild shampoo according to claim 1, wherein amphoteric surfactant is cocamido propyl betaine.
5. mild shampoo according to claim 1, wherein said sulfonated alkyl glucoside is the lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium, the poly-alkyl-glucoside of sulfonation is poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium.
6. according to the shampoo composite of aforementioned any one claim, also contain the pearlescent flake that accounts for composition weight 0.05% to 3.0%.
7. one kind contains the mild shampoo that sulfonation gathers alkyl-glucoside, and its component and content are:
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|---|---|---|---|
| CN201310376310.9A CN103445972B (en) | 2013-08-26 | 2013-08-26 | A kind of mild shampoo containing sulfonated alkyl glucoside |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104274359A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Hair care composition containing paramela plant essential oil |
| CN104274358A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Scalp repair shampoo composition containing plant essential oil and preparation method thereof |
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| US7507399B1 (en) * | 2004-08-05 | 2009-03-24 | Surfatech Corporation | Functionalized polymeric surfactants based upon alkyl polyglycosides |
| WO2011161604A2 (en) * | 2010-06-21 | 2011-12-29 | Ecolab Usa Inc. | Functionalized alkyl polyglucosides for enhanced food and oily soil removal |
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| US7507399B1 (en) * | 2004-08-05 | 2009-03-24 | Surfatech Corporation | Functionalized polymeric surfactants based upon alkyl polyglycosides |
| WO2011161604A2 (en) * | 2010-06-21 | 2011-12-29 | Ecolab Usa Inc. | Functionalized alkyl polyglucosides for enhanced food and oily soil removal |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104274359A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Hair care composition containing paramela plant essential oil |
| CN104274358A (en) * | 2014-09-05 | 2015-01-14 | 拉芳家化股份有限公司 | Scalp repair shampoo composition containing plant essential oil and preparation method thereof |
| CN104274358B (en) * | 2014-09-05 | 2017-07-18 | 拉芳家化股份有限公司 | A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil |
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|---|---|
| CN103445972B (en) | 2015-11-25 |
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