CN103520021B - A kind of cation is modified the conditioner shampoo of alkyglycosides - Google Patents
A kind of cation is modified the conditioner shampoo of alkyglycosides Download PDFInfo
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- CN103520021B CN103520021B CN201310334984.2A CN201310334984A CN103520021B CN 103520021 B CN103520021 B CN 103520021B CN 201310334984 A CN201310334984 A CN 201310334984A CN 103520021 B CN103520021 B CN 103520021B
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Abstract
The present invention relates to the conditioner shampoo of cation modified alkyglycosides, outside dewatering, in this conditioner shampoo, contain: the first type surface activating agent that (A) accounts for conditioner shampoo weight 5.0% to 40% is, the composition of lauryl sulfate and ethoxylated dodecyl alcohol ammonium sulfate; (B) amphoteric surfactant that accounts for conditioner shampoo weight 1.0% to 10.0% is, cocounut oil both sexes sodium acetate or Cocoamidopropyl betaine; (C) cationic polymer that accounts for conditioner shampoo weight 0.05% to 3% is, cation modified alkyglycosides, a kind of composition that comprises polyquaternary amine alkyglycosides and quaternized alkyglycosides; This conditioner shampoo character gentleness, does not contain silicone oil and has dry wet cardability preferably.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of cation modified alkyglycosides of containingConditioner shampoo.
Background technology
Along with improving constantly of living standard, people also come the demand of hair washing product and requirementHigher. How effectively to solve the cardability of hair and don't can bring too much thick and heavy sense, mistake to hairThe problems such as many burdens become the topic that consumer is concerned about day by day. In existing shampoo system, mostly can addA large amount of cationic polymers and dimethyl silicone polymer or modified dimethyl polysiloxane, by sun fromCovering and the dimethyl silicone polymer of sub-polymer to hair positive charge adheres in right amount on hair, withReach the object of improving the dry wet cardability of hair, but, can bring more heavy burden and secondary work to hairBy problems such as thick in sent out, jaundice, jag, fractures. The object of this invention is to provide a kind of shampoo combinationThing, silicate-containing oil not in its formula system, and add a kind of special cationic polymer, can improveThe cardability of hair, also plays gentle clean effect simultaneously, and has greatly reduced cation and siliconOil produces too much gathering to hair and causes the phenomenon of the damage to hair.
This special cationic polymer is exactly bonding cation on alkyl-glucoside or glycan moleculeObtain the novel product with cationic surfactant feature of natural origin. The quaternary ammonium of this uniquenessSalt type cation provides direct effect can to hair and skin, and its effect far surpasses other by APGThe non-ionic surface active agent being derived and be different from again traditional cation, this novel cation tableSurface-active agent in providing lasting conditioning and nursing efficacy for hair and skin, the glucosides in moleculeChain can also reduce the excitant of cationic polymer and sulphate anion surface active agent greatly,And there is good conditioning effect, be therefore used to gentle hair conditioning shampoo product.
Summary of the invention
The object of this invention is to provide a kind of cation and modify the conditioner shampoo of alkyglycosides.
This conditioner shampoo is except containing the acceptable component of shampoo, and this shampoo also contains:
(A) account for the first type surface activating agent of conditioner shampoo weight 5.0% to 40%, this surfactant is monthThe composition of cinnamic alcohol ammonium sulfate and ethoxylated dodecyl alcohol ammonium sulfate, and both ratios are weight ratio1:2－2:1；
(B) account for the amphoteric surfactant of conditioner shampoo weight 1.0% to 10.0%, these both sexes Xu activityAgent is cocounut oil both sexes sodium acetate or Cocoamidopropyl betaine;
(C) account for the cationic polymer of conditioner shampoo weight 0.05% to 3%, this cationic polymer isCation modified alkyglycosides, this cation modified alkyglycosides is that polyquaternary amine alkyl is manyThe composition of glycan glycosides and quaternized alkyglycosides, and both ratios are weight ratio 1:2-2:1;
Wherein, the molecular structural formula of polyquaternary amine alkyglycosides following (I):
In formula (I), R represents that carbon number is 8 to 22 alkyl, and n is the integer between 4-6,
The molecular structural formula following (II) of quaternized alkyglycosides
In formula (II), R1Represent that carbon number is 8 to 22 alkyl, R2Represent carbon number be 1 to22 alkyl, n represents the degree of polymerization, is the integer between 1-2.
Conditioner shampoo, polyquaternary amine alkyglycosides and quaternized alkyglycosides under the present inventionIn, it is 16 alkyl that R is preferably carbon number, R1Carbon number be preferably 10-12, R2Carbon formerSubnumber is preferably 18.
Conditioner shampoo of the present invention, the wherein preferred Cocoamidopropyl betaine of amphoteric surfactant.
Conditioner shampoo of the present invention, wherein said polyquaternary amine alkyglycosides is poly-cetyl PortugalGrape sugar hydroxypropyl cetyl chloride ammonium, quaternized alkyglycosides is ten alkyl-glucoside hydroxypropylsBase octadecyl ammonium chloride.
Conditioner shampoo of the present invention, also contains the pearlescent flake that accounts for composition weight 0.05% to 3.0%.
Conditioner shampoo of the present invention, does not contain silicone oil.
A kind of cation of the present invention is modified the conditioner shampoo of alkyglycosides, its component and containingAmount is:
Compared with prior art, the present invention has the following advantages:
Conditioner shampoo of the present invention, containing dimethyl silicone polymer class conditioner, has avoided because of silicone oilExcessive accumulation and the phenomenon such as the hair chap that causes, jaundice, fracture; Cation modified alkyl polysaccharideAdding of glycosides, can reduce the excitant of sulfate type anion surfactant, and give hair simultaneouslyBring salubriouser and good dry combing and the effect of wet combing.
Detailed description of the invention
To be elaborated to compositional selecting of the present invention and effect below.
In conditioner shampoo of the present invention, contain account for composition weight 5.0% to 40% lauryl sulfate andThe composition of ethoxylated dodecyl alcohol ammonium sulfate, described lauryl sulfate and lauryl alcohol polyethylene glycol oxideThe weight ratio of ether ammonium sulfate is 1:2-2:1. Described lauryl sulfate is called for short K12A or SLSA, its knotStructure formula is: ROSO3NH4 +，R=C12-C18Alkyl, the preferred active matter content of commercially available ammonium alkyl sulfate is 70%,Its outward appearance is white or faint yellow pastel, good detergency that described lauryl sulfate has,Anti-hard water, lower excitant, higher foaming power and excellent compatibility. Described fatAlcohol polyoxyethylene ether ammonium sulfate is called for short AESA, and its structural formula is RO (CH2CH2O)nSO3NH4 +，R=C12-C18Alkyl, n is 2-4, preferably average ethoxyquin degree is n=3. Described ethoxylated dodecyl alcohol sulfuric acidThe active matter content of ammonium commercially available prod has 25% and 70% two kind, the laruyl alcohol polyoxy of 25% active matter contentVinethene ammonium sulfate is water white transparency thick liquid, the ethoxylated dodecyl alcohol sulphur of 70% active matter contentAcid ammonium is white or faint yellow pastel, the ethoxylated dodecyl alcohol sulphur that preferably active matter content is 70%Acid ammonium. Described ethoxylated dodecyl alcohol ammonium sulfate also has the characteristic of non-ionic surface active agent,In hard water, still there is good dirt-removing power. Described lauryl sulfate and laruyl alcohol polyoxy ether sulfuric acidThe composite use of ammonium, can produce good cooperative effect, as: there is densification and abundant foam,Gentle sensation, outstanding thickening properties etc.
In conditioner shampoo of the present invention, contain the amphoteric surfactant that accounts for composition weight 1.0% to 10%As cocounut oil both sexes sodium acetate or Cocoamidopropyl betaine. Described cocoyl both sexes sodium acetate is colourlessTo micro-yellow transparent thick liquid, the active matter content of its commercially available prod is under 30%, 25 DEG C of condition, itsViscosity is 5000-10000, and the pH that sodium chloride content is less than 9.0%, 1% aqueous solution is 6.0-8.0, itsStructural formula is RN(CH2COONa)2, the excitant of described cocoyl both sexes sodium acetate is low, to skin,Eyes are gentle especially, match and can significantly reduce its excitant, and have good with anion surfactantGood foaming power, it is fine and closely woven that foam enriches, and skinfeel is good, can significantly improve the foam state of formula system.Described Cocoamidopropyl betaine is micro-yellow transparent liquid, and the active matter content of its commercially available prod is30%, sodium chloride content is less than 6.0%, and unhindered amina content is less than 0.10%, the pH value of its 1% aqueous solutionFor 5.0-7.0, its structural formula is RCONH (CH2)3N+(CH3)2CH2COO-. Described cocamidopropyl propyl amide is sweetDish alkali has good compatibility, and has good foaminess and significant thickening property, has goodAnti-hard water, antistatic behaviour and biological degradability. The preferred cocounut oil acyl of amphoteric surfactant of the present inventionAmine CAB.
In conditioner shampoo of the present invention, contain the cationic polymerization that accounts for conditioner shampoo weight 0.05% to 3.0%Thing, described cationic polymer is selected from: cationic cellulose polymer, cation melon xanthan polymer,And at least one in cation modified alkyglycosides polymer.
In the present invention, cationic cellulose polymer is hydroxyethylcellulose and alkyl trimethyl ammonium chlorideCopolymer, can be divided into according to the difference of cation substitution value: high-cation substitution value JR, middle-jiao yang, function of the spleen and stomach fromSub-substitution value LR and tri-kinds of models of low cation substitution value LK, preferably the sun of high-cation substitution value fromSubbundle element polymer, i.e. Polyquaternium-10, it is poly-that other is suitable for cationic cellulose of the present inventionCompound also has the copolymer of hydroxyethylcellulose and dialkyl dimethyl ammonium chloride etc.; Described cation melonYoungster's glue is by the product obtaining after quaternized melon glue, and its key component is melon glue oxypropyl trimethyl chlorineChange ammonium, can obtain a series of cation melon glue product according to the difference of substitution value, preferably substitution valueBe 0.1 to 0.2, for cation melon glue of the present invention under 25 DEG C of conditions, its 1% aqueous solutionViscosity is 2000mPa.s to 4000mPa.s.
In the present invention, cationic polymer preferred cationic is modified alkyglycosides polymer. Described sunIon modification alkyglycosides polymer comprise polyquaternary amine alkyglycosides and quaternized alkyl manyGlycan glycosides, comes from poly alkyl glucose (APG for short non-ionic surface active agent), and passes through alkaneThe chemically derived natural derivative with cation attribute that produced of base polyglycosides APG skeleton. PhaseFor non-ionic APG precursor, cation modified alkyglycosides polymer is to hair and scalp toolHave the effect of docile more, the glycan molecule in structure has reduced traditional cationic direct excitant, andAnd there is the effect of long-acting conditioning.
The quaternary amine that in the present invention, cation modified alkyglycosides polymer is different carbon chain lengthsReact synthetic with alkyl-glucoside. And alkyl group in alkyl-glucoside also has different chainsLong. So gentle superior properties of product provide more range of application to formula teacher. By in a large numberExperiment, the inventor finds, the length in polyquaternary amine alkyglycosides in quaternary ammonium salt and APGCarbochain is straight chain and carbon number between the performance aspect clean and conditioning effect at hair of the alkane of 12-18The best, meanwhile, the long carbochain in quaternized alkyglycosides in quaternary ammonium salt and APG is straight chainAnd carbon number is respectively in the time of the alkane of 8-12 and 16-22, and it is clean and conditioning effect side at hairFace is put up the best performance, and two of polyquaternary amine alkyglycosides and quaternized alkyglycosides according toThe ratio of weight ratio 1:2 to 2:1 has synergy while arranging in pairs or groups use.
In the present invention cation modified alkyglycosides be selected from polyquaternary amine alkyglycosides andQuaternized alkyglycosides, wherein, polyquaternary amine alkyglycosides is poly-cetyl glucoseHydroxypropyl cetyl chloride ammonium; Quaternized alkyglycosides is ten alkyl-glucoside hydroxypropyls tenEight alkyl ammomium chlorides, and poly-dodecyl glucose hydroxypropyl lauryl ammonium chloride and ten alkyl PortugalsThe weight ratio of polyglycoside hydroxypropyl octadecyl ammonium chloride is 1:2 to 2:1.
The physicochemical property of the cation modified alkyglycosides of the present invention: active quantities (solid content):30%, viscosity, cps20-1800, pH(10% solution) 6-8, color Gardner≤1.
The molecular structural formula following (I) of polyquaternary amine alkyglycosides of the present invention:
In molecular structural formula (1), R represents that carbon number is 8 to 22 alkyl, and n is between 4-6Integer. More preferably carbon number is 16.
The molecular structural formula following (II) of quaternized alkyglycosides
In molecular structural formula (2), R1Represent that carbon number is 8 to 22 alkyl, R2Represent carbon atomNumber is 1 to 22 alkyl, and n represents the degree of polymerization, is the integer between 1-2. R in the present invention1Carbon formerSubnumber is preferably 10-12, and more preferably 10, R2More preferably 16-22 of carbon number,More preferably 18.
In conditioner shampoo of the present invention, contain the cation modified alkane that accounts for composition weight 0.05% to 3.0%Base polyglycosides, and be selected from respectively polyquaternary amine alkyglycosides (poly-cetyl glucose hydroxylPropyl group cetyl chloride ammonium) and quaternized alkyglycosides (ten alkyl-glucoside hydroxypropyls tenEight alkyl ammomium chlorides),
Cation modified alkyglycosides in the present invention, is selected from respectively polyquaternary amine alkyl polysaccharideGlycosides, comprises poly-ten alkyl-glucoside hydroxypropyl lauryl ammonium chlorides, poly-dodecyl glucosideHydroxypropyl lauryl ammonium chloride and, poly-six to eight alkyl-glucoside hydroxypropyl dodecyl chlorinationsAmmonium, poly-dodecyl glucoside hydroxypropyl octadecyl ammonium chloride, poly-ten alkyl-glucoside hydroxylsPropyl group octadecyl ammonium chloride, poly-cetyl glucoside hydroxypropyl cetyl chloride ammonium etc., thisPreferably poly-cetyl glucoside hydroxypropyl Cetyl Chloride of polyquaternary amine alkyglycosides in inventionChange ammonium; And quaternized alkyglycosides, comprise ten alkyl-glucoside hydroxypropyl dodecyl chloridesChange ammonium, lauryl glucosyl hydroxypropyl lauryl ammonium chloride, six to eight alkyl-glucosidesHydroxypropyl lauryl ammonium chloride, lauryl glucosyl hydroxypropyl octadecyl ammonium chloride, ten alkaneBase glucoside hydroxypropyl octadecyl ammonium chloride, lauryl glucosyl hydroxypropyl Cetyl ChlorideChange ammonium etc., preferably ten alkyl-glucoside hydroxypropyl octadecanes of quaternized alkyglycosides in the present inventionAmmonium chloride.
Conditioner shampoo of the present invention also contains the pearlescent flake that accounts for composition weight 0.05% to 3.0%, described inPearlescent flake is ethylene glycol monostearate and EGDS. Adding of described pearlescent flake, canTo give the pearl effect that shampoo is beautiful.
Shampoo composite of the present invention can also comprise other optional components, comprises viscosity-controlling agent, chelaMixture, pH adjusting agent, anticorrisive agent, pigment and spices etc. Described viscosity-controlling agent accounts for composition weight0.1% to 5.0%, the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, listMonoethanolamine chloride, cellulose derivative, acrylic copolymer etc. Described chelating agent accounts for composition weight0.01% to 0.30% of amount, the non-limiting example of described chelating agent has: ethylenediamine tetra-acetic acid, second twoAmine tetraacethyl disodium, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferably secondEdetate disodium; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., and excellentSelect citric acid, the pH of regulation system is 5.0 to 8.0, and preferably 5.5 to 6.5; Described anticorrisive agent,Choosing of essence, pigment, meets the regulation of hygienic standards for cosmetics, selects safe raw material.
In conditioner shampoo of the present invention, except the above component, water is mended to aequum.
Preparation method
Conditioner shampoo of the present invention can by any known or other be effectively applicable to provide shampoo groupThe technology preparation of compound, the method for preparing shampoo composite of the present invention comprises conventional preparation and mixingTechnology.
Using method
Conditioner shampoo of the present invention uses in the mode of the clean and conditioning hair of routine, mainly comprise withLower several steps:
(A) water is wetting by hair;
(B) on described hair, use the conditioner shampoo of the aforementioned any one claim of effective dose, instituteThe scope of stating effective dose is generally 1 gram to 50 grams, preferably 2 to 20 grams;
(C) with the conditioner shampoo on hair described in water rinse.
These steps can be as required repeatedly, to reach look for clean, conditioning, to moistenEffect with moisturizing.
Embodiment
The non-limiting example of conditioner shampoo of the present invention below. Only providing of these embodiment isFor illustrative purposes, can not be interpreted as limitation of the invention because do not depart from of the present inventionOn the basis of spirit and scope, can carry out many changes to the present invention. In these embodiments, removeNon-special instruction, all concentration is all percentage by weight. Term used " a small amount of material " refers toThose optional materials, as anticorrisive agent, viscosity modifier, pH adjusting agent, spices, pigment etc., thisThe selection of some a small amount of materials by along with selected in order to prepare the physics and chemistry of special component of the present inventionCharacteristic and changing.
Preparation Example I-X V
Described in suitable Preparation Example I-X V, the method for conditioner shampoo is as follows: suitable quantity of water is addedEnter in retort, under slowly stirring, add cation modified alkyglycosides to comprise poly-hexadecaneBase glucoside hydroxypropyl cetyl chloride ammonium and ten alkyl-glucoside hydroxypropyl octadecyl chlorinationsAmmonium disperses, and is slowly being stirred and heated to 60 DEG C to 80 DEG C, then add bay alkyl ammonium sulfate,Ethoxylated dodecyl alcohol ammonium sulfate, cocounut oil both sexes sodium acetate, Cocoamidopropyl betaine, pearly-lustreSheet, disodium ethylene diamine tetraacetate (if using these materials), make these materials disperse rear cooling completely.In the time that being down to 45 DEG C of left and right, temperature add again sodium chloride, citric acid, anticorrisive agent, pigment, essence etc. to continueContinuous stirring, guarantees to obtain uniform mixture. Adding after all components, can add as requiredViscosity modifier and pH adjusting agent, regulate the viscosity of product and pH to arrive suitable degree. OptionallyAfter can add a small amount of water to supply.
Embodiment I-V
Embodiment VI-X
As can be seen from the above embodiments, embodiment I, II, III has adopted respectively traditional cation to adjustReason agent, its wet combing power and dry combing power be all than embodiment IV, V, VI, VII, VIII, IX, X is large,Combing power is larger, and conditioning property is poorer. Embodiment IV, V, VI, VII, VIII, IX, X presents totallyDownward trend, illustrates that the conditioning (dry conditioning property or wet conditioning property) of product increases.
Effect Evaluation operation example
Be divided into sensory evaluation method and two parts of cardability test for effect evaluation method of embodiment.
Described sensory evaluation method is: Preparation Example 1-10 is issued respectively to 60 testers and use.When tester uses shampoo sample, according to identical method hair washing, every kind of shampoo respectively uses two weeks,Tester according to oneself feel mark, standards of grading adopt 7 points of systems, 1 point the poorest, 7 points areGood, the higher effect of mark is more good. Various conditioner shampoo result of use evaluation results are listed in table 1.
Table 1 conditioner shampoo result of use is evaluated
Described cardability test comprises dry cardability, wet cardability test, and described wet cardability test is:First hair is wetting, rub with 2g embodiment (1)-(10) (blank sample with 3% Sodium Laurylsulfate)Wash 2-3min, then rinse well with flowing water, with comb combing once to remove unnecessary moisture,On Instron2343 miniature spring tester, measure wet cardability, rate of extension is 300mm/min;Repeat above-mentioned steps, each sample determination 6 times, the measurement result row after each embodiment rinses for the 6th timeIn table 2.
Described dry cardability test is: wet cardability is placed in air dry by hair sample after having testedDry, after it is dry, measure its dry cardability. The dry cardability test result of each embodiment is listed in table 2.
Table 2 shampoo composite cardability test result
Claims (4)
1. cation is modified a conditioner shampoo for alkyglycosides, can except containing shampooAccept outside component, this shampoo also contains:
(A) account for the first type surface activating agent of conditioner shampoo weight 5.0% to 40%, this surface-activeAgent is the composition of lauryl sulfate and ethoxylated dodecyl alcohol ammonium sulfate, and both ratiosExample is weight ratio 1:2-2:1;
(B) account for the amphoteric surfactant of conditioner shampoo weight 1.0% to 10.0%, these both sexesSurfactant is cocounut oil both sexes sodium acetate or Cocoamidopropyl betaine;
(C) account for the cation modified alkyglycosides of conditioner shampoo weight 0.05% to 3%,This cation modified alkyglycosides is poly-cetyl glucoside hydroxypropyl cetylThe composition of ammonium chloride and ten alkyl-glucoside hydroxypropyl octadecyl ammonium chloride, and bothRatio is weight ratio 1:2-2:1.
2. conditioner shampoo according to claim 1, wherein amphoteric surfactant is cocounut oilAmido propyl betaine.
3. conditioner shampoo according to claim 1, also contains and accounts for conditioner shampoo weight 0.05%To 3.0% pearlescent flake.
4. cation is modified a conditioner shampoo for alkyglycosides, its component and contentFor:
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