CN104168883A - Shampoo composition including efficient anti-remval agent - Google Patents

Shampoo composition including efficient anti-remval agent Download PDF

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Publication number
CN104168883A
CN104168883A CN201380006887.9A CN201380006887A CN104168883A CN 104168883 A CN104168883 A CN 104168883A CN 201380006887 A CN201380006887 A CN 201380006887A CN 104168883 A CN104168883 A CN 104168883A
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account
weight
composite
shampoo
composite reactive
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CN104168883B (en
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胡卫华
庄严
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LAF INTERNATIONAL GROUP Ltd
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LAF INTERNATIONAL GROUP Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q7/00Preparations for affecting hair growth
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/673Vitamin B group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair

Abstract

The invention refers to a shampoo composition including an efficient anti-remval agent. Besides water, the shampoo includes (A) an anion surface active agent accounting for 5.0% to 40% of a composition weight; (B) a composition of coconut oil amphoteric sodium acetate and alkyl polyglycoside accounting for 1.0% to 10.0% of a composition weight; (C) an anti-remval compound active matter accounting for 0.1% to 10% of a composition weight, the anti-remval compound active matter is composed of hydrolyzed soy protein, amino acid, amino sugar, vitamin B group, zinc salt, ginseng essence, essence of burdock root in May and organic silicon and poly quaternary ammonium salt; and (D) a positive ion polymer accounting for 0.05% to 3.0% of a composition weight.

Description

A kind of shampoo composite containing efficient anticreep complexing agent
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of shampoo composite containing efficient anticreep complexing agent.
Background technology
Hair is the first element of human beauty, and alopecia is the great society problem that many people face.Alopecia is the maximum infringement to appearance, can affect people's profile, reduces captivation and glamour, to a self-confidence strike greatly especially, also can have influence on occupation and select, marriage, even future.The growth cycle of hair can be divided into trophophase, catagen and resting stage, and the hair in catagen and resting stage is constantly in dynamic equilibrium, so maintained the 50-75 root hair that will come off normal every day.What hair was abnormal or excessive come off has just caused pathologic alopecia.Trophic factor and seborrheic alopecia that the internal factors such as main cause spiritedness factor, congenital heredity factor and the hormone of alopecia and albumen, aminoacid, vitamin etc. lack.The object of this invention is to provide a kind of shampoo composite, add and a kind ofly derive from plant and biochemical synthetic there is synergistic anti-alopecia complex, can promote natural on-off cycles of hair growth, improve the ratio of natural on-off cycles of hair growth phase and resting stage, promote to form healthy scalp and hair, help hair loss patient to return to normal alopecia speed.
Summary of the invention
Anticreep shampoo composite of the present invention, outside dewatering, contains in this shampoo: in this shampoo, contain:
(A) account for the anion surfactant of composition weight 5.0% to 40%;
(B) account for the cocos nucifera oil both sexes sodium acetate of composition weight 1.0% to 10.0% and the compositions of alkyl androstanediol;
(C) account for the anticreep composite reactive thing of composition weight 0.1% to 10%, described anticreep composite reactive thing is, outside dewatering, to contain:
Account for the Radix Ginseng essence of the 10-25% of composite reactive thing weight;
Account for the hydrolyzed soybean protein of composite reactive thing weight 1-5%;
Account for the ispol of composite reactive thing weight 4-20%, this ispol is that Jing An Suan ︰ acetyl network An Suan ︰ Gua An Suan ︰ dlornithine hydrochloride mixes with the ratio of weight ratio 1:1 ︰ 1 ︰ 1;
Account for the vitamin B group mixture of composite reactive thing weight 3-10%, this vitamin B group mixture is that vitamin B 3 ︰ vitamin B 5 ︰ biotins mix with the ratio of weight ratio 1 ︰ 1 ︰ 1;
Account for the glucosamine hydrochloride of composite reactive thing weight 5-10%;
Account for the zinc gluconate of composite reactive thing weight 1-5%;
Account for the Radix Arctii essence in May of composite reactive thing weight 1-5%;
Account for the PEG-12 dimethicone of composite reactive thing weight 1-5%;
Account for polyquaternary ammonium salt-11 of composite reactive thing weight 1-5%;
(D) account for the cationic polymer of composition weight 0.05% to 3.0%.
Shampoo composite of the present invention, wherein said anticreep composite reactive thing is hydrolyzed soybean protein, containing the ispol of arginine, acetyl TYR, citrulline, dlornithine hydrochloride, glucosamine hydrochloride, containing the vitamin B group mixture of vitamin B3, vitamin B5, biotin, zinc gluconate, Radix Ginseng essence, May Radix Arctii essence and PEG-12 dimethicone and polyquaternary ammonium salt-11 compositions.
Shampoo composite of the present invention, wherein said anion surfactant is selected from: at least one in alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt, glycerine monofatty ester sulfate, alkylsulfonate, N-acylsarcosine salt, N-acyl glutamate, Glu, alkyl phosphate salt.
Shampoo composite of the present invention, the ratio of wherein said cocos nucifera oil both sexes sodium acetate and alkyl androstanediol is 3:1-1:3.
Shampoo composite of the present invention, wherein said cationic polymer is selected from: at least one in cationic cellulose polymer, cation guar gum polymer.
Compared with prior art, the present invention has the following advantages:
Shampoo composite of the present invention, be a kind ofly derive from plant and biochemical synthetic there is synergistic anti-alopecia complex, can promote natural on-off cycles of hair growth, improve the ratio of natural on-off cycles of hair growth phase and resting stage, promote to form healthy scalp and hair, help hair loss patient to return to normal alopecia speed.
Detailed description of the invention
To be elaborated to compositional selecting of the present invention and effect below.
In shampoo composite of the present invention, contain and account for composition weight 0.1% to 10%, preferably 5% to 10% anticreep composite reactive thing, described anticreep composite reactive thing is limpid light yellow liquid, with special odor, under 20 DEG C of conditions, its density is 1.010-1.050, index of refraction is 1.350-1.360, and pH value is 5.2-6.2.The concrete composition of described anticreep composite reactive thing and active as follows: hydrolyzed soybean protein (hydrolyzed soy sulfuration peptide, MW-15000Da) can provide cytotrophy and growth regulating, promotes the biosynthesis of albumen; Amino acids comprises TYR, arginine, ornithine, citrulline be albumen and and melanic precursor; Glucosamine strengthening hair papilla and around substrate; Vitamin B group regulates cytotrophy; Zinc salt regulates fat secretion; Radix Ginseng essence and May Radix Arctii extract can improve microcirculation; Organosilicon and polyquaternary ammonium salt provide the opsonic action of hair.
The compositions that contains the ammonium lauryl sulfate and the polyoxyethylene lauryl ether ammonium sulfate that account for composition weight 5.0% to 40% in shampoo composite of the present invention, the ratio of described ammonium lauryl sulfate and polyoxyethylene lauryl ether ammonium sulfate is 1:2-2:1.Described ammonium lauryl sulfate is called for short K 12a or SLSA, its structural formula is: ROSO 3nH 4 +, R=C 12-C 16alkyl, its active matter content is 70%, its outward appearance is white or faint yellow pastel.Described ammonium lauryl sulfate have action temperature and, can on hair, leave good conditioning, have good foams performance and clean-up performance, can provide good compatibility for outward appearance, the viscosity rheological equationm of state stability of product.Described AESA is called for short AESA, and its structural formula is RO (CH 2cH 2o) nsO 3nH 4 +, R=C 12-C 16alkyl, n is 2-3, preferably average ethoxyquin degree is n=3.The active matter content of described polyoxyethylene lauryl ether ammonium sulfate commercially available prod is 70%, and its outward appearance is white or faint yellow pastel.Described polyoxyethylene lauryl ether ammonium sulfate also has the characteristic of non-ionic surface active agent, still has good dirt-removing power in hard water.The composite use of described ammonium lauryl sulfate and lauryl alcohol polyoxy ether ammonium sulfate, can produce good cooperative effect, as: gentle performance and the outstanding thickening properties etc. with good washability, brilliance.
In shampoo composite of the present invention, contain and account for the cocos nucifera oil both sexes sodium acetate of composition weight 1.0% to 10.0% and the compositions of alkyl androstanediol, the ratio of described cocos nucifera oil both sexes sodium acetate and alkyl androstanediol is 3:1-1:3.Described cocoyl both sexes sodium acetate is colourless to micro-yellow transparent thick liquid, and the active matter content of its commercially available prod is under 30%, 25 DEG C of condition, its viscosity is 5000-10000, the pH that sodium chloride content is less than 9.0%, 1% aqueous solution is 6.0-8.0, and its structural formula is RN (CH2COONa) 2, the zest of described cocoyl both sexes sodium acetate is low, gentle especially to skin, eyes, match and can significantly reduce its zest with anion surfactant, and have good foaming power, foam enriches fine and closely woven, skinfeel is good, can significantly improve the foam state of formula system.Described alkyl androstanediol comprises lauryl glucoside, Coco-Glucoside, decyl glucoside and octyl group/decyl glucoside, preferably decyl glucoside, its outward appearance is the viscous liquid of light yellow muddiness, the active matter content of its commercially available prod is 51%-55%, the pH value of its 15% aqueous isopropanol of 20% is 11.5-12.5, under 25 DEG C of conditions, its viscosity is 1000-6000.Described decyl glucoside comes from natural, has remarkable gentle cleaning capacity, can improve the foaming properties of shampoo.Improve quantity and the foam stability of foam.The composite use of described cocoyl both sexes sodium acetate and decyl glucoside has good foam and skin-friendliness, zest is dropped to minimum.
In shampoo composite of the present invention, contain the cationic polymer that accounts for composition weight 0.05% to 3.0%, described cationic polymer is selected from: at least one in cationic cellulose polymer, cation guar gum polymer, preferred cationic guar gum.Described cation melon glue is by the product obtaining after quaternized melon glue, its key component is melon glue oxypropyl trimethyl ammonium chloride, can obtain a series of cation melon glue product according to the difference of substitution value, preferably substitution value is 0.1 to 0.2, nitrogen content is 1.3-1.7%, for cation melon glue of the present invention, under 25 DEG C of conditions, the viscosity of its 1% aqueous solution is 3500mPa.s to 4500mPa.s; Described cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, can be divided into according to the difference of cation substitution value: high-cation substitution value JR, middle-jiao yang, function of the spleen and stomach ionic replacement degree LR and tri-kinds of models of low cation substitution value LK, the preferably cationic cellulose of middle-jiao yang, function of the spleen and stomach ionic replacement degree.
Shampoo composite of the present invention can also comprise other optional components, comprises pearling agent, viscosity-controlling agent, chelating agen, pH adjusting agent, antiseptic, pigment and spice etc.Described pearling agent accounts for 0.05% to 3.0% of composition weight, the non-limiting example of described pearling agent has: zinc oxide and the titanium dioxide of ethylene glycol stearate monoesters and ethylene glycol stearate, monostearate and Palmic acid propylene glycol ester and glyceride, stearic acid alkylolamides magnesium stearate, fine dispersion, preferably ethylene glycol stearate.Described viscosity-controlling agent accounts for 0.1% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, sodium sulfate, ammonium phosphate, hydroxyethyl-cellulose, hydroxypropyl cellulose, acrylic acid and long chain alkyl methacrylate copolymer, acrylates/stearic alcohol ether-20/ methacrylic acid salt copolymer, methyl glucosamine polyoxyethylene ether (120) dioleate etc.Described chelating agen accounts for 0.01% to 0.30% of composition weight, and the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, sodium versenate, tetrasodium ethylenediamine tetraacetate etc., preferably disodiumedetate; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., and optimization citric acid, the pH of regulation system is 5.0 to 8.0, and preferably 5.5 to 6.5; Choosing of described antiseptic, essence, pigment, meets the regulation of hygienic standards for cosmetics, selects safe raw material.
In shampoo composite of the present invention, except the above component, water is mended to aequum.
Preparation method
Shampoo composite of the present invention can by any known or other be effectively applicable to provide the technology preparation of shampoo composite, the method for preparing shampoo composite of the present invention comprises conventional preparation and hybrid technology.
Using method
Shampoo composite of the present invention uses in the mode clean and conditioning hair of routine, mainly comprises following step:
(A) water is by hair moistening;
(B) on described hair, use the shampoo composite of the aforementioned any one claim of effective dose, the scope of described effective dose is generally 1 gram to 50 grams, preferably 2 to 20 grams;
(C) with the shampoo composite on hair described in water rinse.
These steps can be as required repeatedly, to reach effect of look for clean, conditioning, moisturizing and water retention.
Embodiment
The non-limiting example of shampoo composite of the present invention below.The providing of these embodiment is only used to the object of explanation, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, pigment etc., the selection of these a small amount of materials is by along with selected changing in order to prepare the physics and chemistry characteristic of special component of the present invention.
Preparation Example I-X
Described in suitable Preparation Example I-X, the method for shampoo composite is as follows: suitable quantity of water is joined in retort, under slowly stirring, add guar gum to disperse, be slowly stirred and heated to 60 DEG C to 80 DEG C, add appropriate citric acid neutralization.Then add Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, cocos nucifera oil both sexes sodium acetate, decyl glucoside, ethylene glycol stearate, disodiumedetate (if using these materials), make after the complete dispersing and dissolving of these materials, be incubated 30 minutes, start cooling.In the time that temperature is down to 50 DEG C of left and right, add anticreep composite reactive thing, sodium chloride, citric acid, antiseptic, pigment, essence etc. to continue to stir, guarantee to obtain uniform mixture.Adding after all components, can add as required viscosity modifier and pH adjusting agent, regulating the viscosity of product and pH to arrive suitable degree.Optionally finally can add a small amount of water to supply.Embodiment I-V
Embodiment VI-X
Most preferred embodiment of the present invention is:
Component Content % by weight
Laurel alkyl ammonium sulfate (70%) 10.0
Polyoxyethylene lauryl ether ammonium sulfate (70%) 12.0
Cocos nucifera oil both sexes sodium acetate 3.0
Decyl glucoside 5.0
Guar gum 0.3
Anticreep composite reactive thing 8
Ethylene glycol stearate 1.2
Disodiumedetate 0.1
Citric acid, antiseptic, coloring agent, spice, sodium chloride In right amount
Water Add to 100%
In embodiment I-X, the each component of anticreep composite reactive thing and content (weight ratio) are: containing 23% Radix Ginseng essence, 4% hydrolyzed soybean protein, 16% ispol (Jing An Suan ︰ acetyl network An Suan ︰ Gua An Suan ︰ dlornithine hydrochloride=1 ︰ 1 ︰ 1 ︰ 1), 7.5% vitamin B group mixture (vitamin B 3 ︰ vitamin B 5 ︰ biotin=1 ︰ 1 ︰ 1), 6% glucosamine hydrochloride, 2.5% zinc gluconate, 4% May Radix Arctii essence and 2%PEG-12 dimethicone and 1.5% polyquaternary ammonium salt-11 and excess water.
Sense organ physical and chemical index
The checking of Anti-hair loss effect
Method of testing: select 40 volunteers that have alopecia, require without allergy, without the scalp health patient of wound, unsystematic local disease, by image viewing, the trophophase of its patient's hair and the ratio of resting stage are lower than normal condition.Before on probation, patient is carried out to sense organ and hair image evaluation, allow patient use the most preferred embodiment shampoo of invention, continue to use 112 days, carried out sensory evaluation and hair image evaluation at the 56th day and 112 days.In process on probation, volunteer uses this shampoo according to the frequency of normally washing hair at ordinary times, requires this shampoo can rest on hair 3-5 minute and carry out soft scalp massage, and then clean with warm water washing.For the hair sensory evaluation who uses volunteer before and after this shampoo in table 1, table 2 and hair image evaluation in table 3:
Table 1
Table 2
Table 3

Claims (4)

1. containing a shampoo composite for efficient anticreep complexing agent, outside dewatering, in this shampoo, contain:
(A) account for the anion surfactant of composition weight 5.0% to 40%;
(B) account for the cocos nucifera oil both sexes sodium acetate of composition weight 1.0% to 10.0% and the compositions of alkyl androstanediol;
(C) account for the anticreep composite reactive thing of composition weight 0.1% to 10%, described anticreep composite reactive thing is composed of the following components:
Account for the Radix Ginseng essence of composite reactive thing weight 10-25%;
Account for the hydrolyzed soybean protein of composite reactive thing weight 1-5%;
Account for the ispol of composite reactive thing weight 4-20%, this ispol is that Jing An Suan ︰ acetyl network An Suan ︰ Gua An Suan ︰ dlornithine hydrochloride mixes with the ratio of weight ratio 1:1 ︰ 1 ︰ 1;
Account for the vitamin B group mixture of composite reactive thing weight 3-10%, this vitamin B group mixture is that vitamin B 3 ︰ vitamin B 5 ︰ biotins mix with the ratio of weight ratio 1 ︰ 1 ︰ 1;
Account for the glucosamine hydrochloride of composite reactive thing weight 5-10%;
Account for the zinc gluconate of composite reactive thing weight 1-5%;
Account for the Radix Arctii essence in May of composite reactive thing weight 1-5%;
Account for the PEG-12 dimethicone of composite reactive thing weight 1-5%;
Account for polyquaternary ammonium salt-11 of composite reactive thing weight 1-5%;
And the water of surplus;
(D) account for the cationic polymer of composition weight 0.05% to 3.0%.
2. shampoo composite according to claim 1, wherein said anion surfactant is selected from: at least one in alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt, glycerine monofatty ester sulfate, alkylsulfonate, N-acylsarcosine salt, N-acyl glutamate, Glu, alkyl phosphate salt.
3. shampoo composite according to claim 1, the ratio of wherein said cocos nucifera oil both sexes sodium acetate and alkyl androstanediol is 3:1-1:3.
4. shampoo composite according to claim 1, wherein said cationic polymer is selected from: cationic cellulose polymer or cation guar gum polymer.
CN201380006887.9A 2013-09-12 2013-09-12 A kind of shampoo composite containing efficient anticreep complexing agent Active CN104168883B (en)

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PCT/CN2013/083393 WO2015035585A1 (en) 2013-09-12 2013-09-12 Shampoo composition containing complexing agent for efficiently preventing hair loss

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CN104168883B CN104168883B (en) 2016-05-25

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CN105213251A (en) * 2015-09-22 2016-01-06 拉芳家化股份有限公司 A kind of anticreep shampoo with hotness
CN106265458A (en) * 2016-10-08 2017-01-04 拉芳家化股份有限公司 A kind of aging containing Effective Anti and the shampoo composite of anticreep complexing agent
CN107454837A (en) * 2016-09-12 2017-12-08 拉芳家化股份有限公司 A kind of shampoo composite of the complexing agent of moisturizing containing hair
WO2020132930A1 (en) * 2018-12-26 2020-07-02 拉芳家化股份有限公司 Anti-dandruff anti-itch shampoo composition containing multiple-component zinc
US10959933B1 (en) 2020-06-01 2021-03-30 The Procter & Gamble Company Low pH skin care composition and methods of using the same
US11110049B2 (en) 2017-06-23 2021-09-07 The Procter & Gamble Company Composition and method for improving the appearance of skin
US11583488B2 (en) 2020-06-01 2023-02-21 The Procter & Gamble Company Method of improving penetration of a vitamin B3 compound into skin
US11622963B2 (en) 2018-07-03 2023-04-11 The Procter & Gamble Company Method of treating a skin condition

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WO2010121919A1 (en) * 2009-04-23 2010-10-28 Unilever Plc Hair care composition comprising trichogen complex and an azole
DE102011089357A1 (en) * 2011-12-21 2012-08-23 Henkel Ag & Co. Kgaa Hair treatment agent useful for hair care, comprises four different quaternary ammonium compounds comprising e.g. quaternary imidazoline compounds, cationic keratin hydrolyzate, alpha-hydroxy acid, and ethanol or isopropanol
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JP2005041826A (en) * 2003-07-23 2005-02-17 Pyuru:Kk Hair-growth stimulant/hair restorer with hair-dyeing effect
CN101835462A (en) * 2007-10-25 2010-09-15 荷兰联合利华有限公司 Hair care composition
CN101785747A (en) * 2008-12-30 2010-07-28 欧莱雅公司 Use of monosaccharides and composition
WO2010121919A1 (en) * 2009-04-23 2010-10-28 Unilever Plc Hair care composition comprising trichogen complex and an azole
DE102011089357A1 (en) * 2011-12-21 2012-08-23 Henkel Ag & Co. Kgaa Hair treatment agent useful for hair care, comprises four different quaternary ammonium compounds comprising e.g. quaternary imidazoline compounds, cationic keratin hydrolyzate, alpha-hydroxy acid, and ethanol or isopropanol
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105213251A (en) * 2015-09-22 2016-01-06 拉芳家化股份有限公司 A kind of anticreep shampoo with hotness
CN105213251B (en) * 2015-09-22 2017-11-07 拉芳家化股份有限公司 A kind of anticreep shampoo with thermal sensation
CN107454837A (en) * 2016-09-12 2017-12-08 拉芳家化股份有限公司 A kind of shampoo composite of the complexing agent of moisturizing containing hair
WO2018045584A1 (en) * 2016-09-12 2018-03-15 拉芳家化股份有限公司 Hair moisturising complexing agent-containing shampoo composition
CN107454837B (en) * 2016-09-12 2019-08-20 拉芳家化股份有限公司 A kind of shampoo composite of the complexing agent of moisturizing containing hair
CN106265458A (en) * 2016-10-08 2017-01-04 拉芳家化股份有限公司 A kind of aging containing Effective Anti and the shampoo composite of anticreep complexing agent
US11110049B2 (en) 2017-06-23 2021-09-07 The Procter & Gamble Company Composition and method for improving the appearance of skin
US11622963B2 (en) 2018-07-03 2023-04-11 The Procter & Gamble Company Method of treating a skin condition
WO2020132930A1 (en) * 2018-12-26 2020-07-02 拉芳家化股份有限公司 Anti-dandruff anti-itch shampoo composition containing multiple-component zinc
US10959933B1 (en) 2020-06-01 2021-03-30 The Procter & Gamble Company Low pH skin care composition and methods of using the same
US11583488B2 (en) 2020-06-01 2023-02-21 The Procter & Gamble Company Method of improving penetration of a vitamin B3 compound into skin
US11911498B2 (en) 2020-06-01 2024-02-27 The Procter & Gamble Company Low pH skin care composition and methods of using the same

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