CN107454837B

CN107454837B - A kind of shampoo composite of the complexing agent of moisturizing containing hair

Info

Publication number: CN107454837B
Application number: CN201680004552.7A
Authority: CN
Inventors: 赵文忠; 陈贤鹰; 林学镁; 洪盛杰; 谷志静; 周起; 董志扬
Original assignee: LAF INTERNATIONAL GROUP Ltd
Current assignee: LAF INTERNATIONAL GROUP Ltd
Priority date: 2016-09-12
Filing date: 2016-09-12
Publication date: 2019-08-20
Anticipated expiration: 2036-09-12
Also published as: WO2018045584A1; CN107454837A

Abstract

A kind of shampoo composite of the complexing agent of moisturizing containing hair, the anionic surfactant of composition weight 5-30% is accounted for containing (A) and accounts for the amphoteric surfactant of composition weight 1-8%, wherein anionic surfactant is the sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate compositions of weight ratio 1:2, (B) the alkyl glucoside nonionic surfactant of composition weight 1-8% is accounted for, (C) the hair moisturizing composite reactive agent of composition weight 0.5-12% is accounted for, (D) cationic polymer of composition weight 0.2% is accounted for, (E) methyl glucosamine polyoxyethylene ether (120) dioleate of composition weight 1.2% is accounted for, and the water of (F) surplus.

Description

A kind of shampoo composite of the complexing agent of moisturizing containing hair

Technical field

The invention belongs to daily chemicals fields, and in particular to a kind of shampoo composite containing efficient hair moisturizing composite reactive agent.

Background technique

Usually " drying " of hair and following factor are had one's hair wash in relation to (1): with the raising of hair washing frequency, hair More or less will appear hair degreasing phenomenon, thus hair easily cause it is dry and astringent；(2), swim: swimming-pool water contains chlorine, can injure hair Matter epidermis and cortical layer, if drying will be easy by not cleaning and handle carefully hair after swimming；(3), solarization: for a long time by too Positive ultraviolet light irradiation, the moisture on hair surface layer can be lost, thus dried-up phenomenon is presented, and color development can also shoal；(4), it is commonly used Hair jelly and hot wind blow head hair because hair jelly has chemical component, with perming, having hair dyed, be all easily destroyed hair group too much Temperature when knitting and drying is too high, is also easy to enable the moisture stream of hair surface,；(5), it often has a perm, have hair dyed and floats and is shallow: adding The agent for permanent hair waving or hair dye for having added chemical component, more or less can all destroy the tissue of hair, if along with subsequent ill-considered Processing or maintenance are bound to enable hair " dry upper plus dry "；(6), partial eclipse: this point can be what many people often ignored, the life of hair The nutrition that the source of life is absorbed from we itself, so if the food that we eat on ordinary days does not provide enough nutrients to hair, Protein-contng foodstuffs are especially eaten less, and hair is difficult to grow dense, glossy.(7), cold air: dry air allows hair in cold air room The situation of silk water shortage is even more serious than the cold air in winter.(8) dry hair: dry hair is usually associated with the head of stemness Skin, often hair can also be dried while dry scalp in a sense, and therefore, the moisturizing nursing of scalp is also extremely important. Other than supplementing body fluids, using the real-time maintenance product of nutrient and moisture can be provided immediately, it will not just allow scalp dry more It is dry, because " drought " of hair will likely be caused while dry scalp；

Hair wants water bright, and primary is exactly the health that must keep hair scale piece, because in the case of hair healthy, hair scale piece Hair tail can be aligned to by root of hair, to protect hair interior tissue, healthy hair seems that nature is soft bright glossy as roofing tile.Through Normal hair washing, exposure sunlight, swimming, dyeing and perm are sent out etc., can all bring more or less physically or chemically injury to hair structure, and one Denier hair scale piece comes to harm, and hair just will appear dry, fracture, jag, if wanting that hair is allowed to restore soft light pool at this time, just must It must keep the skin wet by hair products are washed on ordinary days and hair nutrient, make hair quality healthy once again.

Shampoo is necessary hair cleaning supplies in people's daily life, and frequency of use is relatively high, and southern area is average Hair washing in 1-2 days is primary, and northern area hair washing in average 2-3 days is primary.Although can also use hair conditioner such as hair conditioner after hair washing, send out Film etc. carrys out hair conditioning, but since how much the cleaning effect of surfactant in shampoo still can wash away scalp during hair washing With the natural oil on hair with protective effect and make hair is impaired to cause drying.In addition, table used in shampoo The either anionic table work of face activating agent, nonionic table is living, and both sexes table is living, and even amino acid pattern table work etc. all can be irritating Property, only their irritation has height to have low.The irritation of surfactant is also to cause hair to be damaged in shampoo One of dry factor.

Therefore, the purpose of the present invention is to provide a kind of shampoo composites, are added to original that is a kind of natural and deriving from skin care Material and technology, have the compound of collaboration scalp and hair moisture-keeping function, and collaboration reduces the irritation of surfactant, makes scalp The care of various dimensions moisturizing factor and the supplement of moisture content are obtained with hair, improve the dry-out phenomenon of hair.

Summary of the invention

The object of the present invention is to provide a kind of shampoo composites containing efficient hair moisturizing complexing agent.

Hair moisturizing shampoo composite of the invention contains in the shampoo:

(A) it accounts for the anionic surfactant containing sulfate of composition weight 5%-40% and accounts for composition weight The amphoteric surfactant of 1.0%-15.0%, the sulphate anion surface active agent are aliphatic alcohol sulfate, fatty alcohol The weight ratio of polyoxyethylene ether sulfate composition, aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate is 1:2；

(B) the alkyl glucoside nonionic surfactant of composition weight 0.5% to 10.0% is accounted for；

(C) the hair moisturizing composite reactive agent of composition weight 0.5-15% is accounted for, the hair moisturizing composite reactive agent removes It is aqueous outer, also include；

(I) hexylene glycol of composite reactive agent weight 10-28% is accounted for；

(II) account for the carbohydrate admixture of composite reactive agent weight 10-20%, the carbohydrate admixture be by monosaccharide, oligosaccharide and Polysaccharide composition, and monosaccharide: oligosaccharide: polysaccharide is mixed with the ratio of weight ratio 5:2:1；Monosaccharide is fructose and glucose, and fructose: Glucose is mixed with the ratio of weight ratio 1:1；Oligosaccharide is sucrose and cyclodextrin, and sucrose: cyclodextrin is with weight ratio 1:0.5's Ratio mixing；Polysaccharide is Sodium Hyaluronate, and molecular weight is 400,000 dalton to 2,200,000 dalton；

(III) water-soluble silicon oil of composite reactive agent weight 3-20% is accounted for, the water-soluble silicon oil is poly- for PEG/PPG-22/23 Dimethyl siloxane；

(IV) ispol of composite reactive agent weight 5-10% is accounted for, which is by alanine, silk Propylhomoserin, glycine, glutamic acid, cysteine composition, and alanine: serine: glycine: glutamic acid: cysteine is with weight Ratio mixing than 1:1:1:0.2:0.1；

(IV) pyrrolidone sodium carboxylate (Anjidew NL50) of composite reactive agent weight 1-5% is accounted for；

(V) the ethoxy urea of composite reactive agent weight 0.5-3% is accounted for；

(D) cationic polymer of composition weight 0.2% is accounted for；

(E) composition weight 1.2% methyl glucosamine polyoxyethylene ether (120) dioleate is accounted for；

(F) and the water of surplus.-

Shampoo composite of the present invention, wherein the hair moisturizing composite reactive agent is by hexylene glycol moisturizer, pyrrolidones Carboxylic acid sodium (Anjidew NL50) moisturizer, ethoxy urea moisturizer, carbohydrate moisturizer, water-soluble silicon oil moisturizer, amino acids moisturizer It is formed with the water of surplus；Wherein, carbohydrate moisturizer is to be mixed by monosaccharide, oligosaccharide and polysaccharide with the ratio of weight ratio 5:2:1, Middle monosaccharide is fructose and glucose, and oligosaccharide is sucrose and cyclodextrin, and polysaccharide is Sodium Hyaluronate；Amino acids moisturizer is third Propylhomoserin, serine, glycine, glutamic acid and cysteine are mixed with the ratio of weight ratio 1:1:1:0.2:0.1, the glycine For trimethylglycine.

Shampoo composite of the invention, wherein the sulfate type anionic surfactant is sulfated lauryl alcohol and the moon The mixture of cinnamic alcohol polyoxyethylene ether sulfate.

Shampoo composite of the present invention, wherein the alkyl glucoside nonionic surfactant is lauryl glucoside or certain herbaceous plants with big flowers Base glucoside is one such.

Shampoo composite of the present invention, wherein the cationic polymer is selected from: cationic cellulose polymer, cationic melon One of your xanthan polymer.

Compared with prior art, the invention has the following advantages that

Shampoo composite of the present invention is a kind of from the natural composite reactive agent group with collaboration hair moisture-keeping function Be hexylene glycol at, the composite reactive agent, containing fructose, glucose, sucrose, cyclodextrin, Sodium Hyaluronate carbohydrate admixture, contain third Propylhomoserin, serine, trimethylglycine, glutamic acid, cysteine ispol, pyrrolidone sodium carboxylate, ethoxy The various dimensions moisturizing composition such as urea and water-soluble silicon oil composition.Shampoo composite of the present invention has good water lock, and water supplement function is grown Moisten dry scalp, improve hair conditioning, flexibility and the dry-out phenomenon of hair, the hair after making hair washing drying hair, which moistens, not to be dried, soft Obey note not fly upward.

Specific embodiment

The selection of instant component and effect are described in detail below.

Containing the hair moisturizing composite reactive agent for accounting for composition weight 0.5-15% in shampoo composite of the invention, preferably 5% to 12% hair moisturizing composite reactive agent, the hair moisturizing composite reactive agent is by hexylene glycol moisturizer, pyrrolidones Carboxylic acid sodium (Anjidew NL50) moisturizer, ethoxy urea moisturizer, carbohydrate moisturizer, water-soluble silicon oil moisturizer, amino acids moisturizer It is formed with water；Wherein, carbohydrate moisturizer is oligosaccharide and polysaccharide composition by monosaccharide, and wherein monosaccharide is fructose and glucose, oligomeric Sugar is sucrose and cyclodextrin, and polysaccharide is Sodium Hyaluronate；Amino acids moisturizer is by alanine, serine, glycine, paddy ammonia Acid and cysteine composition.Concrete composition and activity are as follows:

Account for the hexylene glycol of composite reactive agent weight 10-28%；

The carbohydrate admixture of composite reactive agent weight 10-20% is accounted for, which is by monosaccharide, oligosaccharide and polysaccharide Composition, and monosaccharide: oligosaccharide: polysaccharide is mixed with the ratio of weight ratio 5:2:1；Monosaccharide is fructose and glucose, and fructose: grape Sugar is mixed with the ratio of weight ratio 1:1；Oligosaccharide is sucrose and cyclodextrin, and sucrose: cyclodextrin is with the ratio of weight ratio 1:0.5 Mixing, polysaccharide is Sodium Hyaluronate；

The water-soluble silicon oil of composite reactive agent weight 3-20% is accounted for, which is the poly- diformazan of PEG/PPG-22/23 Radical siloxane；

Account for the ispol of composite reactive agent weight 5-10%, the ispol be by alanine, serine, Glycine, glutamic acid and cysteine composition, wherein alanine: serine: glycine: glutamic acid: cysteine is with weight ratio 1:1:1:0.2:0.1 ratio mixing；

Account for pyrrolidone sodium carboxylate (Anjidew NL50) moisturizer of composite reactive agent weight 1-5%；

Account for the ethoxy urea moisturizer of composite reactive agent weight 0.5-3%；

And the water of surplus

Hair moisturizing composite reactive object

Hexylene glycol.Hexylene glycol, English name: 2-Methyl-2,4-pentanediol, Hexylene Glycol. are colourless Transparency liquid.There is mild sweet fragrance.It is dissolved in water, ethyl alcohol, ether, low-carbon aliphatic hydrocarbon.As solvent, fragrance, medical disinfectant. Diacetone alcohol is obtained by condensation of acetone, then is obtained through liquid-phase hydrogenatin.Hexylene glycol molecular formula C6H14O2, molecular weight, 118.17g/ Mol, relative density (g/mL): 0.925, it can be miscible with water, lower alcohol, ether, various aromatic hydrocarbon, aliphatic hydrocarbon etc..In the present invention As solvent and scalp and hair moisturizer.

Carbohydrate, also known as carbohydrate (English: carbohydrate or saccharide), are polyhydroxy aldehyde or polyhydroxy The general name of ketone and its condensation polymer and certain derivatives, it is similar in the performance of chemical formula since it is made of carbon, hydrogen, oxygen element It polymerize in " carbon " with " water ", therefore also referred to as carbohydrate.Carbohydrate is important organic of widely distributed one kind in nature Compound.Sucrose, the starch in grain, the cellulose in plant, glucose in blood of human body of daily consumption etc. belong to Carbohydrate.For from biological function, carbohydrate plays an important role during vital movement, is that one kind in human body is important Energy source.

Carbohydrate is the important nutrient of human body, is broadly divided into monosaccharide, oligosaccharide and polysaccharide, and play very in human body Important role.In the present invention using monosaccharide, oligosaccharide and polysaccharide and with the ratio of weight ratio 5:2:1 mixing, molecular weight from Bottom is uniformly distributed to height again in.The proportion optimizing dry scalp of monosaccharide, oligosaccharide and polysaccharide that the present invention contains has certain Moisture-keeping functions, to hair have good coordination moisture-keeping function.

Monosaccharide.Monosaccharide (monosaccharide): due to that can not hydrolyze as smaller carbohydrate, it is this The smallest molecule in class.They are some aldehydes or ketones classes with two or more hydroxyl.The monosaccharide chemical formula of unmodified mistake Can be expressed as: (C 〃 H2O)) n, it is known as because it is all the multiple of carbon and hydrone: " carbohydrate ".Monosaccharide is a kind of important Fuel molecule and nucleic acid structure fragment.N=3 in the smallest monosaccharide, it may be assumed that dihydroxyacetone (DHA) or D- and L- glyceraldehyde, And so on such as triose (glyceraldehyde)；Pentose, pentose such as: ribose, deoxyribose；Hexose is such as: glucose, fructose (chemical formula All it is C6H12O6), glucose is pyranose, and fructose is furanose.Monosaccharide is fructose and glucose in the present invention.Fructose (C6H12O6) be a kind of simple sugared (monosaccharide), be highly soluble in water, exist in numerous food product and glucose, galactolipin together Constitute three kinds of main ingredient of blood glucose.Honey, the fruit on tree, berry, melon and some roots vegetables such as: beet, sweet tea Potato, parsnip, onion etc. contain fructose；Compound is usually formed together with glucose with sucrose.

Fructose molecule it is small compared with sucrose be also sucrose decomposition product, sucrose is a kind of disaccharide, in digestion process, due to enzyme Catalysis characteristics and be decomposed into a glucose and a fructose.Fructose is polyhydroxy ketose, molecular formula: CH2OH (CHOH) 3C =OCH2OH, molecular weight: 180.16, water-soluble: 3750g/L (20 DEG C), in carbohydrate, the hygroscopicity of fructose is most strong, it is easy to Absorb moisture.Fructose is monosaccharide, and molecule is small compared with sucrose, and osmotic pressure is higher by one times than sucrose, can penetrating cell tissue quickly, it is molten Solution degree is high, and diffusion velocity is fast in water, and therefore, fructose has good permeability moisture-keeping functions to hair.

Glucose (Glucose) (chemical formula C6H12O6), white crystals or particulate powder, also known as corn sugar, jade Chinese sorghum sugar, referred to as glucose.Glucose is polyhydroxy aldose, so it is also reduced sugar, molecular formula: CH2OH (CHOH) 4CHO, point Son amount: 180.16, it is the indispensable nutriment of metabolism in organism, is that distributed in nature is most wide and mostly important A kind of monosaccharide.Glucose, chemical name: 2,3,4,5,6- penta hydroxy group hexanals, glucose have critical role in field of biology, are The energy source of living cells and metabolic intermediate product, i.e. biological main Energy supply material, physical characteristic: white crystal, It is soluble easily in water, it is sweet, 146 DEG C of fusing point, contain five hydroxyls, an aldehyde radical, the property with polynary alcohols and aldehydes.With hygroscopicity, It is soluble easily in water, there are moisture-keeping functions.

Oligosaccharide.Oligosaccharide is also known as oligosaccharides (English control: oligosaccharide；oligosaccharides； Oligose), refer to the compound being polymerized containing 2-10 glycosidic bond, can make be a monosaccharide glycosides hydroxyl and another list Certain monohydroxy of sugar shrinks to be formed.They usually with protein or lipid covalent bond, exist in the form of glycoprotein or glycolipid. Oligosaccharide usually passes through glycosidic bond and 2~4 monosaccharide is formed by connecting small aggressiveness, it includes functional oligose and common oligomeric Sugar, the most common oligosaccharide are disaccharides, also known as disaccharide, are that two monosaccharide are combined by glycosidic bond, connect being total to for they The main two major classes of valence link type: the sweet bond type of N- sugar and O-glycosides bond type.1. N- glucosides bond type: oligonucleotide chain is with the Asn's on polypeptide Amino is connected.There are three types of main Types for this kind of oligonucleotide chain: high mannose type, heterozygous and complexity.2. O-glycosides bond type, oligosaccharides Chain is connected with the hydroxyl of Ser or Thr on polypeptide chain, or is connected with the hydroxyl of film rouge.In garlic, onion, fructus arctii, asparagus, beans There is the presence of oligosaccharide in the foods such as class, honey.Oligosaccharide can come out from natural plant extraction, also can use biochemical section Skill and ferment reaction, are synthesized using starch and disaccharide (such as sucrose).Common oligosaccharide such as malto-oligosaccharide glucose (α- The combination of Isosorbide-5-Nitrae glycosidic bond), isomalto-oligosaccharide glucose (α -1,6 glycosidic bond combinations) anti-caries promote Bifidobacterium proliferation, ring Shape dextrin glucose (cyclic annular α-Isosorbide-5-Nitrae glycosidic bond combination) low heat value, prevents Cholesterol Accumulation, and gentiobiose glucose (β -1,6 Glycosidic bond combination) bitter taste can form packaging junctor, coupling sugar (Coup ling sugar) glucose (α-Isosorbide-5-Nitrae glucosides bond Close), sucrose anti-caries, fructose oligosaccharides fructose (β -1,2 glycosidic bond combinations), sucrose promotion Bifidobacterium proliferation, panose grape Sugared (α -1,6 glycosidic bond combinations), fructose anti-caries, trehalose glucose (α -1,1 glycosidic bond combination), fructose anti-caries are excellent Matter sweet taste, sucrose oligosaccharide glucose (α -1,6 glycosidic bond combinations), the anti-caries such as sucrose promote Bifidobacterium proliferation, cow's milk Oligosaccharide galactolipin (β-Isosorbide-5-Nitrae glycosidic bond combination), glucose backbone anti-caries promote Bifidobacterium proliferation, chitin oligosaccharide acetyl Glucosamine (β-Isosorbide-5-Nitrae glycosidic bond combination), sucrose antitumor activity, soyabean oligosaccharides galactolipin (α -1,6 glycosidic bond combinations), sugarcane Sugar promotes Bifidobacterium proliferation, galactose oligosaccharides galactolipin (β -1,6 glycosidic bond combinations), and sucrose promotes Bifidobacterium proliferation, Fructose type oligosaccharide galactolipin (1,2 ': β -1 ', 2 glycosidic bond combination of α -) high-quality sweet taste, different qualityxylans xylose (β-Isosorbide-5-Nitrae glucosides Bond is closed) water activity adjusting.

Oligosaccharide of the present invention uses sucrose and cyclodextrin.

Sucrose is photosynthetic primary product, is distributed widely in plant, is especially contained in beet, sugarcane and fruit Measure high, usually edible white sugar, brown sugar is all sucrose.Sucrose is by a molecule glucose and a molecule fructose dehydrating condensation shape At molecular weight 342.3.Molecular formula: C12H22O11, density 1.5805, fusing point 190-192&ordm；C, specific rotatory power 67& ordm；(C=26, IN WATER 25&ordm；C), water-soluble 1970G/L (15&ordm；C).

Cyclodextrin is a kind of glucose oligosaccharide annular in shape.In general, cyclodextrin is by 6,7 or 8 glucose Unit claims α-, β-or gamma-cyclodextrin by α, the cyclic annular crystalline solid interconnected of 1.4 keys respectively.Cyclodextrin is tied in ring-type The center of structure has hole, and there be oxygen atom of the C-H bond in conjunction with glycoside in inside, 2 position of glucose, 3 and 6 aqueous in sulphur The hydroxyl of position is in hydrophily, that is, in presenting water delivery external hydrophilicity characteristic, can be by faint Van der Waals force by other molecules Inclusion compound is complexed into.There are many substance that can be connect by cyclodextrin packet, such as dyestuff, fragrance, drug, food, pesticide and preservative.Packet After connecing, stability, volatility, dissolubility, reactivity all make moderate progress.This special role of cyclodextrin, makes it tool The packet for the value that is widely used connects material such as, and 1. purposes in medical industry can generate inclusion compound with drug using cyclodextrin (capsulation), the drug substance stable that (1) can be made unstable；(2) hygroscopy, adherence or liquid medicine powdered；(3) indissoluble Property or insoluble drugs solubilized (solubilising) etc.；2. improving the stability of institute's coating active components；3. in daily chemical industry side The purposes in face can also make emulsifier and quality improver etc. in cosmetics manufacture with cyclodextrin.

Cyclodextrin of the present invention is by 6 glucose units through α -1.4 sugar key connection cyclization using cyclohexaamylose The dextrin of shape structure, it is the product that glucosyltransferase acts on starch syrup.Due to the interior chamber size of cyclohexaamylose It is that its is more stable more suitable for inclusion small-molecular-weight by inclusion complex less than cycloheptaamylose.Alpha-cyclodextrin water solubility is 25 DEG C be 14.5g/100ml, it is higher than beta-cyclodextrin solubility, thus be applied to require the higher occasion of cyclodextrine solubility.α- Cyclodextrin: No. CAS: 51211-51-9, molecular formula C36H60O30, molecular weight: 972.8436, relative density: 1.624g/cm3, Appearance: white crystalline powder, fusing point: 278 DEG C, pH value 5.0-8.0.The effect of cyclodextrin (alpha-cyclodextrin) of the present invention is to provide Moisturizing, hydrotropy and sustained release.

Polysaccharide.Polysaccharide (polysaccharide) is to pass through the strong polymerization of glucosides by 10 or more monosaccharide molecules or derivatives thereof Made of high-molecular compound, as many monosaccharide molecules or derivatives thereof condensation made of high polymer, also known as high glycan.It can divide For two class of homopolysaccharide and heteroglycan.The polysaccharide formed is condensed by a kind of monosaccharide and is known as homopolysaccharide, such as starch, cellulose.By two Kind or more the polysaccharide that is formed of monosaccharide or derivatives thereof condensation be known as heteroglycan, such as hyaluronic acid, chondroitin sulfate；By glycan molecule In have unbranched, be divided into straight-chain polysaccharide and branched polysaccharides；According to the difference of function, it is more to be divided into structural polysaccharide, storage polysaccharide, antigen Sugar etc.；It is divided into exocellular polysaccharide, intracellular polyse again by its Germ distribution.Polysaccharide of the present invention is selected from chondroitin sulfate and hyalomitome Acid, preferably clear matter acid.

Chondroitin sulfate (CS), extraction source are the cartilage of shark, ox, pig, chicken, are to be covalently attached to be formed on protein A kind of glycosaminoglycan of proteoglycans.Chondroitin sulfate is distributed widely in the extracellular matrix and cell surface of animal tissue, sugar Chain is made of alternate glucuronic acid and N- acetylgalactosamine (also known as N- acetylamino galactosamine) disaccharide unit, passes through one It is a to be connected on the serine residue of core protein like sugared link zone.Chondroitin sulfate: soft with sulfuric acid as mucopolysaccharide substance Ossein sodium salt (CHONDROITIN SULFATE SODIUM) is most commonly seen.Chondroitin sulfate is white or off-white powder, nothing It is smelly, have and draw moist, aqueous solution has toughness, heat it is non-condensing, it is readily soluble in water, it is organic insoluble in ethyl alcohol, acetone and ether etc. In solvent, its esters is more stable to heat, heated not also to be destroyed up to 80 DEG C.Chondroitin sulfate aqueous solution meets higher temperature or acid It is i.e. unstable, mainly deacetylation or it is degraded into monosaccharide or the lesser polysaccharide of molecular weight.Chondroitin sulfate of the present invention is sulfuric acid Chondroitin sodium has the effects that beauty, anti-aging, improves the drying of skin and hair.

Sodium Hyaluronate also known as sodium hyaluronate, sodium hyaluronate sodium, uronic acid sodium can also lead to for the substance extracted from cockscomb Lactococcus fermentation is crossed to be made, for white or off-white color particle or powder, odorless, when dry, nitrogen content 2.8%- 4.0%, glucuronic acid content is 37.0%-51.0%.Hyaluronic acid is a kind of high molecular polymer.It is by unit D- grape The higher polysaccharides of uronic acid and N-acetyl-glucosamine composition.By β -1 between D-Glucose aldehydic acid and N-acetyl-glucosamine, 3- is with sugar Key is connected, and is connected between dissacharide units by β-Isosorbide-5-Nitrae-glycosidic inkage.Dissacharide units are up to as many as 25000.Hyaluronic acid in vivo Molecular weight is from 5 thousand to 2 thousand Wan Daoer.Molecular formula: (C14H21NO11) n, hyaluronic acid are a kind of acid mucopolysaccharide, beauty in 1934 State's Columbia University's ophthalmology professor Meyer etc. isolated from bovine vitreous body first the substance (sodium hyaluronate is wrong translated name, The hyal- of RESTIAID hyaluronic acid mean glass-like, clear transparent, and uronic acid refers to Be uronic acid, sodium hyaluronate and uric acid do not have any relationship).Hyaluronic acid is with its unique molecular structure and physicochemical property in machine A variety of important physiological functions are shown in vivo, and such as lubricating joint adjusts the permeability of vascular wall, regulatory protein matter, water electrolysis Matter diffusion and operating, promote wound healing etc..Particular, it is important that contain a large amount of carboxyl and hydroxyl in hyaluronan molecule, Hydrogen bond can be formed with water, there is very strong packet outlet capacity, be the substance that moisture retention is best in presently found nature, referred to as Ideal natural moisture preserving because of (Natural moisturizing factor, NMF), such as: 2% pure hyaluronic acid aqueous solution 98% moisture can be firmly held.Hyaluronic acid is a kind of multi-functional matrix, and hyaluronic acid (sodium hyaluronate) HA is distributed widely in people Each position of body.Wherein skin also contains a large amount of hyaluronic acid.Human skin maturation and ageing process are also with hyaluronic acid Content and metabolism and change, it can improve skin-nourishing metabolism, make skin it is tender, it is smooth, go wrinkle, increase it is elastic, anti- Only aging is good skin penetration enhancer again while moisturizing.It is used cooperatively with other nutritional ingredients, rush can be played Into the more preferable effect of nutrient absorption, hyaluronic acid can be used in the products such as cream, frost, honey, milk, facial mask, the shampoo of cosmetics, It to keep the moisture of skin, hair, moisturizes the skin, hair, increases gloss, and the generation of chapped skin and wrinkle can be prevented.This Invention polysaccharide is chondroitin sulfate, Sodium Hyaluronate, preferably Sodium Hyaluronate.Sodium Hyaluronate molecular weight of the present invention is 400,000 Dalton is advanced optimized to 2,200,000 dalton as 1,000,000 dalton to 1,800,000 dalton, Sodium Hyaluronate pair of the present invention Hair plays the role of film forming and moisturizing.

Water-soluble silicon oil

A kind of polyether-modified polydimethylsiloxanecopolymer copolymer makes because its silicone backbone and hydrophilic radical coexist It is with good water solubility, while smell is mild, and temperature and photostability are outstanding, has well with the polar component in formula Compatibility, the skin sense that mild, salubrious and silk can be brought sliding, and in the case where being combined with hydrone strength holding skin and hair it is wet Profit has the function of that wetting, foam are stable, emulsifies, can be used as hair conditioner, provides moist and silky soft and smooth sense for hair Feel.As the DC-193 of DOW CORNING, INCI are named as PEG/PPG-22/23 dimethyl silicone polymer；The DMC6038 of wacker chemicals, INCI is named as the DMC6031 of two polyethylene glycol -15- methyl ether dimethicones and wacker chemicals, and NICI is named as - 25/25 dimethyl silicone polymer of polyethylene/polypropylene glycol.Water-soluble silicon oil of the present invention is sought healthy and free from worry DC-193, is PEG/ PPG-22/23 dimethyl silicone polymer.

Amino acid.

Scald dye, blowing hot wind, frequently using bad shampoo, drying weather the problems such as enable hair scale piece be damaged, inside hair Protein-loss, cause hair to become short-tempered, it is inelastic, it is difficult to arrange.Amino acid is a kind of moisturizing ingredient of natural structure, Biostearin substance.Amino acid is relatively good to the affinity of hair, can fill up the cavity in hair, reaches the work for repairing hair With.Amino acid used in the present invention is the moisturizing for hair, and alanine known to us can be to the moisturizing of hair, essence Propylhomoserin can improve the hydrophobicity on hair surface layer, and serine and Glutamatergic supplement hair moisture, glycine promoted moisture retention and Antistatic property, cysteine and histidine can improve the toughness etc. of hair.The amino acid that the present invention is included such as arginine, asparagus fern Propylhomoserin, glycine, alanine, serine, proline, threonine, isoleucine, histidine, phenylalanine, glutamic acid, half Guang Propylhomoserin etc..The preferred alanine of the present invention, glutamic acid, serine, glycine and cysteine.

Alanine.Alanine is the basic unit for constituting protein, is one of the 20 kinds of amino acid for forming human body protein. There are two kinds of isomers of α alanine and beta Alanine, Beta-alanine is that sterling is that white prismatic crystallizes, 200 DEG C of fusing point, relatively Density 1.437 (19 DEG C), molecular weight 89.09 are dissolved in water, are slightly soluble in methanol and ethyl alcohol, do not dissolve in ether and acetone.The present invention Beta-alanine is moisturizer.

Glutamic acid.Glutamic acid is a kind of acidic amino acid.Molecule includes two carboxyls, and chemical name is alpha-amido penta 2 Acid, molecular formula: C5H₉NO₄, appearance: white or colourless flake shape crystal, sublimation point: 200 DEG C, decomposition point: 247-249 DEG C, close Degree: 1.538, solubility (water): 7.5g/L, molecular weight: 147.13076.Glutamic acid of the present invention is moisturizer.

Serine.Serine also known as β serine are a kind of nonessential amino acid, rich in egg, fish, soybean, people Body can also synthesize serine from glycine, it plays work in the metabolism of fat and fatty acid and the growth of muscle With because it facilitates the generation of immunoglobulin and antibody, maintain health immune system be also required to serine.Serine exists Effect is all played in the synthesis of the sheath for manufacturing processing, musculature and encirclement nerve cell of cell membrane.Serine is white Crystalline solid or crystalline powder, slightly sweet, soluble easily in water and formic acid do not dissolve in ethyl alcohol and ether.Serine of the present invention is hair taste Form part.

Glycine.Also known as amion acetic acid, it is human body nonessential amino acid.Title abbreviation: Gly glycine is amino acid series Middle structure is the simplest, a kind of nonessential amino acid of human body, has acid and basic functionality simultaneously in the molecule, in water It is ionizable, there is very strong hydrophily, belong to polar amino acid, be dissolved in polar solvent, and it is insoluble in nonpolar solvent, and have There are higher boiling point and fusing point, can make glycine that different molecular conformations be presented by the adjusting of aqueous solution acid-base property.This hair Bright glycine is trimethylglycine, also known as glycine betaine, is good moisturizer, antistatic agent, thickening agent, viscosity-control additive. Trimethylglycine chemical formula C5H11NO2, molecular formula C5H11NO2, molecular weight 117.15, solubility: 160g/100G water.

Cysteine, alias include: 2- amino-3-mercaptopropionic acid, β-sulfydryl-α-aminopropionic acid, 3- cysteine；Sulphur For serine, L-cysteine, L- cysteine.Cysteine is a kind of amino acid with physiological function, is composition egg The only amino acid with reproducibility group sulfydryl (- SH) in more than 20 kinds of amino acid of white matter, now in medicine, food addition It is widely applied in agent and cosmetics.Cysteine molecule formula: C3H7NO2S, molecular weight: 121.15, solubility in water: 277.433g/L (25 DEG C, water), dissolubility aspect: it is dissolved in diluted mineral acid and alkaline solution, is not readily dissolved in water, is insoluble in ethyl alcohol, Insoluble in ether and chloroform.Cysteine energy maintenance hair, enhances the toughness of hair.

Pyrrolidone sodium carboxylate (Anjidew NL50).Pyridine alkanone carboxylic acid sodium, the entitled L- pyridine alkanone -5- carboxylic acid sodium of chemistry, referred to as L-PCA-Na (Anjidew NL50), molecular weight: 151.1. pyridine alkanone carboxylic acid sodium is to belong to natural moisturizing factor class moisturizer, as solid The composition of water moisturizing is important one of the composition of human body moisturizing factor.Anjidew NL50 has shrink moisturizing function to scalp and hair The effects of energy, the structure for reinforcing hair, polishing, color protection.

Ethoxy urea.Ethoxy urea is a kind of chemical substance, and molecular formula is C3H8N2O2, CAS#:[2078-71-9], point Son amount: 104.11, appearance: colourless to light yellow clear liquid, pH (10% aqueous solution): 6.0-10.0, solid content %:48.0- 52.0 conductivity (10% aqueous solution): < 150, urea (wt%): < 1%.It is largely used in skin care moisturizer, is used as moisturizing Agent, the effect of ethoxy urea is to repair the undamaged portion Evening Primerose Oil of hair to nourish in the present invention, is also had to scalp certain Moisture retention.

Surfactant system

Contain the sulfate type anion surface active for accounting for composition weight 5.0% to 40% in shampoo composite of the present invention Agent and the amphoteric surfactant for accounting for composition weight 1.0%-15.0%, the anionic surfactant containing sulfate Selected from aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate composition, aliphatic alcohol sulfate and aliphatic alcohol polyethenoxy The weight ratio of ether sulfate is 1:2.

Sulfate type anionic surfactant used in the present invention be selected from alkyl sulfate, alkyl ether sulfate, Alkyl amino ether sulfate, alkyl aryl ether sulfate, alkyl ether thio succinate.Used salt is alkali metal salt, ammonium Salt, amine salt, ethylaminoethanol salt, magnesium salts.Wherein alkali metal salt tends to using sodium salt and ammonium salt, and the length of alkyl carbon chain is usually situated between Between 8-24, between the usual 2-50 of the number of ethylene oxide or propylene oxide, and advanced optimize between 2-10.

Sulphate anion surface active agent is selected from the composition of alkyl sulfate and alkyl ether sulfate in the present invention, Alkyl carbon chain is C₈To C₁₄, further it is optimized for C₁₂To C₁₄Alkyl ether sulfate.

Sulphate anion surface active agent is selected from the composition of alkylsurfuric acid ammonium and alkyl sulfates in the present invention, Alkyl carbon chain is C₈To C₁₄, further it is optimized for C₁₂To C₁₄Alkyl ether sulfate.

The quantity of ethylene oxide is preferred alkyl ether sulfate middle ring in the 2-5. present invention on the above sulfate aliphatic chain The molal quantity of oxidative ethane is average 2.2.

Sulfate type anionic surfactant of the present invention is sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate Mixture, the commercially available sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate, active matter content are 70%, wherein the moon The weight ratio of cinnamic alcohol sulfate and ethoxylated dodecyl alcohol sulfate is 1:2；Sulfate type anion surface active of the present invention It is 5% to 30% that agent, which accounts for composition weight percentage,.

The nonionic surfactant of alkyl glycosides used in the present invention (APG) type is known a kind of mild on the market Surfactant, chemical formula general formula are following (1):

R₁—O—(R₂O)_t-(G)_v

Wherein:

R₁It is saturated or unsaturated selected from linear and branch, the about carbon chain lengths alkane that is 8 to 24 carbon atoms The alkylbenzene that hydrocarbon, and selected from linear and branch, about carbon chain lengths are 8 to 24 carbon atoms；

R₂Selected from the alkene containing 2 to 4 carbon atoms；

G is selected from the reduced sugar for possessing 5 to 6 carbon atoms；

T is between 0 to 10；

V is between 1 to 15.

Currently preferred alkyl glucoside is the compound for meeting chemical general formula (1), wherein R₁Selected from linear, saturation , about carbon chain lengths be 8 to 14 carbon atoms alkane；T is 0 in the present invention between 0 to 3；G is selected from glucose, Fructose and galactolipin, the preferred glucose of the present invention.The degree of polymerization V value of glucose is between 1 to 15 in general formula (1).According to this The degree of polymerization of invention, percent 80 or more sugar controls between 1 to 4, and average degree of polymerization then controls between 1 to 2.

Meet the compound of general formula (1), the alkyl glucosides of for example commercially available BASF (BASF) of representative product Glycosides APG, e.g., APG300, APG350, APG500, APG550, APG625, APG810, APG818, APG1200, APG2000.

The APG1200 that alkyl glucoside nonionic surfactant of the present invention is produced it is preferable to use BASF AG is Plantacare 1200UP or Plantacare 2000UP.Plantacare 1200UP is a kind of C that muddiness is sticky_12-14's The aqueous solution of glycan glycosides, active matter 50%, pH value (20% in 15% isopropanol) 11.5-12.5；Viscosity (40 DEG C) 1000- 6000mPas, density (40 DEG C) 1.07-1.08g/cm³, molecular weight about 420g/mol, free alkyl alcohol≤1%；Plantacare 2000UP is a kind of C that muddiness is sticky_8-14Glycan glycosides aqueous solution, active matter 50%, pH value (20% in 15% isopropanol) 11.5-12.5；Viscosity (40 DEG C) 2000-4000mPas, density (40 DEG C) 1.07-1.08g/cm³, molecular weight about 390g/mol, Free alkyl alcohol≤1%.

Alkyl glucoside of the present invention is a kind of mild nonionic surfactant, living with sulfate type surface in the present invention Property agent compatibility have the function of reduce surfactant irritation and assist moisturizing.

It is 0.5% to 10% that alkyl glucoside nonionic surfactant of the present invention, which accounts for composition weight percentage, into one Step is optimized for 1% to 8%.

Amphoteric surfactant selected by the present invention includes conventional use of Cocoamidopropyl betaine or cocounut oil both sexes vinegar Sour sodium, cocounut oil both sexes sodium acetate of the present invention, structural formula are following (II):

R₂—CONHCH₂CH₂—N(R₂)(R₄)(CH₂COO—)

Wherein, R₂Alkyl and heptyl in the fatty acid that coconut oil obtains after hydrolysis, nonyl, 11 Alkyl；R₃It is beta-hydroxyethyl, R₄It is carboxymethyl.

Or structural formula is following (III):

R_2`—CONHCH₂CH₂—N(D)(E)

Wherein, D representative-CH₂CH₂OX`, E representative-(CH₂)_Z- Y`, Z=1 or 2, R₂Selected from coconut oil by hydrolyzing The alkyl and heptyl in fatty acid obtained afterwards, nonyl, undecyl；R₃It is beta-hydroxyethyl, R₄It is carboxymethyl, X` is selected from In-CH₂CH₂- COOH and H atom, Y` is selected from-COOH and-CH₂—CHOH—SO₃H,；R_2`Selected from linseed oil and coconut palm Seed oil obtained fatty acid and alkyl after hydrolysis, the alkyl of carbon chain lengths 7,9,11,13,17 alkyl of carbon and its different 17 alkyl of structure body and unsaturated carbon.

Above-described amphoteric surfactant such as, cocoyl both sexes sodium acetate, lauroyl both sexes sodium acetate, caprinoyl Base both sexes sodium acetate, cocoyl both sexes sodium propionate, lauroyl both sexes sodium propionate, capryl both sexes sodium propionate etc. belong to this A scope.

Amphoteric surfactant used in the present invention is produced selected from BASF (BASF) company, product name Are as follows: DEHYTON ML-CN, INCI Intemational Nomenclature are as follows: sodium cocoamphoacetate, color (APHA) is less than or equal to 3.0, admittedly contain Measure (%) 35 ± 2, pH value 9.5-10.5, viscosity≤5000, sodium chloride (%) 5.5-7.5.

Amphoteric surfactant of the present invention be at least one of Cocoamidopropyl betaine or cocounut oil both sexes sodium acetate, It accounts for present composition weight 0.5%-10.0%, advanced optimizes as 1.0%-8.0%.

Heretofore described cationic polymer is selected from quaternized cellulose ethers derivative, such as the JR-400 of Tao Shi, LR400, and the copolymerization of 2 methyl chloride ammonium salt homopolymer of diallyl and diallyl 2 methyl chloride ammonium salt and acrylamide Object, such as the poly- ammonium salt -6 of Merquat 100 and the poly- ammonium salt -7 of Merquat 550 of Merck & Co., Inc., the diallyl of BASF AG Alkyl dimethyl ammonium chloride/acrylamide copolymer (SALCARE Super7), the acrylamido propyl trimethyl chlorine of BASF AG Change ammonium/acrylamide copolymer (SALCARE SC60), and cationization polysaccharide as cationization guar gum, sun from Son is selected from 2,3- epoxypropyltrimethylchloride chloride.Cation guar gum, such as Rhodia Jaguar C13S, Jaguar C14S, or the selective crosslinking homopolymer and copolymer of (methyl) acryloyloxyethyl trimethyl ammonium chloride, such as National Starch Salcare SC92, a kind of cationic solution (methacryloyloxyethyl three of the content being dispersed in mineral oil percent 50 The cross-linked copolymer of ammonio methacrylate and acrylamide) and Salcare SC95 (methacryloyloxyethyl trimethyl ammonia chloride The cross-linked homopolymer of ammonium).

According to the present invention, cationic polymer is selected from cationic melon rubber polymer or cationic cellulose polymer, this It is 0.2% that the cationic melon rubber polymer of invention or cationic cellulose polymer, which account for composition weight percentage,.

Such as, the solvent or polyalcohol contained in deionized water and aqueous solution is such as cosmetically acceptable carrier in the present invention C₁-C₄Alcohol, such as ethyl alcohol, isopropanol, the tert-butyl alcohol, n-butanol, polyalcohol such as propylene glycol or glycol ester etc..

Surfactant used in the present invention, final pH range be 3 to 10, and advanced optimize for 5 to 8, the pH value for being further optimized for 5.5. system can be obtained by the way that the reconciliation of organic or inorganic alkali is added, such as sodium hydroxide, ammonia Water, brothers tertiary amine, monoethanolamine, diethanol amine, triethanolamine, isopropanolamine or 1,3 malonamides, and by the way that acid is added, Such as carboxylic acids, citric acid etc..

The present invention also includes system viscosity modifier, such as electrolyte or thickener, such as sodium chloride, sodium xylene sulfonate, the Chinese Raw rubber, fatty acid alkanol amides (such as coconut monoethanol amide, diglycollic amide), acrylate copolymer, methyl glucosamine polyoxy Vinethene (120) dioleate etc..Preferred methyl glucosamine polyoxyethylene ether (120) dioleate of viscosity modifier of the present invention, Methyl glucosamine polyoxyethylene ether (120) dioleate accounts for the 1.2% of present composition weight.

The pearling agent or opacifier such as ethylene glycol that the present composition can also be 0.5% to 5% comprising weight percent Monostearate, ethylene glycol double stearate, polyethylene glycol mono stearate, polyethylene glycol stearate diester etc., preferably second two The double stearates of alcohol.

The non-limiting example of chelating agent of the present invention has ethylene glycol tetraacetic disodium, four sodium of ethylene glycol tetraacetic, preferably second Glycol tetraacetic disodium (EDTA-2 sodium).

In the present invention it is also an option that property using or comprising the acceptable ingredient of some cosmetics such as, cation surface activating Agent, anion or nonionic or cation or amphoteric ion polymer, protein, protein hydrolysate, 18- methyl arachic acid, hydroxyl Base acid, vitamin, D-pantothenyl aleohol, aliphatic ester, volatilization or non-volatile silicone oil, moisturizer, anti-dandruff agent or anti-sebum overflow agent, prevent Agent, free radical resisting ingredient are shone, mineral oil synthesizes organic grease and mixture.

The present composition can also include a kind of steady foaming agent, selected from carbon 10 to 18,1,2- alkyl of carbon, 2 alcohol or rouge Fat alkanolamide includes fatty monoethanolamine and fatty diethanol amide.The present invention preferably use coconut monoethanol amide as Foam stabilizer, it is 0.1% to 5% that coconut monoethanol amide, which accounts for composition weight percentage, and advanced optimizing is 0.5% to 2%.

A small amount of substance that inventive composition is also possible that such as preservative, essence, pigment are chosen, and cosmetics health mark is met Quasi- regulation.

In shampoo composite of the present invention, exceptionally in addition to the above group, mended with water to aequum.

Preparation method:

Shampoo composite of the invention can pass through any known or other effective preparations for being suitable for shampoo composite Technology is produced, including conventional configuration and hybrid technology.

Application method:

It takes about 12 grams of I compositions of embodiment to be uniformly applied on hair wet in advance, gets foam, then use warm water It rinses well, this can according to need repeatedly using step, the effect of to reach required cleaning, conditioning, moisturizing.

Embodiment

Here is the non-limiting example of shampoo composite of the present invention.These examples be only given in order to illustrate mesh , it should not be understood as limitation of the invention, because without departing from the spirit and scope of the present invention, it can be to this hair It is bright to carry out many changes.In provided embodiment, unless stated otherwise, all concentration is all weight percent.It is described Those of the optionally substance that " a small amount of substance " refers to, such as preservative, viscosity modifier, pH adjusting agent, flavors and fragrances, pigment. The selection of these a small amount of substances will be with the change of the selected substance and chemical characteristic for being used to prepare specific composition of the invention And change.

Prepare embodiment I-Ⅹ

The preparation of embodiment I-Ⅹ is using conventional shampoo preparation method.

Embodiment I-V

Embodiment VI-Ⅹ

Highly preferred embodiment of the present invention is:

In embodiment I-Ⅹ, moisturizing composite reactive agent each component and content (weight ratio) are as follows: containing 26% hexylene glycol, contain (carbohydrate admixture is by monosaccharide, oligosaccharide, polysaccharide composition, and monosaccharide: oligosaccharide: polysaccharide is with weight for 16% carbohydrate admixture Measure the ratio mixing than 5:2:1；Monosaccharide is by fructose and glucose group at and fructose: glucose is mixed with the ratio of weight ratio 1:1 It closes；Oligosaccharide is by sucrose, cyclodextrin composition, and sucrose: cyclodextrin is mixed with the ratio of weight ratio 1:0.5；Polysaccharide is transparent Matter acid sodium), containing 10% water-soluble silicon oil (water-soluble silicon oil is PEG/PPG-22/23 dimethyl silicone polymer), containing 8% Ispol (ispol is alanine: serine: glycine: glutamic acid: cysteine is with weight ratio 1:1: The ratio of 1:0.2:0.1 mixes), containing 4% pyrrolidone sodium carboxylate (Anjidew NL50), ethoxy urea and surplus containing 2.5% Water.

The verifying of hair moistening effect

The selection of volunteer: moistening effect after test hair hair washing, an important thing are the suitable volunteers of selection. The type selection (stemness, neutral, oiliness) of volunteer's hair is extremely important.The generation of dry hair often derives from three kinds of feelings Condition, first is that it is physiological, second is that pathology, third is that environment or human factor.Hair is glossy necessary to lose, and can seem more withered Dry, real heredity drying hair is more rare, and only 5% life to be exactly drying type hair, and this drying hair is typically more thick Rough stiff, often tangled mass due to curling, has no gloss.And the drying hair of vast majority of people belongs to third seed type, be due to Excessive solarization, dry wind brush or using shampoo it is improper caused by, therefore after the raw drying hair phenomenon of many human hairs, mistakenly Reduction the number of shampoo is taken, it is expected that the hair oil of naturally secret assembles to get up to moisten hair, as a result generates a large amount of dandruffs, until stifled The adipose gland for filling in skin in hair follicle, causes hair more dry.Therefore, the present invention selects the drying hair that the third situation is selected when volunteer Volunteer tests the city's tune result that will generate more preferable reference value.

Test method: the improvement to drying hair moistness: 1- is invalid；2- is general, and (hair is similar with before compared with, can one Point)；3- good (hair has a little sticking nature after doing, and has texture)；4- is very good, and (hair has sticking nature after doing, and has compared with before Texture, hair tail hair, which will not be dried, to be flown to stick up)；And count the number of " good " and " very good ", if " good " or " very in 10 people Number well " is that then hair moistness improvement number percentage is 10% to 1 people, and so on.

The volunteer for selecting 40 the third above-mentioned drying hair situations, is divided into 4 groups, respectively corresponds using the embodiment of the present invention II (first group), VIII (second group) compare 2 (the 4th groups) of 1 (third group) and comparison.It persistently uses one week and evaluates respectively after two weeks The number (having one's hair wash 3-4 times weekly) that hair moistness improves, fills in city's tune and reports and counted, be shown in Table 1

Table 1

By table 1, the embodiment of the present invention II (first group), the embodiment of the present invention VIII (second group), present invention comparison 1 (the Three groups) and the present invention 2 (the 4th groups) of comparison felt respectively using 7 days and using 14 days persistently using after 7 days and 14 days Official's assessment, as the result is shown: the embodiment of the present invention II (first group) and the embodiment of the present invention VIII (second group) and present invention comparison 1 (third group) and (the 4th group) comparison of present invention comparison 2, it is suitable using the product percentage that hair moistness improves after a week；Make After product second week, the embodiment of the present invention II (first group) and the embodiment of the present invention VIII (second group) and third, the 4th group of phase The percentage for improving number than hair increased significantly, and illustrate that the present invention has good moistening effect for dry hair；Two weeks The increase of moisturizing number percentage obviously also illustrates the increase along with the number of shampoo afterwards, and the embodiment of the present invention is for growing scalp It supports and moistening effect is also being promoted, therefore the moistening effect of hair increases therewith.

Claims

1. a kind of shampoo composite containing efficient hair moisturizing complexing agent, contain in the shampoo:

(A) it accounts for the anionic surfactant containing sulfate of composition weight 5%-30% and accounts for composition weight 1.0%- 8.0% amphoteric surfactant, the amphoteric surfactant are Cocoamidopropyl betaine or cocounut oil both sexes sodium acetate； The sulphate anion surface active agent is sulfated lauryl alcohol, ethoxylated dodecyl alcohol sulfate compositions, laruyl alcohol The weight ratio of sulfate and ethoxylated dodecyl alcohol sulfate is 1:2；

(B) the alkyl glucoside nonionic surfactant of composition weight 1.0% to 8.0% is accounted for；

(C) the hair moisturizing composite reactive agent of composition weight 0.5-12%, the hair moisturizing composite reactive agent, except aqueous are accounted for Outside, also include；

(II) carbohydrate admixture of composite reactive agent weight 10-20% is accounted for, which is by monosaccharide, oligosaccharide and polysaccharide Composition, and monosaccharide: oligosaccharide: polysaccharide is mixed with the ratio of weight ratio 5:2:1；Monosaccharide is fructose and glucose, and fructose: grape Sugar is mixed with the ratio of weight ratio 1:1；Oligosaccharide is sucrose and cyclodextrin, and sucrose: cyclodextrin is with the ratio of weight ratio 1:0.5 Mixing；Polysaccharide is Sodium Hyaluronate, and molecular weight is 1,000,000 dalton to 1,800,000 dalton；

(III) water-soluble silicon oil of composite reactive agent weight 3-20% is accounted for, which is the poly- diformazan of PEG/PPG-22/23 Radical siloxane；

(IV) account for the ispol of composite reactive agent weight 5-10%, the ispol be by alanine, serine, Glycine, glutamic acid, cysteine composition, and alanine: serine: glycine: glutamic acid: cysteine is with weight ratio 1:1: 1:0.2:0.1 ratio mixing；The glycine is trimethylglycine；

(V) pyrrolidone sodium carboxylate of composite reactive agent weight 1-5% is accounted for；

(VI) the ethoxy urea of composite reactive agent weight 0.5-3% is accounted for；

(D) cationic polymer of composition weight 0.2% is accounted for；The cationic polymer be cationic cellulose polymer or Cationic guar polymer；

(E) 1.2% methyl glucosamine polyoxyethylene ether dioleate of composition weight is accounted for；

(F) and the water of surplus.