CN107454837A - A kind of shampoo composite of the complexing agent of moisturizing containing hair - Google Patents
A kind of shampoo composite of the complexing agent of moisturizing containing hair Download PDFInfo
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- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
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- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
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- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A61Q5/00—Preparations for care of the hair
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Abstract
A kind of shampoo composite of the complexing agent of moisturizing containing hair, account for the anion surfactant of composition weight 5 30% containing (A) and account for the amphoteric surfactant of composition weight 1 8%, wherein anion surfactant is weight than 1:2 sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate compositions, (B) the alkyl glucoside nonionic surfactant of composition weight 1 8% is accounted for, (C) the hair moisturizing composite reactive agent of composition weight 0.5 12% is accounted for, (D) cationic polymer of composition weight 0.2% is accounted for, (E) methyl glucosamine APEO (120) dioleate of composition weight 1.2%, and the water of (F) surplus are accounted for.
Description
Technical field
The invention belongs to household chemicals field, and in particular to a kind of shampoo composite containing efficient hair moisturizing composite reactive agent.
Background technology
As a rule " drying " of hair (1) relevant with following factor has one's hair wash：With the raising of hair washing frequency, hair
More or less occur hair degreasing phenomenon, thus hair easily cause it is dry and astringent；(2), swim：Swimming-pool water is chloride, can injure hair
Matter epidermis and cortical layer, if not cleaning and handle carefully hair after swimming will easily dry；(3), Exposure to Sunlight：For a long time by too
Positive ultraviolet irradiation, the moisture on hair top layer can be lost in, thus dried-up phenomenon is presented, and color development can also shoal；(4), it is commonly used
Hair jelly and hot blast blow head hair because hair jelly has chemical composition, with perming, having hair dyed, be all easily destroyed hair group too much
Temperature when knitting and drying is too high, also easily makes the moisture stream of hair surface,；(5), often have a perm, have hair dyed and float and be shallow：Add
The agent for permanent hair waving or hair dye of chemical composition are added, more or less can all destroy the tissue of hair, if along with afterwards ill-considered
Processing or maintenance, it is bound to make hair " dry upper plus dry "；(6), partial eclipse：This point can be what many people often ignored, the life of hair
The nutrition that the source of life absorbs in itself from us, if so the food that we eat on ordinary days does not provide enough nutrients to hair,
Protein-contng foodstuffs are especially eaten less, and hair is difficult to grow dense, glossy.(7), cold air：Dry air allows hair in cold air room
The situation of silk water shortage is even more serious than the cold air in winter.(8) dry hair：Dry hair is usually associated with the head of dryness
Skin, often hair can also be dried while dry scalp in a sense, and therefore, the moisturizing nursing of scalp is also extremely important.
In addition to supplement body fluids more, using the real-time maintenance product that can provide nutrient and moisture immediately, will not just scalp be allowed to do
It is dry, because " drought " of hair will likely be triggered while dry scalp；
Hair wants water bright, and primary is exactly the health that must keep hair scale piece, because in the case of hair healthy, hair scale piece
Hair tail can be aligned to by root of hair, to protect hair interior tissue, healthy hair seems that nature is soft bright glossy as roofing tile.Through
Normal hair washing, exposure sunlight, swimming, dyeing and perm are sent out etc., can all bring more or less physically or chemically injury to hair structure, and one
Denier hair scale piece is come to harm, and hair, which just occurs, to be dried, is broken, jag, if now wanting to allow hair to recover soft light pool, just must
It must be kept the skin wet by hair products are washed on ordinary days and hair nutrient, make hair quality healthy once again.
Shampoo is necessary hair cleaning supplies in people's daily life, and frequency of use is higher, and southern area is average
Once, northern area hair washing in average 2-3 days is once for hair washing in 1-2 days.Although can also use hair conditioner such as hair conditioner after hair washing, send out
Film etc. carrys out hair conditioning, but because how much the cleaning effect of surfactant in shampoo still can wash away scalp during hair washing
With the natural oil on hair with protective effect so that hair is impaired to trigger drying.In addition, the table used in shampoo
Activating agent either anionic table in face is lived, and nonionic table is lived, and both sexes table is lived, and even amino acid pattern table work etc. can all have stimulation
Property, only their excitant has height to have low.The excitant of surfactant is also to trigger hair to be damaged in shampoo
One of dry factor.
It is therefore an object of the present invention to provide a kind of shampoo composite, original a kind of natural and from skin care with the addition of
Material and technology, have the compound of collaboration scalp and hair moisture-keeping function, and collaboration reduces the excitant of surfactant, makes scalp
The care of various dimensions moisturizing factor and the supplement of moisture content are obtained with hair, improves the dry-out phenomenon of hair.
The content of the invention
It is an object of the invention to provide a kind of shampoo composite containing efficient hair moisturizing complexing agent.
The hair moisturizing shampoo composite of the present invention, contains in the shampoo：
(A) account for the composition weight 5%-40% anion surfactant containing sulfate and account for composition weight
1.0%-15.0% amphoteric surfactant, the sulphate anion surface active agent are aliphatic alcohol sulfate, fatty alcohol
The weight ratio of polyoxyethylene ether sulfate composition, aliphatic alcohol sulfate and fatty alcohol polyoxyethylene ether sulfate is 1:2；
(B) the alkyl glucoside nonionic surfactant of composition weight 0.5% to 10.0% is accounted for；
(C) composition weight 0.5-15% hair moisturizing composite reactive agent is accounted for, the hair moisturizing composite reactive agent, is removed
It is aqueous outer, also include；
(I) composite reactive agent weight 10-28% hexylene glycol is accounted for；
(II) account for composite reactive agent weight 10-20% carbohydrate admixture, the carbohydrate admixture be by monose, oligosaccharide and
Polysaccharide forms, and monose：Oligosaccharide：Polysaccharide is with weight than 5：2：1 ratio mixing；Monose is fructose and glucose, and fructose：
Glucose is with weight than 1：1 ratio mixing；Oligosaccharide is sucrose and cyclodextrin, and sucrose：Cyclodextrin is with weight than 1：0.5
Ratio mixes；Polysaccharide is Sodium Hyaluronate, and its molecular weight is 400,000 dalton to 2,200,000 dalton；
(III) composite reactive agent weight 3-20% water-soluble silicon oil is accounted for, the water-soluble silicon oil gathers for PEG/PPG-22/23
Dimethyl siloxane；
(IV) composite reactive agent weight 5-10% ispol is accounted for, the ispol is by alanine, silk
Propylhomoserin, glycine, glutamic acid, cysteine composition, and alanine：Serine：Glycine：Glutamic acid：Cysteine is with weight
Than 1：1：1：0.2：0.1 ratio mixing；
(IV) composite reactive agent weight 1-5% pyrrolidone sodium carboxylate (Anjidew NL50) is accounted for；
(V) composite reactive agent weight 0.5-3% ethoxy urea is accounted for；
(D) cationic polymer of composition weight 0.2% is accounted for；
(E) composition weight 1.2% methyl glucosamine APEO (120) dioleate is accounted for；
(F) and surplus water.-
Shampoo composite of the present invention, wherein the hair moisturizing composite reactive agent is by hexylene glycol NMF, pyrrolidones
Carboxylic acid sodium (Anjidew NL50) NMF, ethoxy urea NMF, carbohydrate NMF, water-soluble silicon oil NMF, amino acids NMF
Formed with the water of surplus；Wherein, carbohydrate NMF is with weight ratio 5 by monose, oligosaccharide and polysaccharide：2：1 ratio mixing, its
Middle monose is fructose and glucose, and oligosaccharide is sucrose and cyclodextrin, and polysaccharide is Sodium Hyaluronate；Amino acids NMF is third
Propylhomoserin, serine, glycine, glutamic acid and cysteine are with weight ratio 1：1：1：0.2：0.1 ratio mixing, the glycine
For trimethylglycine.
The shampoo composite of the present invention, wherein the sulfate type anion surfactant is sulfated lauryl alcohol and the moon
The mixture of cinnamic alcohol polyoxyethylene ether sulfate.
Shampoo composite of the present invention, wherein the alkyl glucoside nonionic surfactant is lauryl glucoside or certain herbaceous plants with big flowers
Base glucoside one kind therein.
Shampoo composite of the present invention, wherein the cationic polymer is selected from：Cationic cellulose polymer, cation melon
One kind in your xanthan polymer.
Compared with prior art, the present invention has advantages below：
Shampoo composite of the present invention is a kind of from the natural composite reactive agent group with collaboration hair moisture-keeping function
Into, the composite reactive agent is hexylene glycol, containing fructose, glucose, sucrose, cyclodextrin, Sodium Hyaluronate carbohydrate admixture, containing third
Propylhomoserin, serine, trimethylglycine, glutamic acid, the ispol of cysteine, pyrrolidone sodium carboxylate, ethoxy
The various dimensions moisturizing such as urea and water-soluble silicon oil composition forms.Shampoo composite of the present invention has good water lock, water supplement function, grows
Profit dries scalp, improves hair conditioning, flexibility and the dry-out phenomenon of hair, moistens the hair after the dry hair of hair washing moist, soft
Obey note not fly upward.
Specific embodiment
The selection to instant component and effect are described in detail below.
Contain the hair moisturizing composite reactive agent for accounting for composition weight 0.5-15% in the shampoo composite of the present invention, preferably
5% to 12% hair moisturizing composite reactive agent, the hair moisturizing composite reactive agent is by hexylene glycol NMF, pyrrolidones
Carboxylic acid sodium (Anjidew NL50) NMF, ethoxy urea NMF, carbohydrate NMF, water-soluble silicon oil NMF, amino acids NMF
Formed with water；Wherein, carbohydrate NMF is by monose, and oligosaccharide and polysaccharide composition, wherein monose are fructose and glucose, oligomeric
Sugar is sucrose and cyclodextrin, and polysaccharide is Sodium Hyaluronate；Amino acids NMF is by alanine, serine, glycine, paddy ammonia
Acid and cysteine composition.Concrete composition and activity are as follows：
Account for composite reactive agent weight 10-28% hexylene glycol；
Composite reactive agent weight 10-20% carbohydrate admixture is accounted for, the carbohydrate admixture is by monose, oligosaccharide and polysaccharide
Composition, and monose：Oligosaccharide：Polysaccharide is with weight than 5：2：1 ratio mixing；Monose is fructose and glucose, and fructose：Grape
Sugar is with weight than 1：1 ratio mixing；Oligosaccharide is sucrose and cyclodextrin, and sucrose：Cyclodextrin is with weight than 1：0.5 ratio
Mixing, polysaccharide is Sodium Hyaluronate；
Composite reactive agent weight 3-20% water-soluble silicon oil is accounted for, the water-soluble silicon oil is the poly- diformazans of PEG/PPG-22/23
Radical siloxane；
Account for composite reactive agent weight 5-10% ispol, the ispol be by alanine, serine,
Glycine, glutamic acid and cysteine composition, wherein, alanine：Serine：Glycine：Glutamic acid：Cysteine is with weight ratio
1：1：1：0.2：0.1 ratio mixing；
Account for composite reactive agent weight 1-5% pyrrolidone sodium carboxylate (Anjidew NL50) NMF；
Account for composite reactive agent weight 0.5-3% ethoxy urea NMF；
And the water of surplus
Hair moisturizing composite reactive thing
Hexylene glycol.Hexylene glycol, English name:2-Methyl-2,4-pentanediol, Hexylene Glycol. are colourless
Transparency liquid.There is gentle sweet fragrance.It is dissolved in water, ethanol, ether, low-carbon aliphatic hydrocarbon.As solvent, spices, medical disinfectant.
Diacetone alcohol is obtained by condensation of acetone, then obtained through liquid-phase hydrogenatin.Hexylene glycol molecular formula C6H14O2, molecular weight, 118.17g/
Mol, relative density (g/mL):0.925, can be miscible with water, lower alcohol, ether, various aromatic hydrocarbon, aliphatic hydrocarbon etc..In the present invention
As solvent and scalp and hair NMF.
Carbohydrate, also known as carbohydrate (English：Carbohydrate or saccharide), it is polyhydroxy aldehyde or polyhydroxy
The general name of ketone and its condensation polymer and some derivatives, it is similar in the performance of chemical formula because it is made up of carbon, hydrogen, oxygen element
It polymerize in " carbon " with " water ", therefore also referred to as carbohydrate.Carbohydrate is widely distributed a kind of important organic in nature
Compound.The sucrose of daily consumption, the starch in grain, the cellulose in plant, glucose in blood of human body etc. belong to
Carbohydrate.For from biological function, carbohydrate plays an important role during vital movement, is a kind of important in human body
Energy source.
Carbohydrate is the important nutrient of human body, is broadly divided into monose, oligosaccharide and polysaccharide, and play very in human body
Important role.Monose, oligosaccharide and polysaccharide are used in the present invention and with weight ratio 5：2：1 ratio mixing, molecular weight from
Bottom is uniformly distributed to height again in.The proportion optimizing dry scalp of monose, oligosaccharide and polysaccharide that the present invention contains has certain
Moisture-keeping functions, there is good coordination moisture-keeping function to hair.
Monose.Monose (monosaccharide)：Turn into smaller carbohydrate due to that can not hydrolyze, therefore it is this
Minimum molecule in class.They are some aldehydes or ketones classes with two or more hydroxyl.The monose chemical formula of unmodified mistake
It can be expressed as：(C 〃 H2O)) n, it is referred to as because it is all the multiple of carbon and hydrone：" carbohydrate ".Monose is a kind of important
Fuel molecule, and the structure fragment of nucleic acid.N=3 in minimum monose, i.e.,：Dihydroxyacetone (DHA) or D- and L- glyceraldehyde,
By that analogy such as, triose (glyceraldehyde)；Pentose, pentose is such as：Ribose, deoxyribose；Hexose is such as：Glucose, fructose (chemical formula
All it is C6H12O6), glucose is pyranose, and fructose is furanose.Monose is fructose and glucose in the present invention.Fructose
(C6H12O6) it is a kind of simple sugared (monose), is highly soluble in water, exists in numerous food product, and glucose, galactolipin are together
Constitute three kinds of Main Ingredients and Appearances of blood glucose.Honey, the fruit on tree, berry is melon, and some roots vegetables are such as：Beet, sweet tea
Potato, parsnip, onion etc. contain fructose；Compound is generally formed together with glucose with sucrose.
Fructose molecule is small compared with sucrose and the product of sucrose decomposition, and sucrose is a kind of disaccharide, in digestion process, due to enzyme
Catalysis characteristics and be decomposed into a glucose and a fructose.Fructose is polyhydroxy ketose, molecular formula：CH2OH(CHOH)3C
=OCH2OH, molecular weight：180.16, it is water-soluble：3750g/L (20 DEG C), in carbohydrate, the hygroscopicity of fructose is most strong, it is easy to
Absorb moisture.Fructose is monose, and molecule is small compared with sucrose, and osmotic pressure is higher by one times than sucrose, can penetration cell tissue quickly, it is molten
Solution degree is high, and diffusion velocity is fast in water, and therefore, fructose has good permeability moisture-keeping functions to hair.
Glucose (Glucose) (chemical formula C6H12O6), white crystals or particulate powder, also known as corn sugar, jade
Chinese sorghum sugar, referred to as glucose.Glucose is polyhydroxy aldose, so reduced sugar is also, molecular formula：CH2OH (CHOH) 4CHO, point
Son amount：180.16, it is the indispensable nutriment of metabolism in organism, is that distributed in nature is most wide and mostly important
A kind of monose.Glucose, chemical name:2,3,4,5,6- penta hydroxy group hexanals, glucose have critical role in field of biology, are
The energy source of living cells and metabolic intermediate product, i.e. biological main Energy supply material, its physical characteristic:White crystal,
It is soluble in water, sweet, 146 DEG C of fusing point, containing five hydroxyls, an aldehyde radical, there is the property of polynary alcohols and aldehydes.With hygroscopicity,
It is soluble in water, there are moisture-keeping functions.
Oligosaccharide.Oligosaccharide is also known as oligosaccharides (English control:oligosaccharide；oligosaccharides；
Oligose), refer to the compound being polymerized containing 2-10 glycosidic bond, can make to be the glycosides hydroxyl of monose and another list
Certain monohydroxy of sugar shrinks to be formed.They usually with protein or lipid covalent bond, exist in the form of glycoprotein or glycolipid.
2~4 monose are generally formed by connecting small aggressiveness by oligosaccharide by glycosidic bond, and it includes functional oligose and common oligomeric
Sugar, most common oligosaccharide are disaccharides, also known as disaccharide, are that two monose are combined into by glycosidic bond, connect being total to for they
Main two major class of valence link type：The sweet of bonding of N- sugar and O-glycosides of bonding.1. N- glucosides of bondings：Oligonucleotide chain is with the Asn's on polypeptide
Amino is connected.This kind of oligonucleotide chain has three kinds of main Types：High mannose type, heterozygous and complexity.2. O-glycosides of bonding, oligosaccharides
Chain is connected with the Ser on polypeptide chain or Thr hydroxyl, or is connected with the hydroxyl of film fat.In garlic, onion, burdock, asparagus, beans
There is the presence of oligosaccharide in the foods such as class, honey.Oligosaccharide can come out from natural plant extraction, can also utilize biochemical section
Skill and ferment reaction, are synthesized using starch and disaccharide (such as sucrose).Common oligosaccharide such as malto-oligosaccharide glucose (α-
The combination of Isosorbide-5-Nitrae glycosidic bond), isomalto-oligosaccharide glucose (α -1,6 glycosidic bond combinations) anti-caries, promote Bifidobacterium propagation, ring
Shape dextrin glucose (ring-type α-Isosorbide-5-Nitrae glycosidic bond combination) low heat value, prevents Cholesterol Accumulation, and gentiobiose glucose (β -1,6
Glycosidic bond combination) bitter taste can form packaging junctor, coupling sugar (Coup ling sugar) glucose (α-Isosorbide-5-Nitrae glucosides bond
Close), sucrose anti-caries, fructose oligosaccharides fructose (β -1,2 glycosidic bond combinations), sucrose promotion Bifidobacterium propagation, panose grape
Sugared (α -1,6 glycosidic bond combinations), fructose anti-caries, trehalose glucose (α -1,1 glycosidic bond combination), fructose anti-caries are excellent
Matter sweet taste, sucrose oligosaccharide glucose (α -1,6 glycosidic bond combinations), the anti-caries such as sucrose, promote Bifidobacterium propagation, cow's milk
Oligosaccharide galactolipin (β-Isosorbide-5-Nitrae glycosidic bond combination), glucose backbone anti-caries, promote Bifidobacterium propagation, chitin oligosaccharide acetyl
Glucosamine (β-Isosorbide-5-Nitrae glycosidic bond combination), sucrose antitumor activity, soyabean oligosaccharides galactolipin (α -1,6 glycosidic bond combinations), sugarcane
Sugar promotes Bifidobacterium propagation, GOS galactolipin (β -1,6 glycosidic bond combinations), and sucrose promotes Bifidobacterium propagation,
Fructose type oligosaccharide galactolipin (α -1,2 '：β -1 ', 2 glycosidic bond combinations) high-quality sweet taste, different qualityxylans xylose (β-Isosorbide-5-Nitrae glucosides
Bond is closed) water activity regulation.
Oligosaccharide of the present invention uses sucrose and cyclodextrin.
Sucrose is photosynthetic primary product, is distributed widely in plant, is particularly contained in beet, sugarcane and fruit
Measure high, usually edible white sugar, brown sugar is all sucrose.Sucrose is by a molecule glucose and a molecule fructose dehydrating condensation shape
Into molecular weight 342.3.Molecular formula:C12H22O11, density 1.5805, fusing point 190-192＆ordm；C, specific rotatory power 67＆
ordm；(C=26, IN WATER 25＆ordm；C), water-soluble 1970G/L (15＆ordm；C).
Cyclodextrin is a kind of glucose oligosaccharide annular in shape.Under normal conditions, cyclodextrin is by 6,7 or 8 glucose
Unit is by α, crystalline solid that 1.4 key ring-types are connected with each other, claim respectively α-, β-or gamma-cyclodextrin.Cyclodextrin is in ring-type knot
The center of structure has a hole, and there is the oxygen atom that C-H bond is combined with glycoside inside, water-based in sulphur, 2 position of glucose, 3 and 6
The hydroxyl of position be in hydrophily, that is, characteristic hydrophilic outside water delivery in presentation, can be by faint Van der Waals force by other molecules
It is complexed into inclusion compound.The material that can be connect by cyclodextrin bag is a lot, such as dyestuff, spices, medicine, food, agricultural chemicals and preservative.Bag
After connecing, its stability, volatility, dissolubility, reactivity all make moderate progress.This special role of cyclodextrin, makes it tool
The bag for the value that is widely used connects material such as, and 1. purposes in medical industry can generate inclusion compound using cyclodextrin with medicine
(capsulation), (1) unstable drug substance stable can be made；(2) hygroscopy, adherence or liquid medicine powdered；(3) indissoluble
Property or insoluble drugs solubilized (solubilising) etc.；2. improve the stability of institute's coating active components；3. in daily chemical industry side
The purposes in face, it can also make emulsifying agent and quality improver etc. with cyclodextrin in cosmetics manufacture.
Cyclodextrin of the present invention is through the sugared key connection cyclization of α -1.4 by 6 glucose units using cyclohexaamylose
The dextrin of shape structure, it is the product that glucosyltransferase acts on starch syrup.Due to the interior chamber size of cyclohexaamylose
It is that its is more stable more suitable for inclusion small-molecular-weight by inclusion complex less than cycloheptaamylose.Alpha-cyclodextrin water solubility is 25
DEG C it is 14.5g/100ml, it is higher than beta-schardinger dextrin solubility, therefore applied to requiring the higher occasion of cyclodextrine solubility.α-
Cyclodextrin:No. CAS:51211-51-9, molecular formula C36H60O30, molecular weight:972.8436, relative density:1.624g/cm3
Outward appearance:White crystalline powder, fusing point:278 DEG C, pH value 5.0-8.0.The effect of cyclodextrin (alpha-cyclodextrin) of the present invention is to provide
Moisturizing, hydrotropy and sustained release.
Polysaccharide.Polysaccharide (polysaccharide) is to pass through the strong polymerization of glucosides by more than 10 monosaccharide molecules or derivatives thereof
The high-molecular compound formed, the also known as high polymer formed by many monosaccharide molecules or derivatives thereof condensation, high glycan.It can divide
For homopolysaccharide and the class of heteroglycan two.The polysaccharide formed is condensed by a kind of monose and is referred to as homopolysaccharide, such as starch, cellulose.By two
The polysaccharide that kind above monose or derivatives thereof condensation is formed is referred to as heteroglycan, such as hyaluronic acid, chondroitin sulfate；By glycan molecule
In have unbranched, be divided into straight-chain polysaccharide and branched polysaccharides；According to the difference of function, it is more to be divided into structural polysaccharide, storage polysaccharide, antigen
Sugar etc.；It is divided into exocellular polysaccharide, intracellular polyse again by its Germ distribution.Polysaccharide of the present invention is selected from chondroitin sulfate and hyalomitome
Acid, preferably clear matter acid.
Chondroitin sulfate (CS), extraction source are shark, ox, pig, the cartilage of chicken, are to be covalently attached to be formed on protein
A kind of glycosaminoglycan of proteoglycans.Chondroitin sulfate is distributed widely in the extracellular matrix and cell surface of animal tissue, sugar
Chain is made up of alternate glucuronic acid and N- acetylgalactosamines (also known as N- acetylamino galactosamines) disaccharide unit, passes through one
It is individual to be connected to like sugared link zone on the serine residue of core protein.Chondroitin sulfate:It is soft with sulfuric acid as mucopolysaccharide material
Ossein sodium salt (CHONDROITIN SULFATE SODIUM) is most commonly seen.Chondroitin sulfate for white or off-white powder, nothing
It is smelly, have draw it is moist, the aqueous solution tool toughness, heating it is non-condensing, it is readily soluble in water, it is organic insoluble in ethanol, acetone and ether etc.
In solvent, its esters is relatively stable to heat, heated not also to be destroyed up to 80 DEG C.The chondroitin sulfate aqueous solution, meet higher temperature or acid
It is i.e. unstable, mainly deacetylation or it is degraded into monose or the less polysaccharide of molecular weight.Chondroitin sulfate of the present invention is sulfuric acid
Chondroitin sodium, there is beauty, the anti-ageing effect of waiting for a long time, improve the drying of skin and hair.
Sodium Hyaluronate also known as sodium hyaluronate, sodium hyaluronate sodium, uronic acid sodium, for the material extracted from cockscomb, it can also lead to
Cross Lactococcus fermentation be made, for white or off-white color particle or powder, odorless, dry when, nitrogen content 2.8%-
4.0%, glucuronic acid content is 37.0%-51.0%.Hyaluronic acid is a kind of high molecular polymer.It is by unit D- grapes
The higher polysaccharides of uronic acid and N-acetyl-glucosamine composition.By β -1 between D-Glucose aldehydic acid and N-acetyl-glucosamine, 3- is with sugar
Key is connected, and is connected between dissacharide units by β-Isosorbide-5-Nitrae-glycosidic inkage.Dissacharide units are up to as many as 25000.Hyaluronic acid in vivo
Molecular weight is from 5 thousand to 2 thousand ten thousand dongles.Molecular formula：(C14H21NO11) n, hyaluronic acid are a kind of acid mucopolysaccharides, U.S. in 1934
State Columbia University's ophthalmology professor Meyer etc. isolated first from bovine vitreous body the material (sodium hyaluronate is wrong translated name,
RESTIAID hyaluronic acid hyal- mean glass-like, clear transparent, and uronic acid refer to
Be uronic acid, sodium hyaluronate does not have any relation with uric acid).Hyaluronic acid is with its unique molecular structure and physicochemical property in machine
Show a variety of important physiological functions in vivo, such as lubricating joint, adjust the permeability of vascular wall, regulatory protein matter, water electrolysis
Matter spreads and operating, promotes wound healing etc..Particular, it is important that contain substantial amounts of carboxyl and hydroxyl in hyaluronan molecule,
Hydrogen bond can be formed with water, there is very strong bag outlet capacity, be the material that moisture retention is best in the nature having now been found that, be referred to as
Preferable natural moisture preserving because of (Natural moisturizing factor, NMF), such as：The 2% pure hyaluronic acid aqueous solution
98% moisture can be firmly held.Hyaluronic acid is a kind of multi-functional matrix, and hyaluronic acid (sodium hyaluronate) HA is distributed widely in people
Each position of body.Wherein skin also contains substantial amounts of hyaluronic acid.Human skin is ripe and ageing process is also with hyaluronic acid
Content and metabolism and change, it can improve skin-nourishing and be metabolized, make skin it is tender, it is smooth, go to wrinkle, increase it is elastic, anti-
Only aging, it is good skin penetration enhancer again while moisturizing.It is used cooperatively with other nutritional ingredients, rush can be played
Entering the more preferable effect of nutrient absorption, hyaluronic acid can be used in the products such as the cream of cosmetics, frost, honey, milk, facial mask, shampoo,
To keep the moisture of skin, hair, skin care, hair, increase gloss, and the generation of chapped skin and wrinkle can be prevented.This
Invention polysaccharide is chondroitin sulfate, Sodium Hyaluronate, preferably Sodium Hyaluronate.Sodium Hyaluronate molecular weight of the present invention is 400,000
Dalton is to 2,200,000 dalton, and one-step optimization of going forward side by side is 1,000,000 dalton to 1,800,000 dalton, Sodium Hyaluronate pair of the present invention
Hair plays a part of film forming and moisturizing.
Water-soluble silicon oil
A kind of polyether-modified polydimethylsiloxanecopolymer copolymer, because its silicone backbone and hydrophilic radical coexist, make
It has good water solubility, while smell is gentle, and temperature and photostability are outstanding, has well with the polar component in formula
Compatibility, the skin sense that gentle, salubrious and silk can be brought to slide, and keep in the case where being combined with hydrone strength the wet of skin and hair
Profit, has the function that wetting, foam stabilization, emulsification, can be used as hair conditioner, provides and moistens and silky soft and smooth sense for hair
Feel.As the DC-193 of DOW CORNING, INCI are named as PEG/PPG-22/23 dimethyl silicone polymers；The DMC6038 of wacker chemicals,
INCI is named as two polyethylene glycol -15- methyl ether dimethicones and the DMC6031 of wacker chemicals, NICI are named as
The dimethyl silicone polymer of polyethylene/polypropylene glycol -25/25.Water-soluble silicon oil of the present invention is sought healthy and free from worry DC-193, is PEG/
PPG-22/23 dimethyl silicone polymers.
Amino acid.
Scald dye, blowing hot wind, frequently using bad shampoo, drying weather the problems such as make hair scale piece be damaged, inside hair
Protein-loss, cause hair to become short-tempered, it is inelastic, it is difficult to arrange.Amino acid is a kind of moisturizing ingredient of natural structure,
Biostearin material.Amino acid is relatively good to the affinity of hair, the cavity that can be filled up in hair, reaches the work for repairing hair
With.Amino acid used in the present invention is the moisturizing for hair, and alanine known to us can be to the moisturizing of hair, essence
Propylhomoserin can improve the hydrophobicity on hair top layer, serine and Glutamatergic supplement hair moisture, glycine lifting moisture retention and
Antistatic behaviour, cysteine and histidine can improve toughness of hair etc..The amino acid such as arginine, asparagus fern that the present invention is included
Propylhomoserin, glycine, alanine, serine, proline, threonine, isoleucine, histidine, phenylalanine, glutamic acid, half Guang
Propylhomoserin etc..The preferred alanine of the present invention, glutamic acid, serine, glycine and cysteine.
Alanine.Alanine is the base unit for forming protein, is one of 20 kinds of amino acid for forming human body protein.
There are two kinds of isomers of α alanine and beta Alanine, Beta-alanine is that sterling is that white prismatic crystallizes, 200 DEG C of fusing point, relatively
Density 1.437 (19 DEG C), molecular weight 89.09, is dissolved in water, is slightly soluble in methanol and ethanol, insoluble in ether and acetone.The present invention
Beta-alanine is NMF.
Glutamic acid.Glutamic acid is a kind of acidic amino acid.Intramolecular contains two carboxyls, and chemical name is alpha-amido penta 2
Acid, molecular formula：C5H9NO4, outward appearance：White or colourless flake shape crystal, sublimation point：200 DEG C, decomposition point：It is 247-249 DEG C, close
Degree：1.538, solubility (water)：7.5g/L, molecular weight：147.13076.Glutamic acid of the present invention is NMF.
Serine.Serine also known as β serines, it is a kind of nonessential amino acid, rich in egg, fish, soybean, people
Body can also synthesize serine from glycine, and it is played in the metabolism of fat and aliphatic acid and the growth of muscle makees
With because it contributes to the generation of immunoglobulin and antibody, maintain health immune system be also required to serine.Serine exists
All play and act in the synthesis of the sheath for manufacturing processing, musculature and encirclement nerve cell of cell membrane.Serine is white
Crystalline solid or crystalline powder, the micro- sweet tea of taste, soluble in water and formic acid, insoluble in ethanol and ether.Serine of the present invention is grown for hair
Form part.
Glycine.Also known as amion acetic acid, it is human body nonessential amino acid.Title is abridged:Gly glycine is amino acid series
Middle structure is the simplest, a kind of nonessential amino acid of human body, has acid and basic functionality simultaneously in the molecule, in water
It is ionizable, there is very strong hydrophily, belong to polar amino acid, be dissolved in polar solvent, and non-polar solven is insoluble in, and have
There are higher boiling point and fusing point, can make glycine that different molecular conformations be presented by the regulation of aqueous solution acid-base property.This hair
Bright glycine is trimethylglycine, also known as glycine betaine, is good NMF, antistatic additive, thickening agent, viscosity-control additive.
Trimethylglycine chemical formula C5H11NO2, molecular formula C5H11NO2, molecular weight 117.15, solubility:160g/100G water.
Cysteine, alias include：2- amino-3-mercaptopropionic acids, β-sulfydryl-α-aminopropionic acid, 3- cysteines；Sulphur
For serine, Cys, L- cysteines.Cysteine is a kind of amino acid with physiological function, is composition egg
The only amino acid with reproducibility group sulfydryl (- SH) in 20 several amino acids of white matter, now in medicine, food addition
Extensive use in agent and cosmetics.Cysteine molecule formula:C3H7NO2S, molecular weight:121.15 solubility in water:
277.433g/L (25 DEG C, water), dissolubility aspect,:Diluted mineral acid and alkaline solution are dissolved in, is not readily dissolved in water, is insoluble in ethanol,
Insoluble in ether and chloroform.Cysteine energy maintenance hair, strengthen the toughness of hair.
Pyrrolidone sodium carboxylate (Anjidew NL50).Pyridine alkanone carboxylic acid sodium, the entitled L- pyridines alkanone -5- carboxylic acid sodiums of chemistry, referred to as
L-PCA-Na (Anjidew NL50), molecular weight：151.1. pyridine alkanone carboxylic acid sodium is to belong to NMF class NMF, as solid
The composition of water moisturizing, it is one of important composition of human body moisturizing factor.Anjidew NL50 has shrink moisturizing work(to scalp and hair
The effects such as energy, the structure for reinforcing hair, polishing, color protection.
Ethoxy urea.Ethoxy urea is a kind of chemical substance, and molecular formula is C3H8N2O2, CAS#:[2078-71-9], point
Son amount:104.11, outward appearance:It is colourless to light yellow clear liquid, pH (10% aqueous solution):6.0-10.0 solid content %:48.0-
52.0 electrical conductivity (10% aqueous solution):<150, urea (wt%):<1%.It is largely used in skin care moisturizer, as moisturizing
Agent, the effect of ethoxy urea is that the undamaged portion Evening Primerose Oil for repairing hair nourishes in the present invention, is also had to scalp certain
Moisture retention.
Surfactant system
Contain the sulfate type anion surface active for accounting for composition weight 5.0% to 40% in shampoo composite of the present invention
Agent and the amphoteric surfactant for accounting for composition weight 1.0%-15.0%, the anion surfactant containing sulfate
Selected from aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate composition, aliphatic alcohol sulfate and aliphatic alcohol polyethenoxy
The weight ratio of ether sulfate is 1:2.
The sulfate type anion surfactant used in the present invention is selected from alkyl sulfate, alkyl ether sulfate,
Alkyl amino ether sulfate, alkyl aryl ether sulfate, alkyl ether thio succinate.Used salt is alkali metal salt, ammonium
Salt, amine salt, ethylaminoethanol salt, magnesium salts.Wherein alkali metal salt tends to use sodium salt and ammonium salt, and the length of alkyl carbon chain is generally situated between
Between 8-24, between the usual 2-50 of number of oxirane or expoxy propane, one-step optimization is gone forward side by side between 2-10.
Composition of the sulphate anion surface active agent selected from alkyl sulfate and alkyl ether sulfate in the present invention,
Alkyl carbon chain is C8To C14, further it is optimized for C12To C14Alkyl ether sulfate.
Composition of the sulphate anion surface active agent selected from alkylsurfuric acid ammonium and alkyl sulfates in the present invention,
Alkyl carbon chain is C8To C14, further it is optimized for C12To C14Alkyl ether sulfate.
The quantity of oxirane is preferable alkyl ether sulfate middle ring in the 2-5. present invention on above sulfate aliphatic chain
The molal quantity of oxidative ethane is average 2.2.
Sulfate type anion surfactant of the present invention is sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate
Mixture, the commercially available sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate, active matter content is 70%, wherein the moon
The weight ratio of cinnamic alcohol sulfate and ethoxylated dodecyl alcohol sulfate is 1:2；Sulfate type anion surface active of the present invention
Agent accounts for composition weight percentage as 5% to 30%.
The nonionic surfactant of APG (APG) type used in the present invention is known a kind of gentle on the market
Surfactant, its chemical formula formula are following (1)：
R1—O—(R2O)t-(G)v
Wherein：
R1Selected from linear and side chain, saturation or undersaturated, about carbon chain lengths are the alkane of 8 to 24 carbon atoms
Hydrocarbon, and selected from linear and side chain, about carbon chain lengths are the alkylbenzene of 8 to 24 carbon atoms；
R2Selected from the alkene containing 2 to 4 carbon atoms；
G is selected from the reduced sugar for possessing 5 to 6 carbon atoms；
T is between 0 to 10；
V is between 1 to 15.
Currently preferred alkyl glucoside is the compound for meeting chemical general formula (1), wherein R1Selected from linear, saturation
, about carbon chain lengths are the alkane of 8 to 14 carbon atoms；T is 0 between 0 to 3, in the present invention；G is selected from glucose,
Fructose and galactolipin, the preferred glucose of the present invention.The degree of polymerization V values of glucose are between 1 to 15 in formula (1).According to this
Invention, the more than percent 80 sugared degree of polymerization are controlled between 1 to 4, and average degree of polymerization is then controlled between 1 to 2.
Meet the compound of formula (1), the alkyl glucosides of for example commercially available BASF of its representative product (BASF)
Glycosides APG, e.g., APG300, APG350, APG500, APG550, APG625, APG810, APG818, APG1200, APG2000.
Alkyl glucoside nonionic surfactant of the present invention preferably using BASF AG produce APG1200 be
Plantacare 1200UP or Plantacare 2000UP.Plantacare 1200UP are a kind of sticky C of muddiness12-14's
The aqueous solution of glycan glycosides, active matter 50%, pH value (20% in 15% isopropanol) 11.5-12.5；Viscosity (40 DEG C) 1000-
6000mPas, density (40 DEG C) 1.07-1.08g/cm3, molecular weight about 420g/mol, free alkyl alcohol≤1%；Plantacare
2000UP is a kind of sticky C of muddiness8-14Glycan glycosides the aqueous solution, active matter 50%, pH value (20% in 15% isopropanol)
11.5-12.5；Viscosity (40 DEG C) 2000-4000mPas, density (40 DEG C) 1.07-1.08g/cm3, molecular weight about 390g/mol,
Free alkyl alcohol≤1%.
Alkyl glucoside of the present invention is a kind of gentle nonionic surfactant, is lived with sulfate type surface in the present invention
Property agent compatibility have the function that reduce surfactant excitant and aid in moisturizing.
It is 0.5% to 10% that alkyl glucoside nonionic surfactant of the present invention, which accounts for composition weight percentage, enters one
Step is optimized for 1% to 8%.
Amphoteric surfactant selected by the present invention includes conventional use of Cocoamidopropyl betaine or cocounut oil both sexes vinegar
Sour sodium, cocounut oil both sexes sodium acetate of the present invention, its structural formula are following (II)：
R2—CONHCH2CH2—N(R2)(R4)(CH2COO—)
Wherein, R2Alkyl in the aliphatic acid obtained selected from coconut oil after hydrolysis, and heptyl, nonyl, 11
Alkyl；R3It is beta-hydroxyethyl, R4It is carboxymethyl.
Or structural formula is following (III)：
R2`—CONHCH2CH2—N(D)(E)
Wherein, D representatives-CH2CH2OX`, E representative-(CH2)Z- Y`, Z=1 or 2, R2Selected from coconut oil by hydrolyzing
Alkyl in the aliphatic acid obtained afterwards, and heptyl, nonyl, undecyl；R3It is beta-hydroxyethyl, R4It is carboxymethyl, X` is selected from
In-CH2CH2- COOH and H atom, Y` is selected from-COOH and-CH2—CHOH—SO3H,；R2`Selected from linseed oil and coconut palm
The aliphatic acid that seed oil obtains after hydrolysis, and alkyl, the alkyl of carbon chain lengths 7,9,11,13, the alkyl of carbon 17 and its different
Structure body and the alkyl of undersaturated carbon 17.
Above-described amphoteric surfactant such as, cocoyl both sexes sodium acetate, lauroyl both sexes sodium acetate, caprinoyl
Base both sexes sodium acetate, cocoyl both sexes sodium propionate, lauroyl both sexes sodium propionate, capryl both sexes sodium propionate etc. belong to this
Individual category.
The amphoteric surfactant used in the present invention produces selected from BASF (BASF) company, its trade name
For：DEHYTON ML-CN, INCI Intemational Nomenclatures are：Sodium cocoamphoacetate, color and luster (APHA) is less than or equal to 3.0, admittedly contain
Measure (%) 35 ± 2, pH value 9.5-10.5, viscosity≤5000, sodium chloride (%) 5.5-7.5.
Amphoteric surfactant of the present invention is at least one of Cocoamidopropyl betaine or cocounut oil both sexes sodium acetate,
It accounts for present composition weight 0.5%-10.0%, is further optimized for 1.0%-8.0%.
Heretofore described cationic polymer is selected from quaternized cellulose ethers derivative, such as Tao Shi JR-400,
LR400, and the copolymerization of the methyl chloride ammonium salt homopolymer of diallyl 2 and the methyl chloride ammonium salt of diallyl 2 and acrylamide
Thing, such as 550 poly- ammonium salt -7 of 100 poly- ammonium salts -6 of Merquat and Merquat of Merck ＆ Co., Inc., the diallyl of BASF AG
Alkyl dimethyl ammonium chloride/acrylamide copolymer (SALCARE Super7), the acrylamido propyl trimethyl chlorine of BASF AG
Change ammonium/acrylamide copolymer (SALCARE SC60), and cationization polysaccharide as be cationized guar gum, sun from
Son is selected from 2,3- epoxypropyltrimethylchloride chlorides.Cation guar gum, sub- Jaguar C13S, Jaguar such as sieve
C14S, or the selective crosslinking homopolymer and copolymer of (methyl) acryloyloxyethyl trimethyl ammonium chloride, such as National Starch
Salcare SC92, a kind of cationic solution (methacryloyloxyethyl three of content being dispersed in mineral oil percent 50
The cross-linked copolymer of ammonio methacrylate and acrylamide), and Salcare SC95 (methacryloyloxyethyl trimethyl ammonia chlorides
The cross-linked homopolymer of ammonium).
According to the present invention, cationic polymer is selected from cation melon xanthan polymer or cationic cellulose polymer, this
Invention cation melon xanthan polymer or cationic cellulose polymer account for composition weight percentage as 0.2%.
Such as, the solvent or polyalcohol contained in deionized water and the aqueous solution is such as cosmetically acceptable carrier in the present invention
C1-C4Alcohol, such as ethanol, isopropanol, the tert-butyl alcohol, n-butanol, polyalcohol such as propane diols or glycol ester etc..
Surfactant used in the present invention, its final pH range be 3 to 10, one-step optimization of going forward side by side be 5 to
8, being further optimized for the pH value of 5.5. systems can be obtained by adding the mediation of organic or inorganic alkali, such as sodium hydroxide, ammonia
Water, brothers tertiary amine, MEA, diethanol amine, triethanolamine, isopropanolamine or 1,3 malonamides, and by adding acid,
Such as carboxylic acids, citric acid etc..
The present invention also includes system viscosity modifier, such as electrolyte or thickener, such as sodium chloride, sodium xylene sulfonate, the Chinese
Rubber, fatty acid alkanol amides (such as coconut monoethanol amide, diglycollic amide), acrylate copolymer, methyl glucosamine polyoxy
Vinethene (120) dioleate etc..Preferred methyl glucosamine APEO (120) dioleate of viscosity modifier of the present invention,
Methyl glucosamine APEO (120) dioleate accounts for the 1.2% of present composition weight.
The present composition can also include the pearling agent or opacifier such as ethylene glycol that percentage by weight is 0.5% to 5%
Monostearate, EGDS, polyethylene glycol mono stearate, polyethylene glycol stearate diester etc., preferably second two
The double stearates of alcohol.
The non-limiting example of chelating agent of the present invention has ethylene glycol tetraacetic disodium, the preferably sodium of ethylene glycol tetraacetic four, second
Glycol tetraacetic disodium (EDTA-2 sodium).
In the present invention it is also an option that property using or comprising the acceptable composition of some cosmetics such as, cation surface activating
Agent, anion or nonionic or cation or amphoteric ion polymer, protein, protein hydrolysate, 18- methyl arachic acids, hydroxyl
Base acid, vitamin, D-pantothenyl aleohol, fatty acid ester, volatilization or non-volatile silicone oil, NMF, anti-dandruff agent or anti-sebum overflow agent, prevent
Agent is shone, Green Tea Extract composition, mineral oil, synthesizes organic grease and mixture.
The present composition can also include a kind of steady foaming agent, selected from carbon 10 to the alcohol of 18,1,2- alkyl of carbon 2, or fat
Fat alkanolamide includes fatty MEA and fatty diethanol amide.The present invention preferably uses coconut monoethanol amide conduct
Foam stabilizer, it is 0.1% to 5% that coconut monoethanol amide, which accounts for composition weight percentage, is further optimized for 0.5% to 2%.
A small amount of material that inventive composition is also possible that such as preservative, essence, pigment are chosen, and meet cosmetics health mark
Quasi- regulation.
In shampoo composite of the present invention, in addition to component described above, mended with water to aequum.
Preparation method：
The shampoo composite of the present invention can pass through any known or other effective preparations for being applied to shampoo composite
Technology is produced, including conventional configuration and hybrid technology.
Application method：
Take about 12 grams of compositions of embodiment I to be uniformly applied on the hair moistened in advance, get foam, then use warm water
Rinse well, this can be repeated as many times as desired using step, the effect of to reach required cleaning, conditioning, moisturizing.
Embodiment
Here is the non-limiting example of shampoo composite of the present invention.These examples are only given the mesh for explanation
, it is impossible to limitation of the invention is interpreted as, because without departing from the spirit and scope of the present invention, can be to this hair
It is bright to carry out many changes.In the embodiment provided, unless stated otherwise, all concentration is all percentage by weight.It is described
Those optional materials that " a small amount of material " refers to, such as preservative, viscosity modifier, pH adjusting agent, essence and flavoring agent, pigment.
The selection of these a small amount of materials is by with the selected material of specific composition and the change of chemical characteristic that are used to prepare the present invention
And change.
Prepare embodiment I-Ⅹ
The preparation of embodiment I-Ⅹ is using conventional shampoo preparation method.
Embodiment I-V
Embodiment VI-Ⅹ
Highly preferred embodiment of the present invention is：
In embodiment I-Ⅹ, moisturizing composite reactive agent each component and content (weight ratio) are：Containing 26% hexylene glycol, contain
(carbohydrate admixture is by monose, oligosaccharide, polysaccharide composition, and monose to 16% carbohydrate admixture：Oligosaccharide：Polysaccharide is with weight
Measure ratio 5：2：1 ratio mixing；Monose is into and fructose by fructose and glucose group：Glucose is with weight than 1：1 ratio is mixed
Close；Oligosaccharide is by sucrose, cyclodextrin composition, and sucrose：Cyclodextrin is with weight than 1：0.5 ratio mixing；Polysaccharide is transparent
Matter acid sodium), containing 10% water-soluble silicon oil (water-soluble silicon oil is PEG/PPG-22/23 dimethyl silicone polymers), containing 8%
(ispol is alanine to ispol：Serine：Glycine：Glutamic acid：Cysteine is with weight than 1：1：
1：0.2：0.1 ratio mixing), containing 4% pyrrolidone sodium carboxylate (Anjidew NL50), containing 2.5% ethoxy urea and surplus
Water.
The checking of hair moistening effect
The selection of volunteer：Moistening effect after hair is had one's hair wash is tested, an important thing is the suitable volunteer of selection.
The type selection (dryness, neutral, oiliness) of volunteer's hair is extremely important.The generation of dry hair often derives from three kinds of feelings
Condition, when it is physiological, two be pathology, third, environment or human factor.Hair is glossy necessary to lose, and can seem more withered
Dry, the dry hair of real heredity is more rare, and only 5% people is exactly drying type hair from birth, and this dry hair is typically more thick
Rough stiff, often the tangled mass because of curling, has no gloss.And the dry hair of vast majority of people belongs to the third type, it is due to
Excessive Exposure to Sunlight, dry wind brush or using shampoo it is improper caused by, therefore dry find as rear, mistakenly occurs for many people
Reduction shampoos are taken, it is expected that the hair oil of naturally secret assembles to get up to moisten hair, a large amount of dandruffs is as a result produced, until stifled
The adipose gland of skin in hair follicle is filled in, causes hair more dry.Therefore, the dry hair of the third situation is selected during present invention selection volunteer
Volunteer, which carries out test, will produce city's tune result of more preferable reference value.
Method of testing：Improvement to dry hair moistness：1- is invalid；2- is general, and (hair is similar with before compared with, can one
Point)；3- good (hair has a little sticking nature after doing, and has texture)；4- is very good, and (hair has sticking nature after doing, and has compared with before
Texture, hair tail hair, which will not be dried, to fly to stick up)；And count the number of " good " and " very good ", if " good " or " very in 10 people
Number well " is that then hair moistness improvement number percentage is 10% to 1 people, the like.
The volunteer of the third the above-mentioned dry heat shape of selection 40, is divided into 4 groups, corresponds to use the embodiment of the present invention II respectively
(first group), VIII (second group), contrast 2 (the 4th groups) of 1 (the 3rd group) and contrast.Evaluated respectively after persistently using one week and two weeks
The number (having one's hair wash 3-4 times weekly) that hair moistness improves, fills in city and adjusts report and counted, be shown in Table 1
Table 1
By table 1, the embodiment of the present invention II (first group), the embodiment of the present invention VIII (second group), present invention contrast 1 (the
Three groups) and the present invention contrast 2 (the 4th groups), persistently using 7 days and 14 days after, felt respectively using 7 days and using 14 days
Official assesses, and as a result shows：The embodiment of the present invention II (first group) and the embodiment of the present invention VIII (second group) and present invention contrast 1
(the 3rd group) and (the 4th group) contrast of present invention contrast 2, the percentage improved using hair moistness after product one week are suitable；Make
After product second week, the embodiment of the present invention II (first group) and the embodiment of the present invention VIII (second group) and the 3rd, the 4th group of phase
Than the percentage showed increased that hair improves number, illustrate that the present invention has good moistening effect for dry hair；Two weeks
The obvious increase also illustrated along with shampoos of the increase of moisturizing number percentage afterwards, the embodiment of the present invention to scalp for growing
Support and moistening effect is also being lifted, therefore the moistening effect of hair increases therewith.
Claims (5)
1. a kind of shampoo composite containing efficient hair moisturizing complexing agent, contains in the shampoo：
(A) account for the composition weight 5%-30% anion surfactant containing sulfate and account for composition weight 1.0%-
8.0% amphoteric surfactant, the sulphate anion surface active agent are sulfated lauryl alcohol, lauryl alcohol polyethylene glycol oxide
The weight ratio of ether sulfate composition, sulfated lauryl alcohol and ethoxylated dodecyl alcohol sulfate is 1:2；
(B) the alkyl glucoside nonionic surfactant of composition weight 1.0% to 8.0% is accounted for；
(C) composition weight 0.5-12% hair moisturizing composite reactive agent, the hair moisturizing composite reactive agent, except aqueous are accounted for
Outside, also include；
(I) composite reactive agent weight 10-28% hexylene glycol is accounted for；
(II) composite reactive agent weight 10-20% carbohydrate admixture is accounted for, the carbohydrate admixture is by monose, oligosaccharide and polysaccharide
Composition, and monose：Oligosaccharide：Polysaccharide is with weight than 5：2：1 ratio mixing；Monose is fructose and glucose, and fructose：Grape
Sugar is with weight than 1：1 ratio mixing；Oligosaccharide is sucrose and cyclodextrin, and sucrose：Cyclodextrin is with weight than 1：0.5 ratio
Mixing；Polysaccharide is Sodium Hyaluronate, and its molecular weight is 400,000 dalton to 2,200,000 dalton；
(III) composite reactive agent weight 3-20% water-soluble silicon oil is accounted for, the water-soluble silicon oil is the poly- diformazans of PEG/PPG-22/23
Radical siloxane；
(IV) account for composite reactive agent weight 5-10% ispol, the ispol be by alanine, serine,
Glycine, glutamic acid, cysteine composition, and alanine：Serine：Glycine：Glutamic acid：Cysteine is with weight than 1：1：
1：0.2：0.1 ratio mixing；
(IV) composite reactive agent weight 1-5% pyrrolidone sodium carboxylate is accounted for；
(V) composite reactive agent weight 0.5-3% ethoxy urea is accounted for；
(D) cationic polymer of composition weight 0.2% is accounted for；
(E) the methyl glucosamine APEO dioleate of composition weight 1.2% is accounted for；
(F) and surplus water.
2. shampoo composite according to claim 1, wherein the amphoteric surfactant is cocamidopropyl propyl amide beet
Alkali or cocounut oil both sexes sodium acetate.
3. shampoo composite according to claim 1, wherein the glycine is trimethylglycine.
4. shampoo composite according to claim 1, wherein the Sodium Hyaluronate molecular weight be 1,000,000 dalton extremely
1800000 dalton.
5. shampoo composite according to claim 1, wherein the cationic polymer is cationic cellulose polymer
Or cationic guar polymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/098694 WO2018045584A1 (en) | 2016-09-12 | 2016-09-12 | Hair moisturising complexing agent-containing shampoo composition |
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| CN107454837A true CN107454837A (en) | 2017-12-08 |
| CN107454837B CN107454837B (en) | 2019-08-20 |
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| WO (1) | WO2018045584A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2597355A (en) * | 2020-05-19 | 2022-01-26 | Henkel Ag & Co Kgaa | Cleaning compositions with a high proportion of natural components |
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| CN1778287A (en) * | 2003-11-26 | 2006-05-31 | 国家淀粉及化学投资控股公司 | Increased moisturization efficacy using hydroxyalkylurea |
| CN101267796A (en) * | 2005-09-16 | 2008-09-17 | 宝洁公司 | Shampoo containing a gel network |
| CN101282708A (en) * | 2005-10-05 | 2008-10-08 | 江崎格力高株式会社 | External preparation for skin containing a phosphorlated saccharide |
| CN104039396A (en) * | 2011-06-13 | 2014-09-10 | 宝洁公司 | PERSONAL CARE COMPOSITIONS COMPRISING A pH TUNEABLE GELLANT AND METHODS OF USING |
| CN104168883A (en) * | 2013-09-12 | 2014-11-26 | 拉芳家化股份有限公司 | Shampoo composition including efficient anti-remval agent |
| CN105078778A (en) * | 2015-07-14 | 2015-11-25 | 拉芳家化股份有限公司 | Anti-dandruff shampoo capable of repairing scalp microecological system and application of anti-dandruff shampoo |
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2016
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- 2016-09-12 WO PCT/CN2016/098694 patent/WO2018045584A1/en active Application Filing
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|---|---|---|---|---|
| CN1778287A (en) * | 2003-11-26 | 2006-05-31 | 国家淀粉及化学投资控股公司 | Increased moisturization efficacy using hydroxyalkylurea |
| CN101267796A (en) * | 2005-09-16 | 2008-09-17 | 宝洁公司 | Shampoo containing a gel network |
| CN101282708A (en) * | 2005-10-05 | 2008-10-08 | 江崎格力高株式会社 | External preparation for skin containing a phosphorlated saccharide |
| CN104039396A (en) * | 2011-06-13 | 2014-09-10 | 宝洁公司 | PERSONAL CARE COMPOSITIONS COMPRISING A pH TUNEABLE GELLANT AND METHODS OF USING |
| CN104168883A (en) * | 2013-09-12 | 2014-11-26 | 拉芳家化股份有限公司 | Shampoo composition including efficient anti-remval agent |
| CN105078778A (en) * | 2015-07-14 | 2015-11-25 | 拉芳家化股份有限公司 | Anti-dandruff shampoo capable of repairing scalp microecological system and application of anti-dandruff shampoo |
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| GB2597355A (en) * | 2020-05-19 | 2022-01-26 | Henkel Ag & Co Kgaa | Cleaning compositions with a high proportion of natural components |
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| WO2018045584A1 (en) | 2018-03-15 |
| CN107454837B (en) | 2019-08-20 |
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