CN105213251A - A kind of anticreep shampoo with hotness - Google Patents

A kind of anticreep shampoo with hotness Download PDF

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Publication number
CN105213251A
CN105213251A CN201510606750.8A CN201510606750A CN105213251A CN 105213251 A CN105213251 A CN 105213251A CN 201510606750 A CN201510606750 A CN 201510606750A CN 105213251 A CN105213251 A CN 105213251A
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anticreep
weight
account
shampoo
active
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CN105213251B (en
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庄严
胡卫华
赵泽华
李洪波
燕道贵
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LAF INTERNATIONAL GROUP Ltd
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LAF INTERNATIONAL GROUP Ltd
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Abstract

The present invention relates to a kind of anticreep shampoo with hotness, this component and content are: (A) accounts for the amphoteric surfactant of composition weight 5.0% to 40%; (B) the alkyl androstanediol surfactant of composition weight 1.0% to 10.0% is accounted for; (C) account for the anticreep active matter of composition weight 0.01% to 10%, described anticreep active matter is the compositions of water, glycerol, sorbitol, Lignum pterocarpi indici bark extract, disodium succinate and glutamic acid; (D) VBE of composition weight 0.01% to 5.0% is accounted for; (E) cationic polymer of composition weight 0.05% to 3.0% is accounted for; (F) surplus is water.The present invention adds anticreep complex, can not only remove the sebum on scalp, also effectively can regulate the liveness of sebaceous gland, bring user hotness, promotes head blood circulation, improves metabolism, promotes to form healthy scalp, safeguards the health of hair.

Description

A kind of anticreep shampoo with hotness
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of anticreep shampoo with hotness.
Background technology
Hair is the first element of human beauty, and alopecia is the great society problem that many people face.Alopecia is the maximum infringement to appearance, can affect the profile of people, reduces captivation and glamour, reduces self-confidence, also can have influence on occupation choice, marriage, even future.Hair derives from the bottom of hair follicle, and hair follicle demonstrates periodic activity, forms the periodicity of natural on-off cycles of hair growth.The growth circulation of hair can be divided into three phases, i.e. trophophase, catagen and resting stage.Be in the hair of trophophase in enlivening growth state, ball top bottom cell division is accelerated, and ball top top cell differentiation is cortex, hair cuticle; Hair papilla increases, cell division is accelerated, increased number, during this hair to increase every day 0.27-0.4mm. enter catagen after the positive hypertrophy of hair stop, form club hair, internal root sheath disappears, and external root sheath is keratinization gradually, and ball top flattens, be not in depression, hair papilla set up reduce, cell number reduce, hair no longer increase and become loosen be easy to come off.During resting stage, the keratinization in Rhizoma Imperatae portion is downward gradually, and be separated with hair papilla, separation place hair follicle shrinks, alopecia.Then, new hair papilla is formed gradually, and hair is the repeated growth cycle again.The hair being in trophophase and resting stage constantly keeps dynamic equilibrium, normally maintains the alopecia within 100 of every day, and hair exception or excessive coming off just cause pathologic alopecia.The trophic factor that internal factor and albumen, aminoacid, the vitamin etc. such as the main cause spiritedness factor of alopecia, congenital heredity factor and hormone lack and seborrheic alopecia.The object of this invention is to provide a kind of shampoo composite, add a kind of derive from plant and biochemical synthesis there is synergistic anti-alopecia complex, the cytotrophy in ball top portion is improved, cytoactive strengthens, division is accelerated, maintain the dynamic equilibrium of natural on-off cycles of hair growth phase and resting stage, add VBE simultaneously, bring user hotness, promote head skin blood circulation, improve scalp metabolism, promote to form healthy scalp and hair, help hair loss patient to return to normal hair loss rate, safeguard the health of hair.
Summary of the invention
The object of this invention is to provide a kind of shampoo composite, said composition has remarkable warm and anticreep effect.
Shampoo of the present invention comprises:
(A) amphoteric surfactant of shampoo gross weight 5.0% to 40% is accounted for;
(B) the alkyl androstanediol surfactant of shampoo gross weight 1.0% to 10.0% is accounted for;
(C) account for the anticreep active matter of shampoo gross weight 0.01% to 10%, described anticreep active matter comprises following component:
Account for the glycerol of anticreep active weight 70-80%;
Account for the sorbitol of anticreep active weight 5-15%;
Account for the Lignum pterocarpi indici bark extract of anticreep active weight 0.1-2%;
Account for the disodium succinate of anticreep active weight 0.1-1%;
Account for the glutamic acid of anticreep active weight 0.01-0.5%;
Anticreep active matter component surplus is water;
(D) VBE of shampoo gross weight 0.01% to 5% is accounted for;
(E) cationic polymer of shampoo gross weight 0.05% to 3.0% is accounted for.
(F) surplus is water
Shampoo composite of the present invention, wherein said anticreep active matter is the compositions of water, glycerol, sorbitol, Lignum pterocarpi indici bark extract, disodium succinate and glutamic acid.
Shampoo composite of the present invention, wherein said amphoteric surfactant is selected from: betaine type amphoteric surfac-tant, imidazoline amophoteric surface active agent and amino acid type surfactant, and its weight ratio is 1:1:3 to 3:3:1.
Shampoo composite of the present invention, wherein said alkyl androstanediol is selected from least one of lauryl glucoside, Coco-Glucoside, decyl glucoside and octyl group/decyl glucoside.
Shampoo composite of the present invention, wherein said cationic polymer is selected from: at least one of cationic cellulose polymer or cationic guar polymer.
The present invention has the anticreep shampoo of hotness, and its preferred ingredient and content are:
Component Content % by weight
Cocamidopropyl propyl amide hydroxyl sulfo betaine 10.0
Cocos nucifera oil acyl both sexes guanidine-acetic acid sodium 8.0
Sodium lauroyl sarcosine 8.0
Decyl glucoside 5.0
Guar gum 0.1
Anticreep active matter 4
VBE 1
Ethylene glycol stearate 1.0
Disodiumedetate 0.1
Citric acid, antiseptic, coloring agent, spice, sodium chloride In right amount
Water Add to 100%
Wherein each component of anticreep active matter and content weight ratio are: the glycerol accounting for anticreep active weight 75%, account for the sorbitol of anticreep active weight 9%, account for the Lignum pterocarpi indici bark extract of anticreep active weight 0.6%, account for the disodium succinate of anticreep active weight 0.2%, account for glutamic acid and the excess water of anticreep active weight 0.05%.
Compared with prior art, the present invention has advantage:
Shampoo of the present invention, special interpolation is a kind of derive from plant and biochemical synthesis there is synergistic anticreep complex, patient can be helped to recover the normal rates of natural on-off cycles of hair growth phase and resting stage, alleviate alopecia, add VBE simultaneously, bring user hotness, promote head skin blood circulation, improve scalp metabolism, promote to form healthy hair and scalp, help de-originator to return to normal hair loss rate.
Detailed description of the invention
To be described in detail to compositional selecting of the present invention and effect below.
Shampoo composite of the present invention contains and accounts for composition weight 0.01% to 10%, the anticreep active matter of preferred 3-5%, described anticreep active matter is limpid light yellow liquid, with faint odor, under 20 DEG C of conditions, its index of refraction is 1.358-1.368, loss on drying is 8.0-14.0%, and pH value is 5.5-6.5, and nitrogen content is 0.75-1.25%.Described anticreep active matter specifically forms and active as follows: Lignum pterocarpi indici bark extract contains steroid class glucoside and alcohols, can automatic emulsified oils and fats, effectively irritation cell, makes tissue regeneration, plays the effect of antiinflammatory; Disodium succinate, glycerol, sorbitol, glutamate source, in biosynthesis, can reduce smegma, the generation of oil-control.
Containing accounting for composition weight 0.01% to 5% in shampoo composite of the present invention, the preferably VBE of 0.1 to 2%, described VBE is colourless to weak yellow liquid, fragrance is the Radix Aucklandiae slightly hay-scented, its relative density (D20/20) is 1.052-1.072, index of refraction (n20/D) is 1.511-1.521, and content is >=98%, flash-point >=154 DEG C.Described VBE has safer hotness effect, and can improve heat retaining and exothermal effect, gentleness does not stimulate.
Containing accounting for the cocamidopropyl propyl amide hydroxyl sulfo betaine of composition weight 5.0% to 40%, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium and sodium lauroyl sarcosine in shampoo composite of the present invention, its ratio is 1:1:1.
Described cocamidopropyl propyl amide hydroxyl sulfo betaine is called for short CAB, and be light yellow transparent liquid, pure odorlessness, the active matter content of its commercially available prod is 30%, and inorganic salt content is less than 6.0%, and the pH of 10% aqueous solution is 4.5-6.0.Described cocos nucifera oil acyl both sexes guanidine-acetic acid sodium is colourless to micro-yellow transparent thick liquid, the active matter content of its commercially available prod is 30%, under 25 DEG C of conditions, its viscosity is 5000-10000, sodium chloride content is less than 9.0%, the pH of 1% aqueous solution is 6.0-8.0, and its structural formula is RN (CH2COONa) 2.Described institute sodium lauroyl sarcosine is colourless pure odorlessness liquid, and the active matter content of its commercially available prod is 30%, and inorganic salt content is less than 0.2%, and the pH of 10% aqueous solution is 7.0-9.0.The zest of described amphoteric surfactant is low, gentle especially to skin, eyes, matches can significantly reduce its zest with anion surfactant, and there is good foaming power, foaming abundancy is fine and closely woven, and skinfeel is good, significantly can improve the foam state of formula system.The composite use of described cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium and sodium lauroyl sarcosine has good foam and skin-friendliness, zest is dropped to minimum.
Shampoo composite of the present invention contains and accounts for composition weight 01.0% to 10.0%, preferred 3-7%'s
Alkyl androstanediol surfactant.Described alkyl androstanediol comprises lauryl glucoside, Coco-Glucoside, decyl glucoside and octyl group/decyl glucoside, preferred decyl glucoside, its outward appearance is the viscous liquid of light yellow muddiness, the active matter content of its commercially available prod is 51%-55%, the pH value of its 15% aqueous isopropanol of 20% is 11.5-12.5, under 25 DEG C of conditions, its viscosity is 1000-6000.Described decyl glucoside comes from natural, has remarkable gentle cleaning capacity, can improve the foaming properties of shampoo.Improve quantity and the foam stability of foam.
Shampoo composite of the present invention contains and accounts for composition weight 0.05% to 3.0%, the cationic polymer of preferred 0.1-1.5%.Described cationic polymer is selected from: at least one in cationic cellulose polymer, cationic guar polymer, preferred cationic guar gum.Described cation melon glue is the product will obtained after quaternized for melon glue, its key component is melon glue hydroxypropyltrimonium chloride, a series of cation melon glue product can be obtained according to the difference of substitution value, preferred substitution value is 0.1 to 0.2, nitrogen content is 1.3-1.7%, for cation melon glue of the present invention under 25 DEG C of conditions, the viscosity of its 1% aqueous solution is 3500mPa.s to 4500mPa.s; Described cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, difference according to degree ofacationic substitution can be divided into: high-cation substitution value JR, cationic substitution value LR and low degree ofacationic substitution LK tri-kinds of models, the cationic cellulose of preferred cationic substitution value.
Shampoo composite of the present invention can also comprise other optional components, comprises pearling agent, viscosity-controlling agent, chelating agen, pH adjusting agent, antiseptic, pigment and spice etc.Described pearling agent accounts for 0.05% to 3.0% of composition weight, the non-limiting example of described pearling agent has: the zinc oxide of ethylene glycol stearate monoesters and ethylene glycol stearate, monostearate and Palmic acid propylene glycol ester and glyceride, stearic acid alkylolamides magnesium stearate, fine dispersion and titanium dioxide, preferred ethylene glycol stearate.Described viscosity-controlling agent accounts for 0.1% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, sodium sulfate, ammonium phosphate, hydroxyethyl-cellulose, hydroxypropyl cellulose, acrylic acid and long chain alkyl methacrylate copolymer, acrylates/stearic alcohol ether-20/ methacrylate copolymer, methyl glucosamine polyoxyethylene ether (120) dioleate etc.Described chelating agen accounts for 0.01% to 0.30% of composition weight, and the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, sodium versenate, tetrasodium ethylenediamine tetraacetate etc., preferred disodiumedetate; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system 5.0 to 8.0, preferably 5.5 to 6.5; Choosing of described antiseptic, essence, pigment, meets the regulation of hygienic standards for cosmetics, selects safe raw material.
In shampoo composite of the present invention, except the above component, mend to aequum with water.
Preparation method
Anticreep shampoo of the present invention can by any known or other be effectively applicable to provide the technology of shampoo composite to prepare, the method preparing anticreep shampoo of the present invention comprises conventional preparation and hybrid technology.
Using method
Anticreep shampoo of the present invention uses in the mode that is clean and conditioning hair of routine, mainly comprises following step:
(A) with water by hair moistening;
(B) on described hair, use the shampoo composite of the aforementioned any one claim of effective dose, the scope of described effective dose is generally 1 gram to 50 grams, preferably 2 to 20 grams;
(C) with the shampoo composite on hair described in water rinse.
These steps can repeatedly repeatedly, to reach effect of sought warm and anticreep.
Embodiment
Here is the non-limiting example of anticreep shampoo composite of the present invention.The providing of these embodiments is only used to the object illustrated, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, pigment etc., the selection of these a small amount of materials changes along with selected in order to prepare the physics and chemistry characteristic of special component of the present invention.
Preparation embodiment I-Ⅹ
The suitable method preparing anticreep shampoo composite described in embodiment I-Ⅹ is as follows: suitable quantity of water joined in retort, add guar gum under slow stirring to disperse, slowly be stirred and heated to 60 DEG C to 80 DEG C, then add pH adjusting agent (such as citric acid), cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium, sodium lauroyl sarcosine, decyl glucoside, ethylene glycol stearate, disodiumedetate (if using these materials), make these materials disperse rear cooling completely.Treat temperature be down to less than 50 DEG C add anticreep active matter, the VBE be dissolved in essence, dispersed with stirring is even, then adds antiseptic, pigment etc. and continue to stir, and guarantees to obtain uniform mixture.After adding all components, can add viscosity modifier and pH adjusting agent as required, the viscosity of adjustment product and pH are to suitable degree.Optionally finally can add a small amount of water to supply.
Embodiment I-V
Embodiment VI-Ⅹ
Most preferred embodiment of the present invention is:
Component Content % by weight
Cocamidopropyl propyl amide hydroxyl sulfo betaine 12.0
Cocos nucifera oil acyl both sexes guanidine-acetic acid sodium 10.0
Sodium lauroyl sarcosine 8.0
Decyl glucoside 5.0
Guar gum 0.1
Anticreep active matter 4
VBE 1
Ethylene glycol stearate 1.0
Disodiumedetate 0.1
Citric acid, antiseptic, coloring agent, spice, sodium chloride In right amount
Water Add to 100%
In embodiment I-Ⅹ and most preferred embodiment, each component of anticreep active matter and content (weight ratio) are: the glycerol accounting for anticreep active weight 75%, account for the sorbitol of anticreep active weight 9%, account for the Lignum pterocarpi indici bark extract of anticreep active weight 0.6%, account for the disodium succinate of anticreep active weight 0.2%, account for glutamic acid and the excess water of anticreep active weight 0.05%.
Sense organ physical and chemical index
Project Detect data
Outward appearance Milky pearlescent liquid
PH value 5.5-6.5
Foam 100-170mm
Viscosity 5000-10000mpa·s
Heat-resistant stability (40 ± 1) DEG C keep 4 weeks, return to after room temperature without segregation phenomenon
Cold-resistant stability -2 DEG C--5 DEG C keep 4 weeks, without dividing a separating water phenomenon after returning to room temperature
Sanitary index Every be qualified
The checking of anticreep effect
Method of testing: select 40 volunteers having alopecia, require without irritated, without the scalp health patient of wound, unsystematic local disease, by image viewing, the trophophase of its patient's hair and the ratio of resting stage are lower than normal condition.Before on probation, sense organ and hair image evaluation carried out to patient, allows patient use the most preferred embodiment shampoo of invention, continue use 112 days, carry out sensory evaluation and hair image evaluation the 56th day and 112 days.In process on probation, volunteer, according to frequency usage this shampoo of normally washing hair at ordinary times, requires that this shampoo can to rest on hair 3-5 minute and carry out soft scalp massage, and then clean with warm water washing.For using the hair sensory evaluation of volunteer before and after this shampoo in table 1, table 2 and hair image evaluation in table 3:
Table 1
Table 2
Table 3

Claims (4)

1. have an anticreep shampoo for hotness, its component and content are:
(A) amphoteric surfactant of shampoo gross weight 5.0% to 40% is accounted for;
(B) the alkyl androstanediol surfactant of shampoo gross weight 1.0% to 10.0% is accounted for;
(C) account for the anticreep active matter of shampoo gross weight 0.01% to 10%, described anticreep active matter comprises following component:
Account for the glycerol of anticreep active weight 70-80%;
Account for the sorbitol of anticreep active weight 5-15%;
Account for the Lignum pterocarpi indici bark extract of anticreep active weight 0.1-2%;
Account for the disodium succinate of anticreep active weight 0.1-1%;
Account for the glutamic acid of anticreep active weight 0.01-0.5%;
Anticreep active matter component surplus is water;
(D) VBE of shampoo gross weight 0.01% to 5% is accounted for;
(E) cationic polymer of shampoo gross weight 0.05% to 3.0% is accounted for,
(F) surplus is water.
2. shampoo according to claim 1, wherein amphoteric surfactant is cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium and sodium lauroyl sarcosine, and its weight ratio is: 1:1:3 to 3:3:1.
3. shampoo according to claim 1, wherein said cationic polymer is selected from: cationic cellulose polymer or cationic guar polymer.
4. have an anticreep shampoo for hotness, its component and content are:
Wherein each component of anticreep active matter and content weight ratio are: the glycerol accounting for anticreep active weight 75%, account for the sorbitol of anticreep active weight 9%, account for the Lignum pterocarpi indici bark extract of anticreep active weight 0.6%, account for the disodium succinate of anticreep active weight 0.2%, account for glutamic acid and the excess water of anticreep active weight 0.05%.
CN201510606750.8A 2015-09-22 2015-09-22 A kind of anticreep shampoo with thermal sensation Active CN105213251B (en)

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WO2019166020A1 (en) * 2018-03-02 2019-09-06 新钰生技股份有限公司 Composition containing vanillyl alkyl ether and application thereof
CN111278499A (en) * 2017-11-02 2020-06-12 日写株式会社 Microneedle sheet and method for producing the same

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