CN104257596A - Mild oil-control shampoo with cool feeling - Google Patents

Mild oil-control shampoo with cool feeling Download PDF

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Publication number
CN104257596A
CN104257596A CN201410471675.4A CN201410471675A CN104257596A CN 104257596 A CN104257596 A CN 104257596A CN 201410471675 A CN201410471675 A CN 201410471675A CN 104257596 A CN104257596 A CN 104257596A
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weight
account
composition
containing
oil
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CN201410471675.4A
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Chinese (zh)
Inventor
庄严
胡卫华
赵泽华
李洪波
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拉芳家化股份有限公司
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Priority to CN201410471675.4A priority Critical patent/CN104257596A/en
Publication of CN104257596A publication Critical patent/CN104257596A/en

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Abstract

The invention relates to mild oil-control shampoo with cool feeling. The shampoo comprises the following ingredients in percentage: (A) an ampholytic surfactant accounting for 5.0-40% of weight of a composition; (B) an alkyl polyglycoside surfactant accounting for 1.0-10.0% of weight of the composition; (C) an oil-control active matter accounting for 0.05-8% of weight of the composition, wherein the oil-control active matter is a composition of water, nicotinamide, a yeast extract, an aesculus hippocastanum extract, ammonium glycyrrhetate, panthenol, propylene glycol, zinc gluconate and caffeine; (D) mint lactate accounting for 0.1-10% of weight of the composition; (E) a cationic polymer accounting 0.05-3.0% of weight of the composition; and (F) the balance being water. The oil-control composition disclosed by the invention not only can remove sebum from scalp but also can effectively regulate the activity of sebaceous gland, so as to bring about cool and clean feeling to a user, keep hair fresh and delay re-greasiness time of hair; and the shampoo is mild and nonirritant.

Description

A kind of gentleness control salted cake fried in sesame oil ripple with refrigerant sense

Technical field

The invention belongs to household chemicals field, be specifically related to a kind of gentleness control salted cake fried in sesame oil ripple with refrigerant sense.

Background technology

Healthy scalp ecological environment is maintained by the balance of finance, credits and materials: oils and fats, flora, metabolic balance.When balancing destroyed, just there will be scalp pomade, head pruritus, dandruff many, etc. the unbalance scalp problems caused of scalp ecological environment.The human hair of oiliness scalp also can be very greasy, and whole head is all oil oil, and hair just seems not angry and lacks flexibility, plain.Control oil just refers to the fat content of adjustment scalp secretion, and this just needs and aly can meet hair and love fuel-displaced demand, them can be helped to repair not angry, inelastic hair.

Most of oil-controlling shampoo is all that the simple control oil component that adds gives control oily function on the basis of common shampoo in the market, is difficult to like this tackle the problem at its root.The object of this invention is to provide a kind of shampoo composite, add a kind of derive from plant and biochemical synthesis there is the oily complex of synergistic control, the sebum on scalp can not only be removed, also the liveness of sebaceous gland can effectively be regulated, reduce the secretion of sebum, add Herba Menthae lactate simultaneously, bring user refrigerant clean refreshing sensation, keep hair pure and fresh, extend the greasy again time of hair.

Summary of the invention

The object of this invention is to provide a kind of shampoo composite, said composition has remarkable control oil and refrigerant effect.

Shampoo of the present invention comprises:

(A) amphoteric surfactant of composition weight 5.0% to 40% is accounted for;

(B) the alkyl androstanediol surfactant of composition weight 1.0% to 10.0% is accounted for;

(C) account for the control oil active matter of composition weight 0.05% to 8%, described control oil active matter comprises following component:

Account for the nicotiamide controlling oily active weight 5-10%;

Account for the yeast extract controlling oily active weight 5-10%;

Account for the Aesculus hippocastanum L. extract controlling oily active weight 5-10%;

Account for the ammonium glycyrrhizinate controlling oily active weight 1-5%;

Account for the pantothenylol controlling oily active weight 1-5%;

Account for the propylene glycol controlling oily active weight 1-5%;

Account for the zinc gluconate controlling oily active weight 1-5%;

Account for the caffeine controlling oily active weight 0.1-1%;

(D) the Herba Menthae lactate of composition weight 0.1% to 10% is accounted for;

(E) cationic polymer of composition weight 0.05% to 3.0% is accounted for.

(F) surplus is water

Shampoo composite of the present invention, wherein said control oil active matter is the compositions of nicotiamide, yeast extract, Aesculus hippocastanum L. extract, ammonium glycyrrhizinate, pantothenylol, propylene glycol, zinc gluconate, caffeine.

Shampoo composite of the present invention, wherein said amphoteric surfactant is selected from: betaine type amphoteric surfac-tant, imidazoline amophoteric surface active agent and amino acid type surfactant, and its weight ratio is 1:1:3 to 3:3:1.

Shampoo composite of the present invention, wherein said alkyl androstanediol is selected from least one of lauryl glucoside, Coco-Glucoside, decyl glucoside and octyl group/decyl glucoside.

Shampoo composite of the present invention, wherein said cationic polymer is selected from: at least one of cationic cellulose polymer or cationic guar polymer.

The present invention has the gentleness control salted cake fried in sesame oil ripple of refrigerant sense, and its preferred ingredient and content are:

Wherein control each component of oily active matter and content weight ratio is: containing the nicotiamide of 8%, containing the yeast extract of 8%, containing the Aesculus hippocastanum L. extract of 6%, containing the ammonium glycyrrhizinate of 3%, containing the pantothenylol of 2%, containing the propylene glycol of 4%, containing the zinc gluconate of 3%, containing caffeine and the excess water of 0.6%.

Compared with prior art, the present invention has advantage:

Shampoo of the present invention, special interpolation is a kind of derive from plant and biochemical synthesis there is the oily complex of synergistic control, the sebum on scalp can not only be removed, also the liveness of sebaceous gland can effectively be regulated, reduce the secretion of sebum, add Herba Menthae lactate simultaneously, bring user refrigerant clean refreshing sensation, keep hair pure and fresh, extend the greasy again time of hair.

Detailed description of the invention

To be described in detail to compositional selecting of the present invention and effect below.

Shampoo composite of the present invention contains and accounts for composition weight 0.05% to 8%, the control oil active matter of preferred 3-5%, the oily active matter of described control is limpid light yellow liquid, with faint odor, under 20 DEG C of conditions, its index of refraction is 1.358-1.368, loss on drying is 8.0-14.0%, and pH value is 5.5-6.5, and nitrogen content is 0.75-1.25%.The oily active matter of described control specifically forms and active as follows: yeast extract contains active component sulfuration peptide ammino acid can regulate fat secretion; Nicotiamide, pantothenylol, propylene glycol, caffeine derive from biosynthesis, can reduce smegma, the generation of oil-control; Zinc gluconate derives from biosynthesis, can regulate fat secretion; Aesculus hippocastanum L. extract and ammonium glycyrrhizinate contain steroid class glucoside, can automatic emulsified oils and fats, play the effect of antiinflammatory.

Containing accounting for composition weight 0.1% to 10% in shampoo composite of the present invention, the preferably Herba Menthae lactate of 0.3 to 5%, described Herba Menthae lactate is that pale is to white crystal, under 20 DEG C of conditions, its specific rotatory power is 78-85 degree ml/g, freezing point is 42-44 degree Celsius, acid number is≤2.0, and content is >=98%, flash-point >=100 DEG C.Described menthyl lactate has long-acting refrigerant effect, and provide pleasant cooling sensation, gentleness does not stimulate.

Containing accounting for the cocamidopropyl propyl amide hydroxyl sulfo betaine of composition weight 5.0% to 40%, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium and sodium lauroyl sarcosine in shampoo composite of the present invention, its ratio is 1:1:1.

Described cocamidopropyl propyl amide hydroxyl sulfo betaine is called for short CAB, and be light yellow transparent liquid, pure odorlessness, the active matter content of its commercially available prod is 30%, and inorganic salt content is less than 6.0%, and the pH of 10% aqueous solution is 4.5-6.0.Described cocos nucifera oil acyl both sexes guanidine-acetic acid sodium is colourless to micro-yellow transparent thick liquid, the active matter content of its commercially available prod is 30%, under 25 DEG C of conditions, its viscosity is 5000-10000, sodium chloride content is less than 9.0%, the pH of 1% aqueous solution is 6.0-8.0, and its structural formula is RN (CH2COONa) 2.Described institute sodium lauroyl sarcosine is colourless pure odorlessness liquid, and the active matter content of its commercially available prod is 30%, and inorganic salt content is less than 0.2%, and the pH of 10% aqueous solution is 7.0-9.0.The zest of described amphoteric surfactant is low, gentle especially to skin, eyes, matches can significantly reduce its zest with anion surfactant, and there is good foaming power, foaming abundancy is fine and closely woven, and skinfeel is good, significantly can improve the foam state of formula system.The composite use of described cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium and sodium lauroyl sarcosine has good foam and skin-friendliness, zest is dropped to minimum.

Shampoo composite of the present invention contains and accounts for composition weight 01.0% to 10.0%, the alkyl androstanediol surfactant of preferred 3-7%.Described alkyl androstanediol comprises lauryl glucoside, Coco-Glucoside, decyl glucoside and octyl group/decyl glucoside, preferred decyl glucoside, its outward appearance is the viscous liquid of light yellow muddiness, the active matter content of its commercially available prod is 51%-55%, the pH value of its 15% aqueous isopropanol of 20% is 11.5-12.5, under 25 DEG C of conditions, its viscosity is 1000-6000.Described decyl glucoside comes from natural, has remarkable gentle cleaning capacity, can improve the foaming properties of shampoo.Improve quantity and the foam stability of foam.

Shampoo composite of the present invention contains and accounts for composition weight 0.05% to 3.0%, the cationic polymer of preferred 0.1-1.5%.Described cationic polymer is selected from: at least one in cationic cellulose polymer, cationic guar polymer, preferred cationic guar gum.Described cation melon glue is the product will obtained after quaternized for melon glue, its key component is melon glue hydroxypropyltrimonium chloride, a series of cation melon glue product can be obtained according to the difference of substitution value, preferred substitution value is 0.1 to 0.2, nitrogen content is 1.3-1.7%, for cation melon glue of the present invention under 25 DEG C of conditions, the viscosity of its 1% aqueous solution is 3500mPa.s to 4500mPa.s; Described cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, difference according to degree ofacationic substitution can be divided into: high-cation substitution value JR, cationic substitution value LR and low degree ofacationic substitution LK tri-kinds of models, the cationic cellulose of preferred cationic substitution value.

Shampoo composite of the present invention can also comprise other optional components, comprises pearling agent, viscosity-controlling agent, chelating agen, pH adjusting agent, antiseptic, pigment and spice etc.Described pearling agent accounts for 0.05% to 3.0% of composition weight, the non-limiting example of described pearling agent has: the zinc oxide of ethylene glycol stearate monoesters and ethylene glycol stearate, monostearate and Palmic acid propylene glycol ester and glyceride, stearic acid alkylolamides magnesium stearate, fine dispersion and titanium dioxide, preferred ethylene glycol stearate.Described viscosity-controlling agent accounts for 0.1% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, sodium sulfate, ammonium phosphate, hydroxyethyl-cellulose, hydroxypropyl cellulose, acrylic acid and long chain alkyl methacrylate copolymer, acrylates/stearic alcohol ether-20/ methacrylate copolymer, methyl glucosamine polyoxyethylene ether (120) dioleate etc.Described chelating agen accounts for 0.01% to 0.30% of composition weight, and the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, sodium versenate, tetrasodium ethylenediamine tetraacetate etc., preferred disodiumedetate; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system 5.0 to 8.0, preferably 5.5 to 6.5; Choosing of described antiseptic, essence, pigment, meets the regulation of hygienic standards for cosmetics, selects safe raw material.

In shampoo composite of the present invention, except the above component, mend to aequum with water.

Preparation method

Control salted cake fried in sesame oil ripple of the present invention can by any known or other be effectively applicable to provide the technology of shampoo composite to prepare, the method preparing control salted cake fried in sesame oil ripple of the present invention comprises conventional preparation and hybrid technology.

Using method

Control salted cake fried in sesame oil ripple of the present invention uses in the mode that is clean and conditioning hair of routine, mainly comprises following step:

(A) with water by hair moistening;

(B) on described hair, use the shampoo composite of the aforementioned any one claim of effective dose, the scope of described effective dose is generally 1 gram to 50 grams, preferably 2 to 20 grams;

(C) with the shampoo composite on hair described in water rinse.

These steps can repeatedly repeatedly, to reach effect of sought clean and control oil.

Embodiment

Here is the non-limiting example of the oily shampoo composite of control of the present invention.The providing of these embodiments is only used to the object illustrated, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, pigment etc., the selection of these a small amount of materials changes along with selected in order to prepare the physics and chemistry characteristic of special component of the present invention.

Preparation embodiment I-Ⅹ

Suitable to prepare the method controlling oily shampoo composite described in embodiment I-Ⅹ as follows: suitable quantity of water joined in retort, add Polyquaternium-10 under slow stirring to disperse, slowly be stirred and heated to 60 DEG C to 80 DEG C, then pH adjusting agent (such as citric acid) is added, Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, cocoamido propyl hydroxy sulfobetaine, lauryl both sexes sodium acetate, fatty monoethanol amide, CTAB, pearlescent flake, disodiumedetate (if using these materials), these materials are made to disperse rear cooling completely.Anti-dandruff agent Bispyrithione is added when temperature is down to about 65 DEG C, be cooled to after being uniformly dispersed that less than 50 DEG C add polydimethylsiloxane, nourishing additive agent is uniformly dispersed, add antiseptic, pigment, essence etc. again to continue to stir, guarantee to obtain uniform mixture.After adding all components, can add viscosity modifier and pH adjusting agent as required, the viscosity of adjustment product and pH are to suitable degree.Optionally finally can add a small amount of water to supply.

Embodiment I-V

Embodiment VI-Ⅹ

Most preferred embodiment of the present invention is:

The each component of oily active matter is controlled and content (weight ratio) is: containing the nicotiamide of 8% in embodiment I-Ⅹ and most preferred embodiment, containing the yeast extract of 8%, containing the Aesculus hippocastanum L. extract of 6%, containing the ammonium glycyrrhizinate of 3%, containing the pantothenylol of 2%, containing the propylene glycol of 4%, containing the zinc gluconate of 3%, containing caffeine and the excess water of 0.6%.

Sense organ physical and chemical index

Control the checking of oily effect

Method of testing: select the volunteer of 40 oily hairs, require without irritated, without the scalp health patient of wound, unsystematic local disease, measured by sebum, mensuration scalp enliven sebum excretion rate.Patient is divided into 2 groups, allows patient use the most preferred embodiment shampoo of common shampoo and invention, continue use 28 days, at 15 minutes of the 0th day and 28 days, 8 hours, within 24 hours, carry out the measurement of scalp sebum secretion and the sensory testing of consumer.In process on probation, volunteer, according to frequency usage this shampoo of normally washing hair at ordinary times, requires that this shampoo can to rest on hair 3-5 minute and carry out soft scalp massage, and then clean with warm water washing.For using the sebum secretion measurement of volunteer before and after this shampoo in table 1 and hair sensory evaluation in table 2.

Table 1

Table 2

? 15 minutes 8 hours 24 hours Very salubrious 30 people 25 people 20 people Clearly 8 people 10 people 15 people Clouding 2 people 5 people 5 people

Claims (4)

1. have a gentleness control salted cake fried in sesame oil ripple for refrigerant sense, its component and content are:
(A) amphoteric surfactant of composition weight 5.0% to 40% is accounted for;
(B) the alkyl androstanediol surfactant of composition weight 1.0% to 10.0% is accounted for;
(C) account for the control oil active matter of composition weight 0.05% to 8%, described control oil active matter comprises following component:
Account for the nicotiamide controlling oily active weight 5-10%;
Account for the yeast extract controlling oily active weight 5-10%;
Account for the Aesculus hippocastanum L. extract controlling oily active weight 5-10%;
Account for the ammonium glycyrrhizinate controlling oily active weight 1-5%;
Account for the pantothenylol controlling oily active weight 1-5%;
Account for the propylene glycol controlling oily active weight 1-5%;
Account for the zinc gluconate controlling oily active weight 1-5%;
Account for the caffeine controlling oily active weight 0.1-1%;
(D) the Herba Menthae lactate of composition weight 0.1% to 10% is accounted for;
(E) cationic polymer of composition weight 0.05% to 3.0% is accounted for,
(F) surplus is water.
2. shampoo according to claim 1, wherein amphoteric surfactant is cocamidopropyl propyl amide hydroxyl sulfo betaine, cocos nucifera oil acyl both sexes guanidine-acetic acid sodium and sodium lauroyl sarcosine, and its weight ratio is: 1:1:3 to 3:3:1.
3. shampoo according to claim 1, wherein said cationic polymer is selected from: cationic cellulose polymer or cationic guar polymer.
4. have a gentleness control salted cake fried in sesame oil ripple for refrigerant sense, its component and content are:
Wherein control each component of oily active matter and content weight ratio is: containing the nicotiamide of 8%, containing the yeast extract of 8%, containing the Aesculus hippocastanum L. extract of 6%, containing the ammonium glycyrrhizinate of 3%, containing the pantothenylol of 2%, containing the propylene glycol of 4%, containing the zinc gluconate of 3%, containing caffeine and the excess water of 0.6%.
CN201410471675.4A 2014-09-16 2014-09-16 Mild oil-control shampoo with cool feeling CN104257596A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104997644A (en) * 2015-07-14 2015-10-28 拉芳家化股份有限公司 Oil-control spray for hair and skin
CN105213251A (en) * 2015-09-22 2016-01-06 拉芳家化股份有限公司 A kind of anticreep shampoo with hotness
CN106619310A (en) * 2017-01-11 2017-05-10 杭州菲丝凯化妆品有限公司 Moisturizing oil-control spray and preparation method thereof
CN107496317A (en) * 2017-07-22 2017-12-22 深圳诺漫斯生物科技有限公司 A kind of restoration care shampoo of the active component containing American cockroach
CN107693389A (en) * 2017-09-22 2018-02-16 拉芳家化股份有限公司 A kind of shampoo composite containing the oil-control factor
CN107898666A (en) * 2017-10-11 2018-04-13 拉芳家化股份有限公司 A kind of restoring consciouness of high-content geraniol plants essential oil synergy, anticreep hair-care shampoo

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CN1214628A (en) * 1996-01-29 1999-04-21 庄臣消费者有限公司 Detergent compositions
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CN101536969A (en) * 2009-04-08 2009-09-23 江苏省制盐工业研究所 Salt Chinese herbal medicine paste shampoo
CN103126935A (en) * 2013-03-21 2013-06-05 上海滇虹药业有限公司 Two-in-one shampoo and preparation method thereof
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104997644A (en) * 2015-07-14 2015-10-28 拉芳家化股份有限公司 Oil-control spray for hair and skin
CN105213251A (en) * 2015-09-22 2016-01-06 拉芳家化股份有限公司 A kind of anticreep shampoo with hotness
CN105213251B (en) * 2015-09-22 2017-11-07 拉芳家化股份有限公司 A kind of anticreep shampoo with thermal sensation
CN106619310A (en) * 2017-01-11 2017-05-10 杭州菲丝凯化妆品有限公司 Moisturizing oil-control spray and preparation method thereof
CN107496317A (en) * 2017-07-22 2017-12-22 深圳诺漫斯生物科技有限公司 A kind of restoration care shampoo of the active component containing American cockroach
CN107693389A (en) * 2017-09-22 2018-02-16 拉芳家化股份有限公司 A kind of shampoo composite containing the oil-control factor
CN107898666A (en) * 2017-10-11 2018-04-13 拉芳家化股份有限公司 A kind of restoring consciouness of high-content geraniol plants essential oil synergy, anticreep hair-care shampoo

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Application publication date: 20150107