CN107693389A - A kind of shampoo composite containing the oil-control factor - Google Patents

A kind of shampoo composite containing the oil-control factor Download PDF

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Publication number
CN107693389A
CN107693389A CN201710864408.7A CN201710864408A CN107693389A CN 107693389 A CN107693389 A CN 107693389A CN 201710864408 A CN201710864408 A CN 201710864408A CN 107693389 A CN107693389 A CN 107693389A
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CN
China
Prior art keywords
oil
accounted
composition weight
control
shampoo composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710864408.7A
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Chinese (zh)
Inventor
胡卫华
庄严
李洪波
赵泽华
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LAF INTERNATIONAL GROUP Ltd
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LAF INTERNATIONAL GROUP Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LAF INTERNATIONAL GROUP Ltd filed Critical LAF INTERNATIONAL GROUP Ltd
Priority to CN201710864408.7A priority Critical patent/CN107693389A/en
Publication of CN107693389A publication Critical patent/CN107693389A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365Hydroxycarboxylic acids; Ketocarboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/602Glycosides, e.g. rutin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/008Preparations for oily hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/596Mixtures of surface active compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/74Biological properties of particular ingredients
    • A61K2800/78Enzyme modulators, e.g. Enzyme agonists
    • A61K2800/782Enzyme inhibitors; Enzyme antagonists

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to a kind of shampoo composite containing the oil-control factor, the component and content are:(A) amphoteric surfactant of composition weight 5.0% to 40% is accounted for;(B) the alkyl glucoside surfactant of composition weight 1.0% to 10.0% is accounted for;(C) the oil-control active matter of composition weight 0.05% to 8% is accounted for, the oil-control active matter is the hydracrylic acid zinc of L 2;(D) cationic polymer of composition weight 0.05% to 3.0% is accounted for;(E) surplus is water.Present invention addition oil-control factor composition, energy active balance fat secretion and oil-control, fine, soft fur hole Glycerin simultaneously can be received, allows skin lipids to reach optimal poised state with moisture, maintain the salubrious comfortable sensation of skin.

Description

A kind of shampoo composite containing the oil-control factor
Technical field
The invention belongs to household chemicals field, and in particular to a kind of shampoo composite containing the oil-control factor.
Background technology
The scalp ecological environment of health is maintained by the balance of finance, credits and materials:Grease, flora, metabolic balance.When balance is destroyed, just Occur hair oil, head are itched, dandruff is more, etc. scalp ecological environment it is unbalance caused by scalp problems.The human hair of oiliness scalp also can Very greasy, whole head is all oily, and hair just seems not angry and lacked flexibility, plain.Oil-control just refers to adjust The fat content of scalp secretion, this requires a demand that disclosure satisfy that hair love is fuel-displaced, them can be helped to repair and do not had Animando, inelastic hair.
It is an object of the invention to provide a kind of shampoo composite, adds a kind of factor component containing oil-control, can not only remove head Sebum on skin, the liveness of sebaceous glands also can be effectively adjusted, suppress glyceryl ester in bacterial fatty enzymatic sebum and decompose Into free fatty, the secretion of sebum is reduced.
The content of the invention
It is an object of the invention to provide a kind of shampoo composite, said composition has remarkable oil-control effect.
Shampoo of the present invention includes:
(A) amphoteric surfactant of composition weight 5.0% to 40% is accounted for;
(B) the alkyl glucoside surfactant of composition weight 1.0% to 10.0% is accounted for;
(C) the oil-control active matter of composition weight 0.05% to 8% is accounted for, the oil-control active matter is L-2- hydracrylic acids Zinc:
(D) cationic polymer of composition weight 0.05% to 3.0% is accounted for;
(E) surplus is water.
The shampoo composite of the present invention, wherein the oil-control active matter is L-2- hydracrylic acid zinc.
The shampoo composite of the present invention, wherein the amphoteric surfactant is selected from:Betaine type amphoteric surfac-tant, Imidazoline amophoteric surface active agent and amino acid type surfactant, its weight ratio are 1:1:3 to 3:3:1.
The shampoo composite of the present invention, wherein the alkyl glucoside is selected from lauryl glucoside, cocoyl glucoside, the last of the ten Heavenly stems At least one of base glucoside and octyl group/Plantacare 818.
The shampoo composite of the present invention, wherein the cationic polymer is selected from:Cationic cellulose polymer or sun from At least one of sub- guar polymer.
The present invention contains oil-control factor shampoo, and its preferred ingredient and content are:
Component Content weight %
Cocamidopropyl propyl amide hydroxyl sulfo betaine 12.0
Sodium cocoamphoacetate 10.0
Sodium lauroyl sarcosine 8.0
Plantacare 818 5.0
Guar gum 0.1
L-2- hydracrylic acid zinc 4
Ethylene glycol stearate 1.0
Disodium ethylene diamine tetraacetate 0.1
Citric acid, preservative, colouring agent, spices, sodium chloride In right amount
Water Add to 100%
Compared with prior art, the present invention has advantage:
The shampoo of the present invention, a kind of factor component containing oil-control is added, the sebum on scalp can not only be removed, also can be effective The liveness of sebaceous glands is adjusted, suppresses glyceryl ester in bacterial fatty enzymatic sebum and resolves into free fatty, reduce sebum Secretion.
Embodiment
The compositional selecting of the present invention and effect will be described in detail below.
The shampoo composite of the present invention, which contains, accounts for composition weight 0.05% to 8%, preferably 3-5% oil-control active matter, The oil-control active matter is white powder, and taste is gentle, loss on drying 10.5-13.5%, pH value 5.0-8.0, zinc content For 23.2-24.5%.The oil-control active matter is L-2- hydracrylic acid zinc, has taste gentle, water solubility is strong, zinc ion content Height, the effect of mineral matter can be strengthened, there is infiltration moistening effect, bacteriostasis, which helps, removes oiliness scalp scurf.
Contain the cocamidopropyl propyl amide weight ratio for accounting for composition weight 5.0% to 40% in the shampoo composite of the present invention Glycine betaine, sodium cocoamphoacetate and sodium lauroyl sarcosine, its ratio are 1:1:1.
The cocamidopropyl propyl amide hydroxyl sulfo betaine abbreviation CAB, is light yellow transparent liquid, pure odorlessness, its The active matter content of commercially available prod is 30%, and inorganic salt content is less than 6.0%, and the pH of 10% aqueous solution is 4.5-6.0.The coconut palm Oleoyl both sexes guanidine-acetic acid sodium is colourless to slightly yellow clear viscous liquids, and the active matter content of its commercially available prod is 30%, 25 DEG C Under the conditions of, its viscosity is 5000-10000, and sodium chloride content is less than 9.0%, and the pH of 1% aqueous solution is 6.0-8.0, its structural formula For RN (CH2COONa)2.Institute's sodium lauroyl sarcosine is colourless pure odorlessness liquid, and the active matter of its commercially available prod contains Measure as 30%, inorganic salt content is less than 0.2%, and the pH of 10% aqueous solution is 7.0-9.0.The stimulation of the amphoteric surfactant Property it is low, especially gentle to skin, eyes, its excitant can be significantly reduced by matching with anion surfactant, and with good Foaming power, foaming abundancy is fine and closely woven, and skin sense is good, can significantly improve the foam state of formula system.The cocamidopropyl propyl amide hydroxyl The compounding use of base sulfobetaines, sodium cocoamphoacetate and sodium lauroyl sarcosine has good foam and skin Compatibility, excitant is preferably minimized.
The shampoo composite of the present invention, which contains, accounts for composition weight 01.0% to 10.0%, preferably 3-7% alkyl glucosides Glycosides surfactant.The alkyl glucoside includes lauryl glucoside, cocoyl glucoside, Plantacare 818 and octyl group/last of the ten Heavenly stems Base glucoside, preferably Plantacare 818, its outward appearance are light yellow muddy viscous liquid, and the active matter content of its commercially available prod is 51%-55%, the pH value of its 20% 15% aqueous isopropanol are 11.5-12.5, and under the conditions of 25 DEG C, its viscosity is 1000- 6000.The Plantacare 818 comes from naturally, has remarkable gentle cleaning capacity, can improve the foaming properties of shampoo.Carry The quantity and foam stability of high foam.
The shampoo composite of the present invention, which contains, accounts for composition weight 0.05% to 3.0%, preferably 0.1-1.5% cation Polymer.The cationic polymer is selected from:At least one in cationic cellulose polymer, cationic guar polymer Kind, preferred cationic guar gum.The cation melon glue is the product for obtaining melon glue after quaternized, and its key component is Melon glue hydroxypropyltrimonium chloride, a series of cation melon glue product can obtain according to the difference of substitution value, preferably take Dai Du is 0.1 to 0.2, nitrogen content 1.3-1.7%, and the cation melon glue for the present invention is under the conditions of 25 DEG C, its 1% water The viscosity of solution is 3500mPa.s to 4500mPa.s;The cationic cellulose polymer is hydroxyethyl cellulose and alkyl three The copolymer of ammonio methacrylate, it can be divided into according to the difference of degree ofacationic substitution:High-cation substitution value JR, cationic substitution Spend tri- kinds of models of LR and low degree ofacationic substitution LK, the preferably cationic cellulose of cationic substitution value.
The shampoo composite of the present invention can also include other optional components, including pearling agent, viscosity-controlling agent, chelating Agent, pH adjusting agent, preservative, pigment and spices etc..The pearling agent accounts for the 0.05% to 3.0% of composition weight, the pearl The non-limiting example of photo etching has:Ethylene glycol stearate monoesters and ethylene glycol stearate, monostearate and palmitic acid the third two Alcohol ester and glyceride, stearic acid alkylolamide magnesium stearate, the zinc oxide and titanium dioxide of fine dispersion, preferably ethylene glycol are hard Resin acid dibasic acid esters.The viscosity-controlling agent accounts for the 0.1% to 5.0% of composition weight, the non-limiting reality of the viscosity-controlling agent Example has:Sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, sodium sulphate, ammonium phosphate, hydroxyethyl cellulose, hydroxypropyl cellulose, third Olefin(e) acid and long chain alkyl methacrylate copolymer, acrylates/stearic alcohol ether -20/ methacrylate copolymer, methyl Glucoside APEO (120) dioleate etc..The chelating agent accounts for the 0.01% to 0.30% of composition weight, the chela The non-limiting example of mixture has:Ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, sodium versenate, ethylenediamine tetraacetic Sodium of acetic acid four etc., preferably disodium ethylene diamine tetraacetate;The non-limiting example of the pH adjusting agent has:Citric acid, phosphoric acid etc., it is excellent Citric acid is selected, the pH of regulation system is in 5.0 to 8.0, preferably 5.5 to 6.5;The selection of the preservative, essence, pigment, meets The regulation of hygienic standards for cosmetics, from the raw material of safety.
In the shampoo composite of the present invention, in addition to component described above, mended with water to aequum.
Preparation method
The oil-control shampoo of the present invention can pass through any known or other effective skills for being applied to provide shampoo composite Prepared by art, prepare the method for the oil-control shampoo of the present invention and include conventional preparation and hybrid technology.
Application method
The oil-control shampoo of the present invention is used in a manner of the cleaning of routine and conditioning hair, mainly including following step Suddenly:
(A) hair is soaked with water;
(B) shampoo composite of the foregoing any one claim of effective dose, the effective agent are applied on the hair Amount is generally in the range of 1 gram to 50 grams, preferably 2 to 20 grams;
(C) shampoo composite on the hair is rinsed with water.
These steps can be repeated as many times as desired, the effect of to reach sought oil-control.
Embodiment
Here is the non-limiting example of the oil-control shampoo composite of the present invention.These embodiments be only given in order to The purpose of explanation, limitation of the invention can not be interpreted as, because without departing from the spirit and scope of the present invention, Many changes can be carried out to the present invention.In these embodiments, unless stated otherwise, all concentration is all weight percent Than.Term " a small amount of material " used refers to those optional materials, as preservative, viscosity modifier, pH adjusting agent, spices, Pigment etc., the selections of these a small amount of materials by with selected preparing the physics and chemical characteristic of the special component of the present invention And change.
Prepare embodiment I-Ⅹ
The method of oil-control shampoo composite is as follows described in suitable preparation embodiment I-Ⅹ:Suitable quantity of water is added to reaction In tank, Polyquaternium-10 is added under slow stirring and is disperseed, 60 DEG C to 80 DEG C is heated to being slowly stirred, is subsequently added into PH adjusting agent (such as citric acid), bay alkyl ammonium sulfate, ethoxylated dodecyl alcohol ammonium sulfate, cocamidopropyl propyl amide hydroxyl sulfo group Glycine betaine, lauryl both sexes sodium acetate, fatty monoethanol amide, CTAB, pearlescent flake, ethylenediamine tetrem Acid disodium (if using these materials), makes these materials cool after being completely dispersed.L- is added when temperature is down to 65 DEG C or so 2 hydroxy propanoic acid zinc, less than 50 DEG C addition dimethyl silicone polymers, nourishing additive agents are cooled to after being uniformly dispersed and are uniformly dispersed, then Add preservative, pigment, essence etc. to continue to stir, it is ensured that obtain uniform mixture., can basis after all components are added Need to add viscosity modifier and pH adjusting agent, adjust product viscosity and pH to suitable degree.Optionally it can finally add Enter a small amount of water to supply.
Embodiment I-V
Embodiment VI-Ⅹ
Highly preferred embodiment of the present invention is:
Component Content weight %
Cocamidopropyl propyl amide hydroxyl sulfo betaine 12.0
Sodium cocoamphoacetate 10.0
Sodium lauroyl sarcosine 8.0
Plantacare 818 5.0
Guar gum 0.1
Oil-control active matter 4
Ethylene glycol stearate 1.0
Disodium ethylene diamine tetraacetate 0.1
Citric acid, preservative, colouring agent, spices, sodium chloride In right amount
Water Add to 100%
Sense organ physical and chemical index
Project Detect data
Outward appearance Milky pearlescent liquid
PH value 5.5-6.5
Foam 100-170mm
Viscosity 5000-10000mpa·s
Heat-resistant stability (40 ± 1) DEG C are kept for 4 weeks, without segregation phenomenon after recovering to room temperature
Cold-resistant stability - 2 DEG C -- 5 DEG C are kept for 4 weeks, without separation bleed phenomenon after recovering to room temperature
Sanitary index Items are qualified
The checking of oil-control effect
Method of testing:Select the volunteer of 40 oily hairs, it is desirable to without allergy, without wound, unsystematic local disease Scalp health patient, measured by sebum, determine scalp on enliven sebum excretion rate.Patient is divided into 2 groups, allows patient to use The most preferred embodiment shampoo of common shampoo and invention, persistently using 28 days, 0 minute, 1 hour, 12 hours of the 0th day and 28 days Scalp sebum, which was carried out, with 24 hours replys situation and the sensory testing of consumer.During on probation, volunteer is according to usually just Often hair washing frequency usage shampoo, it is desirable to which the shampoo can rest on 3-5 minutes on hair and carry out soft scalp massage, so It is clean with warm water washing again afterwards.Situation measurement, which is replied, for the sebum using volunteer before and after the shampoo is shown in Table 1 and hair sense organ Assessment is shown in Table 2.
Table 1
Table 2
15 minutes 8 hours 24 hours
It is very salubrious 30 people 25 people 20 people
Clearly 8 people 10 people 15 people
It is clouding 2 people 5 people 5 people

Claims (4)

1. a kind of shampoo composite containing the oil-control factor, its component and content are:
(A) amphoteric surfactant of composition weight 5.0% to 40% is accounted for;
(B) the alkyl glucoside surfactant of composition weight 1.0% to 10.0% is accounted for;
(C) the oil-control active matter of composition weight 0.05% to 8% is accounted for, the oil-control active matter is L-2- hydracrylic acid zinc;
(D) cationic polymer of composition weight 0.05% to 3.0% is accounted for;
(E) surplus is water.
2. shampoo composite according to claim 1, wherein amphoteric surfactant are cocamidopropyl propyl amide weight ratio The mixing of glycine betaine, sodium cocoamphoacetate and sodium lauroyl sarcosine, and the weight ratio of three kinds of material mixings is:1:1: 3 to 3:3:1.
3. shampoo composite according to claim 1, wherein the cationic polymer is selected from:Cationic cellulose polymerize Thing or cationic guar polymer.
4. a kind of shampoo composite containing the oil-control factor, its component and content are:
CN201710864408.7A 2017-09-22 2017-09-22 A kind of shampoo composite containing the oil-control factor Pending CN107693389A (en)

Priority Applications (1)

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CN201710864408.7A CN107693389A (en) 2017-09-22 2017-09-22 A kind of shampoo composite containing the oil-control factor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710864408.7A CN107693389A (en) 2017-09-22 2017-09-22 A kind of shampoo composite containing the oil-control factor

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109793681A (en) * 2018-12-26 2019-05-24 拉芳家化股份有限公司 It is a kind of containing educating the shampoo composite for sending out hair loss composite reactive Essence anti-

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101133145A (en) * 2005-03-01 2008-02-27 味之素株式会社 Detergent composition
CN104257596A (en) * 2014-09-16 2015-01-07 拉芳家化股份有限公司 Mild oil-control shampoo with cool feeling

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101133145A (en) * 2005-03-01 2008-02-27 味之素株式会社 Detergent composition
CN104257596A (en) * 2014-09-16 2015-01-07 拉芳家化股份有限公司 Mild oil-control shampoo with cool feeling

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109793681A (en) * 2018-12-26 2019-05-24 拉芳家化股份有限公司 It is a kind of containing educating the shampoo composite for sending out hair loss composite reactive Essence anti-

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Application publication date: 20180216