CN101342120A - Shower cream - Google Patents

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Publication number
CN101342120A
CN101342120A CNA2008101982543A CN200810198254A CN101342120A CN 101342120 A CN101342120 A CN 101342120A CN A2008101982543 A CNA2008101982543 A CN A2008101982543A CN 200810198254 A CN200810198254 A CN 200810198254A CN 101342120 A CN101342120 A CN 101342120A
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shower cream
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CN101342120B (en
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李世忠
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LAF International Group Limited
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GUANGDONG LAFANG DAILY CHEMICALS CO Ltd
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Abstract

The invention relates to shower lotion, which contains (A) sulphonate anionic surfactants accounting for 20.0 percent to 45.0 percent of the composition weight, (B) N-acyl sarcosinate anionic surfactants accounting for 5.0 percent to 15.0 percent of the composition weight, (C) amphoteric surfactants accounting for 3.0 percent to 12.0 percent of the composition weight, (D) viscosity modifiers accounting for 0.2 percent to 2.0 percent of the composition weight, (E) emollients accounting for 1.0 percent to 5.0 percent of the composition weight and (F) water of the rest. The shower lotion composition of the invention has low irritation and good use effect and successfully solves the thickening problem of the shower lotion system containing N-acyl sarcosinate.

Description

A kind of bath gel
Technical field
The present invention relates to a kind of personal cleansing articles for use, the bath gel of using during particularly a kind of the shower.
Background technology
Along with growth in the living standard, bath gel replaces fancy soap to become the first-selection that people bathe the usefulness product gradually.The national standard of bath gel is divided into two classes according to the kind of its used first type surface activating agent of filling a prescription with bath gel, i.e. soap base type and non-soap base surfactant type; Can be divided into transparent type and opaque type again from bath gel in appearance.Non-soap base surfactant type bath gel flushing sense is more sliding, more moist, adds this type of bath gel and preponderates than soap base type bath gel at aspects such as cost, production technologies, so non-in the market soap base type bath gel occupies most of market share.The used first type surface activating agent of non-soap base surfactant type bath gel mostly is anion surfactant greatly, anion surfactant commonly used as: alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt etc., the product zest is bigger.N-amide sarcosinate is a kind of anionic amino acids surfactant, have low toxicity, low irritant, favorable biological degradability, preferable advantages such as compatibility, composite with other anion surfactant, can reduce the zest that conventional surfactant produces and improve foaming capacity; Amide groups in its molecular structure can form special association body, has chelating ability and antioxygenic property, to the epidermis good penetrability, and can suppress the infiltration that potential zest solute such as sodium ion pass human body skin, therefore with after can not make xerosis cutis.But after N-amide sarcosinate added the bath gel system, system existed the problem that is difficult to thickening.
Summary of the invention
The purpose of this invention is to provide a kind of bath gel, contain N-amide sarcosinate in this bath gel, solved the bigger problem of traditional product zest and contained the thickening problem of N-amide sarcosinate bath gel system.
Shower cream composition of the present invention comprises the Sulfonates anion surfactant that (A) accounts for composition weight 20.0% to 45.0%; (B) account for the N-acylsarcosine salt analog anion surfactants of composition weight 5.0% to 15.0%; (C) account for the amphoteric surfactant of composition weight 3.0% to 12.0%; (D) account for the viscosity-controlling agent of composition weight 0.2% to 2.0%; (E) account for the emollient of composition weight 1.0% to 5.0%; (F) surplus is a water.
In the shower cream composition of the present invention, described Sulfonates anion surfactant is at least a in alkenyl sulphonate, N-acyl glutamic acid and salt thereof, sulfosuccinate, the isethionic acid ester.
In the shower cream composition of the present invention, described Sulfonates anion surfactant is the alkenyl sulphonate that accounts for composition weight 20%~40%, the isethionic acid ester that accounts for composition weight 0.5%~3.0%.
In the shower cream composition of the present invention, described N-acylsarcosine salt analog anion surfactants is at least a in N-sodium lauroyl sarcosine, N-Hamposyl L ammonium, N-Hamposyl C sodium, the N-myristoyl-N-methylaminoacetic acid sodium.
In the shower cream composition of the present invention, contain the fatty acid that accounts for its weight 2.0% to 15.0% in the described N-acylsarcosine salt.
In the shower cream composition of the present invention, described N-acylsarcosine salt is the N-sodium lauroyl sarcosine.
In the shower cream composition of the present invention, described amphoteric surfactant is at least a in betanin and derivant and the both sexes sodium acetate.
In the shower cream composition of the present invention, described amphoteric surfactant is a betanin derivative.
In the shower cream composition of the present invention, described viscosity-controlling agent is at least a in polyethylene glycol stearate diester, acrylate copolymer, glucoside derivative, cellulose derivative or the inorganic salt.
In the shower cream composition of the present invention, described viscosity-controlling agent is a PEG-120 methyl glucoside glycoside derivates.
In the shower cream composition of the present invention, described emollient is a fatty acid ester.
In the shower cream composition of the present invention, described emollient is the PEG-7 glyceryl cocoate.
The preferable range of shower cream composition each component of the present invention is: (A) account for the Sulfonates anion surfactant of composition weight 25.0% to 40.0%, (B) account for the N-acylsarcosine salt of composition weight 6.0% to 12.0%; (C) account for the amphoteric surfactant of composition weight 5.0% to 10.0%; (D) account for the viscosity-controlling agent of composition weight 0.5% to 1.8%; (E) account for the emollient of composition weight 1.5% to 4.5%; (F) surplus is a water.
Compared with prior art, shower cream composition of the present invention has low zest and good result of use, and successful solution contain the thickening problem of N-amide sarcosinate bath gel system.To be elaborated to component selection of the present invention and effect below.
Contain in the shower cream composition of the present invention and account for composition weight 20.0% to 45.0%, preferred 25.0% to 40.0% suitable be used on the skin the Sulfonates anion surfactant.Described Sulfonates anion surfactant is at least a in alkenyl sulphonate, N-acyl glutamic acid and salt thereof, sulfosuccinate, the isethionic acid ester.Described alkenyl sulphonate is a α-Xi Jihuangsuanyan, is the complex mixture of different chemical component, and main component is hydroxyalkylated sulfonic acid salt, alkenyl sulphonate and disulfonate; Described sulfosuccinate comprises lauryl 2-Sulfosuccinic acid ester ammonium salt, lauryl 2-Sulfosuccinic acid ester sodium salt, laureth sulfosuccinate disodium, PEG-2 oleoyl amido sulfosuccinate disodium, Cortex cocois radicis acyl group glycollic amide sulfosuccinate disodium, N-(1,2-two carboxyethyls)-N-octadecyl sulfonation succinamic acid four sodium, the how pure sulfosuccinate disodium of dimethyl-silicon, Fructus Hordei Germinatus sulfosuccinate; Described isethionic acid ester is a neutral again product after the esterification of hydroxyethylsulfonic acid. and natural acid, mainly is the hydroxyethylsulfonic acid. ester sodium salt, preferred coconut oil fat alcohol sodium isethionate.
Contain in the shower cream composition of the present invention and account for composition weight 5.0% to 15.0%, preferred 6.0% to 12.0% suitable be used on the skin N-acylsarcosine salt analog anion surfactants.Described N-acylsarcosine salt is by a kind of multi-functional surfactant that makes after the sarcosine acidylate, and its structural formula is (I):
Figure A20081019825400071
In the formula (I), R is lauryl, cocoyl etc., and M is Na, K, NH 4Deng; Preferred N-sodium lauroyl sarcosine contains 2% to 15% fatty acid in the special requirement N-sodium lauroyl sarcosine.
Other are applicable to that anion surfactant of the present invention also comprises: polyoxyethylene alkyl ether sulfate salt, N-acyl glutamic acid and salt and alkyl phosphate etc.Described polyoxyethylene alkyl ether sulfate salt structural formula is RO (CH 2CH 2O) nSO 3M, wherein M=Na +, NH 4 +, [H (C 2H 5OH) 3] +, R=C 12~C 18Alkyl, n are 2~4, and preferred average ethoxyquin degree is n=3, M=Na +, R=C 12, i.e. lauryl alcohol ether polyoxyethylene sodium sulfate; Described N-acyl glutamic acid and salt thereof comprise N-Cortex cocois radicis acyl sodium glutamate, N-sodium lauroyl glutamate, N-myristoyl sodium glutamate, N-mixing-in fat acyl sodium glutamate, N-Adeps Bovis seu Bubali fatty acyl sodium glutamate, N-Cortex cocois radicis acyl glutamic acid list triethanolamine salt; Described alkyl phosphate is fatty alcohol-polyoxyethylene ether phosphate monoester and dibasic acid esters and its esters etc.
In order to reach good cleaning effect, anionic surfactant system of the present invention is the compositions of alkenyl sulphonate, isethionic acid ester and N-acylsarcosine salt.
Contain in the shower cream composition of the present invention and account for composition weight 3.0% to 12.0%, preferred 5.0% to 10.0% the suitable amphoteric surfactant that is used on the skin.Described amphoteric surfactant is at least a in betanin and derivant and the both sexes sodium acetate.Described betanin derivative comprises coco dimethyl betanin, cocamido propyl betaine, dodecanamide propyl betanin, cocamidopropyl propyl amide hydroxyl sulphur betanin, lauramide hydroxyl sulphur betanin, preferred lauramide hydroxyl sulphur betanin; Described both sexes sodium acetate comprises cocoyl both sexes sodium acetate and the optimum sodium acetate of lauryl.
Contain in the shower cream composition of the present invention and account for composition weight 0.2% to 2.0%, preferred 0.5% to 1.8% viscosity-controlling agent.Described viscosity-controlling agent is at least a in polyethylene glycol stearate diester, acrylate copolymer, glucoside derivative, cellulose derivative and the inorganic salt.Described polyethylene glycol stearate diester is the two stearates of polyethylene glycol 6000; Described acrylate copolymer comprises Carbopol series, C 10-30Alkyl acrylic interlinkage copolymer, C 10-30Alkyl acrylate interlinkage copolymer etc.; Described glucoside derivative is a PEG-120 methyl glucoside dioleic acid ester; Described cellulose derivative comprises hydroxy methocel, hydroxyethyl-cellulose etc.; Described inorganic salt is sodium chloride, ammonium chloride and sodium sulfate.The preferred PEG-120 methyl glucoside of viscosity-controlling agent dioleic acid ester in the shower cream composition of the present invention.
Contain in the shower cream composition of the present invention and account for composition weight 1.0% to 5.0%, preferred 1.5% to 4.5% emollient.Described emollient is a fatty acid ester, comprises PEG-7 glyceryl cocoate, sad capric acid triglyceride, cocoyl glyceride, isopropyl palmitate, isopropyl myristate, decyl oleate, isostearate, preferred PEG-7 glyceryl cocoate.
Shower cream composition of the present invention can also comprise other optional components, comprises chelating agen, pH regulator agent, antiseptic, pigment and spice etc.The non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferred disodiumedetate; The non-limiting example of described pH regulator agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system are 5.0 to 8.0, and preferred 5.5 to 6.5; Choosing of described antiseptic, essence, pigment meets the regulation of hygienic standards for cosmetics, selects safe raw material for use.
In the shower cream composition of the present invention, except the above component, water is mended to aequum.
The specific embodiment
Be the non-limiting example of bath gel of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration all is percentage by weight.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, pH regulator agent, spice, pigment etc., the selection of these small amount of matter will change in order to the physics for preparing special component of the present invention and chemical characteristic along with selected.
Preparation example I-X
Bath gel of the present invention can by any known or other effectively be applicable to the technology preparation that bath gel is provided, the method for preparing bath gel of the present invention comprises conventional preparation and hybrid technology.The suitable method for preparing bath gel described in example I-X is as follows:
Suitable quantity of water is joined in the retort, be heated to 60 ℃ to 80 ℃, add polyoxyethylene lauryl ether ammonium sulfate, α-Xi Jihuangsuanyan, coconut oil fat alcohol sodium isethionate, lauramide hydroxyl sulphur betanin, PEG-7 glyceryl cocoate, disodiumedetate (if using these materials), make these materials disperse the back to add citric acid fully, stir; Treat to add when temperature is reduced to 40 ℃ of left and right sides antiseptic, pigment, essence etc. and continue to stir, guarantee to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, the viscosity and the pH that regulate product arrive suitable degree.Randomly can add low amounts of water at last supplies.
Example I-V
Figure A20081019825400101
Example VI-X:
Figure A20081019825400102
Figure A20081019825400111

Claims (13)

1. shower cream composition comprises:
(A) account for the Sulfonates anion surfactant of composition weight 20.0% to 45.0%;
(B) account for the N-acylsarcosine salt analog anion surfactants of composition weight 5.0% to 15.0%;
(C) account for the amphoteric surfactant of composition weight 3.0% to 12.0%;
(D) account for the viscosity-controlling agent of composition weight 0.2% to 2.0%;
(E) account for the emollient of composition weight 1.0% to 5.0%;
(F) surplus is a water.
2. shower cream composition according to claim 1 is characterized in that: described Sulfonates anion surfactant is at least a in alkenyl sulphonate, N-acyl glutamic acid and salt thereof, sulfosuccinate, the isethionic acid ester.
3. shower cream composition according to claim 2 is characterized in that: described Sulfonates anion surfactant is the alkenyl sulphonate that accounts for composition weight 19.5%~42.0%, the isethionic acid ester that accounts for composition weight 0.5%~3.0%.
4. shower cream composition according to claim 1 is characterized in that: described N-acylsarcosine salt analog anion surfactants is at least a in N-sodium lauroyl sarcosine, N-Hamposyl L ammonium, N-Hamposyl C sodium, the N-myristoyl-N-methylaminoacetic acid sodium.
5. shower cream composition according to claim 4 is characterized in that: contain the fatty acid that accounts for its weight 2.0% to 15.0% in the described N-acylsarcosine salt.
6. according to claim 4 or 5 described shower cream compositions, it is characterized in that: described N-acylsarcosine salt is the N-sodium lauroyl sarcosine.
7. shower cream composition according to claim 1 is characterized in that: described amphoteric surfactant is at least a in betanin and derivant and the both sexes sodium acetate.
8. shower cream composition according to claim 7 is characterized in that: described amphoteric surfactant is a betanin derivative.
9. shower cream composition according to claim 1 is characterized in that: described viscosity-controlling agent is at least a in polyethylene glycol stearate diester, acrylate copolymer, glucoside derivative, cellulose derivative or the inorganic salt.
10. shower cream composition according to claim 9 is characterized in that: described viscosity-controlling agent is a PEG-120 methyl glucoside glycoside derivates.
11. shower cream composition according to claim 1 is characterized in that: described emollient is a fatty acid ester.
12. shower cream composition according to claim 11 is characterized in that: described emollient is the PEG-7 glyceryl cocoate.
13. shower cream composition according to claim 1 is characterized in that comprising the Sulfonates anion surfactant that (A) accounts for composition weight 25.0% to 40.0%, (B) accounts for the N-acylsarcosine salt of composition weight 6.0% to 12.0%; (C) account for the amphoteric surfactant of composition weight 5.0% to 10.0%; (D) account for the viscosity-controlling agent of composition weight 0.5% to 1.8%; (E) account for the emollient of composition weight 1.5% to 4.5%; (F) surplus is a water.
CN2008101982543A 2008-09-02 2008-09-02 Shower cream Active CN101342120B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102048653A (en) * 2011-01-06 2011-05-11 广州壹凡化工有限公司 Amino acid type weak acid facial cleanser and preparation method thereof
CN102552069A (en) * 2011-12-31 2012-07-11 广州市浪奇实业股份有限公司 Bath foam
CN103202781A (en) * 2012-01-16 2013-07-17 南京华狮化工有限公司 Cream body bath composition and application thereof
CN103356439A (en) * 2013-07-19 2013-10-23 泉州市新益日用化妆品有限公司 Tea saponin bath lotion and its making method
CN103705404A (en) * 2013-12-31 2014-04-09 汕头市大千高新科技研究中心有限公司 Emulsion bath foam containing natural oil and preparation method thereof
CN106901998A (en) * 2015-12-22 2017-06-30 广州市浪奇实业股份有限公司 A kind of bath foam
CN109350553A (en) * 2018-12-04 2019-02-19 浙江大学自贡创新中心 A kind of mineral salt amino acid shower cream
EP3256100B1 (en) 2014-12-12 2022-06-29 L'Oréal Cosmetic composition comprising linear sulfonate olefins and non oxyalkylated anionic surfactants
EP3256099B1 (en) 2014-12-12 2022-07-20 L'Oréal Cosmetic composition comprising linear alpha-olefin sulfonates, anionic and nonionic and/or amphoteric surfactants

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101199462B (en) * 2007-12-12 2011-06-29 天津盛世恒安科技发展有限公司 Scouring bath product suited for skin trait of infant 7 to 12 months old and process for preparing same

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102048653A (en) * 2011-01-06 2011-05-11 广州壹凡化工有限公司 Amino acid type weak acid facial cleanser and preparation method thereof
CN102552069A (en) * 2011-12-31 2012-07-11 广州市浪奇实业股份有限公司 Bath foam
CN102552069B (en) * 2011-12-31 2014-11-05 广州市浪奇实业股份有限公司 Bath foam
CN103202781A (en) * 2012-01-16 2013-07-17 南京华狮化工有限公司 Cream body bath composition and application thereof
CN103356439A (en) * 2013-07-19 2013-10-23 泉州市新益日用化妆品有限公司 Tea saponin bath lotion and its making method
CN103705404A (en) * 2013-12-31 2014-04-09 汕头市大千高新科技研究中心有限公司 Emulsion bath foam containing natural oil and preparation method thereof
CN103705404B (en) * 2013-12-31 2015-11-18 汕头市大千高新科技研究中心有限公司 A kind of containing natural oil emulsus bath foam and preparation method thereof
EP3256100B1 (en) 2014-12-12 2022-06-29 L'Oréal Cosmetic composition comprising linear sulfonate olefins and non oxyalkylated anionic surfactants
EP3256099B1 (en) 2014-12-12 2022-07-20 L'Oréal Cosmetic composition comprising linear alpha-olefin sulfonates, anionic and nonionic and/or amphoteric surfactants
CN106901998A (en) * 2015-12-22 2017-06-30 广州市浪奇实业股份有限公司 A kind of bath foam
CN106901998B (en) * 2015-12-22 2020-06-12 广州市浪奇实业股份有限公司 Bath foam
CN109350553A (en) * 2018-12-04 2019-02-19 浙江大学自贡创新中心 A kind of mineral salt amino acid shower cream

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Owner name: LAFANG CHEMICAL CO., LTD.

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Patentee before: Guangdong Lafang Daily Chemicals Co., Ltd.