CN102552069B - Bath foam - Google Patents
Bath foam Download PDFInfo
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- CN102552069B CN102552069B CN201110460524.5A CN201110460524A CN102552069B CN 102552069 B CN102552069 B CN 102552069B CN 201110460524 A CN201110460524 A CN 201110460524A CN 102552069 B CN102552069 B CN 102552069B
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Abstract
The invention belongs to the technical field of liquid washing cosmetic and discloses bath foam not containing dioxane. The bath foam comprises the following components by weight percentage: 5-14% of sulfonate type anionic surfactant, 0.5-5% of N-sodium cocoyl sarcosinate type anionic surfactant, 2-5% of ampholytic surfactant, and 0.5-3% of alkyl alcohol amine type nonionic surfactant, wherein the sum of the weight percentage of four surface active agents is not less than 12%. In the bath foam, the sulfonate type anionic surfactant is used as a main surfactant, the common fatty alcohol-polyoxyethylene ether sulfate is replaced, simultaneously the N-sodium cocoyl sarcosinate type anionic surfactant and the ampholytic surfactant are added to reduce irritation of the system, so that the product is moderate, does not contain dioxane and has good safety.
Description
Technical field
The invention belongs to liquid and wash class cosmetics technical field, be specifically related to a kind of bath foam that does not contain dioxanes.
Background technology
Along with the raising of people's living standard, liquid is washed to the safety of class cosmetics in consumer and the requirement of mildness improves gradually.In common non-soap base class bath foam formula, the overwhelming majority adopts polyoxyethylenated alcohol sodium sulfate or AESA as main surfactant, and fatty alcohol polyoxyethylene ether sulfate can produce by-product diox in synthetic process.Diox is a kind of organic compound, and another name dioxane, Isosorbide-5-Nitrae-dioxane, belong to micro-virus kind, irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and nervous system, during acute poisoning, may cause death.Therefore, use fatty alcohol polyoxyethylene ether sulfate can make to contain diox in bath foam, the health of consumer is threatened.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art part, a kind of bath foam of not Han diox is provided.
For achieving the above object, the present invention adopts following technical scheme:
A bath foam, is characterized in that, the composition that includes following percentage by weight divides:
Wherein, the percentage by weight sum of described four kinds of surfactants is no less than 12%.
As preferably, described Sulfonates anion surfactant is by being grouped into by forming of the percentage by weight of bath foam gross weight as follows:
α olefin sulfonate 2～8%
The aliphatic alcohol sulfate 2～6% of C12～C14
MES 0～4%.
As preferably, described α olefin sulfonate is α-sodium olefin sulfonate or α-olefin sulfonic acid potassium; The aliphatic alcohol sulfate of described C12～C14 is ammonium alkyl sulfate, fatty alcohol sulphuric acid potassium, sodium alkyl sulfate; Described MES is methyl sodiosul foaliphatate.
As preferably, described N-acylsarcosine salt analog anion surfactants is any in N-sodium lauroyl sarcosine, N-Hamposyl L ammonium, N-Hamposyl C sodium and N-myristoyl-N-methylaminoacetic acid sodium, or their combination.
As preferably, described amphoteric surfactant is any in betanin and derivant and both sexes sodium acetate, or their combination.
As preferably, described alkylolamides class non-ionic surface active agent is any in cocoanut fatty acid diethanolamide and coconut oil fatty acid monoethanolamide, or their combination.
As preferably, also include percentage by weight and be 0.1～0.5% viscosity-controlling agent, described viscosity-controlling agent is any in cellulose derivative and inorganic salt, or their combination.
As preferably, also include weight percent and be 0.1～1% plant extract, described plant extract is any in eucalyptus citriodora oil and menthanol lactic acid ester, or their combination.
The present invention also include wetting agent (as glycerol), outward appearance regulator (as Pearl Concentrate), pH adjusting agent (acidic materials or alkaline matter, acidic materials comprise sodium bisulfate and potassium acid sulfate and organic acid acetic acid, citric acid, tartaric acid, maleic acid and itaconic acid; Alkaline matter comprises sodium hydroxide, potassium hydroxide, sodium carbonate, sodium bicarbonate, potassium carbonate and potassium bicarbonate.)
The present invention is usingd Sulfonates anion surfactant as main surfactant, replace conventional fatty alcohol polyoxyethylene ether sulfate, add N-acylsarcosine salt analog anion surfactants, amphoteric surfactant to reduce the zest of system simultaneously, make product milder, and, containing dioxanes, Product Safety is not good.
The specific embodiment
Embodiment 1～4
The concrete composition of the bath foam described in the embodiment of the present invention 1～4 divides as following table.The preparation method of the bath foam described in each embodiment is as follows:
1, in deionized water, add Sulfonates anion surfactant, N-acylsarcosine salt analog anion surfactants, amphoteric surfactant sodium acetate and alkylolamides class non-ionic surface active agent, start stirring paddle, heat temperature raising.When temperature stops heating when rising to 72～80 ℃, constant temperature stirs 30 minutes;
2, open cooling water temperature, when cooling is stirred to 65～68 ℃, add eucalyptus citriodora oil (and menthanol lactic acid ester), constant temperature stirs 15 minutes;
3, when temperature is not more than 50 ℃, add acidic materials or alkaline matter, regulate pH value in 6.0～6.8 scope, stir 15 minutes.When temperature is not more than 48 ℃, add Pearl Concentrate, glycerol, essence and antiseptic etc., stir 15 minutes.
4, with appropriate viscosity modifier, regulate viscosity, stir 15 minutes, obtain finished product.
| Material name | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Ammonium alkyl sulfate | 3 | 0 | 0 | 0 |
| Sodium alkyl sulfate | 0 | 2 | 6 | 2 |
| α-sodium olefin sulfonate or potassium | 6 | 8 | 2 | 3 |
| Methyl sodiosul foaliphatate | 1 | 2 | 0 | 5 |
| Both sexes sodium acetate | 0.5 | 0 | 2 | 0 |
| N-sodium lauroyl sarcosine | 1 | 0.5 | 3 | 5 |
| CAB | 1.5 | 2 | 3 | 3 |
| Coconut oil fatty acid monoethanolamide | 3 | 0 | 0 | 1 |
| Cocoanut fatty acid diethanolamide | 0 | 1 | 1 | 0 |
| Pearl Concentrate | 1.5 | 1.5 | 1.5 | 1.5 |
| Glycerol | 1 | 1 | 1 | 1 |
| Polyquaternary ammonium salt | 0.8 | 0 | 0 | 0 |
| Eucalyptus citriodora oil | 0.8 | 0.8 | 0.5 | 0.6 |
| Menthanol lactic acid ester | 0 | 0.2 | 0.1 | 0 |
| Citric acid | 0.2 | 0.1 | 0.1 | 0.2 |
| Antiseptic | 0.5 | 0.5 | 0.5 | 0.5 |
| Essence | 0.5 | 0.5 | 0.5 | 0.5 |
| Sodium chloride | 0.2 | 0 | 0.5 | 0 |
| Hydroxyethyl-cellulose | 0 | 0.3 | 0 | 0.3 |
| Deionized water | Surplus | Surplus | Surplus | Surplus |
| * diox Content Test result | Do not detect | Do not detect | Do not detect | Do not detect |
* diox Content Test foundation: SN/T 1784-2006 < < imports and exports the mensuration gas chromatogram tandem mass spectrometry > > of cosmetics Zhong diox residual quantity
Claims (7)
1. a bath foam, is characterized in that, the composition that includes following percentage by weight divides:
Wherein, the percentage by weight sum of described four kinds of surfactants is no less than 12%; Described Sulfonates anion surfactant is by being grouped into by forming of the percentage by weight of bath foam gross weight as follows:
α olefin sulfonate 2～8%
The aliphatic alcohol sulfate 2～6% of C12～C14
MES 0～4%.
2. a kind of bath foam according to claim 1, is characterized in that, described α olefin sulfonate is α-sodium olefin sulfonate or α-olefin sulfonic acid potassium; The aliphatic alcohol sulfate of described C12～C14 is ammonium alkyl sulfate, fatty alcohol sulphuric acid potassium, sodium alkyl sulfate; Described MES is methyl sodiosul foaliphatate.
3. a kind of bath foam according to claim 1, it is characterized in that, described N-acylsarcosine salt analog anion surfactants is any in N-sodium lauroyl sarcosine, N-Hamposyl L ammonium, N-Hamposyl C sodium and N-myristoyl-N-methylaminoacetic acid sodium, or their combination.
4. a kind of bath foam according to claim 1, is characterized in that, described amphoteric surfactant is any in betanin and derivant and both sexes sodium acetate, or their combination.
5. a kind of bath foam according to claim 1, is characterized in that, described alkylolamides class non-ionic surface active agent is any in cocoanut fatty acid diethanolamide and coconut oil fatty acid monoethanolamide, or their combination.
6. a kind of bath foam according to claim 1, is characterized in that, also includes percentage by weight and be 0.1～0.5% viscosity-controlling agent, and described viscosity-controlling agent is any in cellulose derivative and inorganic salt, or their combination.
7. a kind of bath foam according to claim 1, is characterized in that, also includes weight percent and be 0.1～1% plant extract, and described plant extract is any in eucalyptus citriodora oil and menthanol lactic acid ester, or their combination.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110460524.5A CN102552069B (en) | 2011-12-31 | 2011-12-31 | Bath foam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110460524.5A CN102552069B (en) | 2011-12-31 | 2011-12-31 | Bath foam |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102552069A CN102552069A (en) | 2012-07-11 |
| CN102552069B true CN102552069B (en) | 2014-11-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110460524.5A Active CN102552069B (en) | 2011-12-31 | 2011-12-31 | Bath foam |
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| Country | Link |
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| CN (1) | CN102552069B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102994242B (en) * | 2012-11-26 | 2015-07-08 | 广州市浪奇实业股份有限公司 | Hyperconcentration detergent powder |
| CN103830124A (en) * | 2014-02-26 | 2014-06-04 | 南通市海顺化工有限公司 | Coconut flavor transparent bath foam |
| CN106562898A (en) * | 2016-11-12 | 2017-04-19 | 然久生物科技(上海)有限公司 | Shower gel and preparation method thereof |
| CN108653027A (en) * | 2018-07-03 | 2018-10-16 | 广州仲思生物科技有限公司 | A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101342120A (en) * | 2008-09-02 | 2009-01-14 | 广东拉芳日化有限公司 | Shower cream |
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- 2011-12-31 CN CN201110460524.5A patent/CN102552069B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101342120A (en) * | 2008-09-02 | 2009-01-14 | 广东拉芳日化有限公司 | Shower cream |
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| CN102552069A (en) | 2012-07-11 |
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Effective date of registration: 20230710 Address after: 511455 No. 8 Xiaohu South Third Road, Xiaohu Island, Huangge Town, Nansha District, Guangzhou City, Guangdong Province Patentee after: GUANGZHOU LANGQI DAILY NECESSITIES CO.,LTD. Address before: 510660 No. 128, Whampoa Avenue, Guangzhou, Guangdong Patentee before: GUANGZHOU LONKEY INDUSTRIAL Co.,Ltd. |