CN102429827A - Preservative-free liquid detergents - Google Patents

Preservative-free liquid detergents Download PDF

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Publication number
CN102429827A
CN102429827A CN2011103895325A CN201110389532A CN102429827A CN 102429827 A CN102429827 A CN 102429827A CN 2011103895325 A CN2011103895325 A CN 2011103895325A CN 201110389532 A CN201110389532 A CN 201110389532A CN 102429827 A CN102429827 A CN 102429827A
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CN
China
Prior art keywords
glycerol
liquid
preservative
liquid detergents
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011103895325A
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Chinese (zh)
Inventor
曹光群
赵秋菊
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Jiangnan University
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Jiangnan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangnan University filed Critical Jiangnan University
Priority to CN2011103895325A priority Critical patent/CN102429827A/en
Publication of CN102429827A publication Critical patent/CN102429827A/en
Pending legal-status Critical Current

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Abstract

The invention discloses preservative-free liquid detergents, and belongs to the technical field of liquid detergents. The liquid detergents comprise facial cleansers, shampoos, hand sanitizers, body wash, dish washing liquids and fabric cleaners, and are prepared by mixing glycerol and a basic washing material, wherein the glycerol accounts for 10 to 90 weight percent. The invention has the advantages that: the preservative-free liquid detergents do not contain any preservative, contain a great amount of glycerol humectant and can effectively reduce the stimulation of the preservative and surfactants to the skin and environmental pollution during use.

Description

A kind of liquid scrubbing articles for use that do not contain antiseptic
Technical field
The present invention relates to a kind of liquid scrubbing articles for use that do not contain antiseptic, belong to liquid scrubbing articles for use technical field.
Background technology
The form of existing articles for washing is varied; Comprise that people are in order to satisfy personal cleanliness's articles for use of requirements such as washing one's hands, wash one's face, have one's hair wash, have a bath; Handwashing liquid, cleansing milk, shampoo and bath gel etc. are generally arranged, also have household cleaning articles for use such as liquid detergent, liquid detergent in addition.
In all kinds of liquid scrubbing articles for use of at present selling on the market all with water as liquid phase carrier, contain antiseptic.Antiseptic commonly used in the articles for washing has certain stimulation, especially sensitive skin to human body skin mostly.Also can cause certain influence to natural environment in addition.
Summary of the invention
Technical problem to be solved by this invention provides a kind of liquid scrubbing articles for use that do not contain antiseptic, and it can reduce, and antiseptic makes safer, the more environmental protection of liquid scrubbing articles for use to the stimulation of skin in the existing liquid scrubbing articles for use.
Technical scheme of the present invention: a kind of liquid scrubbing articles for use that do not contain antiseptic; Comprise cleansing milk, shampoo, handwashing liquid, bath gel, liquid detergent and liquid detergent; It is mixed by glycerol and basic detergent, and the weight percent content of glycerol is 10% ~ 90% in the described liquid scrubbing articles for use.
The described liquid scrubbing articles for use that do not contain antiseptic, wherein the weight percent content of glycerol is 30% ~ 80%.
Described basic detergent is an alkalescence, neutral or acid.
Described basic detergent is liquid, semisolid or paste.
Beneficial effect of the present invention: compared with prior art; The invention has the advantages that in the liquid scrubbing articles for use such as handwashing liquid, cleansing milk, shampoo, bath gel, liquid detergent and liquid detergent and do not contain antiseptic; Water can effectively be restrained bacterial growth as liquid phase carrier in the most of or all existing liquid detergent with the glycerol replacement; Simultaneously glycerol also is a kind of good moisture preserving agent, contains a large amount of glycerol in the product skin has been played the effect of preserving moisture, and has reduced in the liquid detergent surfactant effectively to the stimulation of skin, and is environmentally friendly in addition.
The specific embodiment
Below in conjunction with embodiment the present invention is made further detailed description, but embodiment of the present invention is not limited thereto.
Embodiment 1:
A kind of liquid detergent: handwashing liquid, its each component weight percent content is:
Glycerol 65.8%
Polyoxyethylenated alcohol sodium sulfate (70%) 12%
Cocoyl CAB (30%) 5%
Cocos nucifera oil acyl diethanolamine 4%
Water 13%
Citric acid 0.1%
EDTA?-2Na 0.1%
Production technology: in water, add EDTA-2Na, glycerol, polyoxyethylenated alcohol sodium sulfate, be stirred to dissolving fully, add cocoyl CAB, cocos nucifera oil acyl diethanolamine, citric acid again, stir discharging.
Embodiment 2:
A kind of liquid detergent: cleansing milk, its each component weight percent content is:
Glycerol 54%
Cocoyl sodium isethionate 10%
Monoalkyl phosphoric acid esters potassium salt (30%) 32%
Pearling agent 2%
Polyethylene Glycol-200 2%
Production technology: the cocoyl sodium isethionate is added in the glycerol, be heated to whole dissolvings, add monoalkyl phosphoric acid esters potassium salt, pearling agent, Polyethylene Glycol-200 stirring, after all dissolving, cooling, discharging.
Embodiment 3:
A kind of liquid detergent: shampoo, its each component weight percent content is:
Glycerol 50%
Polyoxyethylenated alcohol sodium sulfate (70%) 15%
Cocos nucifera oil acyl MEA 1%
Pearling agent 1.5%
Guar gum quaternary ammonium salt 0.4%
Cocoyl CAB (30%) 5%
Emulsified silicone oil (50%) 4%
Water 23%
Citric acid 0.1%
Production technology: the guar gum quaternary ammonium salt is added in the entry, and adding citric acid is fully after the dissolving; Add glycerol, polyoxyethylenated alcohol sodium sulfate, be heated to 70~85 ℃, be stirred to dissolving fully; Add pearling agent, cocos nucifera oil acyl MEA, cocoyl CAB, be cooled to 50 ℃, add emulsified silicone oil; Stir discharging.
Embodiment 4:
A kind of liquid detergent: bath gel, its each component weight percent content is:
Glycerol 47.1%
Polyoxyethylenated alcohol sodium sulfate (70%) 12%
Cocos nucifera oil acyl MEA 2%
Pearling agent 1.5%
Cocoyl sodium isethionate (30%) 2%
Cocoyl CAB (30%) 5%
Guar gum 0.3%
Citric acid 0.1%
Water 30%
Production technology: guar gum is added in the entry, and adding citric acid is fully after the dissolving; Add glycerol, polyoxyethylenated alcohol sodium sulfate, be heated to 70~85 ℃, be stirred to dissolving fully; Add pearling agent, cocos nucifera oil acyl MEA, cocoyl CAB, cocoyl sodium isethionate are to dissolving; Cooling, discharging.
Embodiment 5:
A kind of liquid detergent: liquid detergent, its each component weight percent content is:
Glycerol 47.9%
Polyoxyethylenated alcohol sodium sulfate (70%) 15%
Cocos nucifera oil acyl diethanolamine 2%
Cocoyl CAB (30%) 5%
Citric acid 0.1%
Water 30%
Production technology: glycerol, water, citric acid, polyoxyethylenated alcohol sodium sulfate are stirred to dissolving fully together, add cocos nucifera oil acyl diethanolamine, cocoyl CAB again, stir discharging.
Embodiment 6
A kind of liquid detergent: liquid detergent, its each component weight percent content is:
Glycerol 66%
Polyoxyethylenated alcohol sodium sulfate (70%) 8%
Hexadecyltrimethylammonium chloride 0.6%
Fatty alcohol-polyoxyethylene ether (7) 6%
Fatty alcohol-polyoxyethylene ether (9) 6%
Lauryl imidazoline (30%) 3%
Hydroxyethyl-cellulose 0.3%
Water 10%
Citric acid 0.1%
Production technology: hydroxyethyl-cellulose is dissolved in water; Add glycerol, polyoxyethylenated alcohol sodium sulfate; Add hexadecyltrimethylammonium chloride, fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), lauryl imidazoline, citric acid then, stir discharging.
Embodiment 7:
A kind of liquid detergent: shampoo, its each component weight percent content is:
Glycerol 42.8%
AESA (70%) 15%
Ammonium alkyl sulfate (70%) 5%
Cocos nucifera oil acyl MEA 1%
Pearling agent 1.5%
Guar gum quaternary ammonium salt 0.3%
Polyquaternary ammonium salt-10 0.3%
Cocoyl CAB (30%) 5%
Emulsified silicone oil (50%) 4%
Water 25%
Citric acid 0.1%
Production technology: guar gum quaternary ammonium salt, polyquaternary ammonium salt-10 are added in the entry, and adding citric acid is fully after the dissolving; Add glycerol, AESA, ammonium alkyl sulfate, be heated to 70~85 ℃, be stirred to dissolving fully, add pearling agent; Cocos nucifera oil acyl MEA, cocoyl CAB are cooled to 50 ℃, add emulsified silicone oil; Stir discharging.
Embodiment 8:
A kind of liquid detergent: cleansing milk, its each component weight percent content is:
Glycerol 42.7%
Water 20%
Dodecoic acid 1%
Tetradecylic acid 15%
Stearic acid 10%
Potassium hydroxide 5.3%
Polyethylene Glycol-1,500 2%
Glyceryl monostearate 2%
Tween 80 1%
Cera Flava 1%
Production technology:
A (water): KOH is added in the entry, add glycerol, Polyethylene Glycol-1500, tween 80 again, be heated to 80~85 ℃.
B (oil phase): tetradecylic acid, stearic acid, dodecoic acid, Cera Flava, glyceryl monostearate are heated 80~85 ℃.
C: B poured into be stirred to fully neutralization among the A, lower the temperature about 40 ℃ discharging.
In the foregoing description, can also contain other skin protection, the beauty treatment of different content, the mixture of hair care additive in the basic detergent, various raw materials all have commercially available.

Claims (4)

1. liquid scrubbing articles for use that do not contain antiseptic; Comprise cleansing milk, shampoo, handwashing liquid, bath gel, liquid detergent and liquid detergent; It is characterized in that by glycerol and basic detergent mixedly, the weight percent content of glycerol is 10% ~ 90% in the described liquid scrubbing articles for use.
2. the liquid scrubbing articles for use that do not contain antiseptic according to claim 1, the weight percent content that it is characterized in that described glycerol is 30% ~ 80%.
3. the liquid scrubbing articles for use that do not contain antiseptic according to claim 1 is characterized in that described basic detergent is alkalescence, neutral or acid.
4. the liquid scrubbing articles for use that do not contain antiseptic according to claim 1 is characterized in that described basic detergent is liquid, semisolid or paste.
CN2011103895325A 2011-11-30 2011-11-30 Preservative-free liquid detergents Pending CN102429827A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011103895325A CN102429827A (en) 2011-11-30 2011-11-30 Preservative-free liquid detergents

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011103895325A CN102429827A (en) 2011-11-30 2011-11-30 Preservative-free liquid detergents

Publications (1)

Publication Number Publication Date
CN102429827A true CN102429827A (en) 2012-05-02

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CN2011103895325A Pending CN102429827A (en) 2011-11-30 2011-11-30 Preservative-free liquid detergents

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109674677A (en) * 2019-02-15 2019-04-26 深圳市仙迪化妆品有限公司 A kind of faintly acid clean skin without preservative or clean hair composition and preparation method thereof
CN109700673A (en) * 2019-02-27 2019-05-03 深圳市仙迪化妆品有限公司 A kind of acid effect clean skin product and preparation method thereof containing alkaline particle

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06182190A (en) * 1992-07-27 1994-07-05 Hoechst Ag Flowable glossy dispersing liquid free from preservative
CN1354238A (en) * 2000-11-22 2002-06-19 上海白猫有限公司 Detergent for washing infantile clothes
WO2008034699A1 (en) * 2006-09-20 2008-03-27 L'oreal Process for preparing a cosmetic composition from plant or mineral extracts
WO2010034721A2 (en) * 2008-09-23 2010-04-01 Unilever Plc Stable cleansing compositions containing fatty acyl isethionate surfactant products having more than 10 wt.% of fatty acid/fatty soap content using high level of polyol and methods thereof
CN101979489A (en) * 2010-11-03 2011-02-23 广州南顺清洁用品有限公司 Moisture-less and preservative-less super-concentrated hand-washing detergent composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06182190A (en) * 1992-07-27 1994-07-05 Hoechst Ag Flowable glossy dispersing liquid free from preservative
CN1354238A (en) * 2000-11-22 2002-06-19 上海白猫有限公司 Detergent for washing infantile clothes
WO2008034699A1 (en) * 2006-09-20 2008-03-27 L'oreal Process for preparing a cosmetic composition from plant or mineral extracts
WO2010034721A2 (en) * 2008-09-23 2010-04-01 Unilever Plc Stable cleansing compositions containing fatty acyl isethionate surfactant products having more than 10 wt.% of fatty acid/fatty soap content using high level of polyol and methods thereof
CN101979489A (en) * 2010-11-03 2011-02-23 广州南顺清洁用品有限公司 Moisture-less and preservative-less super-concentrated hand-washing detergent composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109674677A (en) * 2019-02-15 2019-04-26 深圳市仙迪化妆品有限公司 A kind of faintly acid clean skin without preservative or clean hair composition and preparation method thereof
CN109700673A (en) * 2019-02-27 2019-05-03 深圳市仙迪化妆品有限公司 A kind of acid effect clean skin product and preparation method thereof containing alkaline particle

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Application publication date: 20120502