CN105012209A - Marine fish oil bath lotion and preparation method thereof - Google Patents
Marine fish oil bath lotion and preparation method thereof Download PDFInfo
- Publication number
- CN105012209A CN105012209A CN201510376678.4A CN201510376678A CN105012209A CN 105012209 A CN105012209 A CN 105012209A CN 201510376678 A CN201510376678 A CN 201510376678A CN 105012209 A CN105012209 A CN 105012209A
- Authority
- CN
- China
- Prior art keywords
- fish oil
- deep sea
- bath gel
- sea fish
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses a marine fish oil bath lotion and a preparation method thereof. The bath lotion provided by the invention takes marine fish oil as the basic component, and the auxiliary materials include strong base, a washing assistant, essential oil, an antiseptic, an antibacterial agent, a skin care agent, essential oil and deionized water etc. Under suitable conditions, marine fish oil and strong base are subjected to saponification reaction according to certain proportion, and an optimized process is employed for preparation to as to form a marine fish oil based bath lotion. The bath lotion provided by the invention has the advantages of strong decontamination ability, no pollution, strong degradation ability and no secondary pollution, has moisturizing effect, and is conducive to environment friendly rapid development. Through component and condition optimization, the bath lotion has the characteristics of excellent washing effect, simple components, health and environmental protection, etc., can relieve skin dryness and tight sense, has nourishing and moistening effects to skin, bactericidal and bacteriostatic efficacy and superstrong decontamination ability, and realizes high value utilization of feed grade fish oil, thus having extensive industrialization prospect and market value.
Description
Technical field
The present invention relates to a kind of health type daily use chemicals washing product, particularly relate to deep sea fish oil bath gel and preparation method thereof.
Background technology
The Main Ingredients and Appearance of fish oil is triglyceride, phosphorus glycerin ether, lipoid, fatsoluble vitamin, and protein degradation thing etc.Hydrargyrum, arsenic, plumbous noxious substance is not all measured in the fish body of marine fishes, and potassium, copper, aluminum, cadmium etc. are all lower than health permissible value, persticide residue is also no better than zero, thus obtaining fish oil with fish and garbage machining thereof, to be used as the quality of oils and fats be reliable, the same with other oils and fatss, fish oil also can be used for carrying out saponification, is applied in daily use chemicals production.Now commercially there is the Cleaning preparations of abundant species, and in existing production technology, major part Cleaning preparations is all synthetic, the use of this type of detergent not only can cause certain injury to health, the discharge of washes also can cause environmental pollution, and therefore this area still needs the bath gel of more healthy natural green.The present inventor, by concentrated research, finds that fish oil soap compound has stronger clean result, and has the surfactant of natural health in ocean, can degradation of contaminant, and does not hinder hands and be beneficial to environment sustainable development.
Up to the present, there is many relevant reports of the bath gel of many health environment-friendlies in prior art, such as:
CN103655314A application discloses a kind of humidity-preserving type bath foam containing marine biomaterial, percentage proportioning is as follows: Sargassum polysaccharides 2.0-4.0%; Chitin 1.0-2.0%; Alcohol ether carboxylate AEC15.0-20.0%; Cocamido propyl betaine 5.0-8.0%; Polyoxyethylenated alcohol sodium sulfate 6.0-10.0%; Disodiumedetate 0.2-0.3%; Glycerol 2.0-5.0%; Sea salt 1.0%; Citric acid is appropriate; Plants essential oil 0.1-0.3%; Antiseptic 0.1%; The humidity-preserving type bath foam of the marine biomaterial of this invention, due to containing Sargassum polysaccharides and chitin composition, can not only effectively remove skin surface dirt after using, and then have the effect of moisturizing, skin moistening, anti-inflammation, have multi-efficiency.
CN103637963A application discloses a kind of bath gel, by surfactant tea saponin, the alkyl polyglucoside of green safety, the gentle surfactant dodecanamide propyl amine oxide of safety, fatty acid potassium soap, cation guar gum, auxiliary agent sucrose fatty acid ester (surely steeping thickening agent), Aloe extraction solution and other safe auxiliary agent as formulated in disodium EDTA, antiseptic and deionized water.This invention formula is reasonable, raw material sources very abundant and belong to Renewable resource, without any side effects to human body, this bath gel green ecological environmental protection, can alleviate dry and astringent, the tight sense of skin, effectively suppress pruritus, and to the nutritious moist effect of skin, life-time service can make skin tender smooth flexible, has bactericidal, anti-inflammatory anti-itch effect, has auxiliary therapeutic action to erythra, miliaria.
CN103637941A application discloses a kind of bath gel, by weight, and Myosotis sylvatica extract 10-20; Dodecyl alcohol polyvinylether sodium sulfate 6-8; Propylene glycol 1-3; Glycol distearate 1-2; LAA 4-8; Oleic acid 3-5; Cocos nucifera oil acyl methyl taurine sodium sulfonate 5-8; Polyquaternary ammonium salt-391-3; Sodium chloride 1.5-3.5; Polyquaternary ammonium salt-71-3; Poly (sodium aspartate) 1-3; Coconut oleoyl amine MEA3-5; Stearic acid 1-3; Hydroxypropyl emthylcellulose 0.05-0.2; EDTA-sodium 0.05-0.2; Deionized water 50-80.This invention bath gel life-time service has improvement result to corse sweat pore, coarse skin quality.
CN103393589A application discloses a kind of highly effective and safe, adopts the sterilization shower cream product of modern biotechnology Product processing.Invention forms primarily of anion surfactant, non-ionic surface active agent, amphoteric surfactant, deionized water, thickening agent, nutrient, emollient and glycerol, it is characterized in that containing antibacterial, this antibacterial is the fermentation broth extract of bacillus subtilis.Bath gel preparation method, comprising the steps: to add deionized water in reactor heats, and add the materials such as anion surfactant and stir, temperature is down to 40 DEG C, adjust pH, adds nutrient etc., deionized water polishing, stir, speed of agitator is at 20 ~ 30 revs/min, degassed.The present invention, not only achieve the function that bath gel removes dirt, and possessed the effect of good sterilization and sterilization, the antibacterial added in invention has antiseptical function, has feature safely and efficiently.
CN103315921A application discloses a kind of bath gel, weight percentage: surfactant 12 ~ 30%, oligofructose 0.1 ~ 5%, thickening agent 0.2 ~ 0.5%, and water is surplus, and the pH value of described bath gel is 5.5 to 7.0.This bath gel, is widely used in male, women and infant.While clean, fragrant health, be conducive to recovering, formed, maintain healthy Tiny ecosystem body surface environment, the growth of propagation profitable strain, competitive inhibition pernicious bacteria, is conducive to health.
CN102973427A application discloses a kind of Mint shower gel, described Mint shower gel is made up of the raw material of following component: deionized water 30-40 part, menthol 10-12 part, Cocamidopropyl sweet soda acid 2-4 part, salicylic acid 4-6 part, hydroxypropyl emthylcellulose 2-6 part, anhydrous sodium sulfate 6-8 part.This Mint shower gel has the effect of refreshment, non-stimulated to skin, meets the demand of people.
Summary of the invention
The object of the invention is to provide one containing artificially synthesised surfactant for prior art, do not add any poisonous and harmful substance, clean result is good, bacteriostasis is strong, the obvious deep sea fish oil bath gel of health environment-friendly, skin protection soothing effect and preparation method thereof.
The present invention solves the problems of the technologies described above adopted technical scheme: deep sea fish oil bath gel and preparation method thereof, and comprising with deep sea fish oil is primary raw material, wherein: with 100 parts by weight, containing, for example lower component:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing assisant 1-8;
Antiseptic 0.2-1;
Skin protectant 1-5;
Antibacterial 0.5-2;
Deionized water surplus.
By component preferably and the optimization of condition, this bath gel is made to have the characteristics such as the simple and health environment-friendly of clean result excellence, composition, dry and astringent, the tight sense of skin can be alleviated, to the nutritious moist effect of skin, there are effect of bactericidal and superpower dirt-removing power, and feed grade fish oil is carried out higher value application, make it have industrial prospect and market value widely.
For optimizing technique scheme, the measure taked also comprises: deep sea fish oil is adopted and prepared with the following method:
1) crude fish oil preparation: the mixing internal organs of fresh fish are removed impurity, and drain after cleaning, then homogenate is smashed to pieces and stirred evenly; Distilled water is added in the ratio of solid-liquid ratio 1 ︰ 1 to 1:1.2, pour in the flask cleaned up in advance after regulating pH=8 with KOH and HCl, then 1.8% neutral protease and tryptic mixture is added, place it in enzymolysis 3.5h in the thermostat water bath of 45 DEG C, by solution after enzymolysis in centrifuges with the centrifugal 15min of 6000r/min, isolate upper strata oils and fats, add the extraction of appropriate petroleum ether solvent, remove unnecessary petroleum ether with Rotary Evaporators, obtain crude fish oil;
2) ferment treatment of crude fish oil: get crude fish oil prepared by step 1) and add 0.3g/kg antioxidant, protease and tryptic mass ratio are 1:1;
3) phosphoric acid degumming: the crude fish oil of precise certain mass is in beaker, be placed on heated and stirred to 80 DEG C in water-bath, slowly adding crude fish oil amount 1% concentration is the phosphoric acid of 75%, continuous stirring is until evenly, 6min is heated under condition at 80 DEG C, then with the centrifugal 15min of 3500rpm, isolate upper strata oil sample, be the crude fish oil that comes unstuck; This step is carried out under being in inflated with nitrogen state always;
4) sodium hydroxide deacidification: add the NaOH solution uniform stirring of 12 ° of Be of 0.2% in the fish oil that comes unstuck after, be heated to 65 DEG C, insulation 30min, is then cooled to room temperature, static layering, with the centrifugal 15min of 4000rpm, removing precipitation.And then remove the soap that remains with the washing of certain volume, until clean up; Upper strata deacidification crude fish oil is got after separatory; This step is carried out under being in inflated with nitrogen state always;
5) crude fish oil decolouring: the deacidification fish oil of above-mentioned gained is heated to 65 DEG C in a water bath, adds 12% active hargil, constantly stirs and makes mix homogeneously, after maintaining 20min, with the centrifugal 15min of 4000rpm, is separated and obtains the fish oil that decolours;
6) fish oil eliminating sargassum smell: step 5) gained decolouring fish oil is put into round-bottomed flask, utilizes Rotary Evaporators to be heated to 70 ~ 80 DEG C of deodorize 30 ~ 40min; Except smelling removal stink substance, obtain deep sea fish oil;
Step 3) to step 6) is carried out under being in inflated with nitrogen state.Antioxidant is selected from any one or multiple mixture of natural Vitamin E, sodium sulfite, sodium pyrosulfite, 2,6-di-tert-butyl-4-methy phenols.Washing assisant is selected from any one or multiple mixing in EDTA-2Na, sodium citrate, sodium bicarbonate, sodium carbonate.Antiseptic is selected from vitamin E or potassium sorbate or sodium benzoate or its combination; Highly basic is selected from potassium hydroxide or sodium hydroxide.Fish oil is selected from common fish oil or bathypelagic fish oil or its and combines.Skin protectant is selected from glycerol.Antibacterial is selected from nanometer silver.9, prepare a kind of preparation method as claim 1 deep sea fish oil bath gel, it is characterized in that: there are following steps:
A) by fish oil heating in water bath to 60 DEG C-80 DEG C;
B) highly basic is dissolved in distilled water, cools to 60 DEG C-80 DEG C;
C) by step B) aqueous solution slowly pour steps A into) basic grease solution in, and constantly stir about 90min, until become pasty state dope;
D) by step C) gains be stored in couveuse inside holding 12 ~ 24h, then take out be placed in ventilation ripening one to fortnight;
E) in the soap base after ripening, add the hot distilled water of preparation ratio, be dissolved into soap lye, in solution, add appropriate washing assisant, antiseptic, skin protectant, antibacterial successively again, uniform stirring forms the strong uniform liquid of mobility, obtains the bath gel based on deep sea fish oil;
Preparation ratio with 100 parts by weight, containing, for example lower ratio component:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing assisant 1-8;
Antiseptic 0.2-1;
Skin protectant 1-5;
Antibacterial 0.5-2;
Deionized water surplus.
Because the present invention passes through the optimization of the preferred of component and condition, this bath gel is made to have the characteristics such as the simple and health environment-friendly of clean result excellence, composition, dry and astringent, the tight sense of skin can be alleviated, to the nutritious moist effect of skin, there are effect of bactericidal and superpower dirt-removing power, and feed grade fish oil is carried out higher value application, make it have industrial prospect and market value widely.Thus the present invention have not containing artificially synthesised surfactant, do not add any poisonous and harmful substance, clean result is good, bacteriostasis is strong, health environment-friendly, the obvious advantage of skin protection soothing effect.
Detailed description of the invention
Below in conjunction with attached embodiment, the present invention is described in further detail.
embodiment 1:
Be 100 parts by total weight parts, a kind of bath gel preparation method based on deep sea fish oil is as follows:
(1) by 15 weight portion fish oil heating in water bath to 60 DEG C;
(2) 3 weight portion potassium hydroxide are dissolved in distilled water, cool to 60 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Poly Foam couveuse inside holding 24h, take out afterwards and be placed in ventilation ripening fortnight.
(5) in the soap base after ripening, add a certain proportion of hot distilled water, be dissolved into soap lye,
In solution, add 2 weight portions more successively washing assisant sodium bicarbonate and sodium citrate (are adjusted
PH=6), the antiseptic vitamin E of 0.4 weight portion, the skin protectant glycerol of 2 weight portions, the antibacterial nanometer silver etc. of 0.6 weight portion, uniform stirring forms the strong uniform liquid of mobility, obtains the bath gel based on deep sea fish oil, called after 1 group.
embodiment 2:
Be 100 parts by total weight parts, a kind of bath gel preparation method based on deep sea fish oil is as follows:
(1) by 19 weight portion fish oil heating in water bath to 65 DEG C;
(2) 3.8 weight portion potassium hydroxide are dissolved in distilled water, cool to 65 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Poly Foam couveuse inside holding 24h, take out afterwards and be placed in ventilation ripening fortnight.
(5) in the soap base after ripening, add a certain proportion of hot distilled water, be dissolved into soap lye,
In solution, add 4 weight portions more successively washing assisant EDTA-2Na and sodium citrate (are adjusted
PH=7), the preservative sodium benzoate of 0.5 weight portion, the skin protectant glycerol of 3 weight portions, the antibacterial nanometer silver etc. of 0.8 weight portion, uniform stirring forms the strong uniform liquid of mobility, obtains the bath gel based on deep sea fish oil, called after 2 groups.
embodiment 3:
Be 100 parts by total weight parts, a kind of bath gel based on deep sea fish oil is prepared as follows:
(1) by 27 weight portion fish oil heating in water bath to 70 DEG C;
(2) 5.4 weight portion potassium hydroxide are dissolved in distilled water, cool to 70 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Poly Foam couveuse inside holding 24h, take out afterwards and be placed in ventilation ripening fortnight.
(5) in the soap base after ripening, a certain proportion of hot distilled water is added, be dissolved into soap lye, the washing assisant sodium citrate of 6 weight portions and sodium carbonate (adjusting pH=7), the potassium sorbate preservative of 0.6 weight portion, the skin protectant glycerol of 4 weight portions, the antibacterial nanometer silver etc. of 1.0 weight portions is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the bath gel based on deep sea fish oil, called after 3 groups.
embodiment 4:
Be 100 parts by total weight parts, a kind of bath gel based on deep sea fish oil is prepared as follows:
(1) by 30 weight portion fish oil heating in water bath to 75 DEG C;
(2) 6 weight portion potassium hydroxide are dissolved in distilled water, cool to 75 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Poly Foam couveuse inside holding 24h, take out afterwards and be placed in ventilation ripening fortnight.
(5) in the soap base after ripening, add a certain proportion of hot distilled water, be dissolved into soap lye,
The washing assisant EDTA-2Na of 8 weight portions and sodium bicarbonate (adjusting pH=6), the antiseptic vitamin E of 0.8 weight portion, the skin protectant glycerol of 5 weight portions, the antibacterial nanometer silver etc. of 1.8 weight portions is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the bath gel based on deep sea fish oil, called after 4 groups.
embodiment 5:
Be 100 parts by total weight parts, a kind of bath gel based on deep sea fish oil is prepared as follows:
(1) by 23 weight portion fish oil heating in water bath to 80 DEG C;
(2) 4.6 weight portion potassium hydroxide are dissolved in distilled water, cool to 80 DEG C;
(3) aqueous solution of step (2) is slowly poured in the basic grease solution of step (1), and constantly stir about 90min, until become pasty state dope.
(4) gains of step (3) are stored in Poly Foam couveuse inside holding 24h, take out afterwards and be placed in ventilation ripening fortnight.
(5) in the soap base after ripening, add a certain proportion of hot distilled water, be dissolved into soap lye,
The washing assisant sodium citrate of 6 weight portions and sodium bicarbonate (adjusting pH=7), the antiseptic vitamin E of 1.0 weight portions, the skin protectant glycerol of 4 weight portions, the antibacterial nanometer silver etc. of 1.6 weight portions is added again successively in solution, uniform stirring forms the strong uniform liquid of mobility, obtain the bath gel based on deep sea fish oil, called after 5 groups.
performance test is tested
The present invention is a kind of to be tested based on the bath gel clean effect based on deep sea fish oil.The healthy bath gel of the deep sea fish oil prepared by the present invention is used to adopt detergency test method(s) (Shiseido method) to measure its detergency.
experimental procedure:
Take CaO and MgO that quantitative ratio is 3:1, with 5
0the artificial hard water of DH is mixed with 1% sample solution.
Wash with gurgle artificial contamination's cloth of sound of a bird chirping of hair.At 40 DEG C, wash with decontamination testing machine, obtain clean result by the reflectance before and after washing.
Calculate clean result, adopt following formula:
Experimental result is in table 1.
R
0: the reflectance of former cloth (hair gurgle sound of a bird chirping)
Rs: the reflectance polluting cloth
R
w: the reflectance of the pollution cloth after cleaning
2, the bactericidal effect that the present invention is based on based on the bath gel of deep sea fish oil is tested.
Use staphylococcus aureus, escherichia coli as the strain of bactericidal assay; The bath gel based on deep sea fish oil of use prepared by the present invention is as bactericidal agent.
experimental procedure
(1) solution that 0.5 mL staphylococcus aureus and colibacillary bacteria suspension be the present invention is based on respectively the bath gel of deep sea fish oil with 4.5 mL mixes, and leaves standstill effect 10 min, obtains two kinds of bacterium medicine suspensions respectively;
(2) nertralizer that 0.5 mL bacterium medicine suspension adds 4.5 mL is respectively got, after mixing, comprehensive function 8 min, get 0.5 mL mixing liquid inoculation plate respectively, pour into plain agar and mix, cultivating 36 hours at 37 DEG C, counting clump count, calculate sterilizing rate, experimental result is in table 2.
interpretation of result
Table 1. each group of clean result based on the bath gel of deep sea fish oil compares
| Group | Clean result |
| 1 group | 89% |
| 2 groups | 90% |
| 3 groups | 93% |
| 4 groups | 92% |
| 5 groups | 90% |
From table 1 result: adopt the clean result after the bath gel of deep sea fish oil of the present invention all to reach more than 88%, the visible suitable selection by component and particular combination, make this bath gel show excellent washing force.
Table 2. each group of Comparison of effect on sterilization based on the bath gel of deep sea fish oil
From table 2 result: adopt the bath gel based on deep sea fish oil of the present invention to carry out bacteriostatic experiment and all obtain the excellent effect that sterilizing rate reaches more than 90%, the visible suitable selection by component and particular combination, make this bath gel be attended by good sterilizing power.
Comprehensively above-mentioned, bath gel based on deep sea fish oil of the present invention has the advantages such as component is simple, preparation is convenient, its suitable selection by component and particular combination and show excellent clean effect, and be attended by good sterilizing power simultaneously, achieve beat all effect, there is industrial production prospect and market value widely.
Embodiment 6: deep sea fish oil bath gel and preparation method thereof, comprising with deep sea fish oil is primary raw material, wherein: with 100 parts by weight, containing, for example lower component:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing assisant 1-8;
Antiseptic 0.2-1;
Skin protectant 1-5;
Antibacterial 0.5-2;
Deionized water surplus.
Of the present invention based in the bath gel of deep sea fish oil, its deep sea fish oil is common fish oil or bathypelagic fish oil, and its parts by weight are 15-30 part, and this scope includes any subinterval scope wherein, as being 15-20 part, 21-25 part, 26-30 part.
Of the present invention based in the bath gel of deep sea fish oil, highly basic is sodium hydroxide or potassium hydroxide, and its parts by weight are 3-6 part, and this scope includes any subinterval scope wherein, as being 3-4 part, 4-5 part, 5-6 part.
Of the present invention based in the bath gel of deep sea fish oil, washing assisant is from any one in EDTA-2Na, sodium citrate, sodium bicarbonate and sodium carbonate or multiple mixture, and adjust pH=6-7, its parts by weight are 1-8 part, this scope includes any subinterval scope wherein, as being 1-4 part, 3-6 part, 5-8 part.
Of the present invention based in the bath gel of deep sea fish oil, antiseptic is any one or multiple mixture in vitamin E, sodium benzoate or potassium sorbate, its parts by weight are 0.2-1 part, this scope includes any subinterval scope wherein, as being 0.2-0.5 part, 0.4-0.7 part, 0.7-1.0 part.
Of the present invention based in the bath gel of deep sea fish oil, skin protectant is glycerol, and its parts by weight are 1-5 part, and this scope includes any subinterval scope wherein, as being 1-2 part, 3-4 part, 4-5 part.
Of the present invention based in the bath gel of deep sea fish oil, antibacterial is nanometer silver, and its parts by weight are 0.5-2 part, and this scope includes any subinterval scope wherein, as being 0.5-0.9 part, 1.0-1.5 part, 1.6-2.0 part.
By component preferably and the optimization of condition, this bath gel is made to have the characteristics such as the simple and health environment-friendly of clean result excellence, composition, dry and astringent, the tight sense of skin can be alleviated, to the nutritious moist effect of skin, there are effect of bactericidal and superpower dirt-removing power, and feed grade fish oil is carried out higher value application, make it have industrial prospect and market value widely.Deep sea fish oil is adopted and is prepared with the following method:
1) crude fish oil preparation: the mixing internal organs of fresh fish are removed impurity, and drain after cleaning, then homogenate is smashed to pieces and stirred evenly; Distilled water is added in the ratio of solid-liquid ratio 1 ︰ 1 to 1:1.2, pour in the flask cleaned up in advance after regulating pH=8 with KOH and HCl, then 1.8% neutral protease and tryptic mixture is added, place it in enzymolysis 3.5h in the thermostat water bath of 45 DEG C, by solution after enzymolysis in centrifuges with the centrifugal 15min of 6000r/min, isolate upper strata oils and fats, add the extraction of appropriate petroleum ether solvent, remove unnecessary petroleum ether with Rotary Evaporators, obtain crude fish oil;
2) ferment treatment of crude fish oil: get crude fish oil prepared by step 1) and add 0.3g/kg antioxidant, protease and tryptic mass ratio are 1:1;
3) phosphoric acid degumming: the crude fish oil of precise certain mass is in beaker, be placed on heated and stirred to 80 DEG C in water-bath, slowly adding crude fish oil amount 1% concentration is the phosphoric acid of 75%, continuous stirring is until evenly, 6min is heated under condition at 80 DEG C, then with the centrifugal 15min of 3500rpm, isolate upper strata oil sample, be the crude fish oil that comes unstuck; This step is carried out under being in inflated with nitrogen state always;
4) sodium hydroxide deacidification: add the NaOH solution uniform stirring of 12 ° of Be of 0.2% in the fish oil that comes unstuck after, be heated to 65 DEG C, insulation 30min, is then cooled to room temperature, static layering, with the centrifugal 15min of 4000rpm, removing precipitation.And then remove the soap that remains with the washing of certain volume, until clean up; Upper strata deacidification crude fish oil is got after separatory; This step is carried out under being in inflated with nitrogen state always;
5) crude fish oil decolouring: the deacidification fish oil of above-mentioned gained is heated to 65 DEG C in a water bath, adds 12% active hargil, constantly stirs and makes mix homogeneously, after maintaining 20min, with the centrifugal 15min of 4000rpm, is separated and obtains the fish oil that decolours;
6) fish oil eliminating sargassum smell: step 5) gained decolouring fish oil is put into round-bottomed flask, utilizes Rotary Evaporators to be heated to 70 ~ 80 DEG C of deodorize 30 ~ 40min; Except smelling removal stink substance, obtain deep sea fish oil;
Step 3) to step 6) is carried out under being in inflated with nitrogen state.Antioxidant is selected from any one or multiple mixture of natural Vitamin E, sodium sulfite, sodium pyrosulfite, 2,6-di-tert-butyl-4-methy phenols.Washing assisant is selected from any one or multiple mixing in EDTA-2Na, sodium citrate, sodium bicarbonate, sodium carbonate.Antiseptic is selected from vitamin E or potassium sorbate or sodium benzoate or its combination; Highly basic is selected from potassium hydroxide or sodium hydroxide.Fish oil is selected from common fish oil or bathypelagic fish oil or its and combines.Skin protectant is selected from glycerol.Antibacterial is selected from nanometer silver.9, prepare a kind of preparation method as claim 1 deep sea fish oil bath gel, it is characterized in that: there are following steps:
A) by fish oil heating in water bath to 60 DEG C-80 DEG C;
B) highly basic is dissolved in distilled water, cools to 60 DEG C-80 DEG C;
C) by step B) aqueous solution slowly pour steps A into) basic grease solution in, and constantly stir about 90min, until become pasty state dope;
D) by step C) gains be stored in couveuse inside holding 12 ~ 24h, then take out be placed in ventilation ripening one to fortnight;
E) in the soap base after ripening, add the hot distilled water of preparation ratio, be dissolved into soap lye, in solution, add appropriate washing assisant, antiseptic, skin protectant, antibacterial successively again, uniform stirring forms the strong uniform liquid of mobility, obtains the bath gel based on deep sea fish oil; Preparation ratio is as aforementioned.
Although describe the present invention in conjunction with preferred embodiment; so itself and be not used to limit the present invention; any those skilled in the art; without departing from the spirit and scope of the present invention; can implement various change, the displacement of coordinate and amendment here to the theme listed, therefore protection scope of the present invention be as the criterion when the scope limited depending on proposed claim.
Claims (10)
1. deep sea fish oil bath gel, comprising with deep sea fish oil is primary raw material, it is characterized in that: with 100 parts by weight, containing, for example lower component:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing assisant 1-8;
Antiseptic 0.2-1;
Skin protectant 1-5;
Antibacterial 0.5-2;
Deionized water surplus.
2. deep sea fish oil bath gel according to claim 1, is characterized in that: described deep sea fish oil is adopted and prepared with the following method:
1) crude fish oil preparation: the mixing internal organs of fresh fish are removed impurity, and drain after cleaning, then homogenate is smashed to pieces and stirred evenly; Distilled water is added in the ratio of solid-liquid ratio 1 ︰ 1 to 1:1.2, pour in the flask cleaned up in advance after regulating pH=8 with KOH and HCl, then 1.8% neutral protease and tryptic mixture is added, place it in enzymolysis 3.5h in the thermostat water bath of 45 DEG C, by solution after enzymolysis in centrifuges with centrifugal 15 min of 6000 r/min, isolate upper strata oils and fats, add the extraction of appropriate petroleum ether solvent, remove unnecessary petroleum ether with Rotary Evaporators, obtain crude fish oil;
2) ferment treatment of crude fish oil: get crude fish oil prepared by step 1) and add 0.3g/kg antioxidant, described protease and tryptic mass ratio are 1:1;
3) phosphoric acid degumming: the crude fish oil of precise certain mass is in beaker, be placed on heated and stirred to 80 DEG C in water-bath, slowly adding crude fish oil amount 1% concentration is the phosphoric acid of 75%, continuous stirring is until evenly, 6 min are heated under condition at 80 DEG C, then with the centrifugal 15min of 3500rpm, isolate upper strata oil sample, be the crude fish oil that comes unstuck; This step is carried out under being in inflated with nitrogen state always;
4) sodium hydroxide deacidification: add the NaOH dissolution homogeneity stirring of 12 ° of Be of 0.2% in the fish oil that comes unstuck after, be heated to 65 DEG C, insulation 30min, is then cooled to room temperature, static layering, with the centrifugal 15min of 4000rpm, removing precipitation.
3. and then remove the soap that remains with the washing of certain volume, until clean up; Upper strata deacidification crude fish oil is got after separatory; This step is carried out under being in inflated with nitrogen state always;
5) crude fish oil decolouring: the deacidification fish oil of above-mentioned gained is heated to 65 DEG C in a water bath, adds 12% active hargil, constantly stirs and makes mix homogeneously, after maintaining 20min, with the centrifugal 15min of 4000rpm, is separated and obtains the fish oil that decolours;
6) fish oil eliminating sargassum smell: step 5) gained decolouring fish oil is put into round-bottomed flask, utilizes Rotary Evaporators to be heated to 70 ~ 80 DEG C of deodorize 30 ~ 40min; Except smelling removal stink substance, obtain deep sea fish oil;
Described step 3) to step 6) is carried out under being in inflated with nitrogen state.
4. deep sea fish oil bath gel according to claim 1, is characterized in that: described antioxidant is selected from any one or multiple mixture of natural Vitamin E, sodium sulfite, sodium pyrosulfite, 2,6-di-tert-butyl-4-methy phenols.
5. deep sea fish oil bath gel according to claim 1, is characterized in that: described washing assisant is selected from any one or multiple mixing in EDTA-2Na, sodium citrate, sodium bicarbonate, sodium carbonate.
6. deep sea fish oil bath gel according to claim 1, is characterized in that: described antiseptic is selected from vitamin E or potassium sorbate or sodium benzoate or its combination; Described highly basic is selected from potassium hydroxide or sodium hydroxide.
7. deep sea fish oil bath gel according to claim 1, is characterized in that: described fish oil is selected from common fish oil or bathypelagic fish oil or its and combines.
8. deep sea fish oil bath gel according to claim 1, is characterized in that: described skin protectant is selected from glycerol.
9. deep sea fish oil bath gel according to claim 1, is characterized in that: described antibacterial is selected from nanometer silver.
10. prepare a kind of method of deep sea fish oil bath gel as claimed in claim 1, it is characterized in that: there are following steps:
A) by fish oil heating in water bath to 60 DEG C-80 DEG C;
B) highly basic is dissolved in distilled water, cools to 60 DEG C-80 DEG C;
C) by step B) aqueous solution slowly pour steps A into) basic grease solution in, and constantly stir about 90min, until become pasty state dope;
D) by step C) gains be stored in couveuse inside holding 12 ~ 24h, then take out be placed in ventilation ripening one to fortnight;
E) in the soap base after ripening, add the hot distilled water of preparation ratio, be dissolved into soap lye, in solution, add appropriate washing assisant, antiseptic, skin protectant, antibacterial successively again, uniform stirring forms the strong uniform liquid of mobility, obtains the bath gel based on deep sea fish oil;
Described preparation ratio with 100 parts by weight, containing, for example lower ratio component:
Deep sea fish oil 15-30;
Highly basic 3-6;
Washing assisant 1-8;
Antiseptic 0.2-1;
Skin protectant 1-5;
Antibacterial 0.5-2;
Deionized water surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510376678.4A CN105012209A (en) | 2015-07-01 | 2015-07-01 | Marine fish oil bath lotion and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510376678.4A CN105012209A (en) | 2015-07-01 | 2015-07-01 | Marine fish oil bath lotion and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105012209A true CN105012209A (en) | 2015-11-04 |
Family
ID=54402768
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510376678.4A Pending CN105012209A (en) | 2015-07-01 | 2015-07-01 | Marine fish oil bath lotion and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105012209A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107753313A (en) * | 2017-12-04 | 2018-03-06 | 胡江宇 | A kind of method that ultrasonic assistant prepares Astragaloside IV bath foam |
| CN107753306A (en) * | 2017-12-04 | 2018-03-06 | 胡江宇 | A kind of method that microwave radiation technology prepares Astragaloside IV bath foam |
| CN107789215A (en) * | 2017-12-04 | 2018-03-13 | 胡江宇 | A kind of preparation method of Astragaloside IV bath foam |
| CN115554219A (en) * | 2022-10-08 | 2023-01-03 | 爱乐士(惠州)化妆品有限公司 | Extraction process of roe extract |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101248821A (en) * | 2007-11-19 | 2008-08-27 | 广东海洋大学 | Process engineering for extracting fishes processing offal fish oil by enzymolysis process |
| CN101328456A (en) * | 2007-06-18 | 2008-12-24 | 上海市七宝中学 | Compound soap |
| JP2009091316A (en) * | 2007-10-10 | 2009-04-30 | Japan Advanced Institute Of Science & Technology Hokuriku | Cosmetic composition |
-
2015
- 2015-07-01 CN CN201510376678.4A patent/CN105012209A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101328456A (en) * | 2007-06-18 | 2008-12-24 | 上海市七宝中学 | Compound soap |
| JP2009091316A (en) * | 2007-10-10 | 2009-04-30 | Japan Advanced Institute Of Science & Technology Hokuriku | Cosmetic composition |
| CN101248821A (en) * | 2007-11-19 | 2008-08-27 | 广东海洋大学 | Process engineering for extracting fishes processing offal fish oil by enzymolysis process |
Non-Patent Citations (1)
| Title |
|---|
| 裘炳毅: "《化妆品化学与工艺技术大全（上册）》", 31 January 2000, 中国轻工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107753313A (en) * | 2017-12-04 | 2018-03-06 | 胡江宇 | A kind of method that ultrasonic assistant prepares Astragaloside IV bath foam |
| CN107753306A (en) * | 2017-12-04 | 2018-03-06 | 胡江宇 | A kind of method that microwave radiation technology prepares Astragaloside IV bath foam |
| CN107789215A (en) * | 2017-12-04 | 2018-03-13 | 胡江宇 | A kind of preparation method of Astragaloside IV bath foam |
| CN115554219A (en) * | 2022-10-08 | 2023-01-03 | 爱乐士(惠州)化妆品有限公司 | Extraction process of roe extract |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104800123B (en) | A kind of antibacterial soap base bath gel and preparation method thereof | |
| CN103637963B (en) | A kind of bath gel | |
| CN103642602B (en) | A kind of liquid detergent | |
| CN103961275A (en) | Daily necessities containing all-natural source surfactant and preparation method thereof | |
| CN101851564B (en) | Laundry detergent used for washing underwear | |
| CN104146889A (en) | Shampoo having scalp nursing efficacy and preparation method thereof | |
| CN102429844B (en) | Biological environment-friendly antioxidant itching-relieving bath wash and preparation method thereof | |
| CN103451037B (en) | A kind of bactericidal liquid detergent containing epsilon-polylysine | |
| MX2014001136A (en) | Personal care compositions having dried zinc pyrithione. | |
| CN103202781A (en) | Cream body bath composition and application thereof | |
| CN105012209A (en) | Marine fish oil bath lotion and preparation method thereof | |
| CN104519860A (en) | Personal care compositions having dried zinc pyrithione-polymer aggregates | |
| CN102871921A (en) | Hand cleaner composition | |
| CN102370607B (en) | Formula of bath cream with crystal salt and preparation method thereof | |
| CN103271834B (en) | Non-irritant pollution-free moisturizing pearly lustre bath foam and preparation method thereof | |
| CN101011319A (en) | Mineral salt shampoo | |
| CN103637964B (en) | A kind of preparation method of bath gel | |
| CN104606119A (en) | Sterilizing and disinfecting waterless hand cleaner | |
| CN102660397B (en) | A kind of for washing composition cleaning underwear and preparation method thereof | |
| CN111575128A (en) | Antibacterial laundry detergent and preparation method thereof | |
| CN104962408A (en) | Marine fish oil washing product and preparation method thereof | |
| CN105542973A (en) | Soap containing Chinese soapberry fruit saponin and preparation method thereof | |
| CN104688634A (en) | Soapberry scurf-removing itching-relieving shampoo | |
| CN107308084A (en) | A kind of konjaku glucomannan hand wash for children and preparation method thereof | |
| CN105733839A (en) | Sterilization mold-proof softening laundry detergent and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151104 |
|
| RJ01 | Rejection of invention patent application after publication |