CN105441215A - Environmentally friendly camellia seed detergent and preparation method thereof - Google Patents
Environmentally friendly camellia seed detergent and preparation method thereof Download PDFInfo
- Publication number
- CN105441215A CN105441215A CN201510936611.1A CN201510936611A CN105441215A CN 105441215 A CN105441215 A CN 105441215A CN 201510936611 A CN201510936611 A CN 201510936611A CN 105441215 A CN105441215 A CN 105441215A
- Authority
- CN
- China
- Prior art keywords
- environmental protection
- camellia seed
- out system
- clean
- protection tea
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C11D1/945—Mixtures with anionic, cationic or non-ionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
Abstract
The invention discloses an environmentally friendly camellia seed detergent and a preparation method thereof. The detergent is prepared through compounding and matching a raw material extract liquid refined from camellia seed meal, water and sodium carbonate with a nonionic surfactant and a gemini surfactant, and adding sodium chloride, essence and an antiseptic. Tea saponins in the camellia seed meal is compound and matched with the gemini surfactant, so the disadvantages of oil residual and weak decontamination capability of the camellia seed meal directly used as a washing product are overcome, and the problems of strong irritation and environmental pollution of completely chemically synthesized detergents are improved. The detergent disclosed in the invention has the advantages of simple synthesis process, no substances destroying environment or difficult to decompose, safety, environmental protection, excellent detergency, good removal ability on various oils, and good stability.
Description
Technical field
The present invention relates to a kind of daily cleaning articles for use, more specifically relate to a kind of environmental protection tea seed clean-out system and preparation method thereof.
Background technology
Clean-out system popular on present market, the thick liquid that the overwhelming majority is all made up of tensio-active agent, essence and water etc., because contained surfactant component is different, therefore often kind of clean-out system can only be applicable to certain scope.Part tensio-active agent there is certain toxicity or danger, the cleaning articles for use of the complete chemosynthesis of life-time service, not only Diazolidinyl Urea impacts health, and use after not easily decompose, waste water to ambient soil and water pollution quite serious.Therefore, prepare that a kind of use range is wide, soil removability is strong, clean-out system that is safety and environmental protection seems very important.
Though camellia seed meal is residue, composition is very abundant, containing tea saponin 10-14wt%, tea oil 6-8wt%, protein 15wt%, robust fibre 6wt% and other compositions.Wherein, tea saponin has the amphiphilic structure of hydrophilic and oleophilic, makes tea saponin become a kind of natural nonionogenic tenside of excellent property.Tea saponin has stronger emulsification, foaming, steady bubble, dispersion, the kinds of surface such as moistening are active, significantly can reduce the surface tension of the aqueous solution, simultaneously to celloglobulin class not damaged, can be used for manufacturing washing composition, pore forming material and emulsifying agent.Tea saponin is being used as while surfactant material, also has decontamination, sterilization, anti-inflammatory, the function such as antipruritic, especially has anti-microbial activity to Dermatophytes, thus can be used for preparing high-grade shampoo and tea saponin cleans articles for use.
China's camellia seed meal output is very high, but major part is taken as fuel burns, and small portion is used as the extraction of tea saponin or is used as animal-feed, causes the significant wastage of resource.At present, the camellia seed meal containing tea saponin directly uses as washing product by people, but there is the shortcoming that the seed dregs of rice itself are residual certain oily, soil removability is not strong.
Summary of the invention
The object of this invention is to provide a kind of environmental protection tea seed clean-out system and preparation method thereof.Employing camellia seed meal is raw material, by tea seed residue higher value application, makes full use of the tea saponin contained in camellia seed meal, avoids the wasting of resources.Prepared tea seed clean-out system plays high-effective cleansing, sterilization, clean effect, and all have good removal ability to each quasi-grease, product stability is good, simultaneously safety and environmental protection.
To achieve these goals, the technical solution used in the present invention is as follows:
The raw material composition of environmental protection tea seed clean-out system according to parts by weight is: a camellia seed meal 30-50 part, water 60-100 part, sodium carbonate 0.5-5 part, nonionic surface active agent 5-15 part, Gemini surface active agent 0.5-2 part, sodium-chlor 1-5 part, essence 0.1-2 part, sanitas 0.03-0.1 part.
Described camellia seed meal is the residue that tea seed is left after squeezing, general in puce particle.
Described nonionic surface active agent is the one in cocoanut fatty acid diethanolamide, sorbitan ester Soxylat A 25-7, polyoxyethylene nonylphenol ether.
Described Gemini surface active agent is two (the Dodecydimethylammonium bronides)-C12-2-12.2Br of dimethylene-1,2-
-, two (dodecyldimethylamine base the brometo de amonio)-C14-2-14.2Br of dimethylene-1,2-
-, one in the Ethylene Diamine diacrylate sodium of N, N'-bimonthly osmanthus.
Described sanitas is the one in Tegosept M, ethyl p-hydroxybenzoate, Imidurea.
Prepare a method for the environmental protection tea seed clean-out system as above-mentioned requirements, specifically comprise the following steps:
(1) camellia seed meal and water are added in retort, and add sodium carbonate, the pH of regulation system is 7.5-8.5, and hierarchy of control temperature is 65-85 DEG C, stirs 1-3h.Cool subsequently and carry out filtration removing residue, obtaining camellia seed meal extracting solution, now contain oil tea saponin 6-10wt% in extracting solution;
(2) the camellia seed meal extracting solution that step (1) is obtained is put into stirred pot, add nonionic surface active agent, Gemini surface active agent, essence and sanitas, hierarchy of control temperature is 40-70 DEG C, stirs 10-30min;
(3) in step (2) mixed solution, slowly add sodium-chlor thickening again, to be mixed evenly and denseness lower the temperature after reaching 0.4PaS ~ 0.6PaS, carry out package encapsulation, obtain environmental protection tea seed clean-out system.
Environmental protection tea seed clean-out system of the present invention adds Gemini surface active agent, can be formed act synergistically with the tea saponin in camellia seed meal, promotes the deep clean ability of clean-out system further.Tea saponin and Gemini surface active agent in camellia seed meal is utilized to carry out composite, camellia seed meal can be overcome preferably and directly there is residual oil, deficiency that soil removability is not strong as articles for washing, the pungency that the clean-out system that can improve complete chemosynthesis again brings is strong, to problems such as environment are unfriendly.
Beneficial effect of the present invention is:
(1) the camellia seed meal extracting solution in the present invention is natural component, and security is high, can not produce stimulation to skin, has effect of anti-bacteria and anti-virus simultaneously.
(2) clean-out system synthesis technique of the present invention is simple, not containing welding or the material being difficult to decomposition, and safety and environmental protection.
(3) washing composition of the present invention shows excellent scourability, all has good removal ability to each quasi-grease, and product stability can be good.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1:
Raw material needed for environmental protection tea seed clean-out system and formula: camellia seed meal 100g, water 200g, sodium carbonate 1.5g, cocoanut fatty acid diethanolamide 30g, two (the Dodecydimethylammonium bronides)-C12-2-12.2Br of dimethylene-1,2-
-1.2g, sodium-chlor 10g, essence 0.5g, Tegosept M 0.3g.
Environmental protection tea seed clean-out system preparation method: camellia seed meal and water are added in retort, and add sodium carbonate, the pH of regulation system is 7.5, and hierarchy of control temperature is 65 DEG C, stirs 3h.Cool subsequently and carry out filtration removing residue, camellia seed meal extracting solution can be obtained, now contain oil tea saponin 6wt% in extracting solution; Obtained camellia seed meal extracting solution is put into stirred pot, adds cocoanut fatty acid diethanolamide, two (the Dodecydimethylammonium bronides)-C12-2-12.2Br of dimethylene-1,2-
-, essence and Tegosept M, hierarchy of control temperature is 70 DEG C, stirs 10min; In above-mentioned mixed solution, slowly add sodium-chlor thickening again, to be mixed evenly and denseness lower the temperature after reaching 0.5PaS, carry out package encapsulation according to demand, environmental protection tea seed clean-out system can be obtained.
Embodiment 2:
Raw material needed for environmental protection tea seed clean-out system and formula: camellia seed meal 80g, water 180g, sodium carbonate 2g, sorbitan ester Soxylat A 25-7 20g, two (dodecyldimethylamine base the brometo de amonio)-C14-2-14.2Br of dimethylene-1,2-
-1g, sodium-chlor 7g, essence 0.8g, ethyl p-hydroxybenzoate 0.2g.
Environmental protection tea seed clean-out system preparation method: camellia seed meal and water are added in retort, and add sodium carbonate, the pH of regulation system is 8.0, and hierarchy of control temperature is 70 DEG C, stirs 2.5h.Cool subsequently and carry out filtration removing residue, camellia seed meal extracting solution can be obtained, now contain oil tea saponin 8wt% in extracting solution; Obtained camellia seed meal extracting solution is put into stirred pot, adds 20g sorbitan ester Soxylat A 25-7, two (dodecyldimethylamine base the brometo de amonio)-C14-2-14.2Br of 1g dimethylene-1,2-
-, essence and ethyl p-hydroxybenzoate, hierarchy of control temperature is 55 DEG C, stirs 20min; In above-mentioned mixed solution, slowly add sodium-chlor thickening again, to be mixed evenly and denseness lower the temperature after reaching 0.4PaS, carry out package encapsulation according to demand, environmental protection tea seed clean-out system can be obtained.
Embodiment 3:
Raw material needed for environmental protection tea seed clean-out system and formula: camellia seed meal 120g, water 220g, sodium carbonate 3.5g, polyoxyethylene nonylphenol ether 32g, N, N'-bimonthly osmanthus Ethylene Diamine diacrylate sodium 1.4g, sodium-chlor 11g, essence 1.2g, Imidurea 0.35g.
Environmental protection tea seed clean-out system preparation method: camellia seed meal and water are added in retort, and add sodium carbonate, the pH of regulation system is 8.5, and hierarchy of control temperature is 80 DEG C, stirs 2h.Cool subsequently and carry out filtration removing residue, camellia seed meal extracting solution can be obtained, now contain oil tea saponin 9wt% in extracting solution; Obtained camellia seed meal extracting solution is put into stirred pot, and add polyoxyethylene nonylphenol ether, N, N'-bimonthly osmanthus Ethylene Diamine diacrylate sodium, essence and Imidurea, hierarchy of control temperature is 50 DEG C, stirs 25min; In above-mentioned mixed solution, slowly add sodium-chlor thickening again, to be mixed evenly and denseness lower the temperature after reaching 0.55PaS, carry out package encapsulation according to demand, environmental protection tea seed clean-out system can be obtained.
Embodiment 4:
Raw material needed for environmental protection tea seed clean-out system and formula: camellia seed meal 150g, water 280g, sodium carbonate 5g, cocoanut fatty acid diethanolamide 40g, two (the Dodecydimethylammonium bronides)-C12-2-12.2Br of dimethylene-1,2-
-2g, sodium-chlor 12g, essence 1.6g, Tegosept M 0.5g.
Environmental protection tea seed clean-out system preparation method: camellia seed meal and water are added in retort, and add 5g sodium carbonate, the pH of regulation system is 8.0, and hierarchy of control temperature is 85 DEG C, stirs 1h.Cool subsequently and carry out filtration removing residue, camellia seed meal extracting solution can be obtained, now contain oil tea saponin 8wt% in extracting solution; Obtained camellia seed meal extracting solution is put into stirred pot, adds cocoanut fatty acid diethanolamide, two (the Dodecydimethylammonium bronides)-C12-2-12.2Br of dimethylene-1,2-
-, essence and Tegosept M, hierarchy of control temperature is 40 DEG C, stirs 30min; In above-mentioned mixed solution, slowly add sodium-chlor thickening again, to be mixed evenly and denseness lower the temperature after reaching 0.6PaS, carry out package encapsulation according to demand, environmental protection tea seed clean-out system can be obtained.
Performance test
1, the soil removability test of environmental protection tea seed clean-out system
By environmental protection tea seed clean-out system dilute with water, be mixed with the scavenging solution that massfraction is 5%, the test piece scribbling equivalent Vegetable oil lipoprotein, animal grease, lubricating oil and diesel oil is placed in scavenging solution respectively and soaks 5min, swing cleaning, swinging distance (45 ~ 50) mm, hunting frequency 300 times/min.After swing terminates, rinsing in 60 DEG C of distilled water after taking-up, the time is no more than 5s, and after rinsing terminates, hot blast drying, cooling is weighed.
Soil removability calculation formula such as formula:
In formula: m
0: test piece quality, g;
M
1: the quality after test piece coating greasy dirt, g;
M
2: the quality after coating greasy dirt test piece cleaning, g.
Table 1 embodiment 1-4 gained environmental protection tea seed clean-out system soil removability test result
2, the stability test of environmental protection tea seed clean-out system
The environmental protection tea seed clean-out system of various embodiments of the present invention is rested on normal temperature next year, clean-out system can be found without layering without deposited phenomenon.The environmental protection tea seed clean-out system of various embodiments of the present invention is placed in the refrigerator 7 days of subzero 4 DEG C to subzero 15 DEG C, observes when returning to room temperature after taking-up, can find that clean-out system nodeless mesh occurs without deposited phenomenon.The environmental protection tea seed clean-out system of various embodiments of the present invention is placed in the insulation can 7 days of 45 DEG C, observes immediately after taking-up, can find that clean-out system occurs without turbid phenomenon without layering, not change original smell and color.
The foregoing is only preferred embodiment of the present invention, all equalizations done according to the present patent application the scope of the claims change and modify, and all should belong to covering scope of the present invention.
Claims (5)
1. an environmental protection tea seed clean-out system, it is characterized in that: the raw material composition of environmental protection tea seed clean-out system according to parts by weight is: camellia seed meal 30-50 part, water 60-100 part, sodium carbonate 0.5-5 part, nonionic surface active agent 5-15 part, Gemini surface active agent 0.5-2 part, sodium-chlor 1-5 part, essence 0.1-2 part, sanitas 0.03-0.1 part.
2. environmental protection tea seed clean-out system according to claim 1, is characterized in that: described nonionic surface active agent is the one in cocoanut fatty acid diethanolamide, sorbitan ester Soxylat A 25-7, polyoxyethylene nonylphenol ether.
3. environmental protection tea seed clean-out system according to claim 1, is characterized in that: described Gemini surface active agent is two (the Dodecydimethylammonium bronides)-C12-2-12.2Br of dimethylene-1,2-
-, two (dodecyldimethylamine base the brometo de amonio)-C14-2-14.2Br of dimethylene-1,2-
-, one in the Ethylene Diamine diacrylate sodium of N, N'-bimonthly osmanthus.
4. environmental protection tea seed clean-out system according to claim 1, is characterized in that: described sanitas is the one in Tegosept M, ethyl p-hydroxybenzoate, Imidurea.
5. prepare a method for environmental protection tea seed clean-out system as claimed in claim 1, it is characterized in that: specifically comprise the following steps:
(1) camellia seed meal and water are added in retort, and add sodium carbonate, the pH of regulation system is 7.5-8.5, and hierarchy of control temperature is 65-85 DEG C, stirs 1-3h; Cool subsequently and carry out filtration removing residue, obtaining camellia seed meal extracting solution, now contain oil tea saponin 6-10wt% in extracting solution;
(2) the camellia seed meal extracting solution that step (1) is obtained is put into stirred pot, add nonionic surface active agent, Gemini surface active agent, essence and sanitas, hierarchy of control temperature is 40-70 DEG C, stirs 10-30min;
(3) in step (2) mixed solution, slowly add sodium-chlor thickening again, to be mixed evenly and denseness lower the temperature after reaching 0.4PaS ~ 0.6PaS, carry out package encapsulation, obtain environmental protection tea seed clean-out system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510936611.1A CN105441215A (en) | 2015-12-16 | 2015-12-16 | Environmentally friendly camellia seed detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510936611.1A CN105441215A (en) | 2015-12-16 | 2015-12-16 | Environmentally friendly camellia seed detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105441215A true CN105441215A (en) | 2016-03-30 |
Family
ID=55551864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510936611.1A Pending CN105441215A (en) | 2015-12-16 | 2015-12-16 | Environmentally friendly camellia seed detergent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105441215A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085611A (en) * | 2016-06-03 | 2016-11-09 | 潘星辑 | A kind of cleaning agent containing tea saponin and preparation method thereof |
| CN106191875A (en) * | 2016-07-13 | 2016-12-07 | 吴迪 | A kind of preparation method of environment-friendly type composition metal abluent |
| CN106635453A (en) * | 2016-12-30 | 2017-05-10 | 湖南林之神生物科技有限公司 | Fruit and vegetable cleaning fluid containing oiltea seed extract and preparation method of fruit and vegetable cleaning fluid |
| CN107556359A (en) * | 2017-09-18 | 2018-01-09 | 江南大学 | A kind of method for improving water extraction Tea Saponin dissolution rate |
| CN108373949A (en) * | 2018-03-30 | 2018-08-07 | 湖南淳湘农林科技有限公司 | A kind of cleaning agent containing tea seed cake |
| CN110184138A (en) * | 2019-06-27 | 2019-08-30 | 湖南淳湘农林科技有限公司 | A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser |
| CN113337347A (en) * | 2021-05-31 | 2021-09-03 | 湖南万象生物科技有限公司 | Washing liquid prepared from defatted tea seed meal and preparation method thereof |
| CN113621017A (en) * | 2021-08-25 | 2021-11-09 | 青岛职业技术学院 | Comprehensive utilization method of camellia seed meal |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766542A (en) * | 2012-07-09 | 2012-11-07 | 陈文志 | Detergent containing tea saponin |
| CN104031753A (en) * | 2014-05-27 | 2014-09-10 | 广州立白企业集团有限公司 | Detergency-improved tableware detergent composition with suspended particles |
-
2015
- 2015-12-16 CN CN201510936611.1A patent/CN105441215A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102766542A (en) * | 2012-07-09 | 2012-11-07 | 陈文志 | Detergent containing tea saponin |
| CN104031753A (en) * | 2014-05-27 | 2014-09-10 | 广州立白企业集团有限公司 | Detergency-improved tableware detergent composition with suspended particles |
Non-Patent Citations (2)
| Title |
|---|
| 冯玉军: "双子表面活性剂的应用", 《精细与专用化学品》 * |
| 周为群: "《现代生活与化学》", 28 February 2014, 苏州：苏州大学出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106085611A (en) * | 2016-06-03 | 2016-11-09 | 潘星辑 | A kind of cleaning agent containing tea saponin and preparation method thereof |
| CN106191875A (en) * | 2016-07-13 | 2016-12-07 | 吴迪 | A kind of preparation method of environment-friendly type composition metal abluent |
| CN106635453A (en) * | 2016-12-30 | 2017-05-10 | 湖南林之神生物科技有限公司 | Fruit and vegetable cleaning fluid containing oiltea seed extract and preparation method of fruit and vegetable cleaning fluid |
| CN107556359A (en) * | 2017-09-18 | 2018-01-09 | 江南大学 | A kind of method for improving water extraction Tea Saponin dissolution rate |
| CN108373949A (en) * | 2018-03-30 | 2018-08-07 | 湖南淳湘农林科技有限公司 | A kind of cleaning agent containing tea seed cake |
| CN110184138A (en) * | 2019-06-27 | 2019-08-30 | 湖南淳湘农林科技有限公司 | A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser |
| CN113337347A (en) * | 2021-05-31 | 2021-09-03 | 湖南万象生物科技有限公司 | Washing liquid prepared from defatted tea seed meal and preparation method thereof |
| CN113621017A (en) * | 2021-08-25 | 2021-11-09 | 青岛职业技术学院 | Comprehensive utilization method of camellia seed meal |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105441215A (en) | Environmentally friendly camellia seed detergent and preparation method thereof | |
| CN104017661B (en) | Tea saponin dishwashing liquid and preparation method thereof | |
| CN104263566A (en) | Multifunctional cleaning cream for stain removal and sterilization and preparation method thereof | |
| CN103205332A (en) | Liquid laundry detergent and preparation method thereof | |
| CN105132221A (en) | Green environment-friendly leatherware cleaning agent and production technology thereof | |
| CN108085177A (en) | A kind of efficient agent for carbon hydrogen detergent of food-grade strength | |
| CN106118892A (en) | A kind of omnipotent food stage cleaning agent and preparation method thereof | |
| CN103820240A (en) | Laundry detergent used for washing underwear | |
| CN103773617B (en) | A kind of footgear personal cleansing liquid and preparation method thereof | |
| CN105296179A (en) | Soap-based environment-friendly laundry detergent | |
| CN104962408A (en) | Marine fish oil washing product and preparation method thereof | |
| CN105349276A (en) | Disinfecting washing agent | |
| CN1240228A (en) | Multi-function soap liquid detergent and productive process thereof | |
| CN102552069B (en) | Bath foam | |
| CN102634421B (en) | laundry detergent and preparation method thereof | |
| CN104017663A (en) | Fabric sofa cleaning agent | |
| CN109705994B (en) | Decontamination flavor enhancer and preparation method thereof | |
| CN106318738A (en) | Herbal ingredient laundry detergent and preparing method thereof | |
| CN103690400A (en) | Natural plant type body wash and preparation method thereof | |
| CN108865503A (en) | A kind of Tea Saponin washing powder and preparation method thereof | |
| CN108004066A (en) | It is a kind of suitable for soap of sensitiveness skin and preparation method thereof | |
| CN106811348A (en) | A kind of antibacterial special soap of mosquito repellent | |
| CN108467803A (en) | A kind of environment-friendly type natural liquid detergent and preparation method thereof | |
| CN103849494A (en) | Infant laundry detergent | |
| CN104450299A (en) | Environment-friendly bacteriostatic detergent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160330 |
|
| RJ01 | Rejection of invention patent application after publication |