CN110184138A - A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser - Google Patents

A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser Download PDF

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Publication number
CN110184138A
CN110184138A CN201910569183.1A CN201910569183A CN110184138A CN 110184138 A CN110184138 A CN 110184138A CN 201910569183 A CN201910569183 A CN 201910569183A CN 110184138 A CN110184138 A CN 110184138A
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CN
China
Prior art keywords
tea
cleanser
parts
slag powder
cake
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910569183.1A
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Chinese (zh)
Inventor
喻应辉
胡建科
钟海雁
王红
许望龙
黄燕
吴慧
王春梅
林小君
喻红华
喻红丽
胡能兵
喻运泽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Chun Xiang Agriculture And Forestry Science And Technology Co Ltd
Original Assignee
Hunan Chun Xiang Agriculture And Forestry Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Chun Xiang Agriculture And Forestry Science And Technology Co Ltd filed Critical Hunan Chun Xiang Agriculture And Forestry Science And Technology Co Ltd
Priority to CN201910569183.1A priority Critical patent/CN110184138A/en
Publication of CN110184138A publication Critical patent/CN110184138A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1213Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/221Mono, di- or trisaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

This application discloses a kind of Extracted From Oil-tea-cake biology novel surface activity cleanser, the raw material including following parts by weight: 40-75 parts of leached tea oil slag powder;15-40 parts of sodium alkyl benzene sulfonate;1-15 parts of sodium carbonate;1-15 parts of magnesia;1-15 parts of sodium chloride;1-15 parts of sucrose.Cleanser provided by the present application, whole raw materials are all made of plant, food and food grade materials, harmless, non-stimulated to skin, safety and environmental protection is easy to clean, it is especially suitable for the cleaning of kitchen utensils and hearth, can efficiently removes body surface greasy dirt, increases tableware surface gloss.

Description

A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser
Technical field
This application involves daily chemical product technical fields, wash more particularly to a kind of Extracted From Oil-tea-cake biology novel surface activity Wash powder.
Background technique
Detergent has become one of the daily necessities that today's society people be unable to do without.The wash removability of detergent is main From surfactant.Because surfactant plays the role of reducing surface tension, it can penetrate into what Lian Shui can not penetrate into In fiber gap, the dirt in plant fiber gap is extruded, but simultaneously, surfactant can also penetrate into human body.Currently, Detergent on the market is extract from petroleum mostly, and main component is the by-product developed with petroleum rubbish Product, these chemical by-products decline into will cause calcium ion concentration in blood afterwards into the human body, and acidification of blood makes one to be easy tired Labor.Since the harm of this pollution will not be showed obviously in a short time, it is often ignored.But micro dirt Dye continues into vivo, and serious consequence can be caused by taking care of the pence, and lead to the various lesions of human body.
Therefore, how a kind of environmentally protective, harmless detergent is provided, is that those skilled in the art are urgently to be resolved The technical issues of.
Summary of the invention
In order to solve the above technical problem, the present invention provides one kind with leached tea oil slag powder for main surface active ingredient, cooperation The builder of some other environment-friendly high-efficiency is the Extracted From Oil-tea-cake biology novel surface activity cleanser of formula.Washing provided by the invention Powder, whole raw materials are all made of plant, food and food grade materials, harmless, safety and environmental protection non-stimulated to skin, hold Easy cleaning is especially suitable for the cleaning of kitchen utensils and hearth, can efficiently remove body surface greasy dirt, increases tableware surface light Pool.
Technical solution provided by the invention is as follows:
A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser, the raw material including following parts by weight:
Preferably, the raw material including following parts by weight:
Preferably, the raw material including following parts by weight:
Preferably, the partial size of the leached tea oil slag powder is -500 mesh of 100 mesh.
Preferably, the partial size of the leached tea oil slag powder is -250 mesh of 150 mesh.
Preferably, the leached tea oil slag powder is specially that tea seed or tea seeds are obtained through broken, leaching grease and after removing solvent The material arrived.
Preferably, the content of Tea Saponin is greater than or equal to 16% in the leached tea oil slag powder.
Preferably, in the leached tea oil slag powder fat content below 1%.
It preferably, further include one or more of essence, light stabilizer, antioxidant, pigment.
The present invention uses pure natural leached tea oil slag powder, and environment protection health, not can cause environmental pollution will not damage human body.Tea Effect ingredient Tea Saponin also known as tea saponin, are a kind of glycoside compounds by extracting in tea tree seed contained in seed dregs of rice powder, It is a kind of natural surfactant of good performance.Through detecting, Tea Saponin has the function such as good emulsification, dispersion, foaming, wet Can, and there is anti-inflammatory, analgesia, the pharmacological actions such as impermeabilisation have extremely strong ability of cleaning greasy dirt.
The present invention by camellia seed meal crushed after being dried, smashed camellia seed meal in use, due to response area Increase, so active effect is more preferable.Other than leached tea oil slag powder, cleanser provided by the invention further includes helping for other environment-friendly high-efficiencies Lotion, these builders all have good compatibility, act synergistically with leached tea oil slag powder, can effectively remove greasy dirt, increase meal Has lustrous surface.
Due to containing magnesia in cleanser, magnesia can produce positive charge in water, so in cleaning glass, pottery When these material surfaces with high negative charge density of porcelain, metal, the electrolyte cation in water can reduce body surface to band The repulsive interaction of the anionic surfactant of negative electrical charge makes the active constituent quick adsorption in cleanser in tableware surface, adds The removal of fast greasy dirt.By the washed tableware of this product cleanser, not only surface cleaning is without dirt, simultaneously as in cleanser Containing sodium chloride, there is lustrous surface protective effect to glass, ceramics, so washed dose of washed tableware surface light is such as Newly.
In addition, so it is quick to be easy to use, can both be dissolved in impregnating in 50 DEG C of hot water needs since the present invention is pulvis The tableware of washing;When tableware surface the heavy scale, it is also possible to which rag is stained with this product dry powder wiping tableware, passes through the chemical efficiency of dry powder Cooperation physical friction quickly removes the dirt of tableware surface, and the tableware after washing is simply rinsed with water.
Specific embodiment
In order to make those skilled in the art better understand the technical solutions in the application, will implement below to the application Technical solution in example is clearly and completely described, it is clear that described embodiment is only that the application a part is implemented Example, instead of all the embodiments.Based on the embodiment in the application, those of ordinary skill in the art are not making creativeness Every other embodiment obtained, shall fall within the protection scope of the present application under the premise of labour.
The embodiment of the present invention provides a kind of Extracted From Oil-tea-cake biology novel surface activity cleanser, the original including following parts by weight Material:
The present invention uses pure natural leached tea oil slag powder, and environment protection health, not can cause environmental pollution will not damage human body.Tea Effect ingredient Tea Saponin also known as tea saponin, are a kind of glycoside compounds by extracting in tea tree seed contained in seed dregs of rice powder, It is a kind of natural surfactant of good performance.Through detecting, Tea Saponin has the function such as good emulsification, dispersion, foaming, wet Can, and there is anti-inflammatory, analgesia, the pharmacological actions such as impermeabilisation have extremely strong ability of cleaning greasy dirt.
The present invention is by camellia seed meal crushed after being dried, in use due to smashed camellia seed meal, response area Increase, so active effect is more preferable.Other than leached tea oil slag powder, cleanser provided by the invention further includes helping for other environment-friendly high-efficiencies Lotion, these builders all have good compatibility, can act synergistically with leached tea oil slag powder.Cleanser provided by the invention, Whole raw materials are all made of plant, food and food grade materials, harmless, safety and environmental protection non-stimulated to skin, are easy Cleaning is especially suitable for the cleaning of kitchen utensils and hearth, can efficiently remove body surface greasy dirt, increases tableware surface light Pool.
Since the present invention is pulvis, so very convenient to use quick, can both be dissolved in impregnating in 50 DEG C of hot water is needed The tableware of washing;When tableware surface the heavy scale, it is also possible to which rag is stained with this product dry powder wiping tableware, passes through the chemical efficiency of dry powder Cooperation physical friction quickly removes the dirt of tableware surface, and the tableware after washing is simply rinsed with water.When cleaning hearth, This product dry powder is stained with wet rag to be wiped repeatedly, and then wipes cleanser clear with clean wet cloth.
Preferably, the raw material including following parts by weight:
Preferably, the raw material including following parts by weight:
Extracted From Oil-tea-cake biology novel surface activity cleanser provided by the invention obtains first by camellia seed meal crushed after being dried Leached tea oil slag powder;Above-mentioned parts by weight are pressed again, and sodium alkyl benzene sulfonate, sodium carbonate, magnesia, chlorination are sequentially added in leached tea oil slag powder Sodium, sucrose, are dispersed with stirring, and after former raw material is uniformly dispersed in leached tea oil slag powder, add a kind of lower raw material, until all It mixes, obtains finished product.It should be noted that the order of addition of said components can adjust accordingly according to the actual situation, Order of addition will not influence technical effect of the invention.
Sodium alkyl benzene sulfonate in cleanser has good wetability, strong detergency, and dissolubility is good, to skin irritatin Small, biological degradability is excellent, good with Tea Saponin compatibility.
Sodium carbonate can be effectively removed greasy dirt, while have antiseptic and inhibiting bacteria function effect.
Sodium chloride has lustrous surface protective effect to glass, the ceramics of tableware.
Magnesia can produce positive charge in water, cleaning glass, ceramics, metal these with high negative charge density When material surface, the electrolyte cation in water can reduce repulsion of the body surface to negatively charged anionic surfactant Effect, is conducive to surfactant in the absorption of tableware surface.
In addition, the present invention replaces the APG used in conventional formulation using sucrose, not only strong detergency, matches with other components 5 property are good;Simultaneously as Price of Sugar is cheap and highly-safe, the life of this product can also be further decreased with its substitution APG Produce cost.
Leached tea oil slag powder in the embodiment of the present invention, partial size are preferably -500 mesh of 100 mesh, and the partial size is sieved with Unite States Standard It measures.
It should be noted that since leached tea oil slag powder is not soluble in water at normal temperature deposition can be generated when partial size is excessive, seriously When will cause sewer blockage;And partial size is too small that there will be gelatin phenomenon generations.Therefore, preferably, by the grain of leached tea oil slag powder Diameter controls between -250 mesh of 150 mesh.It is further preferred that the partial size of control leached tea oil slag powder is 200 mesh, since 200 mesh are tea This index is not achieved in the technique threshold of seed dregs of rice powder manufacturing process, general dry powder crushing process, only could be real by colloid mill It is existing, but this mode can greatly improve the production cost of leached tea oil slag powder.In order to obtain 200 purposes under the premise of controlling cost Leached tea oil slag powder, this programme collect the tea of target grain size using the wind election process in tea seed cake production process while obtaining tea seed cake Dregs of rice powder, the process not will increase extra energy consumption.
Preferably, leached tea oil slag powder is specially that tea seed or tea seeds are obtained through broken, leaching grease and after removing solvent Material.
Wherein, tea seed (Oil-tea camellia seed) is black, the brown particles seed of Camellia oil species. Tea seed includes C. olelfera (Camellia Oleifera Abe1), camellia meiocarpa (Camellia meiocarpa Hu), length It valve short column tea (Camellia grijsii Hance), Camellia chekiangoleosa (Camellia chekiangoleosa Hu) and rises Rush the seed of the species such as safflower oil tea (Camellia reticulata f.simplex).And tea seeds are tealeaves (Camellia Sinesnis seed).
Traditional resulting tea seed cake after oil is produced in squeezing, the cleaning agent as chemical field be it is worthless, mainly Because tea seed is after first of object squeezes, still also containing the grease of 5-8% in remaining cake block (referred to as tea cake).This Oil content in the kind excessively high composite waste that will cause after having washed subject matter of tea cake fat content is excessively high, environmental protection treatment pressure Greatly, processing will lead in waste water that grease is smelly not in time, cause new environmental pollution.And the grease of tea seed cake this 5-8% is difficult to use Physical method, which squeezes out, to be come, and the oil of remaining 5-8% in " food-grade vegetable oil extraction solvent " extraction (leaching) out is generallyd use Rouge.The tea seed cake that the present invention uses, exactly after extraction grease (grease is separated with tea seed cake), then remove solvent (solvent with Tea seed cake separation) after obtained material, oil content substantially reduces, and is suitable for washing field.
Preferably, the content of Tea Saponin is more than or equal to 16% in leached tea oil slag powder.
Component of the leached tea oil slag powder as cleanser it is preferable to use the content of Tea Saponin more than or equal to 16%.Tea Saponin is one The natural nonionic surface active agent of kind has the functions such as good emulsification, decomposition, foaming, wet, there is good decontamination work With.
Preferably, in leached tea oil slag powder fat content below 1%.
Oil content in the excessively high composite waste that will cause after having washed subject matter of fat content is excessively high, environmental protection treatment pressure Greatly, processing will lead in waste water that grease is smelly not in time, cause new environmental pollution.Therefore, present invention preferably employs greases to contain Measure component in 1% leached tea oil slag powder below as detergent, avoid excessively high grease to the sewage after washing process, washing at Reason causes adverse effect.
Preferably, the cleanser in the embodiment of the present invention can also be including in essence, light stabilizer, antioxidant, pigment One or more.
It should be noted that cleanser provided by the invention, porcelain determination of corrosion presses the side GB/T3810.13-2016 Method measurement, porcelain plate on probation meet GB/T 4100-2006 standard, and measurement result is qualified.PH after the molten water of cleanser provided by the invention Value is between 6-9.Other standards meet GB/T9985-2000 detergent for washing dishware with hand national standard.
Embodiment 1
1, a kind of Extracted From Oil-tea-cake biology novel surface activity cleanser, the raw material including following parts by weight:
Wherein, the partial size of leached tea oil slag powder is 200 mesh, and the content of Tea Saponin is 16%, and fat content is 1% in tea seed cake.
By above-mentioned parts by weight, sodium alkyl benzene sulfonate is added in leached tea oil slag powder, is mixed;Sodium carbonate is added, is dispersed with stirring Uniformly;Magnesia is added, is mixed;Sodium chloride, sucrose, essence are sequentially added, gets product washing after being dispersed with stirring uniformly Powder.
Above-mentioned finished product cleanser was in use, both dissolved in the tableware that immersion need to wash in 50 DEG C of hot water, it is also possible to which rag is viscous Upper this product dry powder wipes tableware, cooperates physical friction quickly to remove the dirt of tableware surface by the chemical efficiency of dry powder, washes Tableware after washing simply is rinsed with water.
Due to containing magnesia in cleanser, magnesia can produce positive charge in water, so in cleaning glass, pottery When these material surfaces with high negative charge density of porcelain, metal, the electrolyte cation in water can reduce body surface to band The repulsive interaction of the anionic surfactant of negative electrical charge makes the active constituent quick adsorption in cleanser in tableware surface, adds The removal of fast greasy dirt.
By the washed tableware of this product cleanser, not only surface cleaning is without dirt, simultaneously as containing chlorine in cleanser Change sodium, there is lustrous surface protective effect to glass, ceramics, so washed dose of washed tableware surface light is for example new.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (9)

1. a kind of Extracted From Oil-tea-cake biology novel surface activity cleanser, which is characterized in that the raw material including following parts by weight:
2. cleanser according to claim 1, which is characterized in that the raw material including following parts by weight:
3. cleanser according to claim 2, which is characterized in that the raw material including following parts by weight:
4. cleanser according to any one of claim 1-3, which is characterized in that the partial size of the leached tea oil slag powder is 100 - 500 mesh of mesh.
5. cleanser according to claim 4, which is characterized in that the partial size of the leached tea oil slag powder is -250 mesh of 150 mesh.
6. cleanser according to any one of claim 1-3, which is characterized in that the leached tea oil slag powder is specially tea seed Or the material that tea seeds are obtained through broken, leaching grease and after removing solvent.
7. cleanser according to any one of claim 1-3, which is characterized in that Tea Saponin contains in the leached tea oil slag powder Amount is greater than or equal to 16%.
8. cleanser according to any one of claim 1-3, which is characterized in that fat content exists in the leached tea oil slag powder 1% or less.
9. cleanser according to any one of claim 1-3, which is characterized in that further include essence, light stabilizer, antioxygen One or more of agent, pigment.
CN201910569183.1A 2019-06-27 2019-06-27 A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser Pending CN110184138A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910569183.1A CN110184138A (en) 2019-06-27 2019-06-27 A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser

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Application Number Priority Date Filing Date Title
CN201910569183.1A CN110184138A (en) 2019-06-27 2019-06-27 A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113549501A (en) * 2021-08-03 2021-10-26 安徽淮仁堂药业股份有限公司 Environment-friendly antiviral soap composition, soap and preparation method thereof

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CN108048225A (en) * 2017-12-12 2018-05-18 四川才阁机械有限公司 A kind of environment friendly and pollution-free washing powder and preparation method thereof
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113549501A (en) * 2021-08-03 2021-10-26 安徽淮仁堂药业股份有限公司 Environment-friendly antiviral soap composition, soap and preparation method thereof

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Application publication date: 20190830