CN109055042A - Cleanser and preparation method thereof - Google Patents

Cleanser and preparation method thereof Download PDF

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Publication number
CN109055042A
CN109055042A CN201810984803.3A CN201810984803A CN109055042A CN 109055042 A CN109055042 A CN 109055042A CN 201810984803 A CN201810984803 A CN 201810984803A CN 109055042 A CN109055042 A CN 109055042A
Authority
CN
China
Prior art keywords
raw material
parts
cleanser
powder
skin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810984803.3A
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Chinese (zh)
Inventor
王志勇
陶建军
王文纤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan Tianhua Oil Tea Science & Technology Co Ltd
Original Assignee
Hunan Tianhua Oil Tea Science & Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Tianhua Oil Tea Science & Technology Co Ltd filed Critical Hunan Tianhua Oil Tea Science & Technology Co Ltd
Priority to CN201810984803.3A priority Critical patent/CN109055042A/en
Publication of CN109055042A publication Critical patent/CN109055042A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • C11D7/12Carbonates bicarbonates

Abstract

The invention discloses a kind of cleansers, are made of the raw material of following proportion by weight: 35~60 parts of camellia seed meal, 30~50 parts of sodium bicarbonate, 2~5 parts of atlapulgite, 5~10 parts of sea salt, 0.5~2 part of ginger powder.The preparation method is as follows: (1) takes raw material: weighing raw material according to the ratio;(2) it crushes: raw material drying being crushed by pulverizer respectively, obtains each raw material powder;(3) it mixes: each raw material powder being mixed, is stirred evenly;(4) it sterilizes: being sterilized by 100-120 DEG C of hot wind, then sealed package, obtain cleanser.The cleanser effectively removes spot, it is non-toxic, nonirritant to skin, without anaphylaxis act on, low bubble, water-saving, be suitble to daily life utensil cleaning.

Description

Cleanser and preparation method thereof
Technical field
The invention belongs to articles for washing technical field, in particular to a kind of cleanser and preparation method thereof is mainly used for People's daily life washing, it is nontoxic, non-stimulated, without allergy, low bubble, water-saving.
Background technique
Existing cleaning product is mainly chemical synthesis currently on the market, although detergency is strong, it has chemistry examination Agent, insecurity are used for a long time the stimulation to skin, cause pachylosis dry and cracked, and not exclusively, residual causes to endanger body for cleaning Body, while because being not easily decomposed, it is quite serious to the pollution of ambient soil and water body.
Our most-often used Dish-Washing Products --- dish washing liquid, main component are sodium alkyl sulfonate, fatty alcohol ether sulphur Sour sodium, foaming agent, solubilizer, essence, water, pigment and preservative etc..Sodium alkyl sulfonate and fatty alcohol-ether sodium sulfate be all yin from Sub- surfactant is petroleum chemicals, to decontamination grease stain.An investigation was once done by Jilin TV station, discovery in the market 9 Kind dish washing liquid, after washing tableware, tap water is rinsed 12 times, moreover it is possible to detect average 0.03% residual.Perhaps the residual quantity is unlikely to Harm obviously is generated to human body, but after all or certain toxicity.
Summary of the invention
An object of the present invention is to overcome the above-mentioned insufficient of the prior art and provide a kind of cleanser, effectively removes dirt Stain, it is non-toxic, nonirritant to skin, without anaphylaxis act on, low bubble, water-saving can be used as cleaning food in people's daily life The ideal safety and environmental protection washing product such as Work tool, tableware and veterinary antibiotics.
It is a further object of the present invention to provide the preparation method of above-mentioned cleanser, simple process, raw material is common, cheap.
The technical scheme is that a kind of cleanser, is made: camellia seed meal of the raw material of following proportion by weight 35~60 parts, 30~50 parts of sodium bicarbonate, 2~5 parts of atlapulgite, 5~10 parts of sea salt, 0.5~2 part of ginger powder.
It is of the invention another solution is that a kind of preparation method of cleanser comprising following steps:
(1) it takes raw material: weighing raw material according to the ratio;
(2) it crushes: acquirement dry feedstock being passed through into pulverizer respectively and is crushed, each raw material powder is obtained;
(3) it mixes: each raw material powder being mixed, is stirred evenly;
(4) it sterilizes: being sterilized by 120 DEG C of hot winds, then with non-woven fabrics sealed package, obtain cleanser.
Wherein the smashed raw material particle size of the step (2) is 40~50 mesh.
The primary symbols and name resolving that the present invention uses are as follows:
~: numberical range, such as 1~5 expression 1 to 5.
The main material that the present invention uses is described as follows:
Non-woven fabrics (English name: Non Woven Fabric or Nonwoven cloth) is also known as nonwoven fabric, is by orienting Or random fiber and constitute.Cloth is called because of the appearance and certain performances with cloth.Non-woven fabrics has moisture-proof, ventilative, soft Tough, light, not combustion-supporting, easy the features such as decomposing, is nontoxic nonirritant, rich in color, cheap, recyclable
Camellia seed meal: after squeezing, extract technology extract, the remaining bits of institute, referred to as camellia seed meal contain camellia seed kernel About 10% protein, 10% tea polysaccharide, 12% Tea Saponin, 50% cellulose and lignin.
Sodium bicarbonate(edible): white powder or monoclinic crystal crystalline powder, it is odorless, taste is salty, soluble easily in water, but compare sodium carbonate Solubility in water is small, does not dissolve in ethyl alcohol, and aqueous solution is in alkalescence.It is heated easily to decompose.It is slowly decomposed in humid air.About Start to lose carbon dioxide at 50 DEG C, becomes sodium carbonate in 100 DEG C of wholes.It is decomposed rapidly in weak acid, aqueous solution is at 20 DEG C When start to split the carbon dioxide off and sodium carbonate, all decomposed when to boiling point.It is dissolved in 10 parts of water at 25 DEG C, about 18 DEG C of whens are dissolved in 12 Part water, does not dissolve in ethyl alcohol.The solution not stirred made of its cold water is only in alkalescence reaction to phenolphthalein test paper, places or rise High-temperature, alkalinity increase.The 0.1mol/L pH value of water solution of 25 DEG C of Fresh is 8.3, shows alkalinity, but be free of OH ﹣, no Belong to alkali, belongs to acid carbonate (bicarbonate).Storage: it is dry, it is protected from light, is sealed.Purposes: analytical reagent.Organic conjunction At.Pharmacy (treatment hyperhydrochloria).Leavening (roasting cake).Extinguishing chemical (foam or dry powder).
Sea salt: salt marsh is come from, sea salt contains trace mineral, such as calcium, magnesium, potassium, bromide and other various micro members Element.The mollusk (insect) that slug, snail, leech one kind have mucus can be killed.
Atlapulgite: being raw material with clay (mainly bentonite), handle through inorganic acidifying, then through water rinsing, dry system At adsorbent, appearance is off-white powder, and odorless, tasteless, nontoxic, absorption property is very strong, can adsorb coloring matter, organic matter Matter.The easy moisture absorption in air, placement can reduce absorption property too long.But it is heated to 300 degrees Celsius or more and just starts to lose knot Brilliant water, makes structure change, and influences fading effect.Atlapulgite is not soluble in water, in organic solvent and various oils, almost complete It is dissolved in hot caustic soda and hydrochloric acid entirely, relative density 2.3-2.5, swelling is minimum in water and oil.
Ginger powder: powder, main material are gingers, and the function of ginger powder has warm, excited, sweating, preventing or arresting vomiting, removing toxic substances, warm lung The effects of cough-relieving, especially for ichthyophagy crab poison, the drug poisoning such as the tuber of pinellia, rhizoma arisaematis have detoxication.Suitable for affection of exogenous wind-cold, head Bitterly, phlegm retention, cough, gastrofrigid vomiting;It is anxious that it is drunk with ginger decoction after by ice and snow, water-wet, cold invasion, blood can be promoted, dispersed Cold-evil.
Usage and dosage:
1. dosage: using non-woven fabrics be prepared into 10-15 grams/packet powder packet, usage amount, according to cleaning food Work tool, tableware and The amount etc. of veterinary antibiotics, it is reusable.
2. usual usage: cleanser 1 of the invention wraps, and adds suitable quantity of water slightly to soak and mixes well, and directly smears the meal such as washing dish Tool, then clear water washes down.
Compared with the prior art, the invention has the following features:
1. cleanser strong cleaning force of the invention, is packed using non-woven fabrics, slowly infiltration cleaning, reach continuous clean effect.
2. cleanser of the invention is after use, hand feels pleasant, lubrication, takees good care of hand skin.
3. cleanser of the invention have it is non-toxic, nonirritant, without sensitization, safety is environmentally friendly, can be used for a long time.
4. cleanser of the invention is easy to use, low bubble, water-saving, can be used as cleaned in people's daily life kitchen appliance, The ideal safety and environmental protection household washing product such as fruits and vegetables.
In order to illustrate more clearly of the present invention, following embodiment and detection test situation, but its range to invention are enumerated It is without any restrictions.
Specific embodiment
Embodiment 1
Take 55 kilograms of camellia seed meal, 35 kilograms of sodium bicarbonate, 2 kilograms of atlapulgite, 6 kilograms of sea salt, 2 kilograms of ginger powder;It will obtain former Material is crushed by pulverizer respectively, is crossed 40~50 meshes, is obtained each raw material powder;Each raw material powder is put into agitator tank In, it is mixed, mixing time is 20~40min, obtains mixing powder;Gained mixing powder is passed through into 120 DEG C of sterilizations Non-woven fabrics sealed package is used afterwards, obtains cleanser.
Embodiment 2-5
Raw material used in embodiment 2-5 and quality are as shown in Table 1 below, and preparation method is same as Example 1;Following Table 1 shows specific raw material and quality used in embodiment 1-5.
Table 1, unit are kilogram
Comparative example 1 eliminates atlapulgite on the basis of embodiment 1, and comparative example 2 eliminates on the basis of embodiment 1 Ginger powder is other same as Example 1.
Detection and test
The cleanser of various embodiments of the present invention is sent to the detection and test that special detection mechanism has carried out system by applicant, master It is as follows to detect test result.
One, by the resulting cleanser of the above various embodiments, by examining pH(GB 9985-2000 detection) etc., it obtains following Testing result shown in table 2:
Table 2
From the above table 2 it can be seen that the cleanser of various embodiments of the present invention has the advantages that safety, health, comparative example 1 are bright Aobvious detection heavy metal, microorganism;Comparative example 2 detects microorganism.Various embodiments of the present invention control in bacterial action better than comparison Example 1 and 2.
Two, cleaning action detects
Purpose: the cleanser and sodium bicarbonate, camellia seed meal, standard detergent of various embodiments of the present invention and comparative example are taken, it is tested Cleaning capacity.
Method: the cleanser of various embodiments of the present invention and comparative example 15g/packet, sodium bicarbonate 15g, camellia seed meal 15g/packet, Standard detergent 15g measures cleaning capacity with the method for national standard GB9985-2000.
As a result: see the table below shown in 3.
The contrasting detection result (N=6, %) of 3. cleaning action of table
Conclusion: as can be seen from Table 3, the cleaning force of the cleanser of various embodiments of the present invention is better than sodium bicarbonate, oil tea The seed dregs of rice and standard detergent, this absolutely prove various embodiments of the present invention cleaning packet each raw material component in cleaning force It is to form synergistic effect, the cleaning force of the cleaning packet of various embodiments of the present invention is not only not being averaged for all components cleaning force Value, and it is higher than any group of point of cleaning force, if each component of the cleaning packet of various embodiments of the present invention does not form collaboration Effect is cleaned in de-sludging, then the cleaning capacity of each component mixture of same quality can be lower than highest cleaning capacity in each component The cleaning capacity of the camellia seed meal of same quality, i.e., present invention produces unexpected cleaning capacities.For efficacy factor infiltration Prepare into skin.
Three, antibacterial action detects
1, antibacterium range detection (measurement of inhibition zone diameter size)
Purpose: with agar slant dilution method detection various embodiments of the present invention cleaning packet solution (concentration 0.1g/ml) and Saleratus solution (concentration is 0.1g/ml), camellia seed meal solution (concentration is 0.1g/ml) are to being distributed wide, resistance in environment By force, the pathogenic bacteria of food spoilage, food poisoning, pyogenic infection can be caused to have antibacterial action, specifies its antibacterial range.
Method: taking diameter 12cm plate, be poured into culture medium 15ml, is dipped with the cotton swab of sterilizing for prescribed limit after condensation The test organisms bacterium solution of the logarithmic growth phase of density, is uniformly coated on media surface;Then sterilizing Oxford is clamped with aseptic nipper Cup is put in plate, and the cleaning packet solution of various embodiments of the present invention and comparative example is added in every Oxford cup (concentration is 0.1g/ml) 200ul, and carry out parallel test three times;37 DEG C of constant temperature incubations are taken out after lower 24 hours, survey inhibition zone diameter, and find out and put down three times The average value of the inhibition zone diameter of row test.And detection test is compared using sodium bicarbonate, camellia seed meal with same method.
As a result: contrasting detection result see the table below shown in 4:
4. antibacterium range of table contrasting detection result (mm, ±s)
2, antibacterium degree detecting (MIC;The measurement of MBC)
Purpose: with the cleaning packet solution (concentration is 0.1g/ml) and little Su of liquid dilution method detection various embodiments of the present invention Solution (concentration is 0.1g/ml), camellia seed meal solution (concentration is 0.1g/ml) 3 or more various concentration point are beaten in environment Distribution is wide, resistance is strong, can cause food spoilage, food poisoning, pyogenic infection pathogenic bacteria antimicrobial levels, detection is most Low Mlc (MIC) and minimum bactericidal concentration (MBC), specify its antimicrobial levels.
Method: taking sterile test tube several, dilutes various embodiments of the present invention and comparative example with fluid nutrient medium equimultiple Cleaning packet solution (concentration be 0.1g/ml) after, each pipe plus 0.1ml set culture medium control tube and bacterium solution pair for trying bacterium solution It looks after, 37 DEG C of cultures are taken out afterwards for 24 hours to be seen as a result, each developmental tube is observed one by one in the case where control tube meets the requirements, can press down The various embodiments of the present invention of test organisms growth processed and cleaning packet solution (concentration is 0.1g/ml) highest dilution of comparative example For minimum inhibitory concentration (MIC), and the culture in the test tube of each asepsis growth is forwarded to the agar plate of corresponding culture medium On, 37 DEG C of cultures take out observation afterwards for 24 hours as a result, to kill the various embodiments of the present invention and comparative example of 99.9% test organisms thallus Cleaning packet solution (concentration is 0.1g/ml) highest dilution be minimum bactericidal concentration (MBC).And it is used with same method Sodium bicarbonate, camellia seed meal compare detection test.
As a result: it see the table below shown in 5:
The contrasting detection result (mg/mL) of 5. antibacterium degree of table
Conclusion: from table 4,5 as can be seen that the antibacterial and bactericidal effect of the cleaning packet of various embodiments of the present invention is better than comparison Example 2, sodium bicarbonate, camellia seed meal.That is the cleaning packet of various embodiments of the present invention is relative to its primary raw material sodium bicarbonate, oil Leached tea oil slag has improved bactericidal effect, and the cleaning packet of various embodiments of the present invention disappears than camellia seed meal is used alone as nursing Toxicity can be more preferable.
Four, animal toxicity test
Purpose: observation rabbit intact skin and damaged skin contact tested material (cleansers of various embodiments of the present invention) in a short time Generated toxic reaction afterwards, to provide safety foundation.
Method: white New Zealand rabbits 12 are selected, is randomly divided into 3 groups, every group 4.A group: intact skin group, B group: broken Damage skin group, C group: blank control group.Experiment position is skin of back, and control group is to distilled water, and tested material group is to of the invention The cleanser of each embodiment, is coated directly on intact skin and damaged skin, and Tu Houfu is fixed with polyethylene film, then gauze, Guarantee itself and skin contact 24 hours, after applying examination 24 hours, is not poisoned to death such as, can be gone with warm water or other nonirritant solvents Tested material.It is observed continuously 7 days, is observed and recorded daily to the systemic toxicity profiles performance and death condition of animal after tested material, including The variation of the weight of animals, skin, hair, eyes and mucous membrane, the variation of breathing, circulation, central nervous system, four limbs activity etc..
As a result: white New Zealand rabbits are given and have no systemic toxicity profiles performance and dead after the cleansers of various embodiments of the present invention Situation, the weight of animals increases, on breathing, circulation, central nervous system, four limbs activity etc. without influence.It does not move to damaged skin Object has slight erythema and disappears for 24 hours without oedema, after drug withdrawal, medication area drug residue free spot.
Conclusion: the cleanser of various embodiments of the present invention is to white New Zealand rabbits intact skin and damaged skin without apparent toxicity Reaction.
Five, skin irritation test
Purpose: detect the cleanser of various embodiments of the present invention skin irritation reaction, for clinical application provide safety according to According to.
Method: it is carried out according to the related requirement in " skin irritation test and skin allergy test guideline ".Family Rabbit skin gives the cleanser of various embodiments of the present invention, distilled water, observation skin irritation reaction.
As a result: after family's rabbit skin gives the cleanser of various embodiments of the present invention, not to intact skin and damaged skin The skin wound repairs such as show spot, oedema.
Conclusion: the cleanser percutaneous drug delivery of various embodiments of the present invention, it is stingless to complete normal skin and damaged skin Swash property.
Six, skin allergy test
Purpose: detecting the allergic reaction of the intact skin of the cleanser of various embodiments of the present invention, provides peace for clinical application Full property foundation.
Method: it is carried out according to the related requirement in " skin irritation test and skin allergy test guideline ", globefish Mouse sensitization contact and excitation contact detect the cleanser of various embodiments of the present invention, distilled water and positive control medicine 2,4- bis- Nitro-chlorobenzene, observation skin hypersensitivity reaction.
As a result: after the cleanser that cavy gives various embodiments of the present invention is detected, not finding the part of tested cavy There are the allergic reactions such as erythema, oedema in skin.
Conclusion: the cleanser of various embodiments of the present invention without anaphylaxis.
Seven, application test
Purpose: the care of oily camellia seed meal, sodium bicarbonate, sea salt, ginger powder to skin is tested.
Method: according to embodiment 1, after the single raw material of any one of removal camellia seed meal, sodium bicarbonate, sea salt, ginger powder, group Pairs of ratio 2, comparative example 3, comparative example 4, comparative example 5, after washing, hand feels situation.
6 embodiment 1 of table and comparative example 2, comparative example 3, comparative example 4, comparative example 5, kilogram
As a result: see the table below (70 people participate in test, are divided into A-G group, every group of 10 people) shown in 7.
The rear hand of the application of table 7 is felt
Conclusion: after the single raw material removal of any one of camellia seed meal, sodium bicarbonate, sea salt, ginger powder, hand is washed to formulation product It is very big that portion feels that pleasant, lubricant effect influences.

Claims (3)

1. a kind of cleanser, which is characterized in that be made of the raw material of following proportion by weight: 35~60 parts of camellia seed meal, little Su Make a call to 30~50 parts, 2~5 parts of atlapulgite, 5~10 parts of sea salt, 0.5~2 part of ginger powder.
2. cleanser according to claim 1, which is characterized in that be made of the raw material of following proportion by weight: tea seed 25 parts of the dregs of rice, 65 parts of sodium bicarbonate, 2 parts of atlapulgite, 5 parts of sea salt, 2 parts of ginger powder.
3. the preparation method of cleanser according to claim 1, which comprises the steps of:
(1) it takes raw material: weighing raw material according to the ratio;
(2) it crushes: acquirement dry feedstock being passed through into pulverizer respectively and is crushed, each raw material powder is obtained;
(3) it mixes: each raw material powder being mixed, is stirred evenly;
(4) it sterilizes: being sterilized by 120 DEG C of hot winds, then with non-woven fabrics sealed package, obtain cleanser.
CN201810984803.3A 2018-08-28 2018-08-28 Cleanser and preparation method thereof Pending CN109055042A (en)

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Application Number Priority Date Filing Date Title
CN201810984803.3A CN109055042A (en) 2018-08-28 2018-08-28 Cleanser and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201810984803.3A CN109055042A (en) 2018-08-28 2018-08-28 Cleanser and preparation method thereof

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Publication Number Publication Date
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110184138A (en) * 2019-06-27 2019-08-30 湖南淳湘农林科技有限公司 A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser
US20210024859A1 (en) * 2019-07-24 2021-01-28 Hua-Chun CHAO Washing product

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1667111A (en) * 2004-03-09 2005-09-14 李强 Plant type and mineral type environmental protection tableware cleaning agent
CN103451032A (en) * 2013-08-30 2013-12-18 湖南大三湘油茶科技有限公司 Safe and environment-friendly tea seed washing powder and preparation method thereof
CN104178379A (en) * 2014-08-08 2014-12-03 福州喜自然生物科技有限公司 Natural washing product with strong oil and dirt removal capacity and preparation method of natural washing product with strong oil and dirt removal capacity
CN105695163A (en) * 2016-01-15 2016-06-22 普洱健源油脂有限公司 Preparation method of tea seed washing powder and washing agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1667111A (en) * 2004-03-09 2005-09-14 李强 Plant type and mineral type environmental protection tableware cleaning agent
CN103451032A (en) * 2013-08-30 2013-12-18 湖南大三湘油茶科技有限公司 Safe and environment-friendly tea seed washing powder and preparation method thereof
CN104178379A (en) * 2014-08-08 2014-12-03 福州喜自然生物科技有限公司 Natural washing product with strong oil and dirt removal capacity and preparation method of natural washing product with strong oil and dirt removal capacity
CN105695163A (en) * 2016-01-15 2016-06-22 普洱健源油脂有限公司 Preparation method of tea seed washing powder and washing agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110184138A (en) * 2019-06-27 2019-08-30 湖南淳湘农林科技有限公司 A kind of Extracted From Oil-tea-cake biology novel surface activity cleanser
US20210024859A1 (en) * 2019-07-24 2021-01-28 Hua-Chun CHAO Washing product
US11098272B2 (en) * 2019-07-24 2021-08-24 Hua-Chun CHAO Washing product

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Application publication date: 20181221