CN105695163A - Preparation method of tea seed washing powder and washing agent - Google Patents
Preparation method of tea seed washing powder and washing agent Download PDFInfo
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- CN105695163A CN105695163A CN201610025452.4A CN201610025452A CN105695163A CN 105695163 A CN105695163 A CN 105695163A CN 201610025452 A CN201610025452 A CN 201610025452A CN 105695163 A CN105695163 A CN 105695163A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
- C07H1/06—Separation; Purification
- C07H1/08—Separation; Purification from natural products
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
- C07H15/20—Carbocyclic rings
- C07H15/24—Condensed ring systems having three or more rings
- C07H15/256—Polyterpene radicals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J63/00—Steroids in which the cyclopenta(a)hydrophenanthrene skeleton has been modified by expansion of only one ring by one or two atoms
- C07J63/008—Expansion of ring D by one atom, e.g. D homo steroids
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Abstract
The invention belongs to the technical field of daily-use chemical industry and particularly relates to a preparation method of tea seed washing powder and a washing agent. The preparation method of tea seed washing powder and the washing agent is characterized in that tea seeds are prepared into the washing powder through the following steps of 1, drying; 2, husking; 3, degreasing; 4, crushing; 5, screening; 6, sterilizing and 7 metering and packaging; or the tea seeds are prepared into the washing agent through the following steps of 1, drying; 2, husking; 3, degreasing; 4, crushing; 5, extracting; 6, distillation; 7, filtering and impurity removal and 8, preparation of the tea seed washing agent. According to the preparation method of tea seed washing powder and the washing agent, in the production process of the washing agent and the washing powder, people do not make contact with any chemical auxiliaries, no additive is added, and no adverse influence is caused to the health of the human body; meanwhile, tea saponin in the tea seeds serves as the effective ingredients of the washing agent and the washing powder, 10% of the washing agent and the washing powder can be degraded after the washing agent and the washing powder are used, and no influence is caused to the environment.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, the preparation method being specifically related to a kind of camellia oleosa seed cleanser and detergent。
Background technology
It is mostly chemical industry synthesis that current China is used for washing one's hands and cleaning the articles for washing of tableware, fruit etc., often there is chemical industry synthetic detergent in life-time service process to remain in, on tableware, fruit, the health of people is produced dysgenic situation, chemical industry synthesis tableware detergent is mainly composed of sodium alkyl sulfonate, fatty alcohol-ether sodium sulfate, foaming agent, solubilizing agent, thickening agent, essence, water, pigment and preservative etc.。Wherein, principle active component sodium alkyl sulfonate and fatty alcohol-ether sodium sulfate are the surfactant that petrochemical industry is extracted。Because the surfactant of chemical industry synthesis makes tableware be not easy to rinse well from tableware surface after using detergent washing with the strong adhesion of object, all having detergent residual, life-time service remains the tableware of chemical detergent will certainly cause huge hidden danger to health。
Summary of the invention
The present invention is to solve the deficiencies in the prior art, it is provided that the preparation method of a kind of camellia oleosa seed cleanser and detergent, and the present invention is achieved by the following technical solution:
The preparation method of a kind of camellia oleosa seed cleanser, prepares into cleanser by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%-12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) screening: screening obtains the camellia oleosa seed powder that granularity is 30-120 order from the camellia oleosa seed powder that step (4) obtains；
(6) sterilizing: the camellia oleosa seed powder obtained in step (5) being carried out to camellia oleosa seed cleanser after sterilization treatment, in the camellia oleosa seed cleanser obtained, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams；
(7) metering packing: by the camellia oleosa seed cleanser that obtains in step (6) by constant weight bag distribution packaging。
Described camellia oleosa seed is tea-seed or Semen Camelliae。
The method that sterilization treatment described in step (7) adopts is the one in microwave sterilizating, electronics speed sterilizing, ozone sterilization, ultraviolet disinfection, high temperature sterilize, irradiation。
Its packaging material of bag distribution packaging described in step (8) are corn fiber cloth or non-woven fabrics。
The preparation method of a kind of camellia oleosa seed detergent, prepares into camellia oleosa seed detergent by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%-12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) extract: the camellia oleosa seed powder obtained in step (4) and extractant fully being soaked in leaching equipment, soak time is 30-120min, takes extract, and in the camellia oleosa seed powder after extraction, tea saponin content is less than 5%(weight ratio)；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 65-100 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) prepared by camellia oleosa seed detergent: take the mixed liquor obtained in step (7), camellia oleosa seed detergent is obtained after concentrated, in described camellia oleosa seed detergent, the ratio of tea saponin and water is 1:0.3-5, and in camellia oleosa seed detergent, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
Described camellia oleosa seed is tea-seed or Semen Camelliae。
Described extractant is ethanol and/or methanol；When adopting the methanol mixture with ethanol as extractant, the ratio of methanol and ethanol is 1:1.5-3；Described ethanol is the alcoholic solution of ethanol content >=75%, and described methanol is the methanol solution of methanol content >=75%。
The preparation method of a kind of teasaponin powder, prepares into teasaponin powder by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%-12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) extract: the camellia oleosa seed powder obtained in step (4) and extractant fully being soaked in leaching equipment, soak time takes extract when being 30-120min, in the camellia oleosa seed powder after extraction, tea saponin content is less than 5%(weight ratio)；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 65-100 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) dry: to take the mixed liquor obtained in step (7), obtain teasaponin powder after drying, content >=65% of tea saponin in described teasaponin powder, moisture≤15%, in teasaponin powder, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
Described camellia oleosa seed is tea-seed or Semen Camelliae。
Described extractant is ethanol and/or methanol；When adopting the methanol mixture with ethanol as extractant, the ratio of methanol and ethanol is 1:1.5-3；Described ethanol is the alcoholic solution of ethanol content >=75%, and described methanol is the methanol solution of methanol content >=75%。
Compared with prior art, there is advantages that the detergent of (1) present invention and cleanser production process does not contact any chemical assistant, without any additive, health is not resulted in harmful effect。(2) detergent of the present invention and cleanser utilize tea saponin in camellia oleosa seed as effective ingredient, after using can 100% degraded, environment will not be impacted。(3) detergent of the present invention and cleanser take full advantage of tea resource, extend tea industry chain。(4) detergent of the present invention and cleanser clean result are better, are used for washing effect when tableware and cup particularly evident。
Detailed description of the invention
Embodiment 1
The preparation method of a kind of camellia oleosa seed cleanser, prepares into cleanser by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out physical squeezing defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) screening: screening obtains the camellia oleosa seed powder that granularity is 30 orders from the camellia oleosa seed powder that step (4) obtains；
(6) sterilizing: the camellia oleosa seed powder obtained in step (5) being carried out to camellia oleosa seed cleanser after sterilization treatment, in the camellia oleosa seed cleanser obtained, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams；
(7) metering packing: by the camellia oleosa seed cleanser that obtains in step (6) by constant weight bag distribution packaging。
Described camellia oleosa seed is tea-seed。
Sterilizing methods in step (6) is irradiation。
Its packaging material non-woven fabrics of bag distribution packaging described in step (7)。
Embodiment 2
The preparation method of a kind of camellia oleosa seed cleanser, prepares into cleanser by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 10%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: undertaken squeezing, leaching defat by the camellia oleosa seed obtained in step (2), obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) screening: screening obtains the camellia oleosa seed powder that granularity is 75 orders from the camellia oleosa seed powder that step (4) obtains；
(6) sterilizing: the camellia oleosa seed powder obtained in step (5) being carried out to camellia oleosa seed cleanser after sterilization treatment, in the camellia oleosa seed cleanser obtained, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams；
(7) metering packing: by the camellia oleosa seed cleanser that obtains in step (6) by constant weight bag distribution packaging。
Described camellia oleosa seed is Semen Camelliae。
Sterilizing methods in step (6) is electronics speed sterilizing。
Its packaging material of bag distribution packaging described in step (7) are corn fiber cloth。
Embodiment 3
The preparation method of a kind of camellia oleosa seed cleanser, prepares into cleanser by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；In shelling camellia oleosa seed after peeling off, the amount containing shell is too high can affect the content of laundry active in finished product, reduces clean result, and easily blocks sewer, therefore shell proportion in camellia oleosa seed should be less than 20%。
(3) defat: the camellia oleosa seed obtained in step (2) is carried out CO2Supercritical physics defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) screening: if the camellia oleosa seed powder granularity after defat camellia oleosa seed crushing and screening is crossed slightly, dissolubility can be affected and granularity is crossed detailed rules and regulations and material can be caused to swim, therefore screen from the camellia oleosa seed powder that step (4) obtains and obtain the camellia oleosa seed powder that granularity is 120 orders；
(6) sterilizing: the camellia oleosa seed powder obtained in step (5) being carried out to camellia oleosa seed cleanser after sterilization treatment, in the camellia oleosa seed cleanser obtained, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams；
(7) metering packing: by the camellia oleosa seed cleanser that obtains in step (6) by constant weight bag distribution packaging。
Described camellia oleosa seed is tea-seed。
Sterilizing methods in step (6) is microwave sterilizating。
Its packaging material of bag distribution packaging described in step (7) are corn fiber cloth。
The cleanser of the present embodiment gained and other cleaning products contrast situation are in Table 1。
Table 1: the cleanser of the present embodiment gained and other cleaning product contrast tables
From table 1, the cleanser of the present embodiment is compared with generic camellia oleosa seed cleanser, free from foreign meter, and activity is high；Compared with existing detergent and liquid detergent, have without adding, the features such as activity is high, degradable, safety and Health。
Embodiment 4-6
Except being followed successively by ozone sterilization, ultraviolet disinfection, high temperature sterilize except the sterilizing methods in step (6) in embodiment 4-6, all the other are with embodiment 2。
Embodiment 7
The preparation method of a kind of camellia oleosa seed detergent, prepares into detergent by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) extract: the defat camellia oleosa seed obtained in step (4) and extractant fully being soaked in leaching equipment, soak time takes extract when being 30min, in the defat camellia oleosa seed after extraction, tea saponin content is less than 5%(weight ratio)；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 65 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) prepared by camellia oleosa seed detergent: take the mixed liquor obtained in step (7), camellia oleosa seed detergent is obtained after concentrated, in described camellia oleosa seed detergent, the ratio of tea saponin and water is 1:0.3, and in camellia oleosa seed detergent, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
Described camellia oleosa seed is tea-seed。
Described extractant is the alcoholic solution of ethanol content >=75%。
Embodiment 8
The preparation method of a kind of camellia oleosa seed detergent, prepares into detergent by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) extract: the defat camellia oleosa seed obtained in step (3) and extractant fully being soaked in leaching equipment, soak time takes extract when being 120min, in the defat camellia oleosa seed after extraction, tea saponin content is less than 5%(weight ratio)；
(5) pulverize: the defat camellia oleosa seed obtained in step (4) is carried out pulverization process, obtains camellia oleosa seed powder；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 100 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) prepared by camellia oleosa seed detergent: take the mixed liquor obtained in step (7), camellia oleosa seed detergent is obtained after concentrated, in described camellia oleosa seed detergent, the ratio of tea saponin and water is 1:5, and in camellia oleosa seed detergent, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
Described camellia oleosa seed is Semen Camelliae。
Described extractant is the alcoholic solution mixture with the methanol solution of methanol content >=75% of ethanol content >=75%, and the ratio of methanol and ethanol is: 1:1.5。
The detergent of the present embodiment gained and other cleaning products contrast situation are in Table 2。
Table 2: the detergent of the present embodiment gained and other cleaning product contrast tables
| Project | This product | Other camellia oleosa seed cleanser | Detergent, liquid detergent |
| Character | Liquid | Powder | Liquid |
| Raw material | Physics defat camellia oleosa seed | Chemical degreasing camellia oleosa seed | Petrochemical industry extract (chemical products, preservative) |
| Color | Pale yellow | Black palm fibre | Transparent |
| Cleanliness | Free from admixture | Containing shell, Caulis et Folium Oryzae | Containing the industrial chemicals such as thickening agent, foaming agent |
| Dissolubility | Good | Not good (not allowing impurities left in a large number) | Fabulous |
| Microorganism | Reach country's Dish-Washing Products standard | Exceed standard。Do not reach country's Dish-Washing Products standard | Reach country's Dish-Washing Products standard |
| Gross activity thing Matter | > 30%(has good washing clean effect) | About 20% (there is washing clean effect) | 15%-20%(has well washing decontamination effect Really) |
| Safety | Extremely safe (pure plant material, without chemical contact and interpolation), Yi Chong Wash, noresidue | Basic security (plant material, have chemical contact or interpolation) easily rinses, noresidue, but insoluble material is more, Easily block sewer | Huge hidden danger (petroleum chemicals) 5--> |
| The feature of environmental protection | Degradable, will not cause secondary pollution to environment | Degradable, will not cause secondary pollution to environment | It is difficult to degraded, to environment (tens Year does not degrade) |
From table 2, the detergent of the present embodiment is compared with generic camellia oleosa seed cleanser, free from foreign meter, and activity is high；Compared with existing detergent and liquid detergent, have without adding, the features such as activity is high, degradable, safety and Health。
Embodiment 9
The preparation method of a kind of camellia oleosa seed detergent, prepares into detergent by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 9%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) extract: the defat camellia oleosa seed obtained in step (3) and extractant fully being soaked in leaching equipment, soak time takes extract when being 75min, in the defat camellia oleosa seed after extraction, tea saponin content is less than 5%(weight ratio)；
(5) pulverize: the defat camellia oleosa seed obtained in step (4) is carried out pulverization process, obtains camellia oleosa seed powder；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 80 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) prepared by camellia oleosa seed detergent: take the mixed liquor obtained in step (7), camellia oleosa seed detergent is obtained after concentrated, in described camellia oleosa seed detergent, the ratio of tea saponin and water is 1:3, and in camellia oleosa seed detergent, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
Described camellia oleosa seed is Semen Camelliae。
Described extractant is the methanol solution of methanol content >=75%。
Embodiment 10
Described extractant is the alcoholic solution mixture with the methanol solution of methanol content >=75% of ethanol content >=75%, and wherein methanol with the ratio of ethanol is: 1:2.2, all the other are with embodiment 9。
Embodiment 11
Described extractant is the alcoholic solution mixture with the methanol solution of methanol content >=75% of ethanol content >=75%, and wherein methanol with the ratio of ethanol is: 1:3, all the other are with embodiment 9。
Embodiment 12
The preparation method of a kind of teasaponin powder, prepares into teasaponin powder by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out physics defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) extract: the camellia oleosa seed powder obtained in step (4) and extractant fully being soaked in leaching equipment, soak time takes extract when being 30min, in the camellia oleosa seed powder after extraction, tea saponin content is less than 5%(weight ratio)；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 65 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) dry: to take the mixed liquor obtained in step (7), obtain teasaponin powder after drying, content >=65% of tea saponin in described teasaponin powder, moisture≤15%, in teasaponin powder, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
Described camellia oleosa seed is tea-seed。
The alcoholic solution of described extractant ethanol content >=75%。
Embodiment 13
The preparation method of a kind of teasaponin powder, prepares into teasaponin powder by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 12%；
(5) soak time takes extract when being 80min；
(6) distillation: vapo(u)rizing temperature is: 100 DEG C；
Described camellia oleosa seed is Semen Camelliae。
Described extractant is the methanol solution of methanol content >=75%。
All the other are with embodiment 12。
Embodiment 14
The preparation method of a kind of teasaponin powder, prepares into teasaponin powder by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 10%；
(4) extract: soak time takes extract when being 75min；
(6) distillation: vapo(u)rizing temperature is: 75 DEG C；
Described extractant is the alcoholic solution mixture with the methanol solution of methanol content >=75% of ethanol content >=75%, and wherein methanol with the ratio of ethanol is: 1:3, all the other are with embodiment 12。
Embodiment 15
The preparation method of a kind of teasaponin powder, prepares into teasaponin powder by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 11%；
(4) extract: soak time takes extract when being 90min；
(6) distillation: vapo(u)rizing temperature is: 88 DEG C；
Described camellia oleosa seed is Semen Camelliae。
Described extractant is the alcoholic solution mixture with the methanol solution of methanol content >=75% of ethanol content >=75%, and wherein methanol with the ratio of ethanol is: 1:1.5, all the other are with embodiment 12。
Embodiment 16
The preparation method of a kind of teasaponin powder, prepares into teasaponin powder by camellia oleosa seed through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 11%；
(4) extract: soak time takes extract when being 120min；
(6) distillation: vapo(u)rizing temperature is: 68 DEG C；
Described extractant is the alcoholic solution mixture with the methanol solution of methanol content >=75% of ethanol content >=75%, and wherein methanol with the ratio of ethanol is: 1:2, all the other are with embodiment 12。
Claims (10)
1. the preparation method of a camellia oleosa seed cleanser, it is characterised in that camellia oleosa seed is prepared into cleanser through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%-12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) screening: screening obtains the camellia oleosa seed powder that granularity is 30-120 order from the camellia oleosa seed powder that step (4) obtains；
(6) sterilizing: the camellia oleosa seed powder obtained in step (5) being carried out to camellia oleosa seed cleanser after sterilization treatment, in the camellia oleosa seed cleanser obtained, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams；
(7) metering packing: by the camellia oleosa seed cleanser that obtains in step (6) by constant weight bag distribution packaging。
2. the preparation method of a kind of camellia oleosa seed cleanser according to claim 1, it is characterised in that described camellia oleosa seed is tea-seed or Semen Camelliae。
3. the preparation method of a kind of camellia oleosa seed cleanser according to claim 1, it is characterized in that, the method that the sterilization treatment described in step (7) adopts is the one in microwave sterilizating, electronics speed sterilizing, ozone sterilization, ultraviolet disinfection, high temperature sterilize, irradiation。
4. the preparation method of a kind of camellia oleosa seed cleanser according to claim 1, it is characterised in that its packaging material of bag distribution packaging described in step (8) are corn fiber cloth or non-woven fabrics。
5. the preparation method of a camellia oleosa seed detergent, it is characterised in that camellia oleosa seed is prepared into camellia oleosa seed detergent through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%-12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) extract: the camellia oleosa seed powder obtained in step (4) and extractant fully being soaked in leaching equipment, soak time is 30-120min, takes extract, and in the camellia oleosa seed powder after extraction, tea saponin content is less than 5%(weight ratio)；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 65-100 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) prepared by camellia oleosa seed detergent: take the mixed liquor obtained in step (7), camellia oleosa seed detergent is obtained after concentrated, in described camellia oleosa seed detergent, the ratio of tea saponin and water is 1:0.3-5, and in camellia oleosa seed detergent, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
6. the preparation method of a kind of camellia oleosa seed detergent according to claim 5, it is characterised in that described camellia oleosa seed is tea-seed or Semen Camelliae。
7. the preparation method of a kind of camellia oleosa seed detergent according to claim 5, it is characterised in that described extractant is ethanol and/or methanol；When adopting the methanol mixture with ethanol as extractant, the ratio of methanol and ethanol is 1:1.5-3；Described ethanol is the alcoholic solution of ethanol content >=75%, and described methanol is the methanol solution of methanol content >=75%。
8. the preparation method of a teasaponin powder, it is characterised in that camellia oleosa seed is prepared into teasaponin powder through following steps；
(1) dry: in dried camellia oleosa seed, moisture is 7%-12%；
(2) peel off: the camellia oleosa seed obtained in step (1) is carried out process of peeling off, obtain after process in camellia oleosa seed ratio shared by tea seed episperm less than 20%(quantity than)；
(3) defat: the camellia oleosa seed obtained in step (2) is carried out defat, obtains defat camellia oleosa seed and Oleum Camelliae after defat, in described defat camellia oleosa seed, oil content is less than 8%；
(4) pulverize: the defat camellia oleosa seed obtained in step (3) is carried out pulverization process, obtains camellia oleosa seed powder；
(5) extract: the camellia oleosa seed powder obtained in step (4) and extractant fully being soaked in leaching equipment, soak time takes extract when being 30-120min, in the camellia oleosa seed powder after extraction, tea saponin content is less than 5%(weight ratio)；
(6) distillation: being distilled by the extract obtained in step (5), vapo(u)rizing temperature is 65-100 DEG C, the condensed rear reuse of extractant, takes the remaining liquid after distillation；
(7) filtering and impurity removing: the remaining liquid obtained in step (6) is filtered, takes the mixed liquor after filtration；
(8) dry: to take the mixed liquor obtained in step (7), obtain teasaponin powder after drying, content >=65% of tea saponin in described teasaponin powder, moisture≤15%, in teasaponin powder, total number of bacteria is less than 1000/gram, coliform less than 3/100 grams。
9. the preparation method of a kind of teasaponin powder according to claim 8, it is characterised in that described camellia oleosa seed is tea-seed or Semen Camelliae。
10. the preparation method of a kind of teasaponin powder according to claim 8, it is characterised in that described extractant is ethanol and/or methanol；When adopting the methanol mixture with ethanol as extractant, the ratio of methanol and ethanol is 1:1.5-3；Described ethanol is the alcoholic solution of ethanol content >=75%, and described methanol is the methanol solution of methanol content >=75%。
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| CN107213844A (en) * | 2017-08-03 | 2017-09-29 | 广州大学 | A kind of tealeaves seed saponin and preparation method and application |
| CN108324616A (en) * | 2018-03-30 | 2018-07-27 | 湖南林之神林韵油茶科技发展有限公司 | Hair washing foot care powder containing tea seed and preparation method |
| CN108486715A (en) * | 2018-05-03 | 2018-09-04 | 广东护康宝农林生物科技有限公司 | A kind of Tea Saponin washes clean bag and its application method |
| CN109055042A (en) * | 2018-08-28 | 2018-12-21 | 湖南天华油茶科技股份有限公司 | Cleanser and preparation method thereof |
| CN109679788A (en) * | 2019-01-30 | 2019-04-26 | 江苏安心养老服务股份有限公司 | The preparation method and applications of tea seed cake detergent |
| CN110003999A (en) * | 2019-03-25 | 2019-07-12 | 苏州优养健康科技有限公司 | A kind of camellia seed cleaning powder and its preparation process |
| CN113337347A (en) * | 2021-05-31 | 2021-09-03 | 湖南万象生物科技有限公司 | Washing liquid prepared from defatted tea seed meal and preparation method thereof |
| CN113621017A (en) * | 2021-08-25 | 2021-11-09 | 青岛职业技术学院 | Comprehensive utilization method of camellia seed meal |
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| CN107213844A (en) * | 2017-08-03 | 2017-09-29 | 广州大学 | A kind of tealeaves seed saponin and preparation method and application |
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| CN108486715B (en) * | 2018-05-03 | 2019-04-26 | 广东护康宝农林生物科技有限公司 | A kind of Tea Saponin washes clean bag and its application method |
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| CN109679788A (en) * | 2019-01-30 | 2019-04-26 | 江苏安心养老服务股份有限公司 | The preparation method and applications of tea seed cake detergent |
| CN110003999A (en) * | 2019-03-25 | 2019-07-12 | 苏州优养健康科技有限公司 | A kind of camellia seed cleaning powder and its preparation process |
| CN110003999B (en) * | 2019-03-25 | 2021-11-05 | 苏州优养健康科技有限公司 | Camellia seed cleaning powder and preparation process thereof |
| CN113337347A (en) * | 2021-05-31 | 2021-09-03 | 湖南万象生物科技有限公司 | Washing liquid prepared from defatted tea seed meal and preparation method thereof |
| CN113621017A (en) * | 2021-08-25 | 2021-11-09 | 青岛职业技术学院 | Comprehensive utilization method of camellia seed meal |
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Application publication date: 20160622 |