CN110511832A - A kind of antibacterial environment protection liquid detergent and preparation method thereof - Google Patents

A kind of antibacterial environment protection liquid detergent and preparation method thereof Download PDF

Info

Publication number
CN110511832A
CN110511832A CN201910831727.7A CN201910831727A CN110511832A CN 110511832 A CN110511832 A CN 110511832A CN 201910831727 A CN201910831727 A CN 201910831727A CN 110511832 A CN110511832 A CN 110511832A
Authority
CN
China
Prior art keywords
parts
liquid detergent
environment protection
extract
protection liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910831727.7A
Other languages
Chinese (zh)
Inventor
谢怀周
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Goldman Sachs Fine Chemical Co Ltd
Original Assignee
Suzhou Goldman Sachs Fine Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Goldman Sachs Fine Chemical Co Ltd filed Critical Suzhou Goldman Sachs Fine Chemical Co Ltd
Priority to CN201910831727.7A priority Critical patent/CN110511832A/en
Publication of CN110511832A publication Critical patent/CN110511832A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618—Protease or amylase in liquid compositions only
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of antibacterial environment protection liquid detergents, it in parts by weight include following component: 13-20 parts of laureth sodium sulfovinate, double 10-15 parts of the stearates of Macrogol 6000, 1-3 parts of color stabilizer, 0.5-1 parts of tea tree ethereal oil, 0.2-0.6 parts of Geranium Essential, 1-3 parts of Herba Patriniae extract, 0.2-0.6 parts of Honegsukle flower P.E, 0.2-0.6 parts of dandelion extract, 3-7 parts of linseed cake fatty acid, 15-22 parts of cosolvent, 8-13 parts of enzyme preparation, 3-6 parts of nonionic surfactant, 2-4 parts of anionic surfactant, 2-4 parts of brightening agent, 50-75 parts of deionized water, liquid detergent of the invention has not phosphorous, dirt-removing power is strong, it is not damaged to fabric, with submissive, low-residual, the advantages that environmentally friendly；Natural sterilization component is added, field pennycress, honeysuckle and dandelion have the antibacterial action of wide spectrum.

Description

A kind of antibacterial environment protection liquid detergent and preparation method thereof
Technical field
The present invention relates to household chemicals technical fields, and in particular to a kind of antibacterial environment protection liquid detergent and preparation method thereof.
Background technique
Soap, washing powder have used many decades as traditional fabric washing cleaning supplies, in people's daily life may be used Meaning is very important, and historical value is justifiable, but soap needs rubbing, machine washing not to be available then in washing process, washing powder The dissolution that is first soaked in water is needed in washed kind, additional trouble is brought to people's washing process, while some traditional It is blocky and powdery solid in soap, washing powder, needs to add a large amount of solid-filling agent in forming process, these fillings Agent has been then a molding effect mostly, meaningless to washing effect itself, increases cost and also largely wastes substance Resource, and to be phosphorous minerals rely the mankind to filler causes adverse effect according to the environment of existence mostly, with modern people The economizing type of pursuit and friendly environment society be not on one's beat.
Summary of the invention
For above-mentioned technical deficiency, the object of the present invention is to provide a kind of antibacterial environment protection liquid detergent and its preparation sides Method.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
The present invention provides a kind of antibacterial environment protection liquid detergent, in parts by weight includes following component:
Double 10-15 parts of the stearate of 13-20 parts of laureth sodium sulfovinate, Macrogol 6000,1-3 parts of color stabilizer, 0.5-1 parts of tea tree ethereal oil, 0.2-0.6 parts of Geranium Essential, 1-3 parts of Herba Patriniae extract, 0.2-0.6 parts of Honegsukle flower P.E, 0.2-0.6 parts of dandelion extract, 3-7 parts of linseed cake fatty acid, 15-22 parts of cosolvent, 8-13 parts of enzyme preparation, nonionic table Activating agent 3-6 parts of face, 2-4 parts of anionic surfactant, 2-4 parts of brightening agent, 50-75 parts of deionized water.
A kind of antibacterial environment protection liquid detergent includes following component in parts by weight:
16 parts of laureth sodium sulfovinate, Macrogol 6000 double 13 parts of stearates, 2 parts of color stabilizer, tea tree ethereal oil 0.8 part, 0.4 part of Geranium Essential, 2 parts of Herba Patriniae extract, 0.4 part of Honegsukle flower P.E, 0.4 part of dandelion extract, Asia 5 parts of numb seedcake fatty acid, 18 parts of cosolvent, 11 parts of enzyme preparation, 5 parts of nonionic surfactant, anionic surfactant 3 Part, 3 parts of brightening agent, 62 parts of deionized water.
Preferably, color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows: degree of oxidation >=90%, active constituent 33%-37%, Ghana's moral (i.e. Gardn) coloration 6-13, viscosity 40cps-80cps, pH value 4.0-5.0.
Preferably, the cosolvent is pressed by tridecanol acrylic acid, polyethoxy fatty alcohol, the pure and mild niacinamide of dimethyl methyl It is mixed according to mass ratio 1:1-5:1-5:4-6.
Preferably, the nonionic surfactant is alkyl glycosides, straight-chain fatty alcohol polyoxyethylene ether, isomery fatty alcohol At least one of polyoxyethylene ether, condensation product of propylene oxide block copolymer.
Preferably, the anionic surfactant is dodecyl benzene sulfonic acid, sodium sulfate of polyethenoxy ether of fatty alcohol, rouge Fat alcohol polyoxyethylene ether carboxylic acid sodium, ethoxylated fatty acid sulfonate, diisooctyl Disodium sulfosuccinate or secondary alkyl sulphur One of sour sodium or at least two mixture.
Preferably, the enzyme preparation include amylase, cellulase, mannonase lipase, in pectase at least It is a kind of.
Preferably, the Herba Patriniae extract is prepared with the following method:
50-100 mesh is crushed to micronizer after field pennycress is dried and obtains Patrinia scaniosaefolia grass meal, by Patrinia scaniosaefolia grass meal in 75- It is 70% ethanol solution circumfluence distillation 3-6 times that concentration is used under the conditions of 85 DEG C, and concentration is that the dosage of 70% ethanol solution is Patrinia scaniosaefolia 5-10 times of grass meal weight later merges the filtrate extracted every time, and residue is abandoned in filtering, is in 55 DEG C and pressure by filtrate Be concentrated under reduced pressure under conditions of 0.1MPa, ethyl alcohol recycling, obtain Herba Patriniae extract,
Preferably, the Honegsukle flower P.E is prepared with the following method:
(1) dry honeysuckle is taken, 50-100 mesh is crushed to and obtains honeysuckle powder, is extracted 1-3 times with hydrous ethanol, after extraction Anti-oxidant protective agent is added into extracting solution, mixes, ethyl alcohol is recovered under reduced pressure, dry, pulverize, obtains honeysuckle alcohol-extracted extract powder；
(2) by filter residue obtained by step (1), add 15-20 times of water boiling and extraction 1-3 times, each 1-3h, filtration, gained filtrate It is concentrated under reduced pressure, be dry, pulverize, obtain the water extracted immersing paste powder；
(3) the water extracted immersing paste powder obtained by honeysuckle alcohol-extracted extract powder obtained by step (1) and step (2) is mixed, obtains honeysuckle Extract.
The preparation method of dandelion extract is identical as Honegsukle flower P.E.
Preferably, the brightening agent is stilbenesulphonic acid derivative brightening agent.
Preferably, the flaxseed meal means of supercritical extraction fatty acid the preparation method is as follows: will to squeeze linseed oil surplus Flaxseed meal is crushed to 30-50 mesh fineness, is reloaded into extraction kettle, spe medium carbon dioxide is measured through flowmeter laggard Enter extraction kettle, extraction temperature is 25-45 DEG C, extraction time 90-150min, extracting pressure 20-30MPa, carbon dioxide stream Amount is 50-80kg/h, obtains extract, separates, obtains crude oil, crude oil passes sequentially through anion exchange resin and cation exchange tree again Rouge carries out ion-exchange treatment, obtains level-one purified oil, level-one purified oil is using rectifying column, pressure 10-12Mpa, temperature ladder Degree is 30-55 DEG C, and separating still pressure is 4-5MPa, and temperature is 30-35 DEG C, obtains flaxseed meal means of supercritical extraction fatty acid.
A kind of preparation method of antibacterial environment protection liquid detergent, includes the following steps:
(1) it weighs: according to formula rate, accurately weighing raw material, it is spare；
(2) it prepares: a certain amount of deionized water being added in a stirring kettle, temperature is raised to 50 DEG C -60 DEG C, laruyl alcohol is added Nonionic surfactant, anion table is added to being completely dissolved in polyethers sodium sulfovinate, polyethylene glycol stearate diester, stirring Face activating agent, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding shield Toner, tea tree ethereal oil, Geranium Essential, Herba Patriniae extract, linseed cake fatty acid, cosolvent, brightening agent, enzyme preparation, are stirred It mixes to being completely dissolved, filters and filling, that is, antibacterial environment protection liquid detergent is prepared.
The invention has the following advantages:
(1) liquid detergent of the invention with not phosphorous, dirt-removing power is strong, it is not damaged to fabric, have submissive, low-residual, The advantages that environmentally friendly；Low-foam and easily rinsing, can effectively remove the stain on clothing；Deep layer is clean, keeps washed clothing pure whiter It is more bright-coloured.
(2) natural sterilization component is added in liquid detergent, there is the antibacterial of wide spectrum to make for field pennycress, honeysuckle and dandelion With, meanwhile, the effect of can not only preferably playing each active constituent, moreover it is possible to act synergistically, so that effect doubles, to golden yellow Portugal Grape coccus, Escherichia coli, typhoid bacillus, Shigella shigae, Diplococcus pneumopniae etc. have inhibiting effect, can effectively kill Bacterium in washing machine and on clothes, is easy to rinse, will not stimulate skin.Contain volatile oil in Herba Patriniae extract, predominantly loses Sauce alkene, isopatrinene, another A containing scabioside, scabioside B, scabioside C, scabioside D, Huang Flower patrinoside E, scabioside F, scabioside G and oleanolic acid etc..Also contain villoside, ivy soap The ingredients such as aglycon, β-sitosterol-β-D-Glucose glycosides, patrinoside.
(3) it joined flaxseed meal fatty acid in inventive formulation, one of the primary raw material as plant surface activating agent, Flaxseed meal can not only be made full use of, its utility value is improved, reduces environmental pollution and waste discharge, while also effectively mentioning The dirt-removing power of high plant surface activating agent and its residual quantity on clothing of reduction.
(4) addition of tea tree ethereal oil, Geranium Essential, not only taste is pure and fresh, enables that brains is pure and fresh, rejuvenates, simultaneously also Have the function of antibacterial bacteriostatic, avoids damage of the traditional chemical fungicide to clothing.Addition tea tree ethereal oil, Geranium Essential are in washing In clothing liquid, the clothes after can also making cleaning has natural fragrance.
(5) antibacterial environment protection liquid detergent of the invention, prepares simple to operation, and indices meet dress material detergent " dress material Wash agent by liquid " requirement in Q/BT 1224-2012, low concentration is rapidly dissolvable, easily rinses, anti-dilution capacity is strong, has Antibacterial, the multi-efficiencies such as submissive, bleaching, strong detergency, can deep layer cleaning substrate, do not add perfume (or spice) in the laundry liquid formulation Essence, fragrance naturally, pH value in 7-9, it is small to skin damage.
Detailed description of the invention
Fig. 1 is liquid detergent foam height figure of the present invention；
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
A kind of antibacterial environment protection liquid detergent includes following component in parts by weight:
13 parts of laureth sodium sulfovinate, Macrogol 6000 double 10 parts of stearates, 1 part of color stabilizer, tea tree ethereal oil 0.5 part, 0.2 part of Geranium Essential, 1 part of Herba Patriniae extract, 0.2 part of Honegsukle flower P.E, 0.2 part of dandelion extract, Asia 3 parts of numb seedcake fatty acid, 15 parts of cosolvent, 8 parts of enzyme preparation, 3 parts of nonionic surfactant, 2 parts of anionic surfactant, 2 parts of brightening agent, 50 parts of deionized water.
Further, color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows: oxidation journey Spend >=90%, active constituent 33%-37%, Ghana's moral (i.e. Gardn) coloration 6-13, viscosity 40cps-80cps, pH value 4.0- 5.0。
The cosolvent is by tridecanol acrylic acid, polyethoxy fatty alcohol, the pure and mild niacinamide of dimethyl methyl according to quality It is mixed than 1:1:1:4.
The nonionic surfactant is alkyl glycosides, straight-chain fatty alcohol polyoxyethylene ether, isomery fatty alcohol polyoxy second Alkene ether is mixed according to mass ratio 4:1:1.
The anionic surfactant is dodecyl benzene sulfonic acid, sodium sulfate of polyethenoxy ether of fatty alcohol, poly alkyl alcohol Ethylene oxide ether carboxylic acid sodium according to mass ratio 1:2:5 mixture.
The enzyme preparation is amylase, cellulase, mannase are mixed according to mass ratio 3:2:1.
Further, the Herba Patriniae extract is prepared with the following method:
50-100 mesh is crushed to micronizer after field pennycress is dried and obtains Patrinia scaniosaefolia grass meal, by Patrinia scaniosaefolia grass meal in 75 DEG C Under the conditions of with concentration be 70% ethanol solution circumfluence distillation 3 times, concentration is that the dosage of 70% ethanol solution is Patrinia scaniosaefolia grass meal weight 5 times of amount later merge the filtrate extracted every time, and residue is abandoned in filtering, the condition for being 0.1MPa in 55 DEG C and pressure by filtrate Under be concentrated under reduced pressure, ethyl alcohol recycling, obtain Herba Patriniae extract.
Further, the Honegsukle flower P.E is prepared with the following method:
(1) dry honeysuckle is taken, 50 mesh is crushed to and obtains honeysuckle powder, is extracted 1 time with hydrous ethanol, to extraction after extraction Anti-oxidant protective agent is added in liquid, mixes, ethyl alcohol is recovered under reduced pressure, dry, pulverize, obtains honeysuckle alcohol-extracted extract powder；
(2) by filter residue obtained by step (1), add 15 times of water boiling and extractions 1 time, each 1h, filter, gained filtrate is dense through depressurizing Contracting, dry, pulverize, obtain the water extracted immersing paste powder；
(3) the water extracted immersing paste powder obtained by honeysuckle alcohol-extracted extract powder obtained by step (1) and step (2) is mixed, obtains honeysuckle Extract.
The preparation method of dandelion extract is identical as Honegsukle flower P.E.
Preferably, the brightening agent is stilbenesulphonic acid derivative brightening agent.
Further, the flaxseed meal means of supercritical extraction fatty acid the preparation method is as follows: by squeezing linseed oil remain Flaxseed meal be crushed to 30 mesh fineness, be reloaded into extraction kettle, spe medium carbon dioxide measured through flowmeter laggard Entering extraction kettle, extraction temperature is 25 DEG C, extraction time 90min, extracting pressure 20MPa, carbon dioxide flow 50kg/h, Extract is obtained, separation obtains crude oil, and crude oil passes sequentially through anion exchange resin and cation exchange resin again, carries out ion friendship Processing is changed, level-one purified oil is obtained, level-one purified oil is 30 DEG C using rectifying column, pressure 10Mpa, temperature gradient, separating still Pressure is 4MPa, and temperature is 30 DEG C, obtains flaxseed meal means of supercritical extraction fatty acid.
A kind of preparation method of antibacterial environment protection liquid detergent, includes the following steps:
(1) it weighs: according to formula rate, accurately weighing raw material, it is spare；
(2) it prepares: a certain amount of deionized water being added in a stirring kettle, temperature is raised to 50 DEG C -60 DEG C, laruyl alcohol is added Nonionic surfactant, anion table is added to being completely dissolved in polyethers sodium sulfovinate, polyethylene glycol stearate diester, stirring Face activating agent, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding shield Toner, tea tree ethereal oil, Geranium Essential, Herba Patriniae extract, linseed cake fatty acid, cosolvent, brightening agent, enzyme preparation, are stirred It mixes to being completely dissolved, filters and filling, that is, bacterium environment friendly laundry liquid is prepared.
Embodiment 2
A kind of antibacterial environment protection liquid detergent includes following component in parts by weight:
20 parts of laureth sodium sulfovinate, Macrogol 6000 double 15 parts of stearates, 3 parts of color stabilizer, tea tree ethereal oil 1 Part, 0.6 part of Geranium Essential, 3 parts of Herba Patriniae extract, 0.6 part of Honegsukle flower P.E, 0.6 part of dandelion extract, linseed 7 parts of cake fatty acid, 13 parts of enzyme preparation, 6 parts of nonionic surfactant, 4 parts of anionic surfactant, increases 22 parts of cosolvent White dose 4 parts, 75 parts of deionized water.
Further, color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows: oxidation journey Spend >=90%, active constituent 33%-37%, Ghana's moral (i.e. Gardn) coloration 6-13, viscosity 40cps-80cps, pH value 4.0- 5.0。
The cosolvent is by tridecanol acrylic acid, polyethoxy fatty alcohol, the pure and mild niacinamide of dimethyl methyl according to quality It is mixed than 1:5:5:6.
The nonionic surfactant is isomery fatty alcohol polyoxyethylene ether, propylene oxide block copolymer according to quality It is mixed than 1:1.
The anionic surfactant is ethoxylated fatty acid sulfonate, diisooctyl Disodium sulfosuccinate and secondary Sodium alkyl sulfonate is mixed according to mass ratio 3:2:1.
Further, the enzyme preparation is lipase, pectase is mixed according to mass ratio 2:5.
Further, the Herba Patriniae extract is prepared with the following method:
100 mesh are crushed to micronizer after field pennycress is dried and obtain Patrinia scaniosaefolia grass meal, by Patrinia scaniosaefolia grass meal in 85 DEG C of items It is 70% ethanol solution circumfluence distillation 6 times that concentration is used under part, and concentration is that the dosage of 70% ethanol solution is Patrinia scaniosaefolia grass meal weight 10 times, the filtrate extracted every time is merged later, residue is abandoned in filtering, by filtrate in the condition that 55 DEG C and pressure are 0.1MPa Under be concentrated under reduced pressure, ethyl alcohol recycling, obtain Herba Patriniae extract.
Further, the Honegsukle flower P.E is prepared with the following method:
(1) dry honeysuckle is taken, 100 mesh is crushed to and obtains honeysuckle powder, is extracted 3 times with hydrous ethanol, extraction mentions backward It takes and anti-oxidant protective agent is added in liquid, mix, ethyl alcohol is recovered under reduced pressure, dry, pulverize, obtains honeysuckle alcohol-extracted extract powder；
(2) by filter residue obtained by step (1), add 20 times of water boiling and extractions 3 times, each 3h, filter, gained filtrate is dense through depressurizing Contracting, dry, pulverize, obtain the water extracted immersing paste powder；
(3) the water extracted immersing paste powder obtained by honeysuckle alcohol-extracted extract powder obtained by step (1) and step (2) is mixed, obtains honeysuckle Extract.
The preparation method of dandelion extract is identical as Honegsukle flower P.E.
Preferably, the brightening agent is stilbenesulphonic acid derivative brightening agent.
Further, the flaxseed meal means of supercritical extraction fatty acid the preparation method is as follows: by squeezing linseed oil remain Flaxseed meal be crushed to 50 mesh fineness, be reloaded into extraction kettle, spe medium carbon dioxide measured through flowmeter laggard Enter extraction kettle, extraction temperature is 45 DEG C, extraction time 150min, extracting pressure 30MPa, carbon dioxide flow 80kg/ H obtains extract, separation, obtains crude oil, and crude oil passes sequentially through anion exchange resin and cation exchange resin again, carries out ion Exchange processing obtains level-one purified oil, and level-one purified oil is 55 DEG C using rectifying column, pressure 12Mpa, temperature gradient, separation Kettle pressure is 5MPa, and temperature is 35 DEG C, obtains flaxseed meal means of supercritical extraction fatty acid.
A kind of preparation method of antibacterial environment protection liquid detergent, includes the following steps:
(1) it weighs: according to formula rate, accurately weighing raw material, it is spare；
(2) it prepares: a certain amount of deionized water being added in a stirring kettle, temperature is raised to 60 DEG C, laureth is added It is living that nonionic surfactant, anionic surface is added to being completely dissolved in sodium sulfovinate, polyethylene glycol stearate diester, stirring Property agent, stirring is to being completely dissolved；Then balance deionized water is added, and cool the temperature to 40 DEG C hereinafter, sequentially add color stabilizer, Tea tree ethereal oil, Geranium Essential, Herba Patriniae extract, linseed cake fatty acid, cosolvent, brightening agent, enzyme preparation are stirred to complete Fully dissolved filters and filling, that is, bacterium environment friendly laundry liquid is prepared.
Embodiment 3
A kind of antibacterial environment protection liquid detergent includes following component in parts by weight:
16 parts of laureth sodium sulfovinate, Macrogol 6000 double 13 parts of stearates, 2 parts of color stabilizer, tea tree ethereal oil 0.8 part, 0.4 part of Geranium Essential, 2 parts of Herba Patriniae extract, 0.4 part of Honegsukle flower P.E, 0.4 part of dandelion extract, Asia 5 parts of numb seedcake fatty acid, 18 parts of cosolvent, 11 parts of enzyme preparation, 5 parts of nonionic surfactant, anionic surfactant 3 Part, 3 parts of brightening agent, 62 parts of deionized water.
Color stabilizer selects poly 4 vinyl pyridine nitrogen oxides, and the physicochemical property of color stabilizer is as follows: degree of oxidation >=90%, Active constituent 33%-37%, Ghana's moral (i.e. Gardn) coloration 6-13, viscosity 40cps-80cps, pH value 4.0-5.0.
The cosolvent is by tridecanol acrylic acid, polyethoxy fatty alcohol, the pure and mild niacinamide of dimethyl methyl according to quality It is mixed than 1:3:2:5.
The nonionic surfactant is alkyl glycosides, isomery fatty alcohol polyoxyethylene ether, propylene oxide block copolymerization Object is mixed according to mass ratio 1:1:3.
The anionic surfactant is dodecyl benzene sulfonic acid, AEO carboxylic acid sodium, di-sec-alkyl The mixture that sodium sulfonate is mixed according to mass ratio 2:2:5.
The enzyme preparation includes that amylase, mannonase pectase are mixed according to mass ratio 1:1:1.
The Herba Patriniae extract is prepared with the following method:
80 mesh are crushed to micronizer after field pennycress is dried and obtain Patrinia scaniosaefolia grass meal, by Patrinia scaniosaefolia grass meal in 80 DEG C of conditions Lower use concentration is 70% ethanol solution circumfluence distillation 5 times, and concentration is that the dosage of 70% ethanol solution is the 5 of Patrinia scaniosaefolia grass meal weight Times, the filtrate extracted every time is merged later, residue is abandoned in filtering, by filtrate under conditions of 55 DEG C and pressure are 0.1MPa into Row is concentrated under reduced pressure, and ethyl alcohol recycling obtains Herba Patriniae extract.
The Honegsukle flower P.E is prepared with the following method:
(1) dry honeysuckle is taken, 80 mesh is crushed to and obtains honeysuckle powder, is extracted 2 times with hydrous ethanol, to extraction after extraction Anti-oxidant protective agent is added in liquid, mixes, ethyl alcohol is recovered under reduced pressure, dry, pulverize, obtains honeysuckle alcohol-extracted extract powder；
(2) by filter residue obtained by step (1), add 18 times of water boiling and extractions 2 times, each 2h, filter, gained filtrate is dense through depressurizing Contracting, dry, pulverize, obtain the water extracted immersing paste powder；
(3) the water extracted immersing paste powder obtained by honeysuckle alcohol-extracted extract powder obtained by step (1) and step (2) is mixed, obtains honeysuckle Extract.
The preparation method of dandelion extract is identical as Honegsukle flower P.E.
Preferably, the brightening agent is stilbenesulphonic acid derivative brightening agent.
Further, the flaxseed meal means of supercritical extraction fatty acid the preparation method is as follows: by squeezing linseed oil remain Flaxseed meal be crushed to 40 mesh fineness, be reloaded into extraction kettle, spe medium carbon dioxide measured through flowmeter laggard Enter extraction kettle, extraction temperature is 35 DEG C, extraction time 120min, extracting pressure 25MPa, carbon dioxide flow 65kg/ H obtains extract, separation, obtains crude oil, and crude oil passes sequentially through anion exchange resin and cation exchange resin again, carries out ion Exchange processing obtains level-one purified oil, and level-one purified oil is 42 DEG C using rectifying column, pressure 11Mpa, temperature gradient, separation Kettle pressure is 4MPa, and temperature is 33 DEG C, obtains flaxseed meal means of supercritical extraction fatty acid.
A kind of preparation method of antibacterial environment protection liquid detergent, includes the following steps:
(1) it weighs: according to formula rate, accurately weighing raw material, it is spare；
(2) it prepares: a certain amount of deionized water being added in a stirring kettle, temperature is raised to 55 DEG C, laureth is added It is living that nonionic surfactant, anionic surface is added to being completely dissolved in sodium sulfovinate, polyethylene glycol stearate diester, stirring Property agent, stirring is to being completely dissolved；Then balance deionized water is added, and cool the temperature to 40 DEG C hereinafter, sequentially add color stabilizer, Tea tree ethereal oil, Geranium Essential, Herba Patriniae extract, linseed cake fatty acid, cosolvent, brightening agent, enzyme preparation are stirred to complete Fully dissolved filters and filling, that is, bacterium environment friendly laundry liquid is prepared.
1. detergency test of test example
The detergency test of antibacterial environment protection liquid detergent sample referring to GB/T13174-2008 " dress material detergent detergency and Recycle the measurement of scourability " it carries out, the experimental results showed that, liquid detergent made from embodiment 1-3 and commercially available green unrestrained liquid detergent As a comparison case to carbon black oil soiled cotton, albumen soiled cotton, sebum soiled cotton and edible oil soiled cotton decontamination value and standard liquid detergent decontamination value Ratio it is as shown in table 1.
1 liquid detergent dirt-removing power test result of table
Table 1 statistics indicate that, the antibacterial environment protection liquid detergent of 1-3 of embodiment of the present invention preparation is compared to commercially available green unrestrained liquid detergent tool There is stronger detergency, the antibacterial environment protection liquid detergent clean effect that wherein prepared by embodiment 3 is best.
2. anti-microbial property test of test example
The antibacterial ability test of antibacterial environment protection liquid detergent sample is referring to QB/T2738-2012 " daily chemical products antibacterial and antibacterial The evaluation method of effect " it carries out, activity 1:100, action time 20 minutes, the experimental results showed that, made from embodiment 1-3 Liquid detergent and commercially available green unrestrained liquid detergent are as a comparison case to Escherichia coli ATCC25922's and staphylococcus glucose bacterium ATCC6538 Sterilizing rate is as shown in table 2.
The bactericidal effect of the antibacterial environment protection liquid detergent of the present invention of table 2
Table 2 statistics indicate that, when thinner ratio be 1:100 when, for metal staphylococcus and Escherichia coli, embodiment 1-3 Liquid detergent sterilizing rate obtained can reach 99% or more, illustrate the antibacterial environment protection liquid detergent tool of 1-3 of embodiment of the present invention preparation There is stronger fungistatic effect, the antibacterial environment protection liquid detergent fungistatic effect that wherein prepared by embodiment 3 is best.
The test of 3. thermal stability of test example
Liquid detergent made from embodiment 1-3 is measured respectively and commercially available green unrestrained liquid detergent is no less than 100ml as a comparison case Each two groups of sample, be respectively placed in the colourless tool plug wide mouth glass bottle of 250ml, it is a to be put in the incubator of (40 ± 2) DEG C It sets for 24 hours, takes out after restoring to room temperature whether observation liquid detergent is muddy, whether is layered；Another puts in the refrigerator of (- 5 ± 2) DEG C It sets for 24 hours, takes out after restoring to room temperature whether observation liquid detergent is muddy, whether is layered.
The thermal stability of the antibacterial environment protection liquid detergent of the present invention of table 3
As can be seen from Table 3, the antibacterial environment protection liquid detergent of 1-3 of embodiment of the present invention preparation is at 40 DEG C and at a temperature of -5 DEG C, It has good stability, illustrates that the cold-resistant heat resistance of liquid detergent is preferable.
4. appearance of experimental example and smell
Sample is no less than as a comparison case for liquid detergent made from measurement embodiment 1-3 and commercially available green unrestrained liquid detergent respectively The sample of 200ml is placed in clean colourless tool plug wide-mouth bottle, is observed under non-direct projection striation part；Respectively take appropriate sample Identified in colourless tool wide-mouth bottle with smell.
4 liquid detergent appearance of table and smell
Group Embodiment 1 Embodiment 2 Embodiment 3 Comparative example
Appearance Uniform liquid Uniform liquid Uniform liquid Precipitating
Smell Free from extraneous odour Free from extraneous odour Free from extraneous odour Peculiar smell
The antibacterial environment protection liquid detergent sample of 1-3 of embodiment of the present invention preparation is all not stratified, without obvious suspended matter or precipitating, is Uniform liquid without mechanical admixture.And free from extraneous odour, meet the standard of liquid detergent organoleptic indicator.
The test of 5. frothing capacity of experimental example
According to GB7462,2.5mmol/Ca is used2+0.25% solution that hard water prepares sample is measured.Used 2.5mmol/Ca2+Hardness water is prepared according to QB/T1325.Sample includes liquid detergent made from embodiment 1-3 and commercially available green As a comparison case, testing initial foam height, 10min respectively, foam is high later by foam height and 20min later for unrestrained liquid detergent Degree.
5 foam test effect of table
Group Embodiment 1 Embodiment 2 Embodiment 3 Comparative example
0/mm 103 105 98 128
10min/mm 100 102 96 104
20min/mm 96 97 94 82
Reduce trend by a small margin from table 5 and attached drawing 1 it will be evident that the foam performance of embodiment 1-3 sample has, it is overall On be not much different, 3 sample foam performance of embodiment is slightly good.The foam height of embodiment 1-3 samples is below 135mm is less than standard liquid detergent foam dynamic height, meets the development trend of liquid detergent.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art Mind and range.In this way, if these modifications and changes of the present invention belongs to the range of the claims in the present invention and its equivalent technologies Within, then the present invention is also intended to include these modifications and variations.

Claims (10)

1. a kind of antibacterial environment protection liquid detergent, which is characterized in that in parts by weight include following component:
13-20 parts of laureth sodium sulfovinate, Macrogol 6000 double 10-15 parts of stearates, 1-3 parts of color stabilizer, tea tree 0.5-1 parts of essential oil, 0.2-0.6 parts of Geranium Essential, 1-3 parts of Herba Patriniae extract, 0.2-0.6 parts of Honegsukle flower P.E, Pu Gong 0.2-0.6 parts of English extract, 3-7 parts of linseed cake fatty acid, 15-22 parts of cosolvent, 8-13 parts of enzyme preparation, non-ionic surface are living Property 3-6 parts of agent, 2-4 parts of anionic surfactant, 2-4 parts of brightening agent, 50-75 parts of deionized water.
2. a kind of antibacterial environment protection liquid detergent as described in claim 1, which is characterized in that in parts by weight include following component:
16 parts of laureth sodium sulfovinate, Macrogol 6000 double 13 parts of stearates, 2 parts of color stabilizer, tea tree ethereal oil 0.8 Part, 0.4 part of Geranium Essential, 2 parts of Herba Patriniae extract, 0.4 part of Honegsukle flower P.E, 0.4 part of dandelion extract, linseed 5 parts of cake fatty acid, 11 parts of enzyme preparation, 5 parts of nonionic surfactant, 3 parts of anionic surfactant, increases 18 parts of cosolvent White dose 3 parts, 62 parts of deionized water.
3. a kind of antibacterial environment protection liquid detergent as described in claim 1, which is characterized in that color stabilizer selects poly 4 vinyl pyridine Nitrogen oxides, the brightening agent are stilbenesulphonic acid derivative brightening agent.
4. a kind of antibacterial environment protection liquid detergent as described in claim 1, which is characterized in that the cosolvent is by tridecanol propylene Acid, polyethoxy fatty alcohol, the pure and mild niacinamide of dimethyl methyl are mixed according to mass ratio 1:1-5:1-5:4-6.
5. a kind of antibacterial environment protection liquid detergent as described in claim 1, which is characterized in that the nonionic surfactant is alkane Base glucosides, straight-chain fatty alcohol polyoxyethylene ether, isomery fatty alcohol polyoxyethylene ether, propylene oxide block copolymer condensation product in At least one；The anionic surfactant is dodecyl benzene sulfonic acid, sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol Polyoxyethylene ether carboxylic acid sodium, ethoxylated fatty acid sulfonate, diisooctyl Disodium sulfosuccinate or sodium secondary alkyl sulfonate One of or at least two mixture.
6. a kind of antibacterial environment protection liquid detergent as described in claim 1, which is characterized in that the enzyme preparation includes amylase, fibre Tie up at least one of plain enzyme, mannonase lipase, pectase.
7. a kind of antibacterial environment protection liquid detergent as claimed in any one of claims 1 to 6, which is characterized in that the Herba Patriniae extract It is prepared with the following method:
50-100 mesh is crushed to micronizer after field pennycress is dried and obtains Patrinia scaniosaefolia grass meal, by Patrinia scaniosaefolia grass meal in 75-85 DEG C Under the conditions of with concentration be 70% ethanol solution circumfluence distillation 3-6 times, concentration is that the dosage of 70% ethanol solution is Patrinia scaniosaefolia grass meal 5-10 times of weight later merges the filtrate extracted every time, and residue is abandoned in filtering, by filtrate in 55 DEG C and pressure be 0.1MPa Under conditions of be concentrated under reduced pressure, ethyl alcohol recycling, obtain Herba Patriniae extract.
8. such as a kind of described in any item antibacterial environment protection liquid detergents of claim 1-7, which is characterized in that the Honegsukle flower P.E It is prepared with the following method:
(1) dry honeysuckle is taken, 50-100 mesh is crushed to and obtains honeysuckle powder, is extracted 1-3 times with hydrous ethanol, extraction mentions backward It takes and anti-oxidant protective agent is added in liquid, mix, ethyl alcohol is recovered under reduced pressure, dry, pulverize, obtains honeysuckle alcohol-extracted extract powder；
(2) by filter residue obtained by step (1), add 15-20 times of water boiling and extraction 1-3 times, each 1-3h, filtration, gained filtrate is through subtracting Pressure concentration, dry, pulverize, obtain the water extracted immersing paste powder；
(3) the water extracted immersing paste powder obtained by honeysuckle alcohol-extracted extract powder obtained by step (1) and step (2) is mixed, obtains honeysuckle extraction Object.
9. such as a kind of described in any item antibacterial environment protection liquid detergents of claim 1-8, which is characterized in that the flaxseed meal is super to be faced Boundary extract fatty acid the preparation method is as follows:
The surplus flaxseed meal of linseed oil will be squeezed and be crushed to 30-50 mesh fineness, be reloaded into extraction kettle, by spe medium two Carbonoxide enters extraction kettle after flowmeter measures, and extraction temperature is 25-45 DEG C, extraction time 90-150min, extracting pressure Extract is obtained for 20-30MPa, carbon dioxide flow 50-80kg/h, separates, obtains crude oil, crude oil passes sequentially through anion again Exchanger resin and cation exchange resin carry out ion-exchange treatment, obtain level-one purified oil, level-one purified oil is using rectifying Column, pressure 10-12Mpa, temperature gradient are 30-55 DEG C, and separating still pressure is 4-5MPa, and temperature is 30-35 DEG C, obtain flax Seed dregs of rice means of supercritical extraction fatty acid.
10. a kind of preparation method of antibacterial environment protection liquid detergent, which comprises the steps of:
(1) it weighs: according to formula rate, accurately weighing raw material, it is spare；
(2) it prepares: a certain amount of deionized water being added in a stirring kettle, temperature is raised to 50 DEG C -60 DEG C, laureth is added It is living that nonionic surfactant, anionic surface is added to being completely dissolved in sodium sulfovinate, polyethylene glycol stearate diester, stirring Property agent, stirring is to being completely dissolved；Then balance deionized water is added, and cool the temperature to 40 DEG C hereinafter, sequentially add color stabilizer, Tea tree ethereal oil, Geranium Essential, Herba Patriniae extract, linseed cake fatty acid, cosolvent, brightening agent, enzyme preparation are stirred to complete Fully dissolved filters and filling, that is, antibacterial environment protection liquid detergent is prepared.
CN201910831727.7A 2019-09-04 2019-09-04 A kind of antibacterial environment protection liquid detergent and preparation method thereof Pending CN110511832A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910831727.7A CN110511832A (en) 2019-09-04 2019-09-04 A kind of antibacterial environment protection liquid detergent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910831727.7A CN110511832A (en) 2019-09-04 2019-09-04 A kind of antibacterial environment protection liquid detergent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN110511832A true CN110511832A (en) 2019-11-29

Family

ID=68630778

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910831727.7A Pending CN110511832A (en) 2019-09-04 2019-09-04 A kind of antibacterial environment protection liquid detergent and preparation method thereof

Country Status (1)

Country Link
CN (1) CN110511832A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708512A (en) * 2020-12-29 2021-04-27 两面针（江苏）实业有限公司 Natural sweet wormwood sterilization laundry detergent
CN114712281A (en) * 2022-04-07 2022-07-08 扬州大学 Supercritical CO2Extracted plant extract and its preparation method and application
CN115466652A (en) * 2022-09-21 2022-12-13 云南水星生物科技有限公司 Antibacterial color fixative and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106726865A (en) * 2016-11-11 2017-05-31 宁波亿拍客网络科技有限公司 It is a kind of to the addition of the daily chemical product that natural medicinal ingredient is not destroyed Chinese herbal medicine
CN108841460A (en) * 2018-04-10 2018-11-20 湖北健客日化有限公司 A kind of mosquito repellent laundry detergent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106726865A (en) * 2016-11-11 2017-05-31 宁波亿拍客网络科技有限公司 It is a kind of to the addition of the daily chemical product that natural medicinal ingredient is not destroyed Chinese herbal medicine
CN108841460A (en) * 2018-04-10 2018-11-20 湖北健客日化有限公司 A kind of mosquito repellent laundry detergent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112708512A (en) * 2020-12-29 2021-04-27 两面针（江苏）实业有限公司 Natural sweet wormwood sterilization laundry detergent
CN112708512B (en) * 2020-12-29 2022-03-01 两面针（江苏）实业有限公司 Natural sweet wormwood sterilization laundry detergent
CN114712281A (en) * 2022-04-07 2022-07-08 扬州大学 Supercritical CO2Extracted plant extract and its preparation method and application
CN114712281B (en) * 2022-04-07 2023-12-08 扬州大学 Supercritical CO 2 Extracted plant extract and preparation method and application thereof
CN115466652A (en) * 2022-09-21 2022-12-13 云南水星生物科技有限公司 Antibacterial color fixative and preparation method and application thereof

Similar Documents

Publication Publication Date Title
CN107955743B (en) Efficient laundry detergent and preparation method thereof
CN110511832A (en) A kind of antibacterial environment protection liquid detergent and preparation method thereof
CN105062703A (en) Protease super-concentrated laundry detergent and preparation method thereof
CN112646669A (en) Washing and protecting integrated laundry detergent containing biological protease
CN108893212A (en) A kind of solidifying pearl and preparation method thereof of doing washing
CN106190651A (en) A kind of zinc cation liquid and preparation method thereof
CN105623927A (en) Concentrated detergent and preparation method thereof
CN105316119A (en) Sapindoside infant laundry detergent and preparation method thereof
CN112410133A (en) Environment-friendly laundry detergent and preparation method thereof
CN105695163A (en) Preparation method of tea seed washing powder and washing agent
CN110184135A (en) A kind of antibacterial dish washing liquid of propolis and preparation method thereof
CN102304437A (en) High-efficiency liquid-phase washing agent with bleaching effect for colored fabric
CN110964607A (en) Laundry detergent with sterilization function and preparation method thereof
CN106727151A (en) A kind of mildy wash and preparation method thereof
CN112205431A (en) Antibacterial composition, antibacterial infant clothes washing liquor and preparation method thereof
CN108841460A (en) A kind of mosquito repellent laundry detergent
CN106221967A (en) A kind of pure plant extract strong dirt-removing cleaning agent and preparation method thereof
CN107312658A (en) A kind of hand clothes washing soap powder easily rinsed
CN106635459A (en) Plant washing liquid with disinsectization, bacteria inhibition and decontamination effects and preparation method thereof
CN109609302A (en) It is a kind of for clothing macula lutea, the cleaning solution of pigment and preparation method
CN103881854A (en) Raw materials and method for preparing garlic laundry detergent
CN108504461A (en) One kind containing diatomaceous antimicrobial laundry liquid and preparation method thereof
CN109055034A (en) Liquid detergent
CN110452782A (en) A kind of liquid detergent and preparation method thereof containing sunflower pole microcapsules
CN107287059A (en) Baby's children's clothes thing bio-enzyme cleaning agent

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20191129