CN103445972B - A kind of mild shampoo containing sulfonated alkyl glucoside - Google Patents
A kind of mild shampoo containing sulfonated alkyl glucoside Download PDFInfo
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- CN103445972B CN103445972B CN201310376310.9A CN201310376310A CN103445972B CN 103445972 B CN103445972 B CN 103445972B CN 201310376310 A CN201310376310 A CN 201310376310A CN 103445972 B CN103445972 B CN 103445972B
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Abstract
The present invention relates to a kind of mild shampoo containing sulfonated alkyl glucoside, in addition to water, contain in this mild shampoo: the primary surfactant that (A) accounts for mild shampoo weight 5.0% to 40% is that sulfonated alkyl glucoside and sulfonation gather the compositions of alkyl-glucoside; (B) amphoteric surfactant accounting for mild shampoo weight 1.0% to 10.0% is, cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine; (C) cationic polymer accounting for mild shampoo weight 0.05% to 1% is, cation guar gum; This shampoo character is gentle, does not contain silicone oil and has good spumescence.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of mild shampoo containing sulfonated alkyl glucoside.
Background technology
In shampoo formula system, the effect of primary surfactant is extremely important as in foaming characteristic, and spatter property, the aspects such as the synergistic thickening of system all will play desirable effect.In tradition shampoo formula, primary surfactant has been continued to use sulfate type anion surfactant such as Laurel alkyl sulfate (sodium salt or ammonium salt) always and has been called for short K12 or K12A, and Laurel alkyl ether sulfate (sodium salt or ammonium salt) is called for short AES or AESA.As shampoo primary surfactant, Laurel alkyl sulfate (sodium salt or ammonium salt) is called for short K12 or K12A, the collocation application technology (as foam, clean and thickening property etc.) being called for short AES or AESA with Laurel alkyl ether sulfate (sodium salt or ammonium salt) is very ripe, and cost performance is also very high.
But along with improving constantly of living standard, people are to the demand of hair washing product and require also more and more higher.People also turn to the product of the demands such as natural, green, environmental protection, gentleness from the product of traditional attractable point to the demand of product, and the product of natural demand is also more and more subject to pursuing of consumer.Therefore, be necessary that adopting technological means to start with from the primary surfactant of existing shampoo product solves problem.Although the use of the sulfate type anion surface active used in traditional shampoo product is very ripe, but from science angle analysis, there is defat strong (therefore needing to use silicone oil to increase hair conditioning) in sulfate type anion surfactant, come from oil, containing oxirane EO etc., all these runs counter to the demand of natural, green, environmental protection and gentleness.
Can clean, the hair conditioning that how effectively to solve hair good cater to again natural and gentle actual demand? this just the present invention's practical problem that will solve namely, substitute with sulfonated alkyl glucoside (a kind of come from natural gentle anion surfactant) the sulfate type anion surfactant that traditional shampoo uses completely.
This special anion surfactant is exactly bonding hydroxypropyl azochlorosulfonate acid sodium and the novel product with anion surfactant feature of the natural origin obtained on nonionic alkyl-glucoside or glycan molecule.The anion surfactant of this uniqueness provides gentleer cleaning effect can to hair and skin, and foaming abundancy, its foaming properties and clean-up performance far surpass other non-ionic surface active agent be derived by APG, are also better than traditional sulfate type anion surfactant in spumescence and mildness and cleaning force.This new nonionic surfactant is while providing clean and nursing efficacy for hair and skin, glucosides in molecule can also reduce the zest of anion or other cationic polymer greatly, and there is good conditioning effect, be therefore used to gentle hair conditioning shampoo product.
Summary of the invention
The object of this invention is to provide a kind of mild shampoo containing sulfonated alkyl glucoside.
This mild shampoo is except containing except the acceptable component of shampoo, and this shampoo also contains:
(A) account for the primary surfactant of mild shampoo weight 5.0% to 40%, this surfactant is the compositions that sulfonated alkyl glucoside and sulfonation gather alkyl-glucoside, and both ratios are weight ratio 1:2-2:1;
Wherein, sulfonated alkyl glucoside molecular structural formula following (I):
In formula I, R
1represent the alkyl that carbon number is 8 to 22, n represents the degree of polymerization, between 1-3;
Sulfonation gathers the molecular structural formula following (II) of alkyl-glucoside
In formula II, it is 8 to 22 alkyl that R represents carbon number, and n represents the degree of polymerization, is the integer between 4-6;
(B) account for the amphoteric surfactant of mild shampoo weight 1.0% to 10.0%, this amphoteric surfactant is cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine;
(C) cation guar gum of mild shampoo weight 0.05% to 1% is accounted for.
Mild shampoo of the present invention, sulfonated alkyl glucoside and sulfonation gather R and R in alkyl-glucoside
1be respectively the alkyl mild shampoo of the present invention that carbon number is 12, the wherein preferred cocamido propyl betaine of amphoteric surfactant.
Mild shampoo of the present invention, wherein said sulfonated alkyl glucoside is lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium, and it is poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium that sulfonation gathers alkyl-glucoside.
Mild shampoo of the present invention, also containing the pearlescent flake accounting for composition weight 0.05% to 3.0%.
Mild shampoo of the present invention, not containing silicone oil.
A kind of mild shampoo containing sulfonated alkyl glucoside of the present invention, its component and content are:
Compared with prior art, the present invention has the following advantages:
Mild shampoo of the present invention, primary surfactant have employed and comes from natural sulfonated alkyl glucoside (compositions of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium), and instead of the sulfate type anion surfactant that traditional shampoo uses completely.Spumescence of the present invention and spatter property superior, extremely low stimulation, not containing EO, not silicate-containing oil, biological degradability is good, is genuine mild mild shampoo.
Detailed description of the invention
To be described in detail to compositional selecting of the present invention and effect below.
Sulfonated alkyl glucoside in the present invention, sulfonation gathers the alkyl-glucoside Reactive Synthesis thing that alkyl-glucoside is hydroxypropyl sulfonic acid and different carbon chain lengths.The properties of product that gentleness like this is superior provide more range of application to formula teacher.Pass through great many of experiments, the present inventor finds, sulfonated alkyl glucoside and the sulfonation Long carbon chain gathered in alkyl-glucoside in alkyl polyglucoside is straight chain and carbon number is put up the best performance in clean and conditioning effect at hair between the alkane of 10-12, and sulfonated alkyl glucoside and sulfonation gather alkyl-glucoside two ratios according to weight ratio 1:2 to 2:1 carries out having synergy when collocation uses.
Mild shampoo of the present invention, sulfonated alkyl glucoside comprises lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium, ten alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, eight alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, cetyl glucoside hydroxypropyl azochlorosulfonate acid sodium, octadecyl glucoside hydroxypropyl azochlorosulfonate acid sodium etc.; Mild shampoo of the present invention, sulfonation gathers alkyl-glucoside and comprises poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium, poly-ten alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, poly-eight alkyl-glucoside hydroxypropyl azochlorosulfonate acid sodiums, poly-cetyl glucoside hydroxypropyl azochlorosulfonate acid sodium, poly-octadecyl glucoside hydroxypropyl azochlorosulfonate acid sodium etc.
Mild shampoo of the present invention, the preferred lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium of sulfonated alkyl glucoside, the degree of polymerization between 1-3, and further preferably 1.4.
Mild shampoo of the present invention, sulfonation gathers alkyl-glucoside preferred poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium, and the degree of polymerization is between the integer of 4-6.
The physicochemical property of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium of the present invention: active quantities (solid content): 40%, pH (10% solution) 7, color Gardner < 1, the instant height (1% active matter) of foam: 155.
The physicochemical property of poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium of the present invention: active quantities (solid content): 39.5%, pH (10% solution) 7, color Gardner < 1, the instant height (1% active matter) of foam: 150.
Wherein, sulfonated alkyl glucoside molecular structural formula following (I):
In formula I, R
1represent the alkyl that carbon number is 8 to 22, n represents the degree of polymerization, between 1-3, and more preferably 1.4.
Sulfonation gathers the molecular structural formula following (II) of alkyl-glucoside
In formula II, it is 8 to 22 alkyl that R represents carbon number, and n represents the degree of polymerization, is the integer between 4-6.
In mild shampoo of the present invention, primary surfactant instead of the compositions of aliphatic alcohol sulfate that traditional shampoo uses and fatty alcohol ether sulphate with the form that sulfonated alkyl glucoside (lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium) and sulfonation gather alkyl-glucoside (poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium) compositions.
Mild shampoo of the present invention, compositions containing the lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium that account for composition weight 5.0% to 40%, the weight ratio of described lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium is 1:2-2:1.
Described traditional shampoo primary surfactant aliphatic alcohol sulfate and fatty alcohol ether sulphate are the compositions of sulfated lauryl alcohol and lauryl alcohol sulfate.As polyoxyethylene lauryl ether ammonium sulfate is called for short AESA, its structural formula is RO (CH
2cH
2o)
nsO
3nH
4 +, R=C
12-C
18alkyl, n is 2-4, and preferably average ethoxyquin degree is n=3.The active matter content of described polyoxyethylene lauryl ether ammonium sulfate commercially available prod has 25% and 70% two kind, the polyoxyethylene lauryl ether ammonium sulfate of 25% active matter content is water white transparency thick liquid, the polyoxyethylene lauryl ether ammonium sulfate of 70% active matter content is white or faint yellow pastel, and preferred active matter content is the polyoxyethylene lauryl ether ammonium sulfate of 70%.Described polyoxyethylene lauryl ether ammonium sulfate also has the characteristic of non-ionic surface active agent, in hard water, still have good dirt-removing power.The composite use of described ammonium lauryl sulfate and lauryl alcohol polyoxy ether ammonium sulfate, can produce good cooperative effect, as: sensation, the outstanding thickening properties etc. with densification and abundant foam, gentleness.
Containing accounting for the amphoteric surfactant of composition weight 1.0% to 10% as cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine in mild shampoo of the present invention.Described cocoyl both sexes sodium acetate is colourless to micro-yellow transparent thick liquid, and the active matter content of its commercially available prod is under 30%, 25 DEG C of conditions, its viscosity is 5000-10000, sodium chloride content is less than 9.0%, and the pH of 1% aqueous solution is 6.0-8.0, and its structural formula is RN (CH2COONa)
2, the zest of described cocoyl both sexes sodium acetate is low, gentle especially to skin, eyes, match can significantly reduce its zest with anion surfactant, and have good foaming power, foaming abundancy is fine and closely woven, skinfeel is good, significantly can improve the foam state of formula system.Described cocamido propyl betaine is micro-yellow transparent liquid, and the active matter content of its commercially available prod is 30%, and sodium chloride content is less than 6.0%, and free amine content is less than 0.10%, and the pH value of its 1% aqueous solution is 5.0-7.0, and its structural formula is RCONH (CH
2)
3n
+(CH
3)
2cH
2cOO
-.Described cocamido propyl betaine has excellent compatibility, and has excellent foaminess and significant thickening property, has good anti-water hardness tolerance, antistatic behaviour and biological degradability.The preferred cocamido propyl betaine of amphoteric surfactant of the present invention.
Containing the cationic polymer accounting for mild shampoo weight 0.05% to 1.0% in mild shampoo of the present invention, described cationic polymer is selected from: at least one in cationic cellulose polymer, cation melon xanthan polymer and cation modified alkyglycosides polymer
In the present invention, cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, difference according to degree ofacationic substitution can be divided into: high-cation substitution value JR, cationic substitution value LR and low degree ofacationic substitution LK tri-kinds of models, the cationic cellulose polymer of preferred high-cation substitution value, i.e. Polyquaternium-10, other is suitable for the copolymer etc. that cationic cellulose polymer of the present invention also has hydroxyethyl-cellulose and dialkyl dimethyl ammonium chloride; Described cation melon glue is the product will obtained after quaternized for melon glue, its key component is melon glue hydroxypropyltrimonium chloride, a series of cation melon glue product can be obtained according to the difference of substitution value, preferred substitution value is 0.1 to 0.2, for cation melon glue of the present invention under 25 DEG C of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s.
The cation melon glue accounting for composition weight 0.05% to 1.0% is preferably used in mild shampoo of the present invention.
Mild shampoo of the present invention is also containing the pearlescent flake accounting for composition weight 0.05% to 3.0%, and described pearlescent flake is ethylene glycol monostearate and Ethylene Glycol Distearate.Adding of described pearlescent flake, the pearl effect that shampoo is beautiful can be given.
Shampoo composite of the present invention can also comprise other optional components, comprises viscosity-controlling agent, chelating agen, pH adjusting agent, antiseptic, pigment and spice etc.Described viscosity-controlling agent accounts for 0.1% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, ETHANOLAMINE HYDROCHLORIDE, cellulose derivative, acrylic copolymer etc.Described chelating agen accounts for 0.01% to 0.30% of composition weight, the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferred disodiumedetate; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system 5.0 to 8.0, preferably 5.5 to 6.0; Choosing of described antiseptic, essence, pigment, meets the regulation of hygienic standards for cosmetics, selects safe raw material.
In mild shampoo of the present invention, except the above component, mend to aequum with water.
Preparation method
Mild shampoo of the present invention can by any known or other be effectively applicable to provide the technology of shampoo composite to prepare, the method preparing shampoo composite of the present invention comprises conventional preparation and hybrid technology.
Using method
Mild shampoo of the present invention uses in the mode that is clean and gentle hair of routine, mainly comprises following step:
(A) with water by hair moistening;
(B) on described hair, use the mild shampoo of the aforementioned any one claim of effective dose, the scope of described effective dose is generally 1 gram to 50 grams, preferably 2 to 20 grams;
(C) with the mild shampoo on hair described in water rinse.
These steps can repeatedly repeatedly, to reach effect of sought clean, conditioning, moisturizing and water retention.
Embodiment
Here is the non-limiting example of mild shampoo of the present invention.The providing of these embodiments is only used to the object illustrated, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration is all percentage by weight.Term used " a small amount of material " refers to those optional materials, as antiseptic, viscosity modifier, pH adjusting agent, spice, pigment etc., the selection of these a small amount of materials changes along with selected in order to prepare the physics and chemistry characteristic of special component of the present invention.
Preparation embodiment I-Ⅹ V
The suitable method preparing mild shampoo described in embodiment I-Ⅹ V is as follows: suitable quantity of water joined in retort, add cationic polymer under slow stirring to disperse, slowly be stirred and heated to 60 DEG C to 80 DEG C, then lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium is added as required respectively, Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, cocos nucifera oil both sexes sodium acetate, cocamido propyl betaine, pearlescent flake, disodiumedetate (if using these materials), these materials are made to disperse rear cooling completely.When temperature is down to about 45 DEG C, add sodium chloride, citric acid, antiseptic, pigment, essence etc. again continue to stir, guarantee to obtain uniform mixture.After adding all components, can add viscosity modifier and pH adjusting agent as required, the viscosity of adjustment product and pH are to suitable degree 5.5-6.0.Optionally finally can add a small amount of water to supply.
Embodiment I-V
Embodiment VI-Ⅹ
Both effectiveness evaluation and test:
Foam height method of testing: adopt the method for testing of Roche (Ross--Miles) foamer meter to test, test initial foam height respectively, after 1 minute, foam height and foam height after 5 minutes, then average.As can be seen from the embodiment of the present invention: in shampoo formula, the condition such as main and auxiliary surfactant and cationic polymer is approximate, what shampoo of the present invention adopted to be all greater than with conventional fat alcohol sulfate and fatty alcohol ether sulphate compositions for the foam height of primary surfactant formula with the foam height of the compositions of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and the poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium formula that is primary surfactant, the results are shown in Table 1.
Mildness method of testing: adopt erythrocyte hemolysis experiment (RedbloodcelltestRBC) method, the method is that Draize tests one of alternative method, ultimate principle is the change of the damage measuring chemicals cell membrane and the cell membrane permeability therefore caused, evaluated the degree of injury of cell membrane by the amount measuring the hemoglobin spilt from erythrocyte, this degree of injury and the zest of product have directly related property.Main eye irritation research RBC experiment being used for the chemicals such as cosmetic product and raw material in the world.Therefore the present invention passes through with the mildness of erythrocyte hemolysis determination of experimental method formula, and forms contrast, test products mildness.Concrete grammar is: the absorbance using the red cell suspension after the effect of spectrophotometry chemicals, can calculate hemolysis rate and H
50value (even if concentration value of the tested material of 50% erythrocyte generation haemolysis).H
50being worth little, just can there is obvious haemolysis in the sample namely adding small amount, and show that sample stimulus is large, mildness is poor.H
50value is large, shows that sample stimulus is little, and mildness increases.Shampoo of the present invention adopt with the H of the compositions of lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium and the poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium formula that is primary surfactant
50the H that it is primary surfactant formula that value is all greater than with conventional fat alcohol sulfate and fatty alcohol ether sulphate compositions
50value, shows the lifting of mildness, the results are shown in Table 1.
Table 1 foam height and H
50value (mildness)
Claims (7)
1., containing a mild shampoo for sulfonated alkyl glucoside, can accept except component except containing shampoo, this shampoo also contains:
(A) account for the primary surfactant of mild shampoo weight 5.0% to 40%, this surfactant is the compositions that sulfonated alkyl glucoside and sulfonation gather alkyl-glucoside, and both ratios are weight ratio 1:2-2:1;
Wherein, sulfonated alkyl glucoside molecular structural formula following (I):
In formula I, R
1represent the alkyl that carbon number is 8 to 22, n represents the degree of polymerization, between 1-3;
Sulfonation gathers the molecular structural formula following (II) of alkyl-glucoside
In formula II, it is 8 to 22 alkyl that R represents carbon number, and n represents the degree of polymerization, is the integer between 4-6.
(B) account for the amphoteric surfactant of mild shampoo weight 1.0% to 10.0%, this amphoteric surfactant is cocos nucifera oil both sexes sodium acetate or cocamido propyl betaine;
(C) cation guar gum of mild shampoo weight 0.05% to 1% is accounted for.
2. mild shampoo, wherein R and R according to claim 1
1be respectively the alkyl that carbon number is 12.
3. mild shampoo according to claim 1, in sulfonated alkyl glucoside molecular structural formula, polymerization degree n is preferably 1.4.
4. mild shampoo according to claim 1, wherein amphoteric surfactant is cocamido propyl betaine.
5. mild shampoo according to claim 1, wherein said sulfonated alkyl glucoside is lauryl glucosyl hydroxypropyl azochlorosulfonate acid sodium, and it is poly-dodecyl glucoside hydroxypropyl azochlorosulfonate acid sodium that sulfonation gathers alkyl-glucoside.
6. according to the mild shampoo of aforementioned any one claim, also containing the pearlescent flake accounting for composition weight 0.05% to 3.0%.
7. gather a mild shampoo for alkyl-glucoside containing sulfonation, its component and content are:
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| CN104274358B (en) * | 2014-09-05 | 2017-07-18 | 拉芳家化股份有限公司 | A kind of scalp maintenance type hair-washing composition and preparation method containing plants essential oil |
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| US7507399B1 (en) * | 2004-08-05 | 2009-03-24 | Surfatech Corporation | Functionalized polymeric surfactants based upon alkyl polyglycosides |
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| 大卫•安德森等."糖基表面活性剂和不含硫酸盐的香波配方".《日用化妆品科学》.2006,第29卷(第2期),第11页右栏结构式以及第12页左栏倒数第11行至右栏倒数第6行. * |
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