CN101475877B - Transparent liquid shampoo composition - Google Patents
Transparent liquid shampoo composition Download PDFInfo
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- CN101475877B CN101475877B CN2009100367471A CN200910036747A CN101475877B CN 101475877 B CN101475877 B CN 101475877B CN 2009100367471 A CN2009100367471 A CN 2009100367471A CN 200910036747 A CN200910036747 A CN 200910036747A CN 101475877 B CN101475877 B CN 101475877B
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Abstract
The invention relates to a transparent liquid shampoo composition. The shampoo comprises water and also comprises the following compositions: (A), a surfactant system which accounts for 10.0 to 45.0 weight percent of the composition; and (B), a conditioning system which accounts for 0.08 to 11.0 weight percent of the composition and comprises: (i), a cationic surfactant which accounts for 0.01 to 5.0 weight percent of the composition; (ii), silicon wax which accounts for 0.05 to 3.0 weight percent of the composition; (iii), cation polymers which account for 0.02 to 1.0 weight percent of the composition; and (iv), ammonia-end dimethyl polysiloxane which accounts for 0.0 to 2.0 weight percent of the composition.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of transparent liquid shampoo composition.
Background technology
Liquid shampoo is a popular main body in the market, according to its outward appearance difference, shampoo can be divided into aqueous milkiness shampoo and transparent liquid shampoo two classes.Aqueous milkiness shampoo comprises milkiness shampoo and pearly shampoo two classes, the characteristics of this type of shampoo are that its outward appearance is opaque shape, have opacifying propertyly, thereby the range of choice of raw material is wider, can add multiple to hair, material that scalp is useful, to satisfy the requirement of human consumer to shampoo product conditioning property.Transparent liquid shampoo has appearance transparent, foam enriches, is easy to characteristics such as cleaning, be subjected to the favor of young consumers deeply, but owing to will keep the transparency of shampoo, in the selection of raw material, be very limited, usually be principle to select the lower raw material of cloud point for use, even, phenomenons such as precipitation, layering do not occur so that product still can keep transparent clear when low temperature, therefore quite a few amendment can not join in the formula system, so that the conditioning of transparent liquid shampoo is relatively poor.The purpose of this invention is to provide a kind of transparent liquid shampoo composition with outstanding conditioning property.
Summary of the invention
The purpose of this invention is to provide a kind of transparent liquid shampoo composition, said composition has transparent outward appearance and outstanding conditioning performance.
A kind of transparent liquid shampoo composition comprises the surfactant system that (A) accounts for composition weight 10.0% to 45.0%; (B) account for the conditioning system of composition weight 0.08% to 11.0%, this system by: (i) account for the cats product of composition weight 0.01% to 5.0%; (ii) account for the silicon wax of composition weight 0.05% to 3.0%; (iii) account for the cationic polymers of composition weight 0.02% to 1.0%; The ammonia end polydimethylsiloxane that (iv) accounts for composition weight 0.0% to 2.0% is formed, and the composition surplus is a water.
Transparent liquid shampoo composition of the present invention, it is characterized in that described surfactant system comprises: account for composition weight 8.0% to 20.0% ethoxylated dodecyl alcohol sodium sulfate, account for the cocoyl both sexes sodium-acetate of composition weight 2.0% to 15.0% and account for the laurylamide hydroxy sulfo lycine of composition weight 0.0% to 10.0%.
Transparent liquid shampoo composition of the present invention is characterized in that, described cats product is ricinoleic acid amide oxypropyl trimethyl ammonium chloride or palmitic amide oxypropyl trimethyl ammonium chloride.
Transparent liquid shampoo composition of the present invention is characterized in that, described cats product is a ricinoleic acid amide oxypropyl trimethyl ammonium chloride.
Transparent liquid shampoo composition of the present invention is characterized in that, described silicon wax is two-PEG-18 methyl ether dimethylsilane or two-PEG-15 methyl ether polydimethylsiloxane.
Transparent liquid shampoo composition of the present invention is characterized in that, described cationic polymers is the composition of guar gum hydroxypropyl-trimethyl ammonium chloride and polyquaternium-10.
Transparent liquid shampoo composition of the present invention is characterized in that, the ratio of the composition of described guar gum hydroxypropyl-trimethyl ammonium chloride and polyquaternium-10 is 1: 3 to 2: 1.
Transparent liquid shampoo composition of the present invention is characterized in that, described ammonia end polydimethylsiloxane satisfies structural formula (I):
R in the formula (I)
1, R
2Independently be selected from C separately
1-C
22Alkyl or OH; R
3, R
4Independently be selected from C separately
1-C
22Alkyl; M is the integer of 1-500; N, r are the integer a of 0-200, the integer that b is 0-30.
A kind of transparent liquid shampoo composition specifically comprises:
| Component | Content (weight %) |
| Ethoxylated dodecyl alcohol sodium sulfate (70%) | 15 |
| Cocoyl both sexes sodium-acetate | 8.0 |
| The laurylamide hydroxy sulfo lycine | 5.0 |
| The guar gum hydroxypropyl-trimethyl ammonium chloride | 0.1 |
| Polyquaternium-10 | 0.25 |
| Ricinoleic acid amide oxypropyl trimethyl ammonium chloride | 2.0 |
| Two-PEG-18 methyl ether dimethylsilane | 1.0 |
| Ammonia end polydimethylsiloxane | 0.5 |
| Coconut oleoyl amine DEA | 1.0 |
| Disodium ethylene diamine tetraacetate | 0.2 |
| Sanitas, citric acid, sodium-chlor, essence, pigment | In right amount |
| Water | Surplus |
To be elaborated to component selection of the present invention and effect below.
A. surfactant system
Transparent liquid shampoo composition of the present invention comprises the surfactant system that accounts for composition weight 10.0% to 45.0%, and described surfactant system comprises: account for composition weight 8.0% to 20.0% ethoxylated dodecyl alcohol sodium sulfate, account for the cocoyl both sexes sodium-acetate of composition weight 2.0% to 15.0% and account for the laurylamide hydroxy sulfo lycine of composition weight 0.0% to 10.0%.Described ethoxylated dodecyl alcohol sodium sulfate is called for short AES, the commercially available prod active matter content has 25% and 70% two kind, the ethoxylated dodecyl alcohol sodium sulfate of 25% active matter content is the water white transparency thick liquid, the ethoxylated dodecyl alcohol sodium sulfate of 70% active matter content is white or faint yellow mashed prod, and its structural formula is C
12O (CH
2CH
2O)
nSO
3Na, n are 2～4, and preferred average ethoxyquin degree is n=3, and molecular-weight average is 404.23, and described ethoxylated dodecyl alcohol sodium sulfate also has the characteristic of nonionogenic tenside, still has soil removability preferably in hard water.Described cocoyl both sexes sodium-acetate is colourless to little yellow transparent thick liquid, and the active matter content of its commercially available prod is under 30%, 25 ℃ of condition, its viscosity is 5000～10000, sodium chloride content is 6.0～8.0 less than the pH of 9.0%, 1% aqueous solution, and its structural formula is RN (CH2COONa)
2, the pungency of described cocoyl both sexes sodium-acetate is low, and is gentle especially to skin, eyes, match with anion surfactant and can significantly reduce its pungency, and have good foaming power, foam enriches fine and closely woven, the skin sense is good, can significantly improve the foam state of formula system.Described laurylamide hydroxy sulfo lycine is colourless to little yellow transparent liquid, the commercially available prod active matter content is 30%, and unhindered amina content is less than 0.5%, and sodium chloride content is less than 5.5%, 1% pH value of aqueous solution is 6.0～7.0, and the structural formula of laurylamide hydroxy sulfo lycine is RCONH (CH
2)
3N
+(CH
3)
2CH
2CH (OH) CH
2SO
3 -, described laurylamide hydroxy sulfo lycine has good solvability, compatibleness, foaminess, the anti-hard water of thickening property, static resistance and biological degradability, also has low irritant and bactericidal properties, is used for the present invention and also has certain opsonization.
B. amendment
Comprise the conditioning system that accounts for composition weight 0.08% to 11.0% in the transparent liquid shampoo composition of the present invention, comprising: the cats product that (i) accounts for composition weight 0.01% to 5.0%; (ii) account for the silicon wax of composition weight 0.05% to 3.0%; (iii) account for the cationic polymers of composition weight 0.02% to 1.0%; (iv) account for the ammonia end polydimethylsiloxane of composition weight 0.0% to 2.0%.
Transparent liquid shampoo composition of the present invention, wherein said cats product are ricinoleic acid amide oxypropyl trimethyl ammonium chloride or palmitic amide oxypropyl trimethyl ammonium chloride, preferred ricinoleic acid amide oxypropyl trimethyl ammonium chloride.Described ricinoleic acid amide oxypropyl trimethyl ammonium chloride is the little yellow thick liquid of clarification, soluble in water, its 10% pH value of aqueous solution is 5～8, described ricinoleic acid amide oxypropyl trimethyl ammonium chloride is to be raw material and N with the ricinoleic acid, diamines is a raw material in the N-dimethyl, after making palmitic amide propyl group tertiary amine by amidate action, make through quaterisation again.Described palmitic amide oxypropyl trimethyl ammonium chloride has another name called palmitic amide oxypropyl trimethyl ammonium chloride, its exterior of commodity is a white solid, and solid content is greater than 70%, and its 50% aqueous solution is the water white transparency shape, 10% pH value of aqueous solution is 5～9, is suitable for transparent shampoo.Described palmitic amide oxypropyl trimethyl ammonium chloride is with Palmiticacid and N, and diamines is a raw material in the N-dimethyl, make palmitic amide propyl group tertiary amine by amidate action after, carry out quaterisation with chloromethane again and make.Contain the monoamide key in the hydrophobicity long-chain in described ricinoleic acid amide oxypropyl trimethyl ammonium chloride or the palmitic amide oxypropyl trimethyl ammonium chloride molecular structure, compare with traditional quaternary ammonium salt cationic surfactant, improved the compound property of itself and anion surfactant, simultaneously environmentally friendly, easily degraded, on the other hand because the existence of wetting ability amido linkage, improve its hydrophilicity, be difficult for gathering, overcome the shortcoming that palmityl trimethyl ammonium chloride, octadecyl trimethyl ammonium chloride can not be used for transparent shampoo.
Transparent liquid shampoo composition of the present invention, wherein said silicon wax are two-PEG-18 methyl ether dimethylsilane or two-PEG-15 methyl ether polydimethylsiloxanes.Described pair-PEG-18 methyl ether dimethylsilane is a kind of water miscible organosilicon ethylene glycol interpolymer wax, commercial goods white is to little yellow wax shape product, be used for the shampoo system, can increase the foam exquisiteness, improve the wet comb of shampoo and do comb property, typical case's representative of described pair-PEG-18 methyl ether dimethylsilane is the DC 2501 of Dow Corning Corporation.Described two-PEG-15 methyl ether polydimethylsiloxane be a kind of in water dispersive dimethicone polyol, satisfy the structure formula II, x is 1～500 integer in the formula.
Commercially available pair-PEG-15 methyl ether polydimethylsiloxane is the White-opalescent solid, other components in described pair-PEG-15 methyl ether polydimethylsiloxane and the shampoo system have good compatibility, can improve the wet comb of shampoo and do comb property, also have the effect of preserving moisture simultaneously.Typical case's representative of described pair-PEG-15 methyl ether polydimethylsiloxane is the DMC 6038 of Wa Ke company.Other is applicable to that silicon wax of the present invention also has the DC 5330 of Dow Corning Corporation.
Transparent liquid shampoo composition of the present invention, wherein said cationic polymers is the composition of guar gum hydroxypropyl-trimethyl ammonium chloride and polyquaternium-10, and the ratio of the composition of described guar gum hydroxypropyl-trimethyl ammonium chloride and polyquaternium-10 is 1: 3 to 2: 1.Described guar gum hydroxypropyl-trimethyl ammonium chloride is the product that melon glue is obtained after quaternized, difference according to substitution value can obtain a series of positively charged ion melon glue product, preferred substitution value is 0.1 to 0.2, be used for positively charged ion melon glue of the present invention under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s.Described polyquaternium-the 10th, the multipolymer of Natvosol and alkyl trimethyl ammonium chloride, difference according to the positively charged ion substitution value can be divided into: high-cation substitution value JR, middle-jiao yang, function of the spleen and stomach ionic replacement degree LR and three kinds of models of low positively charged ion substitution value LK, the cationic cellulose polymer of preferred high-cation substitution value.
Transparent liquid shampoo composition of the present invention, wherein said ammonia end polydimethylsiloxane satisfies structural formula (I).
R in the formula (I)
1, R
2Independently be selected from C separately
1-C
22Alkyl or OH; R
3, R
4Independently be selected from C separately
1-C
22Alkyl; M is the integer of 1-500; N, r are the integers of 0-200; A, b are the integers of 0-30.The adding of described ammonia end polydimethylsiloxane can improve the wet cardability of doing of hair, increases the body sense of hair.The commodity that are applicable to ammonia end polydimethylsiloxane of the present invention have: the DC 2-1391 microemulsion of Dow Corning Corporation, DC 2-8168 microemulsion, DC 5-7113 microemulsion and DC 8194 microemulsions etc.
Transparent liquid shampoo composition of the present invention also comprises and accounts for composition weight 0.2% to 5.0%, preferred 0.5% to 2.5% suds-stabilizing agent, described suds-stabilizing agent is meant the tensio-active agent with prolongation and stable foam, mainly is selected from alkylol amide, the preferred fatty acid single ethanol amide.
Transparent liquid shampoo composition of the present invention can also comprise other optional components, comprises sequestrant, pH regulator agent, sanitas, pigment and spices etc.The non-limiting example of described sequestrant has: ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, xitix etc., preferred disodium ethylene diamine tetraacetate; The non-limiting example of described pH regulator agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system are 5.0 to 8.0, and preferred 5.5 to 6.5; Choosing of described sanitas, essence, pigment meets the regulation of hygienic standards for cosmetics, selects safe raw material for use.
In the transparent liquid shampoo composition of the present invention, except the above component, water is mended to aequum.
Compared with prior art, the present invention has the following advantages: adopt cats product ricinoleic acid amide oxypropyl trimethyl ammonium chloride, silicon wax, cationic polymers and ammonia end polydimethylsiloxane as amendment, solved the drawback of normal transparent shampoo conditioning property difference.
The preparation method
Transparent liquid shampoo composition of the present invention can by any known or other effectively be applicable to the technology preparation that shampoo composite is provided, the method for preparing transparent liquid shampoo composition of the present invention comprises conventional preparation and hybrid technology.
Using method
Transparent liquid shampoo composition of the present invention uses with the cleaning of routine and the mode of conditioning hair, mainly comprises following step:
(A) water is wetting with hair;
(B) use the shampoo composite of aforementioned each claim of significant quantity on described hair, the scope of described effective dose is generally 1 gram to 50 grams, preferred 2 to 20 grams;
(C) with the shampoo composite on the described hair of water rinse.
These steps can repeat repeatedly as required, to reach the cleaning of looking for, the effect of conditioning.
Embodiment
Be the non-limiting example of transparent liquid shampoo composition of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration all is weight percent.Used term " small amount of matter " refers to those optional materials, as sanitas, viscosity modifier, pH regulator agent, spices, pigment etc., the selection of these small amount of matter will change in order to the physics for preparing special component of the present invention and chemical property along with selected.
Preparation embodiment I-X
The suitable method for preparing transparent liquid shampoo composition described in embodiment I-X is as follows: suitable quantity of water is joined in the retort, adding melon glue and polyquaternium-10 disperse under slowly stirring, slowly be stirred and heated to 60 ℃ to 80 ℃, then add pH regulator agent (for example citric acid), ethoxylated dodecyl alcohol sodium sulfate, cocoyl both sexes sodium-acetate, laurylamide hydroxy sulfo lycine, coconut oleoyl amine DEA, disodium ethylene diamine tetraacetate (if using these materials), make these materials disperse the back cooling fully.Wait to be cooled to and add ricinoleic acid amide oxypropyl trimethyl ammonium chloride, silicon wax and ammonia end polydimethylsiloxane below 50 ℃, add sanitas, pigment, essence etc. again and continue to stir, guarantee to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, the viscosity and the pH that regulate product arrive suitable degree.Randomly can add less water at last supplies.
Embodiment I-V
Embodiment VI-X
Claims (3)
1. transparent liquid shampoo composition comprises:
(A) account for the surfactant system of composition weight 10.0% to 45.0%, described surfactant system comprises: account for composition weight 8.0% to 20.0% ethoxylated dodecyl alcohol sodium sulfate, account for the cocoyl both sexes sodium-acetate of composition weight 2.0% to 15.0% and account for the laurylamide hydroxy sulfo lycine of composition weight 0.0% to 10.0%;
(B) account for the conditioning system of composition weight 0.08% to 11.0%,
Wherein said conditioning system is composed of the following components:
(i) account for the ricinoleic acid amide oxypropyl trimethyl ammonium chloride or the palmitic amide oxypropyl trimethyl ammonium chloride of composition weight 0.01% to 5.0%;
(ii) account for the two-PEG-18 methyl ether dimethylsilane or the two-PEG-15 methyl ether polydimethylsiloxane of composition weight 0.05% to 3.0%;
(iii) account for the guar gum hydroxypropyl-trimethyl ammonium chloride of composition weight 0.02% to 1.0% and the composition of polyquaternium-10;
(iv) account for the ammonia end polydimethylsiloxane of composition weight 0.0% to 2.0%, described ammonia end polydimethylsiloxane satisfies structural formula (I);
R in the formula (I)
1, R
2Independently be selected from C separately
1-C
22Alkyl or OH; R
3, R
4Independently be selected from C separately
1-C
22Alkyl; M is the integer of 1-500; N is the integer of 0-200; R is greater than 0, and less than 200 integer; A, b are the integers of 0-30;
(C) surplus is a water.
2. transparent liquid shampoo composition according to claim 1 is characterized in that, the ratio of the composition of described guar gum hydroxypropyl-trimethyl ammonium chloride and polyquaternium-10 is 1: 3 to 2: 1.
3. transparent liquid shampoo composition, the per-cent of each ingredients constitute composition weight is: active matter content is 70% ethoxylated dodecyl alcohol sodium sulfate 15%, cocoyl both sexes sodium-acetate 8.0%, laurylamide hydroxy sulfo lycine 5.0%, guar gum hydroxypropyl-trimethyl ammonium chloride 0.1%, polyquaternium-10 0.25%, ricinoleic acid amide oxypropyl trimethyl ammonium chloride 2.0%, two-PEG-18 methyl ether dimethylsilane 1.0%, ammonia end polydimethylsiloxane 0.5%, coconut oleoyl amine DEA1.0%, disodium ethylene diamine tetraacetate 0.2%, sanitas, citric acid, sodium-chlor, essence, pigment is an amount of, and water adds to 100%; Wherein said ammonia end polydimethylsiloxane satisfies structural formula (I);
R in the formula (I)
1, R
2Independently be selected from C separately
1-C
22Alkyl or OH; R
3, R
4Independently be selected from C separately
1-C
22Alkyl; M is the integer of 1-500; N is the integer of 0-200; R is greater than 0, and less than 200 integer; A, b are the integers of 0-30.
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| CN2009100367471A CN101475877B (en) | 2009-01-19 | 2009-01-19 | Transparent liquid shampoo composition |
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|---|---|---|---|
| CN2009100367471A CN101475877B (en) | 2009-01-19 | 2009-01-19 | Transparent liquid shampoo composition |
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|---|---|
| CN101475877A CN101475877A (en) | 2009-07-08 |
| CN101475877B true CN101475877B (en) | 2011-06-29 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103520021B (en) * | 2013-08-02 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of cation is modified the conditioner shampoo of alkyglycosides |
| CN103445984B (en) * | 2013-08-26 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer |
| CN103655335B (en) * | 2013-12-11 | 2016-03-02 | 彭再辉 | A kind of hair washing for child is taken a shower two-in-one compositions |
| KR102429835B1 (en) * | 2015-09-23 | 2022-08-05 | (주)아모레퍼시픽 | Hair composition |
| CN107625658A (en) * | 2017-09-29 | 2018-01-26 | 澳宝化妆品（惠州）有限公司 | One kind washes Haircare composition and preparation method thereof |
| CN113545343B (en) * | 2021-07-02 | 2022-09-20 | 中化化工科学技术研究总院有限公司 | Spraying auxiliary agent for removing agricultural pest secretion and preparation and use methods thereof |
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Owner name: LAFANG CHEMICAL CO., LTD. Free format text: FORMER NAME: GUANGDONG LAFANG DAILY CHEMICALS CO., LTD. |
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Address after: 515144 LaFang industrial town, Xin Qing Road, 324 National Highway, Chaonan District, Guangdong, Shantou Patentee after: LAF International Group Limited Address before: 515063 LaFang industrial town, Xin Qing Road, 324 National Highway, Chaonan District, Guangdong, Shantou Patentee before: Guangdong Lafang Daily Chemicals Co., Ltd. |