TW201249473A - Hair shampoo composition in condensed liquid state - Google Patents

Abstract

This invention provides a hair shampoo composition in a condensed liquid state which will not produce precipitates of a cationized polymer, and a method for producing such composition. The hair shampoo composition in a condensed liquid state of this invention contains: (A) a 0.1 to 5mass% cationic polymer having a construction represented by the following formula (1) wherein R represents a primary-tertialy amino group, a quarternary ammonium group, or an alkyl group having a number of carbon atoms of 1 to 3 which may have a hydroxyl group, X- represents a mono-valent anion in such a number that renders the above construction in an electrically neutral state; and, (B) 40 to 60mass% anionic surfactant, and (D) 45mass% or less of water.

Description

201249473 VI. Description of Invention: [Connected Application] This application is the priority of Japanese Patent Application No. 2011-057955, filed on March 16, 2011, and is included in this case. [Technical Field of the Invention] The present invention relates to a concentrated liquid hair cleansing composition, in particular, a concentrated liquid hair cleansing composition which does not form a precipitate due to a cationic polymer, and a method for producing the same. [Prior Art] In the hair cleansing composition using an ionic surfactant, in addition to the liquid form, there is a solid shape such as a solid soap or a synthetic detergent bar (Sin Det Bar, Synthetic Detergent Bar), or For example, a creamy composition of a foaming agent is present. The solid shape or creamy hair cleansing agent composition is an anionic surfactant having a hydrophilic group as a carboxylic acid as a main component, but is used in hair or skin, or foaming property in hard water. The cleaning power is not good. Further, it is known that a hydrophilic resin-containing portion is not a solid-shaped or creamy hair-cleaning agent composition containing an anionic surfactant of a carboxylic acid as a main component, but the feeling of use or ease of use is not good. Therefore, from the viewpoint of ease of use, the formulation of the hair cleanser composition is more like a liquid carrier. This liquid hair cleanser composition is then typically formulated to 20% ionic surfactant at a water content of 60 to 80 °/. Composition. On the other hand, in recent years, the production and flow rate of hair cleanser compositions have an overwhelming ratio in the field of cosmetics, and the energy required for their logistics due to the weight and volume of water (60 to 80%). Too high to become a problem with 323872 4 201249473. For the method of the above-mentioned problem, for example, the transportation technology, the improvement of the means (logical efficiency, mode conversion, improvement of the product packaging technology, etc.) and the weight reduction of the container (container weight) The special efforts of the reduction, the re-filling product. For other means of reducing energy, it is conceivable to reduce the amount of water contained in the liquid hair cleaning composition to form a concentrated type. However, when the liquid hair cleansing composition of the conventional composition is simply concentrated, there is a problem that the cationic polymer is one of the components for precipitation in the detergent composition. In addition to the viscosity-increasing property and the stability, the cationic polymer is formulated in a hair care product containing a hair cleanser composition such as shampoo for the purpose of imparting a conditioning effect. In the case of a cleaning agent composition containing an anionic surfactant such as shampoo as a main component, the cleaning agent composition is used for hair, and the cationic polymer has a hair conditioning effect such as anionic and lubricity during rinsing.

Precipitation of the complex. Therefore, the ionic surfactant forms a composite which precipitates on the surface of the hair to form a thin film. It is known that the Piranf f is kept on the hair in a state in which the detergent composition is washed and dried, and also brings about softness. The above two are not present, usually, the β-face anionic surfactant concentration. In the liquid hair cleaning agent composition, 323872 5 201249473, in order to avoid precipitation of the composite, the anionic surfactant is required to be in the middle concentration range. Adjusting it to migrate to a low concentration area during cleaning will precipitate the complex. [Problem to be Solved by the Invention] Here, when the general liquid hair cleansing composition containing a general cationic polymer as described above is concentrated, the concentration of the anionic surfactant is remarkably increased. . That is, by concentration, the concentration of the anionic surfactant becomes a high concentration region, and in the state of the product, a complex with the cationic polymer is precipitated to cause a precipitate. Among the cationic polymers used in the past, cationized cellulose, cationized locust bean gum, cationized guar gum, and semi-synthetic products made of natural polysaccharides are known. a cationized starch or the like, a homopolymer of a diallyl quaternary ammonium salt of a synthetic product, a diallyl quaternary ammonium salt, a acrylamide copolymer, a quaternized polyvinylpyrrolidone derivative, and a polyethylene Glycol polyamine condensate, ethylene pyridinium ruthenium vinylpyrrolidone copolymer, hydroxyethyl cellulose, dimercapto dialkalium chloride copolymer, vinyl pyrrolidone, quaternary fluorenyl group Dimethylaminoethyl acrylate copolymer, polyvinylpyrrolidone-alkylamine copolymer, polyvinylpyrrolidone, alkyl acrylate, ethylene caprolactam copolymer, vinyl pyrrolidone, mercapto propylene Amidoxime gasification triammonium ammonium copolymer, alkyl acrylamide acrylate acrylate alkyl alkyl decylamine poly methacrylate copolymer, adipic acid dimethylamine Hydroxypropyl-extended ethylenetriamine copolymer, etc., but any one is due to The precipitated above problem is not suitable 3,238,726,201,249,473 concentrated hair cleansing agent in the liquid. The present invention has been made in view of the above problems, and an object thereof is to provide a concentrated liquid hair cleansing composition which does not form a precipitated product by a cationized polymer, and a method for producing the same. [Means for Solving the Problem] As a result of careful review of the above problems, the present inventors have found that a concentrated liquid hair detergent composition can be obtained by using a cationic polymer having a specific structure, and the composition does not precipitate a cation. The present invention has been completed by combining a polymer with an anionic surfactant. In other words, the concentrated liquid hair cleansing composition of the present invention contains (A) 0.1 to 5% by mass of a cationic polymer having a structure represented by the following general formula (1), and (B) 40 to 60% by mass of an anionic surfactant, (D) 45% by mass or less of water,

A C—N—(CH 2 ) 3 —N + —R (1) CH 3 Ο Η (In the above formula (1), R represents a carbon number 1 which may have a 1 to 3 amine group, a 4th ammonium group, and a hydroxyl group. The alkyl group of 3, X_ represents a monovalent anion having the above structure as the number of electroneutrality). Further, another aspect of the concentrated liquid hair cleansing composition of the present invention is characterized in that: (A) 0.1 to 5% by mass of a cationic polymer having the structure represented by the above general formula 323872 7 201249473 (1) (B) an anionic surfactant, (C) an amphoteric surfactant, and (D) 45 mass% or less of water, wherein the total amount of (B) and (C) is 40 to 60 mass%/〇. Further, in the above-mentioned concentrated liquid hair cleansing agent composition, '(A) cationic polymer is composed of: fluorenylphosphonium acrylamidopropyltrimethylammonium chloride polymer; acrylamide hydrazide Aminopropyltrimonium ammonium copolymer; Acrylic acid/Acrylic acid acrylate • Gasified mercapto acrylamide propylamine decyl ammonium copolymer; propyl chloride trimethylammonium acrylamide • Dimercapto acrylamide Any one selected from the group consisting of polyquaternium-74 (acrylic acid/vaporized mercaptopropenyl propyl decyl ammonium hydroxypropyl tridecyl ammonium copolymer) is suitable. Further, the concentrated liquid hair styling agent composition further contains: (E) 5 to 25% by mass of a monovalent or divalent alcohol, (F) 5 to 20 mass% / 〇 of IOB 0.8 to 1. A nonionic surfactant having a molecular weight of 500 or less, wherein the ratio (E): (F) is 3.5:1 to 1:2.5, and the composition is diluted to (B) The viscosity at a concentration of 15% by mass or (C) is preferably 300 mPa·s or more at 30 °C. Further, in the concentrated liquid hair cleansing composition, the (F) nonionic surfactant is a long-chain fatty acid N-mercaptoethanolamine having an average carbon number of 10 to 14 and/or an average carbon number of 10 to A long chain fatty acid diethylene glycol of 14 is suitable. Further, in the concentrated liquid hair cleansing composition, the (B) anionic surfactant is preferably a polyoxyethylene alkyl ether sulfate type interfacial surfactant. Further, in the concentrated liquid hair cleansing composition, a salt of 323872 8 201249473 which is organic or inorganic is suitable. Further, the method of using the concentrated liquid hair cleansing composition described above is characterized in that it is mixed with water. Moreover, the method for producing a concentrated liquid hair cleansing composition is characterized in that: (B) an aqueous solution of an anionic surfactant and (4) a cationic polymer are mixed, and (C) an amphoteric surfactant The step of mixing the aqueous solution. Further, in the method for producing a liquid hair cleansing composition of the present invention, the concentrated liquid hair cleansing composition is mixed with water. [Effects of the Invention] In the present invention, a concentrated liquid hair cleansing agent composition containing a cationic polymer can be produced without producing a precipitate. As a result, a concentrated liquid hair cleansing composition having a sufficiently good hair care effect and the like which cannot be obtained from a cationic polymer can be obtained. The present invention can be expected to contribute to the improvement of the global environment by providing a high-quality concentrated disk product, which can reduce the energy during manufacturing and transportation, and the energy required for use in container and exterior use, and disposal. [Embodiment] [Mode for Carrying Out the Invention] In the present application, the "concentrated" liquid detergent is (B) an anionic surfactant which has a smaller amount of water than a general liquid detergent and a cleaning component. 'Or (B) an anionic surfactant and a bismuth amphoteric surfactant are relatively highly concentrated, that is, a concentrate of a general liquid detergent. The concentrated liquid hair cleansing composition of the present invention is based on the above-mentioned concentrated 323872 9 201249473 liquid detergent, wherein the tunable polymer rail is formed. Cation First, the aforementioned essential components of the present invention are respectively described. (Α) Cationic Polymer The cationized polymer to be formulated in the present invention has a structure represented by the following general formula (Α).

In the above formula (1), R represents an alkyl group having 1 to 3 carbon atoms, a quaternary ammonium group, and a hydroxyl group. Further, χ- indicates that the above structure is an electrically neutral number of monovalent anions. In the above, the amine group of the first order represents - with the 2, 2 amino group representing -NHR1, the 3rd amino group represents -NHR2R3, the 4th ammonium group represents -N+R4R5R6, and R1 to R6 each represent a carbon number of 1 to An alkyl group of 3, that is, any one of a mercapto group, an ethyl group, and a propyl group. Therefore, the "alkyl group having 1 to 3 amino groups, a 4- to ammonium group, or a hydroxyl group having 1 to 3 carbon atoms" may, for example, be an alkyl group, an ethyl group, a propyl group, a hydroxy group or a hydroxy group. Hydroxypropyl, hydroxypropyltrimethylammonium (-CH2CH(0H)CH2N+(CH3)3), hydroxypropyldiguanylamino (-CH2CH(0H)CH2N(CH3)2), hydroxypropyl Mono-monodecylamine 323872 10 201249473 (-CH2CH(0H)CH2NHCH3), hydroxypropylamino (-CH2CH(0H)CH2NH2), hydroxypropyltriethylammonium (-CH2CH(0H)CH2N+(CH2CH3) 3) Hydroxypropyl diethylamino (-CH2CH(0H)CH2N(CH2CH3)2), hydroxypropylmonoethylamine (-CH2CH(OH)CH2NHCH2CH3), hydroxypropyltripropylammonium ( -CH2CH(0H)CH2N+(CH2CH2CH3)3), hydroxypropyldipropylamino (-CH2CH(0H)CH2N(CH2CH2CH3)2), hydroxypropyl monopropylamino (-CH2CH(OH)CH2NHCH2CH2CH3), Trimethylpropylammonium (-CH2CH2CH2N+(CH3)3), dimethylpropylamino (-CH2CH2CH2N(CH3)2), mercaptopropylamino (-CH2CH2CH2NH CH3), propylamino (- CH2CH2CH2NH2), hydroxyethyltrimethylammonium (-CH(0H)CH2N+(CH3)3), hydroxyethyldimethylamino (-CH(0H)CH2N(CH3)2), hydroxyethyl monomethyl Amino group (-CH (OH)CH2NHCH3), hydroxyethylamino (-CH(0H)CH2NH2), hydroxyethyltriethylammonium (-CH(0H)CH2N+(CH2CH3)3), hydroxyethyldiethylamine ( -CH(0H)CH2N(CH2CH3)2), hydroxyethyl monoethylamino (-CH(OH)CH2NHCH2CH3), hydroxyethyltripropylammonium (-CH(OH)CH2N+(CH2CH2CH3)3), Hydroxyethyldipropylamino (-CH(0H)CH2N(CH2CH2CH3)2), hydroxyethyl monopropylamino (-CH(OH)CH2NHCH2CH2CH3), tridecylethylammonium (-CH2CH2N+(CH3) 3), Dimercaptoethylamino (-CH2CH2N (CH3)2), monodecylethylamino (-CH2CH2NHCH3), ethylamino (-CH2CH2NH2), hydroxydecyltridecyl ammonium ( -CH(0H)N+(CH3)3), hydroxydecyldidecylamino (-CH(0H)N(CH3)2), hydroxydecylmonodecylamino (-ch(oh)nhch3), Hydroxymethylamino (-CH(0H)NH2), hydroxymethyltriethylammonium (-CH(0H)N+(CH2CH3)3), hydroxymethyldiethylamine (-CH(0H)N (CH2CH3)2), hydroxydecyl monoethylamine 323872 11 201249473 base (-CH(0H)NHCH2CH3), hydroxydecyltripropylammonium (-CH(0H)N+(CH2CH2CH3)3), hydroxydecyl Dipropylamino (-CH(0H)N(CH2CH2CH3)2), hydroxydecyl monopropylamine (-CH(0H)NHCH2CH2CH3), Mercaptoalkyl ammonium group (-CH2N+(CH3)3), dimercaptoalkylamino group (-CH2N(CH3)2), monodecylmethylamino group (-CH2NHCH3), mercaptoamine group (-CH2NH2) ). In the present invention, R is particularly preferably a fluorenyl group or a hydroxypropyltrimonylammonium group. The monovalent anion suitable for hydrazine may, for example, be a halogen atom such as chlorine, bromine or iodine, an ion such as decyl sulfate or ethyl sulfate. Further, the number of the anions described above is a number corresponding to the cation in the formula (1), and is set so as to be electrically neutral. In the above formula (1), for example, a constituent monomer such as decyl acrylamidopropyltrimethylammonium chloride (MAPTAC) or acrylamidopropyltrimethylammonium (AAPTAC) may be polymerized separately. Alternatively, it may be introduced into a side chain as a polymer by copolymerization with a general ethylene-based or propylene-based monomer. In the case of the copolymer, the constituent monomer having the structure represented by the formula (1) may contain 1% or more in a molar ratio, and desirably contains 10% or more. The cationic polymer having the structure represented by the above formula (1) may, for example, be a gasified mercaptopropenylpropyltrimethylammonium chloride polymer; acrylamide-vaporized mercaptopropenylpropylamine Tridecyl ammonium copolymer; acrylic acid · decyl acrylate · gasified mercapto acrylamide propyl propyl trimethyl ammonium copolymer; gasified propyl triammonium acrylamide phthalamide • dimercapto acrylamide copolymer; Quaternary ammonium salt-74 (acrylic acid; decyl acrylonitrile decyl propyl decyl ammonium hydroxypropyl 323872 12 201249473 trimethyl hydroxy copolymer) may be used singly or in combination. - _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ -74, manufactured by Rhodia Co., Ltd.). (B) Anionic surfactant The anionic surfactant to be used in the present invention can be an anionic surfactant which is generally used in cosmetics, pharmaceuticals and the like. The anionic surfactant which is suitable for the present invention is, for example, a polyoxyethylene alkyl ether sulfate represented by the following general formula (I). .R-0-(CH2CH20)n-S03X (I) In the above general formula (I), R represents a linear or branched alkyl group, and its carbon number is desirably from 10 to 16, more preferably from 12 to 14. . Further, η represents an integer of i to 3. In the case of X, the nitrogen atom is exemplified by an alkali metal, a soil-reporting ammonium, a lower alkanolamine cation, a lower alkylamine cation, and an amine cation. As the polyoxyethylene alkyl ether sulfate described above, for example, cerium (1 to 3) alkyl ether sulfate ' Ρ〇Ε (1 to 3) alkyl ether sulfate triethanolamine ' Ρ〇Ε (1 to 3) ammonium lauryl ether sulfate 'POE (1 to 3) sodium lauryl citrate or the like. Further, another anionic surfactant suitable for the present invention is an alkyl sulfate represented by the following general formula (II). 323872 13 201249473 R-0-S03X (H) In the above general formula (π), R represents a linear or branched alkyl group, and its carbon number is desirably 10 to -6, more preferably 2 to 14. For X, in addition to the argon atom, the metal can be examined, the soil eyebrow, the low-order amine cation, the lower-grade amine cation, and the amino acid cation. The alkyl sulfate as described above may be, for example, ammonium lauryl sulfate, potassium myristyl sulfate, sodium lauryl sulfate, decyl oleyl triethanolamine or the like. Further, a further anionic surfactant which is suitable for the present invention is exemplified by the following general formula (III). R-6'ch2ch2-so3x2 (hi) In the above general formula (III), R represents a linear or branched alkyl group, and the carbon number is desirably 10 to 16, more preferably 12 to 14. X! represents a hydrogen atom or a thiol group. Further, in addition to the hydrogen atom, X2 may, for example, be an alkali metal, an alkaline earth metal, an ammonium, a lower alkanolamine cation, a lower alkylamine cation or a basic amino acid cation. Examples of the N-mercapto taurate as described above include N-laurylmethyl sodium sulphate, N-myristyl sulfonium taurate, and N-stearylmethyl methyl. Nitrogen sodium, N ~ coconut oil fatty acid sodium sulfosyl taurate and the like. Further, the other anionic surfactant which is suitable for the present invention is exemplified by the following N-decylamino acid salts represented by the general formulae (IV) and (V). 323872 201249473 OCH3 rcn-ch2ch2-coox m) OCH3 RCN-CH2-C00X (V) In the above general formulas (iv) and (v), R represents a linear or branched alkyl group, and its carbon number is preferably 10 to 16 More ideally 12 to η. In the case of X, in addition to the hydrogen atom, the metal 'soil test metal' can be examined, the lower serotonin cation, the lower alkylamine cation, and the basic amino acid cation. As the above-mentioned N-decylamino acid salt, for example, sodium lauryl methyl propylamine can be mentioned as 'coco fatty acid sodium sarcosinate, coconut fatty acid creatinine triethanolamine 'laurel thioglycolate 'Laurine-based creatinine unloading. Further, another anionic surfactant suitable for the present invention is exemplified by the following hydroxyether decanoate represented by the general formula (VI). R-CHCH2-OX1 (VI) ox2 In the above general formula (VI), R represents a linear or branched alkyl or alkenyl group, and its carbon number is desirably from 4 to 34, more preferably from 8 to 25. When the number of the alkyl group or the alkenyl group is not 4 or more than 34 af, sufficient foaming properties and feeling of use cannot be obtained. At least one of Χι ' X2 is -CH2C00M or -ch2CH2C00M, and the other may be a hydrogen atom. M is a hydrogen atom, metal test, soil test metal, recorded, low 323872 201249473 grade alkaloid cation, lower grade amine cation, or test amine cation. Examples of the ether tickrate salt as described above include twelfth hospital-1,2-diol-1,2-diacetate ether sodium (dimer '1-monomer, 2-monomer), and the like. . Further, another anionic surfactant which is suitable for the present invention is an ether silicate represented by the following general formula (VII). R-O-(CH2CH2〇) nCH2COOM (νπ) In the above general formula (VII), R represents a linear or branched alkyl or alkenyl group, and its carbon number is desirably from 4 to 34, more preferably from 8 to 25. Further, η is an integer of 0 or more. Μ represents a salt-forming cation of an alkali metal, an alkaline earth metal, an ammonium or an alkanolamine. Examples of the ether carboxylate as described above include cerium (4.5) sodium lauryl ether acetate, sodium cerium (sodium) lauryl ether acetate, and ρ〇Ε(3) tridecyl ether acetate. Na and so on. Further, as another additional anionic surfactant suitable for the present invention, long-chain thiol 2-hydroxyethanesulfonate represented by the following general formula (VIII) (long chain acy1-2-hydroxy-1) -ethanesu1fonate , acylisethionate) o RC0CH2CH2S03M (vni) II ^ 〇 In the above general formula (VIII), R represents a linear or branched alkyl or alkenyl group, and its carbon number is desirably from 4 to 34, more preferably 8 To 25. Μ denotes a salt-forming cation of an alkali metal, an alkaline earth metal, an ammonium, or an alkanolamine. 323872 16 201249473 As the above-mentioned long-chain mercapto 2-light ethyl acid salt, for example, sodium cocoyl 2-hydroxyethanesulfonate, sodium lauryl 2-hydroxyethanesulfonate, palm oil Fatty acid 2-hydroxyethanesulfonic acid triethanolamine, cocoyl ketone 2-hydroxyethanesulfonate magnesium, lauryl ketone 2-hydroxyethanesulfonate magnesium, and the like. Among the above anionic surfactants, in the present invention, a polyoxyethylene alkyl ether sulfate or a polyoxyethylene alkyl ether carboxylate is suitable, and a polyoxyethylene alkyl ether sulfate is more suitable, and particularly suitable. It is p〇E(2) sodium lauryl ether sulfate. For the above-mentioned substance, for example, a commercially available product such as Texapon N70 (manufactured by Cognis Co., Ltd.) or Sinolin SPE-1250 (manufactured by Nippon Chemical Co., Ltd.) can be used. The commercially available product of the long-chain fluorenyl 2-hydroxyethanesulfonate may be jord APON Cl Pwd. (manufactured by BASF Corporation) of sodium cocoyl 2-hydroxyethanesulfonate. In addition, Leb〇n HSA-3 (P) (made by Sanyo Chemical Co., Ltd.) which is a commercial product of the hydroxy ether carboxylate salt may be mentioned by sodium dodecane-^-diol-1,2-diacetate ether. Wait. Further, as a commercial product of the N-mercapto taurate, LMT (manufactured by Nikko Chemical Co., Ltd.) of N. laurylmethylsulfate sodium may be mentioned. In the concentrated detergent composition of the present invention, (B) an anionic surfactant can be used alone as a cleaning agent. Further, the (7)) anionic surfactant may be blended with the (C) amphoteric surfactant described later to impart cleanability. When the (B) anionic surfactant is used alone, the blending amount is set to be 40 to 60% by mass based on the net concentration of the composition. Further, when combined with the (C) amphoteric surfactant, the (β) anionic surfactant can be formulated to have a net concentration of 20 to 40% with respect to the composition, and ideally 323872 17 201249473 is 25 to 30% by mass. The secret amount of the composition of the composition of the net Hi shirt. At this time, (8) over 40 quality, there will be pre-dilution =: up to 2 ° please 'or super ^, the viscosity of the product becomes high, making the modulation sleep = 2 = significantly increased dilution makes it difficult, or diluted a The product _ is lowered and the treatment becomes difficult. . As mentioned above, the city (4) anionic interface activity _ raw material is a liquid aqueous solution with a concentration of 4 〇 / ° ' or 65 / agricultural degree, or a water-free 85 to the brain New M saki for the market, - In the production of a non-concentrated detergent composition, a raw material s which is a liquid to a concentration of 25 to a weight is used. In the present invention, the concentration of the anionic surfactant is more from the viewpoint of obtaining a concentrated composition. High, suitable for more than 50% of the raw materials is rational, and 'anionic surfactant is not dried, powdered raw material H is dissolved into a liquid material, which is easy to produce and is ideal for L' The higher the temperature, the more efficiently the concentrated detergent composition of the anionic surfactant having 3/agricultural thickness can be obtained. (C) Amphoteric surfactant The substance which is generally used in cosmetics or pharmaceuticals can also be used for the amphoteric surfactant to be formulated in the present invention. The amphoteric surfactant suitable for the present invention may, for example, be an acetic acid beet test amphoteric surfactant represented by the following general formulas (IX) and (X). 323872 18 201249473 GH3 r-n+-ch2-coo- (IX) CH3 o ch3 RC-NH-(CH2)3-N+-CH2-CO〇- (X) CH3 In the above general formulas (IX) and (X), R represents a straight bond or a branched burnt group, and its carbon number is desirably 10 to 16, more preferably 12 to 14. As the above-mentioned acetic acid beet test amphoteric surfactant, for example, lauryl dimercaptoacetic acid betaine, coconut fatty amidoxime propyl decylamino acetic acid betaine, palm nucleoside amide Propyldidecylaminoacetic acid betaine and the like. Further, as another additional amphoteric surfactant suitable for the present invention, an imidazolium-type surfactant of the following general formula (XI) may be mentioned. 0 ch2ch2〇h RC-NH-C H2C H2-N-CH2-C OON a (XI) In the above general formula (XI), R represents a linear or branched alkyl group, and its carbon number is preferably 10 to 16 More ideally 12 to 14. As the above-mentioned taste-type surfactant, for example, N-cocomanganyl-N-carboxymethyl-N-hydroxyethylethylenediamine sodium, 2-undecyl-N , N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, and the like. Further, in the case of the additional amphoteric surfactant suitable for the present invention, 323872 19 201249473 may be a tertiary amine oxide of the following general formula (XII).

In the above general formula (XII), the core represents a linear or branched alkyl or alkenyl group having a carbon number of 8 to 22, and R2 and R3 each represent a fluorenyl group or an ethyl group. As the above tertiary amine oxide, there may be mentioned coconut fatty acid decylamine oxide, decylamine laurate oxide, tetradecyldimethylamine oxide, dodecyldifluorenyl group. Amine oxides, etc. Among the above amphoteric active agents, amphoteric surfactants which are particularly suitable in the present invention are: lauryl decylaminoacetic acid betaine, coconut fatty amidoxime propyl decylaminoacetic acid betaine, palm ruthenium nucleus Amidoxime dimethylaminoacetic acid betaine, 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium. For the above-mentioned substances, for example, Anon BL-SF (manufactured by Nippon Oil Co., Ltd.), Levon 2000-SF (manufactured by Sanyo Chemical Co., Ltd.), Genagen Cab 818J (manufactured by Clariant Japan Co., Ltd.), TEGO Betain C60 (manufactured by Degussa Co., Ltd.), Dehyton PK45, can be used. (manufactured by Cognis Co., Ltd.), Nissan Anon BDC-SF (manufactured by Sakamoto Oil & Fats Co., Ltd.), and Obzoline 662N (manufactured by Toho Chemical Co., Ltd.). In the present invention, (C) the amount of the amphoteric surfactant is such that when the (B) anionic surfactant is used alone as a cleaning agent, it is 〇% by mass, and when the components (B) and (C) are used in combination, The purity of the composition is from 1 〇 to 4 〇 323872 20 201249473% by volume, desirably 10 to 25% by mass, more preferably 15 to 5% by weight. When the amount of the component (C) is adjusted to be less than the mass% of the composition, the viscosity of the diluted solution may be remarkably lowered. Further, when the mass is more than sen, the viscosity of the composition before dilution becomes high, and the preparation may be difficult. The viscosity of the composition is remarkably increased during dilution, and dilution is difficult. Further, the commercially available amphoteric surfactant raw material β ^ as described above is supplied to the market in a 25 to 40% aqueous solution. In the present invention, from the viewpoint of r, from the viewpoint of obtaining a concentrated composition, it is preferred that the amphoteric surfactant is used in an amount of more than 35%. The higher the active sword enthalpy in the original/agronomic horn, the more efficient the two concentrated detergent compositions can be obtained. Further, in the present invention, the total amount of the above-mentioned (Β) into eight of the cleaning component is 4 〇 to the purity of the composition and the purity of the blending amount of the component interface meter is less than 4 . Mass 0: 2: The advantage of thick composition is thin, and the lack of suction force is more than 60% by mass. It is not possible to obtain a group L which is easily diluted with water: surface ('D) water. The concentrated detergent composition is composed of enamel water. In the present invention, water may be appropriately added as a separate component, but it is generally sufficient to prepare it with water contained in a solvent of a surfactant raw material. In general, an anionic surfactant or an amphoteric interface activity is commercially available as a high-concentration aqueous solution. Therefore, these interfaces are lived (4) Ux in the aforementioned sap (10) invention. 323872 21 201249473 The presence of more than 45% by mass of water is not preferable from the viewpoint of reducing the amount of sputum required for the manufacture and transportation of products. In particular, the content of water in the present invention is desirably 10 to 30% by mass, and more desirably 20 to 3% by mass based on the composition. Further, in the concentrated cleaning agent composition of the present invention, the surfactant component (cleaning agent) concentrated in the production step is gelated, and it is difficult to mix the components; Therefore, in general, a gelatinization inhibitor such as a salt is used as an additive, and the concentrate is adjusted to have a viscosity which is easy to handle with a general liquid hair cleaning agent. However, since the concentrated composition thus obtained has a viscosity which is further reduced by dilution with water, there are many cases where dripping or the like occurs during use. Tian Ran, it is not impossible to simply obtain a concentrate by simply mixing a large amount of the anionic property of the cleaning agent and the amphoteric surfactant, or reducing the moisture content of the cleaning agent by drying. However, when the composition thus obtained is diluted with water, there is a situation in the field where the viscosity is remarkably increased during the dilution process. For example, in the test example j of Fig. 1, the general POE sodium lauryl ether sulfonate (hereinafter referred to as (3) imaginary 7 〇% aqueous solution (Texapon N70, manufactured by Cognis) is diluted at different magnifications. The composition viscosity (30 ° C) changes. From the first figure 'the above LES 70% aqueous solution, the viscosity rises rapidly from the start of dilution, and the dilution ratio reaches 1.5 times (approximately 100,000 mPa · s). When the dilution ratio exceeds 2 times, the viscosity rapidly decreases, and when the dilution ratio is 2.5 times, it decreases to about 10 〇 mPa.s. That is, the anionic surfactant of the cleaning component is washed in a concentrated liquid of a general 3-fold concentration. 323872 22 201249473 The agent is a restless behavior that is to be hardened to the extent that it is difficult to mix when it is diluted, and then it is tempered to be tempered. In addition, in the test example 2 of Fig. 1, it is indicated that it contains Ρ0Ε lauryl ether sulfate. Sodium, coconut oil fatty guanamine propyl betaine liquid 'alkyl (8 to 16) glucoside, anionic surfactant concentration of about 45% by mass, total amount of surfactant is about 64% by mass of cleaning agent Mixed base Plantapon 611C (manufactured by Cognis Co., Ltd.) was changed in viscosity by dilution. In the same manner as in Test Example 1, the composition of Test Example 2 was rapidly increased in viscosity with a dilution ratio, and was used as a concentrate for dilution. It is extremely difficult to handle. The change in viscosity of this cleaning component due to dilution can be considered to be caused by a change in the association structure of the active agent (ass〇ciati〇n structure). In general, it is known to exceed the surfactant. The critical cell concentration in the solvent (water) (hereinafter abbreviated as cmc) forms a worm-like cell (worml ike micelle), and when the concentration is increased, the association structure will become a layered liquid crystal via the hexagonal liquid crystal. When a high concentration of surfactant is diluted with water, the association structure will change through lamellar liquid crystal-hexagonal liquid crystal-snail-like crystallites. Among them, 'layered liquid crystal and hexagonal liquid crystal are highly viscous gels. The structure "in particular, the hexagonal liquid crystal is a very hard gel. That is, the high viscosity field shown in the test examples 1 and 2 of Fig. 1 can be considered as the association structure of the surfactant. In the field of a layered liquid crystal or a hexagonal liquid crystal. On the other hand, when a solvent having a high solubility is added as a solvent for a cleaning component, the cmc is increased, and the surfactant can be maintained at a high concentration. 23 323872 201249473 worm The structure of the microcells. The test example 3 of Fig. 1 is formulated in a mixed base containing a purity of 32% by mass of P〇E lauryl ether sulfate and a cleaning agent containing 8 masses of 0/〇 of the amphoteric surfactant. There was a change in the viscosity of the propylene glycol 8% by mass. As shown in Test Example 3, in order to maintain the worm-like cells, the surfactant did not see an increase in the viscosity of the layered liquid crystal and the hexagonal liquid crystal. However, when the dilution ratio is increased, the viscosity is immediately lowered, and the viscosity suitable for cleaning (about 300 mPa·s) cannot be maintained. Therefore, it is difficult to use when it is used as a detergent composition. This decrease in viscosity is thought to be caused by the fact that the alcohol weakens the filling state of the hydrophilic group in the micelle to improve the fluidity. It is desirable to formulate a nonionic surfactant in the present invention as a co-surfactant. The co-surfactant is such that the filling of the hydrophilic group is weakened by the alcohol, and it gradually enters the association and exerts the effect of enhancing the hydrophobic interaction. Therefore, as shown in Fig. 1, the non-ionic surfactant-based coconut fatty acid N-methylethanolamine was prepared as in the first example.

In Test Example 4 of Uminon C-11S, manufactured by Kao Corporation, even if the worm-like cells were diluted with water, the fluidity did not increase and the viscosity was maintained to maintain a moderate viscosity. Therefore, in the concentrated liquid hair cleansing composition of the present invention, from the viewpoint of maintaining the viscosity which is easy to handle before and after the dilution, the (E) l or divalent alcohol is blended with (!?) 1卯. A nonionic surfactant having a molecular weight of 5 Å or less is preferably used. Hereinafter, each component will be described. (E) A monovalent or divalent alcohol 323872 24 201249473 The monovalent or divalent alcohol used in the present invention is not particularly limited, but is considered as a storage stability of a concentrated detergent composition, and a treatment at the time of dilution - - The susceptibility of the composition is assumed to be the preservation of the composition. It is desirable to use a liquid at a temperature of less than 50 ° C. Examples of such an alcohol include ethanol, isostearyl alcohol, and benbaol, and divalent alcohols include dipropylene glycol, hydrazine, 3-butanediol, and propanol. 1,2-pentanediol, isoprene glycol, hexanediol, hydrazine, 2-octanediol, and the like. Particularly preferred among these are ethanol, dipropylene glycol, butylene glycol, propylene glycol, and isopentylene glycol. In the present invention, the blending amount of the EM or divalent alcohol is 5 to 25% by mass, more preferably 1 to 2% by mass based on the composition. The amount of the (£) component is relative to the composition. When the amount is less than 5% by mass, the viscosity of the composition before dilution is increased to make preparation difficult, or the viscosity of the composition is remarkably increased during dilution, and dilution is difficult. Further, when the amount is more than 25%, The viscosity of the diluted solution is remarkably lowered, and handling may be difficult. (F) Non-ionic surfactant having a molecular weight of 500 or less and having a molecular weight of 500 or less Nonionics used in the concentrated cleaning composition of the present invention The surfactant in the organic concept diagram is a compound having a molecular weight of 0.8 to 1.1 and a molecular weight of 500 or less. Such a nonionic surfactant may, for example, be a long-chain fatty acid diethylene glycol, a long chain. A fatty acid propylene glycol, a long-chain fatty acid diethanolamine, a long-chain fatty acid N-methylethanolamine, a long-chain fatty acid (p〇e) 2-monoethanolamine or the like, which satisfies the above-mentioned IOB range and the aforementioned molecular weight range. 323872 25 201249473 I〇B is not up to When 〇· 8 ' or I0B exceeds 1.1, a significant increase in viscosity occurs during dilution, the viscosity after dilution is significantly reduced, or the diluted solution composition does not 疋1 phase. Also, when the molecular weight exceeds 5 ,, it is diluted. The viscosity of the composition after the viscosity is remarkably lowered. Particularly preferred in the present invention is a fatty acid diethylene glycol having an average carbon number of 10 to 14, and a fatty acid N-mercaptoethanol decylamine having an average carbon number of 10 to 14. Further, in the case of a commercially available nonionic surfactant, for example, Aminon C-llS (King) made from coconut oil fatty acid N-mercaptoethanol decylamine manufactured by Genapol DELC Clariant Japan Co., Ltd. as diethylene glycol laurate The amount of the (F) nonionic surfactant in the present invention is 5 to 20% by mass, more preferably 10 to 15% by mass based on the composition. When the amount is less than 5% by mass, the viscosity of the solution after dilution is remarkably lowered. When the amount is more than 2% by mass, the viscosity of the composition before the dilution is too high, so that the preparation is difficult. The viscosity of the composition is significantly increased during dilution In the present invention, the total amount of the component (E) and the component (F) is 'the composition containing the component (B) and the component having a purity of 40% by mass or more. , ideally 2 to 30% by mass, more desirably 22 to 24% by mass 'In particular, the ratio of (E) to (F) is, in mass ratio (E): (F) = 3 · 5 : 1 to 1 : 2. 5, ideally 2: 1 to 1: 1.5. When the total amount of the above is less than 20% by mass, that is, when the ratio of the component (B) to the component (c) is too large, it is difficult to concentrate the detergent composition. Dilution with water. Moreover, when the total amount of the above-mentioned compounding amount exceeds 30% by mass, that is, the ratio of the component (B) to the component (C) is too small, the concentration of the cleaning agent composition is easy to dilute with water, but the viscosity of the diluted solution is It becomes a situation that is too low. The concentrated cleaning agent composition of the present invention can be produced by a known method, for example, by adding (A) anionic surfactant to an aqueous solution of an anionic surfactant, adding (A) a cationic poly-polymer, and adding (c) amphoteric activity as needed. An aqueous solution of the agent is obtained by mixing. In addition, when the (Ε) and (F) components are to be used as a solvent and a co-surfactant, for example, in an aqueous solution of an anionic surfactant and a mixture of a (cerium) cationic polymer, (Ε) After mixing the monovalent or divalent alcohol and the (F) nonionic surfactant, if necessary, adding (C) an amphoteric surfactant=aqueous solution and mixing, the water of the composition will not be faced. It is easy to manufacture a concentrated detergent composition by reducing the area of the point of occurrence. 8. In the above production method, the (E) and (卩) components may be added to the aqueous solution of the component (B) and mixed, and the component (A) may be added and mixed. For example, at room temperature, (8) anionic interfacially active indole solution and (Α) cationic polymer are water-soluble (10) or divalent alcohol and (8) nonionic ^; And mix until the sentence. In this case, when the foam formed by the aqueous solution of the surfactant is added, the aqueous solution of the amphoteric surfactant is mixed and mixed, and then the liquid hair having a large water content is added. ^Inventive composition. t constitutes (four) material to minus (four) material preparation ^ remaining secret time 'mixed sputum, in the production of thick material containing (A) to (7) ingredients, the sound of the shirt. But: 'Add order and a 27 201249473 The production of the concentrated hair-like hair cleansing agent of the present invention formed by such a component and the production method is mixed with water, and can be a general liquid hair cleansing agent composition. The present invention is, for example, mixed with an appropriate amount of water or the like at the time of use, diluted and used in the same manner as a conventional shampoo, and used as a shampoo precursor composition. The specific dilution ratio of the present invention is based on the above-mentioned essential components. The blending amount and the blending ratio thereof are suitable for hair care, but generally, the total concentration of the components (B) and (C) is diluted to a purity of 15% by mass, and the same can be obtained as in the conventional liquid shampoo. Degree单词。 In the present application, in the case of water, in the case of the present application, in the case of the present application, in the case of the application, the appropriate dilution ratio is about 2.6. In the process of diluting the total concentration of the component (B) and the component (C) to a purity of 15% by mass, the magnitude of the viscosity change of the composition and the viscosity of the diluted composition are evaluated, which is only 15% by mass. It is used as a standard dilution ratio, and does not limit the dilution ratio of the concentrated detergent composition of the present invention. Further, the temperature of the water used for dilution is such that the higher the temperature, the faster the dilution rate is, but at room temperature (20 to 30) The water of the crucible can also be fully diluted. Moreover, the hardness of the released water is 'no influence on the dilution rate, depending on the dilution method such as A, even if the hardness is high, it can be sufficiently diluted. Z, and, in addition, the concentrated liquid of the present invention The hair cleanser composition can be used by diluting the required amount on the palm of the hand, or can be used by diluting it in a container of an appropriate size before use. Also, when blending the components (8) and (7), Invented concentrated liquid hair 323872 28 20 1249473 The composition of the cleaning agent does not have a high viscosity area which varies with the water content, so the viscosity is easily maintained before the dilution, the dilution, and the dilution. Generally, the liquid composition can be considered to be 30. The viscosity measured by the B-type viscometer at °C is less than 20,000 mPa.s, and the volume is more than 50,000 mPa, and the mixing is _. Therefore, the composition of the present invention described above (stock solution) And the viscosity of the composition is diluted with water until the total concentration of the component (B) and the component (c) reaches a purity of 15% by mass at 30 ° C, and is 5 Torr under normal pressure. 〇〇mPa · s or less is preferably 20,000 mPa·s or less. Further, the liquid viscosity after dilution of the concentrated liquid hair cleansing composition of the present invention is set to 3 〇〇 mPa at 30 ° C under normal pressure. · s or above. After the dilution, when the viscosity of the composition at the time of use is less than 3 〇〇 mPa · s, the viscosity is too low and the grain is easy to handle, and it is difficult to apply the composition to the hair. In particular, the viscosity of the diluted liquid is adjusted to 300 to 2 〇〇〇〇mpa · S (3 (TC) is ideal when considering the ease of handling when used as a cleaning agent. The viscosity at the time of use exceeds 20,000 mPa. · s, the viscosity is too high and it is difficult to apply to the cleaning target and to load and unload the container. That is, in the present application, the composition that is easy to handle before and after dilution is 'associated with the surfactant. The viscosity increase (viscosity change) in the above-mentioned dilution such as the influence of the structure is 5 〇〇〇〇 mPa · s, preferably 20,000 mPa·s, and the viscosity after the dilution (in use) is 3 〇〇 mPa · s or more. 'Ideal is a composition of 300 to 20000 mPa · s. Further, the phase state of the composition of the present invention and the diluted product thereof is preferably one phase. When separated into two phases, it is not only a composition. The handling capacity is 323872 29 201249473. It is not desirable at the point of stability. Further, in the concentrated liquid hair cleaning composition of the present invention, it is easier to reduce the viscosity of the composition in the high viscosity field. Dilution with water, A salt of an organic or inorganic compound is suitable. The salt may, for example, be an organic acid salt, an amine acid salt, an inorganic salt or the like. Examples of the organic acid salt include citric acid, lactic acid, oxalic acid, and succinic acid. , hydrochloric acid, tartaric acid, sulfonic acid, etc., hydrochloride, metal salt (sodium salt, potassium salt), amine salt, etc.. Amino acid, can be mentioned, glycine, alanine, proline, amine Acid, aspartic acid, glutamic acid, etc. hydrochloride, metal salt (sodium salt, potassium salt), amine salt, etc. Inorganic salts, such as sodium, potassium, magnesium, calcium, ammonium, etc. , phosphate, nitrate, borate, sulfate, sulfite, halide (sodium gasification, potassium chloride, ammonium chloride, etc.), etc. In the present invention, the amount of the salt is, relative to the composition It is preferably 0.1 to 5.0% by mass, more preferably 1.0 to 2.0% by mass, and is preferably formulated with sodium carbonate, ammonium chloride or sodium citrate. In the concentrated detergent composition of the present invention, the above ingredients are It can be blended with other ingredients used in general cosmetics and pharmaceuticals within the range that does not impair the effects of the present invention. Other components include, for example, oil, cationic surfactant, powder component, natural polymer, synthetic polymer, tackifier, ultraviolet absorber, chelating agent, pH adjuster, skin nutrient, vitamin antioxidant In terms of oil, it can be mentioned as liquid fat, solid fat, hydrocarbon oil, polyfluorene 323872 30 201249473, oxygen oil, etc. For liquid fats, for example, avocado oil, silk flower, walnut oil from Australia, Corn oil, Shao oil, oyster sauce oil, rapeseed oil, sesame oil, peach kernel oil 'wheat germ oil, camellia oil, oil =, kernel oil, safflower oil, cottonseed oil, perilla oil (PeriUa〇ii), linen Peanut oil, tea oil, oyster sauce, rice bran oil, tung oil, Japanese tung oil = oil, germ oil, triglyceride, etc. For example, solid oils and fats include: cocoa butter, oil (four) oil, honest oil, tallow, sheep wax, hardened tallow, _=^ moon 曰, beef bone fat, hibiscus nuclear oil, hard 彳b pig

Sesame oil and so on. For more oil, beef fat, money, hardened E hydrocarbon oil, for example, liquid stone soil, soil, = a 'stone, called petrolatum: micro-base === lift: chain-like complex (For example, ring (four) diphenyl silk money house, etc.: Hyun, twelve oxygen ^; T-cut ring five stone lithium resin, poly stone oxygen glue, each two ^ formed a three-dimensional mesh structure of the poly stone eve _ change through Oxygen-burning oxygenation (amine-based modified polyoxymethane 323872 poly-stone oxygen burning, straight _ silk enamel / diene / (four) (10) copolymerization 5 money burning, amine diol change, oxygen burning: amine changed to alcohol Change f ... glycerin, :: = oxygen: base; 31 201249473 1 quality polyoxygen, etc.), polydimethyl money (9) Na (10) (4), propylene ^ poly-money. The suitable particle size which can be emulsified in the composition or emulsified and emulsified is the same as that of the general detergent composition. For the cationic surfactant, for example, alkyltrimethylammonium Orphan (for example, stearyl dimethyl ammonium chloride, lauryl trisyl chloride, gasified undecyl tridecyl ammonium, etc.); alkyl pyridinium salt (for example, cetyl chloride) Pyridine rust, etc.); gasification two Fatty dimethyl ammonium dialkyl dimethyl ammonium salt, gasified poly(N,N-dimercapto-3, 5-ylidene hexahydro.bipyridinium); alkyl quaternary ammonium salt; Dimethyl benzyl ammonium salt; alkyl isoquinoline rust salt; dialkyl morpholinium salt; Ρ0Ε carbyl amine; alkyl amine salt; polyamine fatty acid derivative; Benzalkonium chloride; benzethonium chloride, etc. For the powder component, for example, inorganic powder (for example, talc, high-cold soil 'mica' sericite ( Sericite), muscovite, phlogopite, synthetic mica 'red mica, biotite, vermiculite, magnesium carbonate, carbonic acid, aluminum citrate, barium citrate, calcium citrate, magnesium citrate, barium strontium citrate, metal tungstate Salt, magnesium, oxidized stone, zeolite sulphate, calcined sulphuric acid (calcined gypsum), phosphoric acid, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (for example, zinc myristate, palm Calcium acid 'aluminum stearate, boron nitride, etc.); organic powder (for example, polyamide resin powder (ni Powder), polyethylene powder, methacrylate powder Yue acrylate, polystyrene powder, styrene and acrylic acid copolymer resin powder, benzoguanamine (benzoguanamine) resin powder, polytetramethylene failure 323 872 32 201 249 473

Ethylene powder 'cellulose powder, etc.); inorganic white ray (for example, scales, etc.); inorganic red pigment (for example, oxidation _ 'special); inorganic brown pigment (for example, r_iron oxide, etc.) = system = ( For example, yellow iron oxide, loess, etc.; inorganic black _ machine color pigments (for example, (four), Gu Zi, etc.); inorganic green pigments (4) such as, emulsifying, chromium hydroxide, tannic acid, etc.; inorganic blue Pigment (for example, ultramarine blue, Prussian blue, etc.); pearl pigment (for example, titanium oxide coated mica titanium oxide coated with oxygenated M, titanium oxide coated with talc, colored oxidation: covering mica 'oxychlorinated, fish scale (10)); metal powder Pigments (for example, Shao powder, copper powder, etc.) 'H-shell or organic pigments such as Shaoshen Hall (for example, red 201, red 202, red 204, red 2〇5, red 220, red 226) , red 228, red 4〇5 orange 2〇3, orange 204 'yellow 205, yellow 4〇1, and blue 4〇4 organic pigment, red 3, red 1〇4 No., red 1〇6, red 227 'red 230, Color 401, red 5〇5, dial color 205 'yellow 4, yellow 5, yellow 2〇2, yellow 2〇3 'green 3 and blue 1 etc.); natural pigments (eg , chlorophyll, cold-carotene, etc.). Examples of the natural water-soluble polymer include plant-based polymers (for example, gum arabic, tragacanth, polygalactose, guar gura, carobgum, karaya gum). (karayagum), Carrageenan, pectin, pyrophyllum (Cydonia oblonga seed, quince seed; Marmei〇), 323872 33 201249473 Algae colloid ), starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial polymer (for example, xanthan gum, dextrin, succinoglycan, pululan) Etc.; animal-based polymers (for example, collagen, casein, albumin, gelatin, etc.), etc. Also, these derivatives (POE, POP modification, alkyl modification, cationization, anionization, Examples of the semi-synthetic water-soluble polymer include starch-based polymers (for example, carboxymethyl starch, mercaptohydroxypropyl starch, etc.); cellulose-based polymers (sulfonated fibers) Ethyl , mercapto hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, cellulose dialkyl decylammonium sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose , crystalline cellulose, cellulose powder, and hydrophobic modified compounds of these polymers <Examples: a part of stearyloxygen modified> and cationic modified compounds of these polymers; and alginic acid-based polymers ( For example, sodium alginate, propylene glycol alginate, etc.; sodium pectate, etc. The synthetic water-soluble polymer may, for example, be a vinyl polymer (for example, polyvinyl alcohol, polyvinyl methyl ether, poly a vinylpyrrolidone, a carboxyvinyl polymer, etc.; a polyoxyethylene polymer (for example, a polyoxyethylene polyoxypropylene copolymer of polyethylene glycol 20, 000, 40, 000, 60,000, etc.); a mercapto diallyl type cationic polymer (for example, Merquat 100 (manufactured by Merck, USA); a copolymer type cationic polymer of dimethyl diallyl ammonium halide and acrylamide (for example, Merquat) 550, made by Merck, USA; Acid-based polymer (for example, sodium polyacrylate, poly 323872 34 201249473 ethyl acrylate, polyacrylamide, etc.); polyethylenimine; other cationic polymer other than (A) component; AlMg (veegum); polyquatanium-39, etc. For the tackifier, for example, gum arabic, carrageenan, karaya gum, sassafras gum, horn Carob gum, pyrus cydonia, (Cydonia oblonga seed, quince seed), casein, dextrin, gelatin, sodium pectinate, sodium alginate 'mercapto cellulose, ethyl cellulose , CMC, hydroxyethyl cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, renebic ethylene polymer locust bean gum (LBG), guar gum, guar gum, Tamarind gum, dicalcium bismuth sulphate cellulose sulfate xanthan gum, shi yu acid town, saponite, lintelite 'algic acid AlMg (veegum) 'synthesis clock Laponite, anhydrous citric acid, and the like. Examples of the ultraviolet absorber include a benzoic acid-based ultraviolet absorber (for example, p-aminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglyceride 'N,N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N,N-diindenyl PABA ethyl ester, N,N-dimercapto PABA butyl ester, etc.; o-amine benzoic acid-based ultraviolet absorber (for example, N-acetonitrile) Oral amines (homomenthy 1 -N~acety 1 anthran i 1 ate), etc.; salicylic acid-based UV absorbers (eg, amyl salicylate, menthyl salicilate) Homomenthyl salicilate, octyl salicylate, phenyl salicylate, salicylic acid ester, salicylic acid, isopropyl alcohol, etc.; cinnamic acid ultraviolet absorber (octyl cinnamate) , 4-isopropyl 323872 35 201249473 ethyl cinnamate (ethy) 4-isopropyl cinnamate, 2, 5-diisopropyl cinnamic acid methyl vinegar '2, 4-diisopropyl cinnamic acid ethyl ester, 2, 4-diisopropyl cinnamate decyl ester, p-methoxy cinnamate propyl ester, p-methoxy cinnamic acid isopropyl ester, p-methoxy cinnamic acid isoamyl ester, methoxy Octyl cinnamate (2-ethylhexyl p-methoxycinnamate), 2-ethoxyethyl p-methoxycinnamate, cyclohexyl p-methoxycinnamate, cyano-wan-phenyl Ethyl cinnamate, α-cyano-/3-phenyl cinnamic acid 2-ethylhexyl ester, mono-2-ethylhexyl-di-p-methoxy cinnamic acid glyceride, etc.; Absorbent (for example, 2, 4-dihydroxydiphenyl ketone, 2, 2,-dihydroxy-4-methoxydiphenyl ketone, 2, 2'-dihydroxy-4, 4'-dioxine Diphenyl ketone, 2,2',4,4'-tetrahydroxydiphenyl ketone, 2-hydroxy-4-methoxydiphenyl ketone, 2-hydroxy-4-methoxy-4,- Methyl diphenyl ketone, 2-hydroxy-4-indolyl diphenyl ketone-5-propionate, 4-phenyldiphenyl fluorene, 4,-phenyl-diphenyl ketone-2-carboxylate 2-ethylhexyl acid, 2-hydroxy-4-n-octyloxydiphenyl ketone, 4-hydroxy-3-carboxydiphenyl ketone, etc.; 3_(4,-methylbenzylidene)-d, Diterpenoid, 3-benzylidene-d,l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2-pyridyl-5-mercaptophenylbenzotriene. Sit; 2 (2' _ _ _ 5, _ tris-octyl phenyl) benzotriazole; 2-(2' _ hydroxy-5, • methyl phenyl benzotriene, a methoxy Benzylidene methyl; 4-methoxy-4, 3-tert-butyl benzhydryl methane; 5-(3,3-dimethyl-2-arsenyl)_3_pentane 2-ketone, etc.; triazine-based UV absorber (for example, hydroxy-3-3-dodecyloxy)oxy]-2-hydroxyphenyl)-4,6-bis(2,4-dimethyl Phenyl)- 1,3,5-triazine, 2-2-4-[(2-hydroxy-3-trideoxypropyl)oxy]_2-hydroxyphenyl)-4,6-bis (2, 4-dimethylphenyl)-1,3,5-triazine, etc.). 323872 36 201249473 For the chelating agent, for example, 1-hydroxyethane-1 1 -- 醯Μ, > 1 yixin acid, 1~ hydroxyethene-1,1-diphosphonic acid tetrasodium salt 'B Amine tetraacetate, steel _ __ '· C» ___ amine triacetate, sodium edetate, sodium citrate, sodium sulphate, gluconic acid, gluconic acid, ascorbic acid, Amber is partially ethylenediaminetetraacetic acid, ethylenediamine is trisodium ethyltriacetate, and the like. The pH adjusting agent may, for example, be a buffer such as lactic acid-sodium lactate or sodium citrate <succinic acid-succinate. Examples of the vitamins include vitamin A, Bl, B2, B6, E and its derivatives, pantothenic acid and its derivatives, biotin and the like. The term "antioxidant" includes, for example, tocopherols, dibutyl butyl hydroxy methoxybenzene, gallic acid esters and the like. ^ Other optional ingredients, for example, preservatives (for ethyl benzoate, butyl paraben, hydrazine, 2-alkanediol (carbon chain length 6 to its derivatives, benzene) Oxyethanol, methylchloroisothiazolinone, etc.; anti-inflammatory agents (for example, glycyrrhizic acid derivatives, glycyrrhetic acid derivatives, salicylic acid derivatives, eucalyptus, zinc oxide, allantoin, etc.); whitening agents ( For example, Saxifrage extract, arbutin, etc.; various extracts (for example, Astragalus, Huanglian, Zigen 'peony' Japanese Swerth (SWERTIAJAp〇NICA), birch, sage, batch, ginseng' Aloe 'Mallow, Mouth, Grape, Coix Seed, Loofah, Hundred A Fructus I, Chuanxiong 'Ginger, Hypericum erectum, Ononis spinosa, Garlic, Chili, Tangerine, Angelica , seaweed, etc.), activators (eg, royal jelly, photoreceptors, cholesterol derivatives, etc.); gold activators (eg 'vanillinamine (N〇nivamide; pepper test), benzyl nicotinic acid' nicotine Acid-butoxyethyl ester, capsaicin, 323872 37 201 249473 zingerone, cantharides tincture, fish stone ester (ichthammol), tannic acid, alpha-borne brain (a-borneol), ferric acid in alkali acid, six in acid inositol ( Inositol hexanicotinate), cyclandelate, cinnarizine; anticoagulant jk antagonist, Tolazoline, acetaminophen, verapamil, cephalosperm (cepharanthine), 7-methanol (oryzanol, etc.); anti-lipidal leakage agents (eg 'sulphur, thianthol, etc.); anti-inflammatory agents (eg tranexamic acid, thio-sex cattle) a thiotaurine, hypopotaurine, etc.; an aromatic alcohol (for example, benzyl alcohol, benzyloxyethanol, etc.), etc. The concentrated liquid hair cleansing composition of the present invention is used for hair. Shampoo, body wash, face wash, shampoo for infants, baby body wash, kitchen cleaner, medical cleaner, use of various other cleaning agents, use The form is not particularly limited. The invention is described in more detail by way of examples, but the invention is not limited to these, and unless otherwise specified, the amount of the formulation is expressed in mass % (purity). [Embodiment] First, the description will be made in the embodiment A. Method for evaluating the composition of concentrated liquid hair cleansing agent [Evaluation method of composition for concentrated liquid hair cleansing agent] Appearance of visual observation of each sample of concentrated liquid hair cleansing agent composition, and actual use (concentration In the case of the composition, the hair care effect diluted to a cleaning agent concentration of 323872 38 201249473 is 15%, and the evaluation is based on the following criteria. *·. (1) Appearance: 〇: No white precipitate is observed X: White precipitate is formed (2) Hair care effect 〇: There is X: None is shown in Table 1 below, (a) is the concentration of the cleaning agent 15 (b) is a general shampoo of about %, and (b) is a composition which concentrates a washing|cleaning agent (concentration of 40% or more). In each of the compositions, the compounds of the following Test Examples 1-1 to 7 were evaluated as the (A) cationic polymer and the appearance and hair care effect when used. The results are shown in Table 2. [Table 1] Component (a) General component (purity) (b) Concentrated composition (purity) [(A) Cationic polymer] Any of the following Test Examples 1-1 to 1-7 0.5 1.7 [( B) anionic surfactant] polyoxyethylene (2) sodium lauryl ether sulfate 8.4 29.8 [(C) amphoteric surfactant] coconut fat amidoxime propyl beta 3.9 14.0 2-alkyl (C12)-N -carboxymethyl-N-hydroxyethylimidazolium beet test 2.7 9.5 [(D) water] water 76.3 15.8 [(E) 1 or 2 valent alcohol] 95% ethanol 0.5 1.6 dipropylene glycol 4.0 14.6 [(F) non Ionic surfactant] Coconut fatty acid N-methylethanol decylamine (Aminon C11-S) 2.4 8.5 Diglycerin 0.3 1.1 Phenoxyethanol 0.5 1.7 Perfume 0.5 1.7 Detergent concentration ((B) + (C)) 15.0 % 53. 3% 323872 39 201249473 (Manufacturing method) In (B) an aqueous solution of an anionic surfactant, (A) a cationic polymer is added and mixed, and (E) a monovalent or divalent alcohol is further added thereto. After mixing with (F) a nonionic surfactant, an aqueous solution of (C) an amphoteric surfactant is added and mixed. Thereafter, other components were added and mixed to obtain a composition. [(A) Cationic Polymer] Test Example 1-1: Cationized Cellulose Test Example 1-2: Cationized Guanhua Soy Glue Test Example 1-3: Gasified Dimethyldiallyl Ammonium Acetate Amine copolymer (Merquat 550, manufactured by Nalco Japan Co., Ltd.) Test Example 1-4: Acrylic acid, decyl acrylate, gasified decyl acrylamide propyl hydrazide propyl (45 mol / 45 mol / 10 mol) copolymer (Merquat 2001, Nalco Japan Co., Ltd.) Test Example 1-5: Copolymer of acrylamide, hydrazinium chloride, acrylamide propyltrimethylammonium (20 mol/80 mol) Test Example 1-6: Gasification of propyltrimethylammonium propylene Indole dimethyl methacrylamide (Diasleek C-822, manufactured by Mitsubishi Chemical Corporation) Test Example 1-7: Polyquaternium-74 (manufactured by Rhodia Co., Ltd.) 323872 40 201249473 [Table 2] Test Example 1-1 1 -2 1-3 1-4 1-5 1-6 1-7 (a) General composition (1) Appearance 〇〇〇〇〇〇〇 (2) Hair care effect 〇〇〇〇〇〇〇 (b) Concentrated composition (1) Appearance XXX 〇〇〇〇 (2) Hair care effect XXX As shown in Table 2, Tests 1 - 4 to 7 using a cationic polymer having the structure of the above general formula (1) Yes, will When the cleaning agent is made into a composition of a general liquid hair cleaning agent composition, the composition of the concentrated liquid hair cleaning agent having a high concentration of the cleaning agent is also good, and no white precipitate is formed. It has a hair care effect of a cationic polymer. On the other hand, in the case of Test Examples 1-1 to 3 in which the cationic polymer having the above-described structure was not provided, a white precipitate due to the polymer was formed when the composition was concentrated, and the hair styling effect could not be exhibited. From the above results, it is understood that the concentrated liquid hair cleansing composition of the present invention is preferably a cationic polymer having the structure represented by the above general formula (1). Further, the above evaluation was carried out using the concentrated liquid hair cleansing composition of the composition shown in Table 3 below. The results are shown in Table 3. 323872 41 201249473 [Table 3]

Ingredient Test Example 2-1 2-2 2-3 2-4 2-5 2-6 2-7 [(A) Cationic Polymer] Chloromethyl methacrylate styrene propyl trimethyl bond polymer propylene oxime Amine·Chlorohydrinium hydrazide propylamine trimethylammonium (30/70 mol/mol) copolymer acrylamide. Gasification of methacrylamide guanamine propyl tridecyl (20/80 mol / mol) copolymer Acrylic acid decyl acrylate • Gasification methacrylamide decyl propyl trimethyl ammonium copolymer cationized Guanhua Bean Gum 1.8 1.8 1.4 1.8 1.7 1.8 1.7 [(B) anionic surfactant] Polyoxyethylene (2) Sodium lauryl ether sulfate 27.3 27.3 25.4 47.5 a 50.9 _ [(C) amphoteric surfactant] coconut fat amidoxime propyl betaine 1.29 12.9 12.0 _ 22.0 a 23.5 2-alkyl (C12)-N-carboxymethyl -N-hydroxyethylimidazolium betaine 8.8 8.8 8.1 -22.5 - 24.0 [(D water)] Water 21.9 21.9 28.0 26.9 14.6 21.9 9.0 [(E) 1 or 2 valent alcohol] Ethanol 3.1 3.1 2.9 1.7 2.7 1.8 2.8 Dipropylene glycol 13.2 13.2 12.2 11.9 27.2 12.7 29.1 [(F) Nonionic surfactant] Coconut fatty acid N-methylethanol decylamine (Aminon C11-S) 7.8 7.8 7.2 6.8 6.7 7.3 7.1 Phenoxyethanol 1.6 1.6 1.4 1.7 1.3 1.8 1.4 Perfume 1.6 1.6 1.4 1.7 1.3 1.8 1.4 Detergent concentration ((B) + (C)) 49.0 49.0 45.5 47.5 44.5 50.9 47.5 (1) Appearance 〇〇〇〇 XXX (2) Hair care effect〇〇 〇〇 XXX (manufacturing method) In (B) an aqueous solution of an anionic surfactant, (A) a cationic polymer is added and mixed, and (E) a monovalent or divalent alcohol and (F) non are added thereto. After mixing with an ionic surfactant, (C) an aqueous solution of the amphoteric surfactant is added and heated and mixed. Thereafter, other components were added and mixed to obtain a composition. As shown in Table 3, when a cationic polymer having the structure represented by the above general formula (1) is used, (B) an anionic interface 42 323872 201249473 active agent and (C) an amphoteric surfactant are used as a cleaning agent. In Test Examples 2-1 to 3 of both of them, the composition was excellent in both appearance and hair care effect. Further, when the polymer was used, the (B) anionic surfactant was used alone as a cleaning agent to obtain a favorable concentrated liquid hair cleansing composition (Test Example 2-4), but (C) both sexes were used alone. The surfactant produced a white precipitate due to the polymer, and the hair conditioning effect could not be obtained (Test Example 2-5). On the other hand, when a cationized Guanhua bean gum having no specific structure is used as the cationic polymer, any of (B) and (C) alone is used to produce a white precipitate (Test Examples 2-6, 2-7) ). From the above results, it is understood that the concentrated liquid hair cleansing agent composition of the present invention is suitably used as a cleaning agent in which an anionic surfactant, an anionic surfactant, and an amphoteric surfactant are formulated at a high concentration. Further, the above-mentioned evaluation was carried out on the concentrated liquid hair cleansing composition of the composition shown in Table 4 below. The results are shown in Table 4. 323872 43 201249473 [Table 4] Test Example 3-1 3-2 3-3 3-4 [(A) Cationic polymer]. Methyl propylene decyl propyl trimethyl ammonium chloride polymer 1.7 1.7 1.7 1.7 [(B) anionic surfactant] polyoxyethylene (2) sodium lauryl ether sulfate 14.0 14.0 24.5 28.0 sodium lauryl methyl taurate 14.0 - sodium cocoyl isethionate - 14.0 - ten Sodium dialkyl-1,2-diol acetate ether — 4.0 — [(C) amphoteric surfactant] Coco fatty amidoxime beet test 16.5 16.5 13.8 12.7 Lauryl dimethylaminoacetate betaine – — 4.0 [(D)Water] Water 25.2 25.2 31.7 27.0 [(E) 1 or 2 valent alcohol] Ethanol 1.7 1.7 1.7 1.7 Dipropylene glycol 15.0 15.0 10.7 13.0 [(F) Nonionic surfactant] Coconut fatty acid N -Methylethanolamine (Aminon C11-S) 8.5 8.5 8.5 8.5 Phenoxyethanol 1.7 1.7 1.7 1.7 Perfume 1.7 1.7 1.7 1.7 Detergent concentration ((B) + (C)) 44.5 44.5 42.3 44.7 (1) Appearance〇 〇〇〇(2) Hair care effect 制造 (Manufacturing method) In the test cases 3-1 and 3-2, sodium lauryl methyl tauroate and coconut hydroxyethyl sulfonate were used. Sodium each respectively, after mixing (E) l monovalent or divalent alcohols and (F) a nonionic surfactant, addition of polyoxyethylene (2) lauryl ether sulfate aqueous solution. Further, (A) a cationic polymer is added and mixed, and (C) an aqueous solution of an amphoteric surfactant is added and heated and mixed. Thereafter, other components are added and mixed to obtain a composition. In Test Examples 3-3 and 3-4, in (B) an aqueous solution of an anionic surfactant, (A) a cationic polymer was added and mixed, and (E) a price of 323872 44 201249473 or a divalent amount was added. After mixing the alcohol and the (F) nonionic surfactant, (C) an aqueous solution of the amphoteric surfactant is added and heated and mixed. Thereafter, other components were added and mixed to obtain a composition. As shown in Table 4, the concentrated liquid hair cleansing composition of the present invention having the cationic polymer having the configuration shown in the general formula (1), as in Test Example 3-4, (B) an anionic surfactant When one type was used and when two or more types were used in combination as in Tests 3-1 to 3, no white precipitate was formed, which resulted in an excellent hair care effect. Further, as such (B) an anionic surfactant, which is composed of polyoxyethylene alkyl ether sulfate, N-lauroquinone-based mercapto taurate, long-chain fluorenyl 2-hydroxyethyl It is obvious that all of the anionic surfactants can be used as the base sulfonate, or the hydroxy ether carboxylate or the like. Similarly, for the (C) amphoteric surfactant, as shown in Table 4, for example, a compound of the acetic acid beet type can be suitably used and used. Further, the above evaluation was carried out on the composition of the concentrated liquid hair cleansing composition having the composition shown in Table 5 below. The results are shown in Table 5. 323872 45 201249473 [Table 5]

Ingredient Test Example 4-1 4-2 4-3 4-4 4-5 [(A) Cationic Polymer] Methyl propylene decyl propyl trimethyl ammonium phosphate polymer 0.01 0.1 3.0 5.0 10.0 [(B Anionic surfactant] Polyoxyethylene (2) sodium lauryl ether sulfate 28.0 28.0 28.0 28.0 28.0 [(c) amphoteric surfactant] coconut fat amidoxime propyl betaine 12.7 12.7 12.7 12.7 12.7 2-alkyl (C12)-N-carboxymethyl-N-hydroxyethylimidazolium betaine 9.8 9.6 9.6 9.6 9.6 [(9) water] water 22.59 22.5 19.6 17.6 12.6 [(E) 1 or 2 valent alcohol] ethanol 1.7 1.7 1.7 1.7 1.7 Dipropylene glycol 13.5 13.5 13.5 13.5 13.5 [(F) Nonionic surfactant] Coconut fatty acid N-methylethanol decylamine (Aminon C11-S) 8.5 8.5 8.5 8.5 8.5 Phenoxyethanol 1.7 1.7 1.7 1.7 1.7 Perfume 1.7 1.7 1.7 1.7 1.7 Detergent concentration ((B) + (C)) 50.2 50.2 50.2 50.2 50.2 (1) Appearance 〇〇〇〇 X (2) Hair care effect X 〇〇〇 X (Manufacturing method) In (B) In the aqueous solution of the anionic surfactant, (A) a cationic polymer is added and mixed, and (E) a monovalent or divalent alcohol and (F) a nonionic surfactant are added and mixed. Was added an aqueous solution (C) amphoteric surfactant and heating the mixture. Thereafter, other components were added and mixed to obtain a composition. As shown in Table 5, in Test Example 4-1 in which a cationic polymer having a specific structure was adjusted to 0.01% by mass, the formation of a precipitate of the polymer was not obtained, but the hair styling effect was insufficient. Further, in Test Example 4-5 in which the polymer was blended in an amount of 10% by mass, the effect of the filamentary property of the cationic polymer was strong, and handling was difficult. Further, the concentration of the cleaning agent results in the formation of a white precipitate, and the hair care effect is also reduced. 46 323872 201249473 In contrast to the above, the test examples 4-2 to 4 in which the above-mentioned polymers were blended 0.1 to 5.0% by mass were well evaluated performance. 1至五质量百分比 is suitable as the result of the above-mentioned results, in the concentrated liquid hair cleansing composition of the present invention, the cationic polymer having a specific structure is formulated. Further, the above evaluation was carried out on the composition of the concentrated liquid hair cleansing composition having the composition shown in Table 6 below. The results are shown in Table 6. [Table 6]

Ingredient Test Example 5-1 5-2 5-3 5-4 5-5 [(A) Cationic Polymer] Acrylic acid. Methyl acrylate. Mercaptopropyl acrylate-acrylic propyl trimethyl ketone copolymer 0.1 1.5 2.5 3.5 4.5 [(B) anionic surfactant] Polyoxyethylene (2) sodium lauryl ether sulfate 51.8 51.8 51.8 51.8 51.8 [(8) water] water 44.7 43.3 42.3 41.3 40.3 phenoxyethanol 1.7 1.7 1.7 1.7 1.7 Spice 1.7 1.7 1.7 1.7 1.7 Cleaning agent concentration 51.8 51.8 51.8 51.8 51.8 (1) Appearance 〇〇〇〇〇 (2) Hair care effect 〇〇〇〇 X (manufacturing method) (D) aqueous solution of (Β) anionic surfactant In the middle, a cationic polymer is added and mixed, and then other components are added and mixed to obtain a composition. As shown in Table 6, there are 0.1% to 5% by mass of the cation polymer having a specific structure, 40 to 60% by mass of the anionic surfactant, and 45% by mass of the water (D). The following concentrated liquid hair cleansing composition which does not contain an amphoteric and nonionic surfactant or a monovalent or divalent alcohol is also a composition excellent in appearance and hair care effect. The prescription examples of the present invention are shown below, but the present invention is not limited to these. 323872 47 201249473 <Prescription Example 1: Concentrated shampoo> (ingredient) 70% polyoxyethylene (2) sodium lauryl sulfate solution (Texapon N70, manufactured by Cognis) 70% ammonium lauryl sulfate solution (Texapon ALS70 , Cognis Co., Ltd.) Laurel 曱 曱 牛 牛 牛 N N-Coco fat 醯-L-Lactinate sodium 39% coconut guanamine propyl beet test solution (Dehyton PK45, Cognis company, containing sodium 6%) Norwegian fatty acid N-mercaptoethanol, amine, coconut oil, fatty acid, monoethanol, decylamine, dipropylene glycol, sorbitol, gasification, propyl trihydrazide, propylene, decylamine, dimercapto acrylamide copolymer, quaternary ammonium salt-10 Sodium citrate citrate (diisobutyl PEG-14 / amod i thi cone) copolymer myristyl menthol phenoxyethanol POP (70) decaglyceryl ether ( Beltamol DG-25, made by Nippon Oil Co., Ltd.) Perfume quality% 20.0

0.3 37.0

11.

(Manufacturing method) The coconut fatty acid N-methylethanolamine and dipropanediol were stirred and mixed in sodium lauryl methyl taurate and sodium N-cocoyl fatty decyl-L- faceamine. After that, add polyoxyethylene (2) sodium lauryl sulfate solution and ammonium lauryl sulfate solution, and then mix gasified propyl trimethyl ammonium • dimethyl propylene amine and poly quaternary ammonium salt-10, and mix other ingredients. , the composition. The resulting composition is easily diluted with water and diluted with water by 2.68 times. 323872 48 201249473 It is suitable for use as a shampoo. <Prescription Example 2: Concentrated shampoo> (% by mass) Lauryl ether-4 carboxylic acid (Empicol CBC, Huntzman 30.0 10.0 30.0 10.5 5.5 6.0 4.0 0.1 1.7 0.5 0.8 0.1 0.8) 30% π East Saliva Betaine (Obazoline 662N, manufactured by Toho Chemical Co., Ltd.) 40% lauryl bis-decylaminoacetic acid betaine (manufactured by Nissan Anon BL-SF 'Nippon Oil Co., Ltd.) Diethylene glycol laurate (manufactured by Clariant Japan Co., Ltd.) Dipropylene glycol Ethanol 30% ammonia cationization Guanhua bean gum (Catinal CG-100S, manufactured by Toho Chemical Co., Ltd.) Polyquaternium-74 Sodium chloride phenoxyethanol POP (70) Decly glycerol i|(Beitamol DG-25, Nippon Oil Company made) Perfume (manufacturing method) In the laureth-4carboxylic acid, ammonia water, diethylene glycol laurate and dipropylene glycol 'ethanol are stirred and mixed. Next, a cationic guar gum (Cati〇nal CG-100S, manufactured by Toho Chemical Co., Ltd.) and a polyquaternium _74 were mixed, and other components were mixed to obtain a composition. The composition is preferably diluted with water, diluted with water by 2.8 times and suitably used as a shampoo. <Prescription Example 3: concentrated shower gel> (ingredient) (f*%) 70% polyoxyethylene (1) sodium lauryl sulfate (sinolin SPE1150, new 323872 49 201249473 manufactured by 理 理 理 3) 34.6 90% laurel Alcohol-Polymer-4 Bumpy Acid (Empicol CBC, manufactured by Huntzman 3.0) 30% ammonia water 0.4 40% lauryl dimercaptoacetic acid beet test (Nissan Anon BL-SF, manufactured by Oyster Sauce) 31.0 85% cocoamine Propyl betaine (TEGO Betain CKD, manufactured by Degussa, sodium sulphide 15%) 7.0 Diethylene glycol laurate (manufactured by Clariant Japan) 7.0 Ρ〇Ε(1)-1,2-dodecanediol 1.0 II Propylene glycol 12.0 cationized locust bean gum 0.1 Acrylic acid • Methyl acrylate • Mercapto chloride acrylamidopropyl trimethyl ammonium (45 mol / 45 mol / 10 mol) copolymer 1.8 Phenoxyethanol 0.8 Sodium benzoate 0.2 Lactic acid 0.2 PPG (70) glyceride 0.1 Fragrance 0.8 (Manufacturing method) In the laureth-4carboxylic acid, ammonia water, diethylene glycol laurate, P0E(1)-1, 2-dodecanediol and Dipropylene glycol was stirred and mixed. Next, a mixture of cationized locust bean gum, acrylic acid/decyl acrylate, decyl chloride acrylamide propylaminopropylammonium ammonium copolymer, and other components was added to obtain a composition. The obtained composition can be easily diluted with water and diluted with water for 0.02 times and can be suitably used as a shower gel. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing a change in viscosity depending on a dilution ratio of a cleaning component. [Main component symbol description] None 323872 50

Claims (1)

201249473 VII. Patent application scope: 1. A concentrated liquid hair cleansing composition comprising: (A) 0.1 to 5 mass% of a cationic polymerization having a structure represented by the following general formula (1) (B) 40 to 60% by mass of an anionic surfactant, (D) 45% by mass or less of water, CHs I -C - N-(CH2)3 - N + -R ·Χ-(1) II II Ο H CH3 (In the above formula (1), R represents an alkyl group having 1 to 3 amino groups, a 4- to ammonium group, a hydroxyl group having 1 to 3 carbon atoms, and X- represents the above-mentioned structure as an electrically neutral number. Monovalent anion). 2. A concentrated liquid hair cleansing composition comprising: (Α) 0.1 to 5 mass% of a cationic polymer having a structure represented by the following general formula (1), (B) an anionic interface The active agent, (C) an amphoteric surfactant, (D) 45% by mass or less of water, wherein the total amount of (B) and (C) is 40 to 60 mass% / 〇, 323872 1 201249473 CH3 I - C - N—(CH 2 ) 3 —N + —R *X — (1) II II Ο H CH3 (In the above formula (1), R represents a carbon number which may have a 1 to 3 amine group, a 4th ammonium group, and a hydroxyl group. The alkyl group to 3, X" represents a monovalent anion having the above structure as an electrically neutral number. 3. The concentrated liquid hair cleanser composition according to claim 1 or 2, wherein (A) the cationic polymer is: gasified mercapto acrylamide propyl decyl ammonium Polymer; acrylamide, gasification, mercapto acrylamide, propylamine, decyl ammonium copolymer; acrylic acid, decyl acrylate, gasification, mercapto acrylamide, propyl hydrazide, copolymer Any one selected from the group consisting of decyl ammonium acrylamide, dimercapto acrylamide copolymer, and polyquaternium-74. 4. The concentrated liquid hair cleansing composition according to any one of claims 1 to 3, further comprising: (E) 1 or 2 valence of 5 to 25 mass%/◦ 5 : The ratio of the ratio of (E): (F) by mass ratio of 3.5: 5: The ratio of the ratio of (E): (F) by mass ratio of 3.5: 5: 1 to 1: 2. 5, and when the composition is diluted to a concentration of (A) and (B) of 15% by mass, the viscosity at 300 ° C is 300 mPa · s or more. 323872 2 201249473 5. The composition of the tumbling liquid hair cleansing agent according to claim 4, wherein (7), the ionic surfactant is a long-chain fat 驮N having an average carbon number of 1 () to 14 - Methylethanolamine and/or a long chain fatty acid diethylene glycol having an average carbon number of 10 to 14. 6. The concentrated liquid hair cleansing composition according to any one of claims 1 to 5, wherein (8) the anionic surfactant is a polysulfate-containing sulfate-type interface activity Agent. The concentrated liquid hair cleansing composition according to any one of the preceding claims, which further comprises an organic or inorganic salt. The concentrated liquid hair washing according to any one of items 1 to 7 of the above-mentioned patents (4) makes the financial method, and the collateral is mixed with water. 9. The method for preparing a concentrated liquid hair washing product according to the second aspect of the invention, comprising: (8) an aqueous solution of an anionic 1 active agent and (A) a cationic polymer, and then (C) a step of mixing an aqueous solution of an amphoteric surfactant. And a method of producing a concentrated liquid hair cleansing composition according to any one of claims 1 to 8, which is mixed with water. 323872 3