CN103445984B - A kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer - Google Patents
A kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer Download PDFInfo
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- CN103445984B CN103445984B CN201310377403.3A CN201310377403A CN103445984B CN 103445984 B CN103445984 B CN 103445984B CN 201310377403 A CN201310377403 A CN 201310377403A CN 103445984 B CN103445984 B CN 103445984B
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Abstract
The present invention relates to a kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer, outside dewatering, in this shampoo, contain: the first type surface activating agent that (A) accounts for mild shampoo weight 5% to 40% is, the composition of APG hydroxypropyl sodium phosphate copolymer and ethoxylated dodecyl alcohol sodium sulphate, and both weight ratios are 10:1 to 2:1; (B) account for the cation guar gum of mild shampoo weight 0.05% to 0.5%. (C) account for the coconut monoethanol amide of mild shampoo weight 1.0% to 3.0%; This shampoo pH value is 4.5-5.5; APG hydroxypropyl sodium phosphate copolymer uses as first type surface activating agent in the present invention, has greatly reduced the consumption of sulfated surfactant, and foam is abundant, and mildness is good, is applicable to configuration children's shampoo.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to one and contain the copolymerization of APG hydroxypropyl sodium phosphateThe mild shampoo composition of thing.
Background technology
Along with improving constantly of living standard, people also come the demand of hair washing product and requirementHigher, this has proposed more and more higher requirement also to the formula engineers of technical field: foam is abundant,Cleaning capacity is good, and mildness is high, does not contain or contain a small amount of sulfate, does not contain or contain the skills such as a small amount of silicone oilArt demand is also arisen at the historic moment. At present, aspect shampoo formula technique, the main formula of shampooSystem be by first type surface activating agent namely the anion surfactant taking sulfate as representative as bayThe composition such as ether alcohol sulfate and sulfated lauryl alcohol, in addition, in order also to improve lather quickness and mildnessMust add and use zwitterionic surfactant as Cocoamidopropyl betaine, lauryl betaineOr cocounut oil both sexes sodium acetate, and nonionic foam stabilizer, coconut monoethanol amide, cocounut oil diethanol acylAmine etc., for the dry wet conditioning property that increases hair also must be used silicone oil.
Along with new formula technique, the invention of new raw material and use, the formula of traditional shampoo is alsoChange quietly.
The surfactant that for example shampoo formula uses is from traditional sulfate type anion formSurface-active agent is to being listed as with APG deriving technology as APG (APG) and some with green surfactantThe surfactant of the various performances of making shifts. The derivative surfactant of APG and APG have out ofGentle characteristic, and there is good hair conditioning.
APG deriving technology be exactly on alkyl-glucoside or glycan molecule other functional group of bonding obtain skySo source has a novel product out of APG functional character. In the present invention, APG deriving technology is exactlyOn alkyl-glucoside or glycan molecule bonding hydroxypropyl sodium phosphate and the novel product that obtains is thisIt is good that novel product has with anion surfactant compatibility, to eyes and skin as mild as a dove, and noContain silicone oil and there is conditioning, can be in order to produce the shampoo of low pH value, and foam is abundant, easilyIn thickening, in shampoo formula, can greatly reduce the consumption of sulfate type anion surfactantDeng.
Summary of the invention
The present invention relates to a kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer, outside dewatering,In this shampoo, contain: the first type surface activating agent that (A) accounts for mild shampoo weight 5% to 40% is this master meterSurface-active agent is the group of APG hydroxypropyl sodium phosphate copolymer and ethoxylated dodecyl alcohol sodium sulphateCompound, and both weight ratios are 10:1 to 2:1; (B) account for mild shampoo weight 0.05% to 0.5%Cation guar gum; (C) account for the coconut monoethanol amide of mild shampoo weight 1.0% to 3.0%; ShouldShampoo pH value is 4.5-5.5; APG hydroxypropyl sodium phosphate copolymer is in the present invention as master meterSurface-active agent uses, and almost can substitute sulfate type anion surfactant completely, has conditioningProperty is got well and mildness high.
Shampoo of the present invention, APG hydroxypropyl sodium phosphate copolymer is wherein Plantacare APG 1200G hydroxypropylBase sodium phosphate copolymer and cocoyl glucosides hydroxypropyl sodium phosphate copolymer, preferably Plantacare APG 1200G hydroxypropylBase sodium phosphate copolymer.
Shampoo of the present invention, first type surface activating agent adopts Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and the moonCinnamic alcohol polyethenoxy ether sodium sulfate, and both part by weight 10:1-2:1.
Shampoo composite of the present invention, wherein said cationic polymer is selected from: cationic cellulose is poly-Compound, cation melon xanthan polymer, preferred cationic guar polymer of the present invention.
Shampoo composite of the present invention, also contains the pearlescent flake that accounts for composition weight 0.05% to 3.0%.
Containing a mild shampoo for APG hydroxypropyl sodium phosphate copolymer, its component and content are:
| Component | Content % by weight |
| Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer (40%) | 28.4 |
| Ethoxylated dodecyl alcohol sodium sulphate (70%) | 1.8 |
| Cation guar gum | 0.3 |
| Coconut monoethanol amide | 1.5 |
| Pearlescent flake | 1.5 |
| Disodium ethylene diamine tetraacetate | 0.1 |
| Citric acid, anticorrisive agent, colouring agent, spices, sodium chloride | In right amount |
| Water | Add to 100% |
Compared with prior art, the present invention has the following advantages:
The large outstanding feature of mild shampoo one of the present invention has adopted a kind of APG hydroxypropyl phosphoric acid exactlySodium copolymer is that first type surface activating agent uses, and this first type surface activating agent is at alkane based on APG deriving technologyOn base glucoside or glycan molecule bonding hydroxypropyl phosphoric acid and live in a kind of novel anionic surface that obtainsProperty agent, this new nonionic surfactant will have traditional alkyl-glucoside (APG) gentleness concurrentlyWith the characteristic of foam and the good capillary ability of reduction of anion surfactant. In hair washingIn shampoo formula, can serve as that first type surface activating agent uses separately or with traditional sulfate type anionic surfaceActivating agent is used in conjunction with, and greatly reduces the consumption of the sulfate type anion surfactant of tradition use,Make the cleaning capacity of shampoo, spumescence and mildness are all improved. In addition, large molecule polyphosphoric acidThe polyglycoside surfactant activating agent of ester structure also has protection scalp and hair in the clean hair of gentlenessEffect, pH faintly acid formula, the exploitation of more suitable configuration children adacrya hair washing formula.
Detailed description of the invention
To be elaborated to compositional selecting of the present invention and effect below.
In mild shampoo of the present invention, containing the first type surface activating agent that accounts for mild shampoo weight 5.0% to 40% is,This first type surface activating agent is APG hydroxypropyl sodium phosphate copolymer and alkyl polyoxyethylene ether sodium sulphateComposition, or the composition of APG hydroxypropyl sodium phosphate copolymer and sodium alkyl sulfate, or alkaneThe composition of base glucosides hydroxypropyl sodium phosphate copolymer and alkyl polyoxyethylene ether ammonium sulfate, or alkyl sugarThe composition of glycosides hydroxypropyl sodium phosphate copolymer and alkylsurfuric acid ammonium, a preferred scheme in the present inventionThat APG hydroxypropyl sodium phosphate copolymer and alkyl polyoxyethylene ether sodium sulphate are used in combination. ThisInvention sodium alkylether sulphate is that alkylpolyoxyethylene sodium sulphate is called for short AES, and its structural formula isRO(CH2CH2O)nSO3Na，R=C12-C18Alkyl, n is 2-4, preferably average ethoxyquin degree is n=3.The active matter content of described alkylpolyoxyethylene sodium sulphate commercially available prod has 25% and 70% two kind,The alkylpolyoxyethylene sodium sulphate of 25% active matter content is water white transparency thick liquid, and 70% livesProperty thing content alkylpolyoxyethylene sodium sulphate be white or faint yellow pastel, preferably activeThing content is 70% alkylpolyoxyethylene sodium sulphate. Described alkylpolyoxyethylene sulfuric acidSodium also has the characteristic of non-ionic surface active agent, still has good dirt-removing power in hard water.
In the present invention, in APG hydroxypropyl sodium phosphate copolymer surfactants structure, contain multiple phasesSame hydrophobic group and multiple identical hydrophilic group can form micella and show good under low concentrationThe capillary ability of reduction, this material is the anion form based on poly alkyl-glucoside structureSurface-active agent, has good biological degradability and excitant low, to skin, eyes especially temperatureWith, in shampoo, can be used as first type surface activating agent use, also can with sulfate type anion formSurface-active agent, as the composite use of laruyl alcohol polyoxy ether sodium sulphate, can produce good cooperative effect,Can be used as children or baby have one's hair wash cleaning products use.
In the present invention, APG hydroxypropyl sodium phosphate copolymer comprises and is selected from Plantacare APG 1200G hydroxypropylBase sodium phosphate copolymer or cocoyl glucosides hydroxypropyl sodium phosphate copolymer, its molecular structural formula is as follows（1）：
In molecular structural formula (I), R represents alkyl, and its carbon number is 8 to 22; N be betweenThe integer of 4-6. In the present invention, R is selected from respectively C12Lauryl or C8-C18Cocoyl, R of the present inventionPreferably C12Lauryl.
In the present invention, APG hydroxypropyl sodium phosphate copolymer comprises and is selected from Plantacare APG 1200G hydroxypropylSodium phosphate copolymer and cocoyl glucosides hydroxypropyl sodium phosphate copolymer. By great many of experiments, the present inventionPeople's discovery, the APG hydroxypropyl sodium phosphate copolymer that is selected from lauryl glucoside can be independentFirst type surface activating agent as shampoo uses, can also be multiple with sulfate type anion surfactantJoin use, there is splendid gentle characteristic, and it is alive to greatly reduce sulfate type anionic surfaceThe consumption of property agent. In the present invention, Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and dodecyl polyoxyVinethene sodium sulphate has best while arranging in pairs or groups use according to the ratio of weight ratio 10:1 to 2:1Synergy.
Shampoo of the present invention, the preferred Plantacare APG 1200G hydroxypropyl of APG hydroxypropyl sodium phosphate copolymerBase sodium phosphate copolymer. The Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer that the present invention uses, comes from manyPoly-alkyl glucose (APG for short non-ionic surface active agent), and pass through alkyglycosides APGThe chemically derived natural derivative with anionic ion attribute that produced of skeleton. With respect to nonionicAPG precursor, there is the alkyglycosides polymer of anion attribute not only to hair and scalp temperatureWith, also there is the ability at low concentration decline low surface tension, therefore, can be used as shampooFirst type surface activating agent uses separately, and uses also tool with the collocation of sulfate type anion surfactantThere is synergy, and greatly reduce the use amount of sulfate type anion surfactant, in structureGlycan molecule and phosphate molecule can reduce the direct stimulation of traditional sulfate type anion surfactantProperty, be specially adapted to configure shampoo for children and use.
APG hydroxypropyl sodium phosphate copolymer physicochemical property of the present invention: active quantities (solid content):40%, pH(10% solution) 7.8, color Gardner≤1, Roche foam height (1% active matter)mm150；
Mild shampoo of the present invention also comprises a kind of steady foaming agent, is selected from carbon 10 to carbon 181,2-alkyl 2Alcohol, or fatty alkanolamide comprises fatty MEA and fatty diethanol amide. The present invention preferably makesWith coconut monoethanol amide, as foam stabilizer, it is hundred that coconut monoethanol amide accounts for composition weight percentage/ 0.5 to percent 5, be further optimized for percent 1 to percent 3.
Cationic polymer described in the present invention is selected from quaternized cellulose ethers derivative, also referred to as sunIon fiber element, as the JR-400 of Tao Shi, LR400, cationic cellulose polymer is hydroxy ethyl fiberThe copolymer of element and alkyl trimethyl ammonium chloride, can be divided into according to the difference of cation substitution value: GaoyangIon substitution value JR, middle cation substitution value LR and tri-kinds of models of low cation substitution value LK, preferablyThe cationic cellulose polymer of high-cation substitution value, i.e. Polyquaternium-10; And diallyl 2The copolymer of ammonio methacrylate salt homopolymers and diallyl 2 ammonio methacrylate salt and acrylamide, asPoly-ammonium salt-6 of Merquat100 of Merck & Co., Inc. and poly-ammonium salt-7 of Merquat550, BASF public affairsDiallyl alkyl dimethyl ammonium chloride/the acrylamide copolymer (SALCARESuper7) of department, BASFAcrylamide propyl trimethyl ammonium chloride/the acrylamide copolymer (SALCARESC60) of company; WithAnd cationization polysaccharide is as the guar gum of cationization, cation is selected from 2,3-glycidyl threeAmmonio methacrylate. Cation guar gum, as sieve sub-JaguarC13S, JaguarC14S, or (firstBase) selective crosslinking homopolymers and the copolymer of acryloyl ethyoxyl trimethyl ammonium chloride, as its people are formed sedimentThe SalcareSC92 of powder, a kind of cationic solution that is dispersed in content in mineral oil percent 50(cross-linked copolymer of methacryl ethyoxyl trimethyl ammonium chloride and acrylamide), and SalcareSC95 (cross-linked homopolymer of methacryl ethyoxyl trimethyl ammonium chloride). Sun of the present invention fromSub-melon glue is by the product obtaining after quaternized melon glue, and its key component is melon glue propyl group front threeAmmonium chloride, can obtain a series of cation melon glue product according to the difference of substitution value, preferably getsDai Du is 0.1 to 0.2, and for cation melon glue of the present invention, under 25 DEG C of conditions, it is 1% water-solubleThe viscosity of liquid is 2000mPa.s to 4000mPa.s.
According to the present invention, it is hundred that preferred cationic melon xanthan polymer of the present invention accounts for composition weight percentage/ 0.005 to percent 1, be further optimized for 0.05 percent to percent 0.3.
Mild shampoo of the present invention also contains the pearlescent flake that accounts for composition weight 0.05% to 3.0%, described pearlMating plate is ethylene glycol monostearate and EGDS. Adding of described pearlescent flake, canGive the pearl effect that shampoo is beautiful.
Mild shampoo of the present invention can also comprise other optional components, comprise viscosity-controlling agent, chelating agent,PH adjusting agent, anticorrisive agent, pigment and spices etc. Described viscosity-controlling agent accounts for 0.1% of composition weightTo 5.0%, the non-limiting example of described viscosity-controlling agent has: sodium chloride, ammonium chloride, MEAChloride, cellulose derivative, acrylic copolymer etc. Described chelating agent accounts for 0.01% of composition weightTo 0.30%, the non-limiting example of described chelating agent has: ethylenediamine tetra-acetic acid, ethylenediamine tetra-acetic acid twoSodium, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferably ethylenediamine tetra-acetic acidDisodium; The non-limiting example of described pH adjusting agent has: citric acid, phosphoric acid etc., and optimization citric acid,The pH of regulation system is 4.0 to 6.0, and preferably 4.5 to 5.5; Described anticorrisive agent, essence, pigmentChoose, meet the regulation of hygienic standards for cosmetics, select safe raw material.
In mild shampoo of the present invention, except the above component, water is mended to aequum.
Preparation method
Shampoo of the present invention can by any known or other be effectively applicable to provide shampoo compositeTechnology preparation, the method for preparing shampoo composite of the present invention comprises conventional preparation and hybrid technology.
Using method
Mild shampoo of the present invention uses in the mode clean and conditioning hair of routine, mainly comprises followingSeveral steps:
(A) water is wetting by hair;
(B) on described hair, use the shampoo composite of the aforementioned any one claim of effective dose,The scope of described effective dose is generally 1 gram to 50 grams, preferably 2 to 20 grams;
(C) with the shampoo composite on hair described in water rinse.
These steps can be as required repeatedly, to reach look for clean, conditioning, to moistenEffect with moisturizing.
Embodiment
The non-limiting example of shampoo composite of the present invention below. These embodiment only provideBe for illustrative purposes, can not be interpreted as limitation of the invention, because do not departing from the present inventionThe basis of spirit and scope on, can carry out many changes to the present invention. In these embodiments,Unless stated otherwise, all concentration is all percentage by weight. Term used " a small amount of material " refers toThose optional materials, as anticorrisive agent, viscosity modifier, pH adjusting agent, spices, pigment etc.,The selection of these a small amount of materials by along with selected in order to prepare physics and the change of special component of the present inventionLearn characteristic and change.
Preparation Example I-X V
Described in suitable Preparation Example I-X V, the method for shampoo composite is as follows: by suitable quantity of waterJoin in retort, under slowly stirring, add cation melon and glue disperses, in slow stirringBe heated to 60 DEG C to 80 DEG C, then need to add respectively APG hydroxypropyl sodium phosphate altogether according to formulaPolymers, lauryl sulfate, Sodium dodecylpolyoxyethylene sulfate, pearlescent flake, ethylenediamine tetraaceticAcetic acid disodium (if using these materials), makes these materials disperse rear cooling completely. Treat that temperature is down toWhen 45 DEG C of left and right, add sodium chloride, citric acid, anticorrisive agent, pigment, essence etc. to continue to stir, guaranteeObtain uniform mixture. Adding after all components, can add as required viscosity modifier andPH adjusting agent, the viscosity of adjusting product, finally adjusts to 4.5-5.5 by pH. Optionally finally canAdd a small amount of water to supply.
Embodiment I-V
Embodiment VI-X
Foam height method of testing: adopt the method for testing of Roche (Ross--Miles) foamer meter to enterRow test, tests respectively initial foam height, foam height and foam height after 5 minutes after 1 minute,Then average. Can find out from the embodiment of the present invention: shampoo formula, live in main and auxiliary surfaceIn the approximate situation of the conditions such as property agent active quantities and cationic polymer, shampoo of the present invention adoptsTaking Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer and lauryl alcohol sulfate as first type surface activating agentThe foam height of formula is all greater than taking traditional aliphatic alcohol sulfate and fatty alcohol ether sulphate composition as mainThe foam height of surfactant formula, in table 1.
H50Value mildness method of testing: adopt erythrocyte hemolysis experiment (RedbloodcelltestRBC)Method, the method is one of Draize experiment alternative, general principle is to measure chemicals to cellThe change of the damage of film and the cell membrane permeability that therefore causes, spills from red blood cell by measuringThe amount of hemoglobin is evaluated the degree of injury of cell membrane, and the excitant of this degree of injury and product hasDirectly related property. Mainly RBC experiment is used in the world to the eye of the chemicals such as cosmetic product and raw materialExcitant research. Therefore the present invention passes through the mildness with erythrocyte hemolysis determination of experimental method formula,And formation contrast, test products mildness. Concrete grammar is: use spectrophotometry chemicalsThe absorbance of the red cell suspension after effect, can calculate hemolysis rate and H50Value (even 50% red blood cellThere is the concentration value of the tested material of haemolysis). H50Be worth littlely, add the sample of small amount just can occur obviousHaemolysis, show that sample stimulus is large, mildness is poor. H50Value is large, shows that sample stimulus is little,Mildness increases. In the present invention, along with Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer weight in formulaThe increase of percentage, H50Value also increases thereupon, shows that mildness increases, in table 1.
Eyes comfortableness clinical trial method:
Eyes Comfort Evaluation method is: Preparation Example 1-10 is issued respectively to 60 testersUse. When tester uses shampoo sample, according to identical method hair washing, every kind of shampoo usesOne week (washing once at interval of two days), tester according to oneself feel mark, standards of grading are adoptedBy 7 points of systems, 1 point (eyes shed tears or red and swollen) representative is the poorest, 7 points (eyes are comfortable, without any insteadShould) represent preferably, the higher effect of mark is more good. Show this by above eyes Comfort EvaluationThe more traditional shampoo of invention mild shampoo has obvious superiority. Evaluation result is in table 2.
Table 1 foam height and H50Value (mildness)
Table 2 eyes comfort evaluation statistics
Claims (6)
1. containing a mild shampoo for APG hydroxypropyl sodium phosphate copolymer, remove and contain perfume (or spice)Ripple can be accepted outside component, and this shampoo also contains:
(A): account for the first type surface activating agent of mild shampoo weight 5.0% to 40%, this first type surface is livedProperty agent is APG hydroxypropyl sodium phosphate copolymer and ethoxylated dodecyl alcohol sodium sulphateComposition, and APG hydroxypropyl sodium phosphate copolymer and ethoxylated dodecyl alcohol sodium sulphateWeight ratio be 10:1 to 2:1;
(B) account for the cation guar gum of mild shampoo weight 0.05% to 0.5%;
(C) account for the coconut monoethanol amide of mild shampoo weight 1.0% to 3.0%;
Wherein, APG hydroxypropyl sodium phosphate copolymer, its molecular structural formula following (I):
In molecular structural formula (I), R represents alkyl, and its carbon number is 8 to 22; N isBetween the integer of 4-6.
2. shampoo according to claim 1, APG hydroxypropyl sodium phosphate wherein altogetherIn polymers, R is selected from C12Lauryl or C8-C18Cocoyl.
3. shampoo according to claim 1, APG hydroxypropyl sodium phosphate wherein altogetherPolymers is Plantacare APG 1200G hydroxypropyl sodium phosphate copolymer.
4. shampoo according to claim 3, wherein said Plantacare APG 1200G hydroxypropyl phosphorusThe part by weight 10:1-2:1 of acid sodium copolymer and ethoxylated dodecyl alcohol sodium sulphate.
5. shampoo according to claim 1, its pH value is 4.5-5.5.
6. containing the mild shampoo of APG hydroxypropyl sodium phosphate copolymer, its component andContent is:
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