CN101342118A - Shampoo composition for removing dandruff - Google Patents
Shampoo composition for removing dandruff Download PDFInfo
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- CN101342118A CN101342118A CNA2008101982562A CN200810198256A CN101342118A CN 101342118 A CN101342118 A CN 101342118A CN A2008101982562 A CNA2008101982562 A CN A2008101982562A CN 200810198256 A CN200810198256 A CN 200810198256A CN 101342118 A CN101342118 A CN 101342118A
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Abstract
The invention relates to a dandruff removal shampoo composition, which contains: (A) anionic surfactants accounting for 5.0 percent to 40 percent of the composition weight, (B) amphoteric surfactants accounting for 1.0 percent to 10.0 percent of the composition weight, (C) bipyridine thione accounting for 0.1 percent to 2.0 percent of the composition weight, (D) conditioners accounting for 0.25 percent to 3.5 percent of the composition weight, (E) pearlescing agents accounting for 0.25 percent to 3.5 percent of the composition weight and (F) water of the rest. The dandruff removal shampoo composition of the invention adopts a novel dandruff removal agent of bipyridine thione, and can effectively remove the dandruff; the problem of dry hair usually caused by the dandruff removal shampoo is solved.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of anti-dandruff shampoo composition.
Background technology
Anti-dandruff dose that uses always in the anti-dandruff shampoo at present mainly contains: Zinc Pyrithione; octopirox; climbazole; the endecatylene acid derivative; ketoconazole; salicylic acid etc.; wherein Zinc Pyrithione is a kind of anti-dandruff and itching-relieving agent efficiently and wide-spectrum bactericide; also be one of anti-dandruff dose of being most widely used at present; but it is applied in the shampoo formula; sedimentation appears through regular meeting; careless manipulation also metachromatism can occur once in a while; it is also easy to change that it meets iron ion; Zinc Pyrithione and disodiumedetate are incompatible; and to photo-labile; can hide the pearly-lustre of shampoo, its maximum shortcoming is that degreasing power is strong, and life-time service can cause problems such as hair dries up.Octopirox is met ferrum, the easy flavescence of copper ion, and costs an arm and a leg, and other several anti-dandruff dose anti-dandruff effect can not meet the demands.Novel anti-dandruff dose of two pyrithione can effectively be killed ovum shape Testa oryzae rash tinea bacterium, multiple funguses such as ovum shape sporeformer, candida albicans, its sensitivity to metal ion is little, colour stability in the shampoo system improves, its good water solubility can be improved composite effect, brings into play fungicidal effectiveness to greatest extent, and a little less than its degreasing power, it is a kind of comparatively ideal anti-dandruff dose.
Summary of the invention
The purpose of this invention is to provide a kind of anti-dandruff shampoo composition, adopt novel anti-dandruff dose of two pyrithione, can remove dandruff effectively, and solve problems such as the hair that common anti-dandruff shampoo caused dries up.
Anti-dandruff shampoo composition of the present invention comprises: the anion surfactant that (A) accounts for composition weight 5.0% to 40%; (B) account for the amphoteric surfactant of composition weight 1.0% to 10.0%; (C) account for two pyrithione of composition weight 0.1% to 1.5%; (D) account for the conditioner of composition weight 1.0% to 10.0%; (E) account for the pearling agent of composition weight 0.25% to 3.5%; (F) surplus is a water.
Anti-dandruff shampoo composition of the present invention, wherein said anion surfactant is selected from: at least a in aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate, glycerine monofatty ester sulfate, fatty alcohol radical sulfosuccinate ester salt, fatty acyl glutamate, Glu, the N-acyl glutamate.
Anti-dandruff shampoo composition of the present invention, wherein said anion surfactant are aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate compositions.
Anti-dandruff shampoo composition of the present invention, wherein said amphoteric surfactant is selected from: at least a in betanin derivative and the both sexes sodium acetate.
Anti-dandruff shampoo composition of the present invention, wherein said amphoteric surfactant are the compositionss of cocamidopropyl propyl amide hydroxyl sulphur betanin and lauryl both sexes sodium acetate.
Anti-dandruff shampoo composition of the present invention, wherein said pair of pyrithione is anti-dandruff dose, its structural formula is (I).
Anti-dandruff shampoo composition of the present invention, wherein said conditioner is selected from: at least a in cationic cellulose polymer, cation melon xanthan polymer and the polydimethylsiloxane.
Anti-dandruff shampoo composition of the present invention, wherein said conditioner are the compositionss of cationic cellulose polymer and polydimethylsiloxane.
Anti-dandruff shampoo composition of the present invention, wherein said pearling agent is selected from: at least a in ethylene glycol stearate monoesters and dibasic acid esters, fatty acid metal salts, monostearate nuclear Palmic acid propylene glycol ester, higher fatty acids alkylolamides, aliphatic alcohol, stearate acid zinc and magnesium stearate, fine dispersive zinc oxide and titanium dioxide, the Magnesiumaluminumsilicate.
Anti-dandruff shampoo composition of the present invention, wherein said pearling agent are ethylene glycol stearate monoesters and dibasic acid esters.
Anti-dandruff shampoo composition of the present invention is characterized in that said composition also comprises the quaternary ammonium salt cationic surfactant that accounts for composition weight 0.25% to 8.0%.
Anti-dandruff shampoo composition of the present invention is characterised in that it comprises: the anion surfactant that (A) accounts for composition weight 8.0% to 30%; (B) account for the amphoteric surfactant of composition weight 2.0% to 8.0%; (C) account for two pyrithione of composition weight 0.2% to 1.0%; (D) account for the conditioner of composition weight 2.0% to 8.0%; (E) account for the pearling agent of composition weight 0.5% to 3.0%; (F) surplus is a water.
To be elaborated to component selection of the present invention and effect below.
Contain in the anti-dandruff shampoo composition of the present invention and account for composition weight 5.0% to 40%, preferred 10% to 30% the suitable anion surfactant component that is used on hair or the skin.Described anion surfactant is selected from; at least a in aliphatic alcohol sulfate, fatty alcohol ether polyoxyethylene sulfate, glycerine monofatty ester sulfate, fatty alcohol radical sulfosuccinate ester salt, fatty acyl glutamate, Glu, the N-acyl glutamate, preferred fat alcohol sulfate, fatty alcohol ether polyoxyethylene sulphate complex.Described aliphatic alcohol sulfate structural formula is: ROSO
3M, wherein M=Na
+, K
+, [HN (CH
2CH
2OH)
3]
+, [H
2N (CH
2CH
2OH)
2]
+, [H
2NCH
2CH
2OH]
+, NH
4 +, R=C
12～C
18Alkyl, preferred M=NH
4 +, R=C
12, i.e. lauryl alcohol ammonium sulfate; Described fatty alcohol ether polyoxyethylene sulfate structural formula is RO (CH
2CH
2O)
nSO
3M, wherein M=Na
+, NH
4 +, [H (C
2H
5OH)
3]
+, R=C
12～C
18Alkyl, n are 2～4, and preferred average ethoxyquin degree is n=3, M=NH
4 +, R=C
12, i.e. lauryl alcohol ether polyoxyethylene ammonium sulfate; Described glycerine monofatty ester sulfate structural formula [RCOOCH
2CH (OH) CH
2OSO
3M], M=Na wherein
+, NH
4 +Deng, R=C
12～C
18Alkyl, preferred M=NH
4 +, R=C
12, i.e. lauric acid monoglyceride ammonium sulfate; Typical case's representative of described fatty alcohol radical sulfosuccinate ester salt is lauryl 2-Sulfosuccinic acid ester ammonium salt, lauryl 2-Sulfosuccinic acid ester sodium salt, laureth sulfosuccinate disodium; Described fatty acyl glutamate, Glu structural formula is [RCONHCH (COOH) CH
2CH
2COOM], M=Na wherein
+, NH
4 +Deng, R=C
12～C
18Alkyl, preferred M=Na
+, R=C
12, i.e. sodium lauroyl glutamate; Typical case's representative of described N-acyl glutamate is N-coconut sodium glutamate acyl, N-sodium lauroyl glutamate, N-myristoyl sodium glutamate, N-Cortex cocois radicis acyl glutamic acid list triethanolamine salt etc., preferred N-sodium lauroyl glutamate.
Contain in the anti-dandruff shampoo composition of the present invention and account for composition weight 1.0% to 10.0%, preferred 2.0% to 8.0% the suitable amphoteric surfactant component that is used on hair or the skin.Described amphoteric surfactant is at least a in betanin and derivant and the both sexes sodium acetate.Described betanin derivative comprises coco dimethyl betanin, cocamido propyl betaine, dodecanamide propyl betanin, cocamidopropyl propyl amide hydroxyl sulphur betanin, lauramide hydroxyl sulphur betanin, preferred lauramide hydroxyl sulphur betanin; Described both sexes sodium acetate comprises cocoyl both sexes sodium acetate and lauryl both sexes sodium acetate, preferred lauryl both sexes sodium acetate.
Contain in the anti-dandruff shampoo composition of the present invention and account for composition weight 0.1% to 1.5%, two pyrithione of preferred 0.2% to 1.0%.The structural formula of described pair of pyrithione is (I), this chemical compound has antimicrobial activity, effective to many Glan formula positives and negative bacterium and many mycetes and yeast, preferably pair pyrithione is that white is to brown suspension, particulate mean diameter is at most 20 μ m, preferably is at most 5 μ m.
Anti-dandruff shampoo composition of the present invention comprises and accounts for composition weight 1.0% to 10.0%, preferred 2.0% to 8.0% be applicable to conditioner on hair and the skin.Wherein said conditioner is selected from: one or more compositionss in cationic cellulose polymer, cation melon xanthan polymer, the polydimethylsiloxane, the compositions of preferred cationic cellulosic polymer and polydimethylsiloxane.Described cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, difference according to the cation substitution value can be divided into: high-cation substitution value JR, middle-jiao yang, function of the spleen and stomach ionic replacement degree LR and three kinds of models of low cation substitution value LK, the cationic cellulose polymer of preferred high-cation substitution value, be polyquaternary ammonium salt-10, other is suitable for the copolymer that cationic cellulose polymer of the present invention also has hydroxyethyl-cellulose and dialkyl dimethyl ammonium chloride; Described cation melon glue is the product that melon glue is obtained after quaternized, its key component is a melon glue oxypropyl trimethyl ammonium chloride, difference according to substitution value can obtain a series of cation melon glue product, preferred substitution value is 0.1 to 0.2, be used for cation melon glue of the present invention under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s, and its consumption is 0.02% to 3.0%, preferred again 0.05% to 1.0%; Described polydimethylsiloxane is non-volatile polydimethylsiloxane, and its consumption is 0.5% to 10%, preferred 1.0% to 8.0%.Being used for polydimethylsiloxane of the present invention also can be its commercially available pre-emulsifying form, is used for the viscosity that emulsified silicone oil of the present invention records and is preferably 100mPa.s to 2500000mPa.s under 25 ℃, preferred again 500mPa.s to 1500000mPa.s.Select big particle diameter emulsified silicone oil and small particle diameter emulsified silicone oil to be used, improve the dried cardability and the wet cardability of shampoo, described big particle diameter emulsified silicone oil number average particle diameter is at 10 μ m to 30 μ m, preferred 15 μ m to 25 μ m; Described small particle diameter emulsified silicone oil number average particle diameter is at 0.01 μ m to 5 μ m, preferred 0.01 μ m to 2 μ m.Other is applicable to that conditioner of the present invention gets non-limiting example and also has: L-sodium lactate, Oleum Ricini maleic acid glyceride, quaternary ammonium salt-82, different hard ester group ethyl imidazol(e) ethoxy sulfate, Fructus Hordei Germinatus amido propyl ammonio methacrylate etc.
Contain in the anti-dandruff shampoo composition of the present invention and account for composition weight 0.25% to 3.5%, preferred 0.5% to 3.0% the suitable pearling agent that is used on hair or the skin.Described pearling agent is selected from: at least a in ethylene glycol stearate monoesters and dibasic acid esters, fatty acid metal salts, monostearate nuclear Palmic acid propylene glycol ester, higher fatty acids alkylolamides, aliphatic alcohol, stearate acid zinc and magnesium stearate, fine dispersive zinc oxide and titanium dioxide, the Magnesiumaluminumsilicate, preferred ethylene glycol stearate monoesters and dibasic acid esters.
Anti-dandruff shampoo composition of the present invention also comprises and accounts for composition weight 0.25% to 8.0%, preferred 0.5% to 5.0% quaternary ammonium salt cationic surfactant, described quaternary sun comprises from the indefiniteness embodiment of surfactant: alkyl benzyl dimethyl ammonium salt, natural oil base Propylamino benzyl dimethyl ammonium salt, alkyl trimethyl quaternary ammonium salt, two alkyl-dimethyl based quaternary ammonium salts etc., preferred alkyl trimethyl quaternary ammonium salt.
Anti-dandruff shampoo composition of the present invention can also comprise other optional components, comprises viscosity-controlling agent, chelating agen, pH regulator agent, antiseptic, pigment and spice etc.Described viscosity-controlling agent accounts for 0.10% to 5.0% of composition weight, and the non-limiting example of described viscosity-controlling agent has: anionic thickener, C such as electrolyte such as sodium chloride, ammonium chloride, monoethanolamine chloride, diethanolamine chloride, sodium sulfate, ammonium sulfate, disodium hydrogen phosphate, phosphoric acid five sodium and polyglycol distearate, polyethylene glycol mono stearate, polyethylene glycol dilaurate, Carboxymethyl cellulose sodium, hydroxyethyl-cellulose, hydroxypropyl emthylcellulose, acrylic acid/polyoxyethylene (20) octadecanol ether methyl acid copolymer, acrylic copolymer
10Poly-carbamyl macrogol ester, Polyethylene Glycol, polyvinylpyrrolidone etc.; Described chelating agen accounts for 0.01% to 0.30% of composition weight, the non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferred disodiumedetate; The non-limiting example of described pH regulator agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system are 5.0 to 8.0, and preferred 5.5 to 6.5; Choosing of described antiseptic, essence, pigment meets the regulation of hygienic standards for cosmetics, selects safe raw material for use.
In the anti-dandruff shampoo composition of the present invention, except the above component, water is mended to aequum.
Compared with prior art, the present invention has the following advantages:
Adopt novel anti-dandruff dose of two pyrithione, can remove dandruff effectively, and solve problems such as the hair that common anti-dandruff shampoo caused dries up.
Preparation method
Anti-dandruff shampoo composition of the present invention can by any known or other effectively be applicable to the technology preparation that shampoo composite is provided, the method for preparing anti-dandruff shampoo composition of the present invention comprises conventional preparation and hybrid technology.
Using method
Anti-dandruff shampoo composition of the present invention uses with the cleaning of routine and the mode of conditioning hair, mainly comprises following step:
(A) water is with the hair moistening;
(B) use the shampoo composite of aforementioned each claim of effective dose on described hair, the scope of described effective dose is generally 1 gram to 50 grams, preferred 2 to 20 grams;
(C) with the shampoo composite on the described hair of water rinse.
These steps can repeat repeatedly as required, to reach the cleaning looked for and anti-dandruff effect.
Embodiment
Be the non-limiting example of anti-dandruff shampoo composition of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration all is percentage by weight.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, pH regulator agent, spice, pigment etc., the selection of these small amount of matter will change in order to the physics for preparing special component of the present invention and chemical characteristic along with selected.
Preparation example I-X
The suitable method for preparing anti-dandruff shampoo composition described in example I-X is as follows: suitable quantity of water is joined in the retort, adding polyquaternary ammonium salt-10 under slowly stirring disperses, slowly be stirred and heated to 60 ℃ to 80 ℃, then add pH regulator agent (for example citric acid), Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, the cocamidopropyl propyl amide hydroxy sulfo lycine, lauryl both sexes sodium acetate, fatty monoethanol amide, the cetyl trimethyl ammonium chloride, pearlescent flake, disodiumedetate (if using these materials) makes these materials disperse the back cooling fully.Treat to add when temperature is reduced to 65 ℃ of left and right sides anti-dandruff dose of two pyrithione, be cooled to after being uniformly dispersed below 50 ℃ add polydimethylsiloxane, nourishing additive agent is uniformly dispersed, add antiseptic, pigment, essence etc. again and continue to stir, guarantee to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, the viscosity and the pH that regulate product arrive suitable degree.Randomly can add low amounts of water at last supplies.
Example I-V
Weight (%)
Component
I II III IV V
Laurel alkyl ammonium sulfate (70%) 8.0 8.0 8.0 8.0 8.0
Polyoxyethylene lauryl ether ammonium sulfate (70%) 10.0 10.0 12.0 12.0 12.0
Cocamidopropyl propyl amide hydroxyl sulphur betanin 6.0 6.0 6.0 6.0 6.0
Lauryl both sexes sodium acetate 2.0 2.0 2.0 3.0 3.0
Cetyl trimethyl ammonium chloride 0.6 0.6 0.6 0.6 0.6
Polyquaternary ammonium salt-10 0.2 0.2 0.2 0.2 0.2
Pearlescent flake 1.5 1.5 1.5 1.5 1.5
Disodiumedetate 0.1 0.1 0.1 0.1 0.1
Two pyrithione 0.2 0.3 0.4 0.6 0.8
Polydimethylsiloxane 2.0 2.0 2.5 2.5 2.5
Citric acid, antiseptic, coloring agent, spice, sodium chloride are an amount of
Water adds to 100%
Example VI-X
Weight (%)
Component
VI VII VIII IX X
Laurel alkyl ammonium sulfate (70%) 6.0 6.0 6.0 6.0 6.0
Polyoxyethylene lauryl ether ammonium sulfate (70%) 10.0 10.0 12.0 12.0 14.0
Cocamidopropyl propyl amide hydroxyl sulphur betanin 6.0 6.0 5.0 5.0 5.0
Lauryl both sexes sodium acetate 2.0 2.0 3.0 3.0 3.0
Cetyl trimethyl ammonium chloride 0.6 0.6 0.6 0.6 0.6
Polyquaternary ammonium salt-10 0.2 0.2 0.2 0.2 0.2
Pearlescent flake 1.5 1.5 1.5 1.5 1.5
Disodiumedetate 0.1 0.1 0.1 0.1 0.1
Two pyrithione 0.2 0.5 0.6 0.7 1.0
Polydimethylsiloxane 3.0 3.0 3.0 3.0 3.0
Citric acid, antiseptic, coloring agent, spice, sodium chloride are an amount of
Water adds to 100%
Claims (12)
1. the present invention relates to a kind of anti-dandruff shampoo composition, contain in this shampoo: the anion surfactant that (A) accounts for composition weight 5.0% to 40%; (B) account for the amphoteric surfactant of composition weight 1.0% to 10.0%; (C) account for two pyrithione of composition weight 0.1% to 1.5%; (D) account for the conditioner of composition weight 1.0% to 10%; (E) account for the pearling agent of composition weight 0.25% to 3.5%; (F) surplus is a water.
2. anti-dandruff shampoo composition according to claim 1, wherein said anion surfactant is selected from: at least a in aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate, glycerine monofatty ester sulfate, fatty alcohol radical sulfosuccinate ester salt, fatty acyl glutamate, Glu, N-acyl glutamate, the alkyl phosphate salt.
3. anti-dandruff shampoo composition according to claim 2, wherein said anion surfactant are aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate compositions.
4. anti-dandruff shampoo composition according to claim 1, wherein said amphoteric surfactant is selected from: at least a in betanin derivative and the both sexes sodium acetate.
5. anti-dandruff shampoo composition according to claim 4, wherein said amphoteric surfactant are the compositionss of cocamidopropyl propyl amide hydroxyl sulphur betanin and lauryl both sexes sodium acetate.
6. according to the described anti-dandruff shampoo composition of item claim 1, wherein said pair of pyrithione is anti-dandruff dose, and its structural formula is (I).
7. anti-dandruff shampoo composition according to claim 1, wherein said conditioner is selected from: at least a in cationic cellulose polymer, cation melon xanthan polymer and the polydimethylsiloxane.
8. anti-dandruff shampoo composition according to claim 7, wherein said conditioner are the compositionss of cationic cellulose polymer and polydimethylsiloxane.
9. anti-dandruff shampoo composition according to claim 1, wherein said pearling agent is selected from: at least a in ethylene glycol stearate monoesters and dibasic acid esters, fatty acid metal salts, monostearate nuclear Palmic acid propylene glycol ester, higher fatty acids alkylolamides, aliphatic alcohol, stearate acid zinc and magnesium stearate, fine dispersive zinc oxide and titanium dioxide, the Magnesiumaluminumsilicate
10. anti-dandruff shampoo composition according to claim 9, wherein said pearling agent are ethylene glycol stearate monoesters and dibasic acid esters.
11., it is characterized in that said composition also comprises the quaternary ammonium salt cationic surfactant that accounts for composition weight 0.25% to 8.0% according to the described anti-dandruff shampoo composition of aforementioned each claim.
12. anti-dandruff shampoo composition according to claim 1 is characterised in that it comprises: the anion surfactant that (A) accounts for composition weight 8.0% to 30%; (B) account for the amphoteric surfactant of composition weight 2.0% to 8.0%; (C) account for two pyrithione of composition weight 0.2% to 1.0%; (D) account for the conditioner of composition weight 2.0% to 8.0%; (E) account for the pearling agent of composition weight 0.5% to 3.0%; (F) surplus is a water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101982562A CN101342118A (en) | 2008-09-02 | 2008-09-02 | Shampoo composition for removing dandruff |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101982562A CN101342118A (en) | 2008-09-02 | 2008-09-02 | Shampoo composition for removing dandruff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101342118A true CN101342118A (en) | 2009-01-14 |
Family
ID=40244313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008101982562A Pending CN101342118A (en) | 2008-09-02 | 2008-09-02 | Shampoo composition for removing dandruff |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102018633A (en) * | 2010-12-15 | 2011-04-20 | 广州潮徽化工科技有限公司 | Efficient scurf removing and itch relieving composite as well as preparation method and application thereof in shampoos |
| CN102716045A (en) * | 2012-06-11 | 2012-10-10 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN103445984A (en) * | 2013-08-26 | 2013-12-18 | 拉芳家化股份有限公司 | Mild shampoo containing alkyl glycoside-hydroxypropyl sodium phosphate copolymer |
| CN103520021A (en) * | 2013-08-02 | 2014-01-22 | 拉芳家化股份有限公司 | Conditioning shampoo containing cation-modified alkyl polyglycoside |
| CN106420384A (en) * | 2016-12-27 | 2017-02-22 | 江西宜信堂医疗科技有限公司 | Anti-dandruff itching relieving shampoo and preparation method thereof |
| CN107440935A (en) * | 2017-07-28 | 2017-12-08 | 澳宝化妆品（惠州）有限公司 | A kind of creams hair-washing composition for strengthening anti-dandruff agent deposition |
| CN110709059A (en) * | 2018-12-26 | 2020-01-17 | 拉芳家化股份有限公司 | Dandruff-removing and itching-relieving shampoo composition containing multi-element zinc |
| CN110960463A (en) * | 2019-12-24 | 2020-04-07 | 拉芳家化股份有限公司 | Shampoo composition containing hemp leaf extract composite preparation |
| CN112691049A (en) * | 2021-01-15 | 2021-04-23 | 拉芳家化股份有限公司 | Shampoo composition containing zinc hyaluronate |
| CN112691055A (en) * | 2021-02-09 | 2021-04-23 | 惠州市光大化妆品有限公司 | Anti-dandruff shampoo and preparation method thereof |
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2008
- 2008-09-02 CN CNA2008101982562A patent/CN101342118A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102018633A (en) * | 2010-12-15 | 2011-04-20 | 广州潮徽化工科技有限公司 | Efficient scurf removing and itch relieving composite as well as preparation method and application thereof in shampoos |
| CN102018633B (en) * | 2010-12-15 | 2012-04-25 | 广州潮徽化工科技有限公司 | Efficient scurf removing and itch relieving composite as well as preparation method and application thereof in shampoos |
| CN102716045A (en) * | 2012-06-11 | 2012-10-10 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN102716045B (en) * | 2012-06-11 | 2014-01-15 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN103520021A (en) * | 2013-08-02 | 2014-01-22 | 拉芳家化股份有限公司 | Conditioning shampoo containing cation-modified alkyl polyglycoside |
| CN103520021B (en) * | 2013-08-02 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of cation is modified the conditioner shampoo of alkyglycosides |
| CN103445984A (en) * | 2013-08-26 | 2013-12-18 | 拉芳家化股份有限公司 | Mild shampoo containing alkyl glycoside-hydroxypropyl sodium phosphate copolymer |
| CN103445984B (en) * | 2013-08-26 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer |
| CN106420384A (en) * | 2016-12-27 | 2017-02-22 | 江西宜信堂医疗科技有限公司 | Anti-dandruff itching relieving shampoo and preparation method thereof |
| CN107440935A (en) * | 2017-07-28 | 2017-12-08 | 澳宝化妆品（惠州）有限公司 | A kind of creams hair-washing composition for strengthening anti-dandruff agent deposition |
| CN107440935B (en) * | 2017-07-28 | 2020-10-27 | 澳宝化妆品（惠州）有限公司 | Cream shampoo composition for enhancing deposition of anti-dandruff agent |
| CN110709059A (en) * | 2018-12-26 | 2020-01-17 | 拉芳家化股份有限公司 | Dandruff-removing and itching-relieving shampoo composition containing multi-element zinc |
| CN110960463A (en) * | 2019-12-24 | 2020-04-07 | 拉芳家化股份有限公司 | Shampoo composition containing hemp leaf extract composite preparation |
| CN112691049A (en) * | 2021-01-15 | 2021-04-23 | 拉芳家化股份有限公司 | Shampoo composition containing zinc hyaluronate |
| CN112691049B (en) * | 2021-01-15 | 2022-08-02 | 拉芳家化股份有限公司 | Shampoo composition containing zinc hyaluronate |
| CN112691055A (en) * | 2021-02-09 | 2021-04-23 | 惠州市光大化妆品有限公司 | Anti-dandruff shampoo and preparation method thereof |
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Application publication date: 20090114 |