CN101444462A - Shampoo composite for moderately removing dandruff - Google Patents
Shampoo composite for moderately removing dandruff Download PDFInfo
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- CN101444462A CN101444462A CNA2008102204722A CN200810220472A CN101444462A CN 101444462 A CN101444462 A CN 101444462A CN A2008102204722 A CNA2008102204722 A CN A2008102204722A CN 200810220472 A CN200810220472 A CN 200810220472A CN 101444462 A CN101444462 A CN 101444462A
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- polydimethylsiloxane
- removing dandruff
- shampoo composite
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- dandruff
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Abstract
The invention relates to a shampoo composite for moderately removing dandruff. According to the weight percentage, besides water, the shampoo also comprises (A) 5.0%-50.0% of at least a surfactant with a cleaning function; (B) 0.01%-2.0% of moderate anti-dandruff agent, (C) 0.5-6.0% of viscosity regulator and (D) conditioner composite consisting of the following components: (i) 0.02-1.5% of cation polymer; (ii) 0.05-4.0% of modified polydimethylsiloxane; (iii) 0.2-8.0% of polydimethylsiloxane and; (iv) 0.25-8.0% of cation surfactant. The anti-dandruff shampoo composite employs the moderate anti-dandruff agent and the composite conditioner, thereby being capable of effectively removing the dandruff and meanwhile having good conditioning performance.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of shampoo composite for moderately removing dandruff.
Background technology
On April 17th, 2007, the formal externally issue " Chinese residents scalp health conditions investigation report " of market work councils of China health care association, the survey showed that: in China's 20～55 age brackets, still have 83% consumer to be subjected in various degree dandruff puzzlement.The female consumer that wherein is subjected to the dandruff puzzlement accounts for 82%, and male consumer has 56% respondent to think that dandruff has had influence on their operate as normal and life then up to 84%.The dandruff problem has surpassed alopecia, poliosis, becomes the scalp health problem that China consumer pays close attention to most.The generation of dandruff is often relevant with factors such as some fungi autoeciousness, stress, dietetic nutrition imbalance, hormone, medicines.In shampoo, add the anti-dandruff dose of an amount of effect that can partly reach relieving itching and removing dandruff, anti-dandruff dose that early uses has: selenium sulfide, pyrithione zinc, octopirox, climbazole, the endecatylene acid derivative, ketoconazole, salicylic acid etc., wherein pyrithione zinc is to be developed by U.S. Aoqi Chemical Co., Ltd, and by anti-dandruff dose of drugs approved by FDA use, it is to fungus, antibacterial, virus has very strong killing and inhibitory action, be a kind of anti-dandruff and itching-relieving agent efficiently and wide-spectrum bactericide, but its maximum shortcoming is that degreasing power is strong, and life-time service can cause problems such as hair dries up.Novel anti-dandruff dose of hexamidine two (hydroxyethylsulfonic acid .) salt, be a kind of water miscible anti-various gram-positive bacterias and positive bacteria and various mycete, saccharomycetic cationic material of killing of wide spectrum that have, the ovum shape Testa oryzae rash tinea bacterium that causes scalp pathological changes and dandruff had very strong inhibition and insect killing effect, zest to skin, scalp and eyes is little, and good stability, can variable color, be a kind of good anti-dandruff dose.
Summary of the invention
The anti-dandruff shampoo composition that the purpose of this invention is to provide a kind of gentleness adopts gentle anti-dandruff dose and composite conditioner, when effectively removing dandruff, also has the good conditioning performance.
Shampoo composite for moderately removing dandruff of the present invention, contain in this shampoo:
(A) account for the surfactant of at least a cleaning action of composition weight 5.0% to 50.0%;
(B) account for the moderately removing dandruff agent of composition weight 0.01% to 2.0%;
(C) account for the viscosity-controlling agent of composition weight 0.5% to 6.0%;
(D) conditioner composition composed of the following components,
(i) account for the cationic polymer of composition weight 0.02% to 1.5%;
(ii) account for the modified dimethyl polysiloxane of composition weight 0.05% to 4.0%;
(iii) account for the polydimethylsiloxane of composition weight 0.2% to 8.0%;
(iv) account for the cationic surfactant of composition weight 0.25% to 8.0%; With
(E) surplus is a water.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said surfactant are the compositionss of aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate and betanin derivative.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said aliphatic alcohol sulfate accounts for 2.0%～20.0% of composition weight, described fatty alcohol polyoxyethylene ether sulfate accounts for 2.0%～20.0% of composition weight, and described betanin derivative accounts for 1.0%～10.0% of composition weight.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said moderately removing dandruff agent are hexamidine two (hydroxyethylsulfonic acid .) salt.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said viscosity-controlling agent is selected from: at least a in electrolyte, dihydro Adeps Bovis seu Bubali phthalic acid amide, the polyoxyethylene carboxylate.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said viscosity-controlling agent are dihydro Adeps Bovis seu Bubali phthalic acid amide.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said cationic polymer is selected from: at least a in the polyammonium copolymer of cationic cellulose polymer, cation melon xanthan polymer, dimethyl dialkyl ammonia chloride/allylamine copolymer, ethenyl pyrrolidone alkane and dimethylamino isobutyl ester.
The shampoo composite for moderately removing dandruff that this law is bright, wherein said modified dimethyl polysiloxane is selected from: a kind of in amino modified polydimethylsiloxane, polyether-modified polydimethylsiloxane, Radix Betae base modified dimethyl polysiloxane, the quaternary ammonium salt-modified polydimethylsiloxane.
The shampoo composite for moderately removing dandruff that this law is bright, described polydimethylsiloxane are that polydimethylsiloxane exists with dispersed particles through pre-emulsified.
The shampoo composite for moderately removing dandruff that this law is bright, described emulsifying polydimethylsiloxane are that particle diameter is that small particle diameter polydimethylsiloxane and the particle diameter of 0.01 μ m to 5 μ m is the compositions of the big particle diameter polydimethylsiloxane of 10 μ m to 50 μ m.
The shampoo composite for moderately removing dandruff that this law is bright is characterized in that said composition also comprises the cationic surfactant that accounts for composition weight 0.25% to 8.0%, and described cationic surfactant is a quaternary ammonium salt cationic surfactant.
Shampoo composite for moderately removing dandruff of the present invention, its best composition and content are as follows:
| Component | Content (weight %) |
| Laurel alkyl ammonium sulfate (70%) | 8.0 |
| Polyoxyethylene lauryl ether ammonium sulfate (70%) | 12.0 |
| Cocamido propyl betaine | 5.0 |
| Dihydro Adeps Bovis seu Bubali phthalic acid amide | 1.0 |
| Polyquaternary ammonium salt-10 | 0.4 |
| Pearlescent flake | 1.3 |
| Disodiumedetate | 0.1 |
| Amino modified polydimethylsiloxane | 0.4 |
| Polydimethylsiloxane | 2.0 |
| Two ethyl palmitate alkyl dimethyl ammonium chlorides | 1.5 |
| Hexamidine two (hydroxyethylsulfonic acid .) salt | 0.02 |
| Citric acid, antiseptic, coloring agent, spice, sodium chloride | In right amount |
| Water | Add to 100% |
To be elaborated to component selection of the present invention and effect below.
Contain in the shampoo composite for moderately removing dandruff of the present invention and account for composition weight 5.0% to 50%, preferred 10% to 45% the suitable surfactant that is used at least a cleaning action on hair or the skin.Wherein institute's surfactant is the compositions of anion surfactant and amphoteric surfactant.Described anion surfactant is selected from; at least a in aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate, glycerine monofatty ester sulfate, fatty alcohol radical sulfosuccinate ester salt, fatty acyl glutamate, Glu, the N-acyl glutamate; preferred fat alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate complex; described aliphatic alcohol sulfate accounts for 2.0%～20.0% of composition weight, and described aliphatic alcohol sulfate structural formula is: ROSO
3M, wherein M=Na
+, K
+, [HN (CH
2CH
2OH)
3]
+, [H
2N (CH
2CH
2OH)
2]
+, [H
2NCH
2CH
2OH]
+, NH
4 +, R=C
12～C
18Alkyl, preferred M=NH
4 +, R=C
12, i.e. lauryl alcohol ammonium sulfate; Described fatty alcohol polyoxyethylene ether sulfate accounts for 2.0%～20.0% of composition weight, and described fatty alcohol polyoxyethylene ether sulfate structural formula is RO (CH
2CH
2O)
nSO
3M, wherein M=Na
+, NH
4 +, [H (C
2H
5OH)
3]
+, R=C
12～C
18Alkyl, n are 2～4, and preferred average ethoxyquin degree is n=3, M=NH
4 +, R=C
12, i.e. lauryl alcohol polyoxyethylene ether ammonium sulfate; Described glycerine monofatty ester sulfate structural formula [RCOOCH
2CH (OH) CH
2OSO
3M], M=Na wherein
+, NH
4 +Deng, R=C
12～C
18Alkyl, preferred M=NH
4 +, R=C
12, i.e. lauric acid monoglyceride ammonium sulfate; Typical case's representative of described fatty alcohol radical sulfosuccinate ester salt is lauryl 2-Sulfosuccinic acid ester ammonium salt, lauryl 2-Sulfosuccinic acid ester sodium salt, laureth sulfosuccinate disodium; Described fatty acyl glutamate, Glu structural formula is [RCONHCH (COOH) CH
2CH
2COOM], M=Na wherein
+, NH
4 +Deng, R=C
12～C
18Alkyl, preferred M=Na
+, R=C
12, i.e. sodium lauroyl glutamate; Typical case's representative of described N-acyl glutamate is N-coconut sodium glutamate acyl, N-sodium lauroyl glutamate, N-myristoyl sodium glutamate, N-Cortex cocois radicis acyl glutamic acid list triethanolamine salt etc., preferred N-sodium lauroyl glutamate.Described amphoteric surfactant is at least a in betanin and the derivant thereof, and described betanin derivative accounts for 1.0%～10.0% of composition weight.Described betanin derivative comprises coco dimethyl betanin, cocamido propyl betaine, dodecanamide propyl betanin, cocamidopropyl propyl amide hydroxyl sulphur betanin, lauramide hydroxyl sulphur betanin, preferred cocamido propyl betaine.
Contain in the shampoo composite for moderately removing dandruff of the present invention and account for composition weight 0.01% to 2.0%, preferred 0.02% to 1.0% the suitable moderately removing dandruff agent that is used on hair or the skin.Described moderately removing dandruff agent is hexamidine two (hydroxyethylsulfonic acid .) salt.Described hexamidine two (hydroxyethylsulfonic acid .) salt, have another name called 4,4-diamidine-a-ω-two phenoxy group hexane, be a kind of water miscible anti-various gram-positive bacterias and positive bacteria and various mycete, saccharomycetic cationic material of killing of wide spectrum that have, the ovum shape Testa oryzae rash tinea bacterium that causes scalp pathological changes and dandruff had very strong inhibition and insect killing effect, zest to skin, scalp and eyes is little, and good stability, can variable color.Described hexamidine two (hydroxyethylsulfonic acid .) salt is white powder, and active matter content is greater than 99.5%.
Moderately removing dandruff agent of the present invention can also be the compositions of pyrithione zinc and hexamidine two (hydroxyethylsulfonic acid .) salt or the compositions of two pyrithione and hexamidine two (hydroxyethylsulfonic acid .) salt.In the compositions of described hexamidine two (hydroxyethylsulfonic acid .) salt and pyrithione zinc, the ratio of hexamidine two (hydroxyethylsulfonic acid .) salt and pyrithione zinc is 15:1 to 1:3, preferred 10:1 to 1:2; In the compositions of the described pair of pyrithione and hexamidine two (hydroxyethylsulfonic acid .) salt, the ratio of two pyrithione and hexamidine two (hydroxyethylsulfonic acid .) salt is 50:1 to 1:10, preferred 25:1 to 1:5.
Contain in the shampoo composite for moderately removing dandruff of the present invention and account for composition weight 0.5% to 6.0%, preferred 0.75% to 5.0% thickening agent.Wherein said thickening agent is selected from, at least a in electrolyte, dihydro Adeps Bovis seu Bubali phthalic acid amide, the polyoxyethylene carboxylate, preferred dihydro Adeps Bovis seu Bubali phthalic acid amide.Described electrolyte thickening agent comprises sodium chloride, ammonium chloride, monoethanolamine chloride, diethanolamine chloride, sodium sulfate, ammonium sulfate, disodium hydrogen phosphate, phosphoric acid five sodium etc., and wherein sodium chloride and ammonium chloride are the electrolyte thickening agents of using always; Described dihydro Adeps Bovis seu Bubali phthalic acid amide trade name is TAB-2, make by two hydrogenated-tallow group secondary amine and phthalic anhydride, can with all components compatibility in the present composition, salt tolerance is preferably arranged, in wider pH scope, has constant thickening effect, can make compositions viscosity at room temperature is 6000mPa.s to 12000mPa.s, preferred 8000mPa.s to 10000mPa.s; Described polyoxyethylene carboxylate thickening agent mainly contains polyglycol distearate, polyethylene glycol mono stearate and polyethylene glycol dilaurate.Other is applicable to that the bright thickening agent of this law also has cellulose derivative, acrylic copolymer etc.Described cellulose derivative is the non-ionic water-soluble cellulosic polymer that a class side chain that native cellulose forms by modified-reaction contains hydroxyl, mainly contains Carboxymethyl cellulose sodium, hydroxyethyl-cellulose and hydroxypropyl emthylcellulose etc.; Described acrylic copolymer comprises anionic thickener and non-ionic thickening agent C such as acrylic acid/polyoxyethylene (20) octadecanol ether methyl acid copolymer, acrylic copolymer
10Poly-carbamyl macrogol ester; Other is applicable to that the non-limiting example of thickening agent of the present invention also has the water-soluble glue raw material, comprises xanthan gum, Polyethylene Glycol, polyvinylpyrrolidone etc.
Contain the conditioner composition that following component is formed in the shampoo composite for moderately removing dandruff of the present invention.
(i) account for composition weight 0.02% to 1.5%, preferred 0.05% to 1.0% the suitable cationic polymer that is used on hair or the skin.Described cationic polymer is selected from: at least a in the polyammonium copolymer of cationic cellulose polymer, cation melon xanthan polymer, dimethyl dialkyl ammonia chloride/allylamine copolymer, ethenyl pyrrolidone alkane and dimethylamino isobutyl ester.Described cationic cellulose polymer is the copolymer of hydroxyethyl-cellulose and alkyl trimethyl ammonium chloride, difference according to the cation substitution value can be divided into: high-cation substitution value JR, middle-jiao yang, function of the spleen and stomach ionic replacement degree LR and three kinds of models of low cation substitution value LK, the cationic cellulose polymer of preferred high-cation substitution value, be polyquaternary ammonium salt-10, other is suitable for the copolymer that cationic cellulose polymer of the present invention also has hydroxyethyl-cellulose and dialkyl dimethyl ammonium chloride.Described cation melon glue is the product that melon glue is obtained after quaternized, its key component is a guar hydroxypropyltrimonium chloride, difference according to substitution value can obtain a series of cation melon glue product, preferred substitution value is 0.1 to 0.2, be used for cation melon glue of the present invention under 25 ℃ of conditions, the viscosity of its 1% aqueous solution is 2000mPa.s to 4000mPa.s, and its consumption is 0.02% to 3.0%, preferred again 0.05% to 1.0%.Described dimethyl dialkyl ammonia chloride/allylamine copolymer is a polyquaternary ammonium salt-7, has affinity with hair, can give the good wet comb of hair and do comb property, has anti-hair and tangles, repeatedly uses noncumulative advantage.The polyammonium copolymer of described ethenyl pyrrolidone alkane and dimethylamino isobutyl ester is a polyquaternary ammonium salt-11, has cationic conditioning, performance such as affine, can form transparent, not viscid continuous film in hair surface.Other is applicable to that the bright cationic polymer of this law also has vinylpyrrolidone and the rare amido propyl trimethyl ammonium chloride of methyl-prop copolymer, vinylpyrrolidone and the rare amide of dimethylamine propyl methyl-prop and the quaternized copolymer of dodecyl dimethyl propyl methyl amide moral, the vinylpyrrolidone of branched chain type and the copolymer of quaternized imidazoline, the rare salmiac cation polymer of dimethyl dipropyl, rare ammonium chloride of dimethyl dipropyl and acrylic acid cationic polymer, the cationic polymer of the rare ammonium chloride of dimethyl dipropyl and acrylamide and acrylic acid etc.The rare amido propyl trimethyl ammonium chloride of described vinylpyrrolidone and methyl-prop copolymer is a polyquaternary ammonium salt-28, is water-soluble polymer, can give hair conditioning, gloss, repeatedly uses to gather and lacks.Described vinylpyrrolidone and the rare amide of dimethylamine propyl methyl-prop and the quaternized copolymer of dodecyl dimethyl propyl methyl amide moral are polyquaternary ammonium salt-55, can give hair smooth, soft hand feeling.The vinylpyrrolidone of described branched chain type and the copolymer of quaternized imidazoline are polyquaternary ammonium salt-44, can give hair good dried wet cardability.The rare salmiac cation polymer of described dimethyl dipropyl is a polyquaternary ammonium salt-6, has the characteristic and the high tack of adopted son Lee's surfactant, gives the hair good conditioning.Rare ammonium chloride of described dimethyl dipropyl and acrylic acid cationic polymer are polyquaternary ammonium salt-22, have higher adhesive force, and hair and skin are had the good nursing care effect.It is polyquaternary ammonium salt-39 that rare ammonium chloride of described dimethyl dipropyl and acrylamide and acrylic acid get cationic polymer, has extremely strong elimination static usefulness and good wettability.
(ii) account for composition weight 0.05% to 4.0%, preferred 0.15% to 3.0% the suitable modified dimethyl polysiloxane that is used on hair or the skin.Described modified dimethyl polysiloxane is selected from: at least a in amino modified polydimethylsiloxane, polyether-modified polydimethylsiloxane, Radix Betae base modified dimethyl polysiloxane, the quaternary ammonium salt-modified polydimethylsiloxane.Described amino modified polydimethylsiloxane satisfies structural formula (III).R in the formula (III)
1, R
2Independently be selected from C separately
1～C
22Alkyl, OH or OC
1～C
20Alkoxyl; R
3, R
4Independently be selected from C separately
1～C
22Alkyl; M is 1～500 integer; N, r are 1～200 integers; A, b are 0～30 integers.
Described polyether-modified polydimethylsiloxane satisfies structural formula (IV).In the formula (IV), 1 is 0～100 integer, and m is 0～100 integer, and k, n are 0～1000 integer, and p, q are 3～16 integer, and r is 1～25 integer, and s is 0～18 integer, R
1, R
2, R
3Independently be selected from C separately
1～C
22Alkyl, OH or OC
1～C
20Alkoxyl.
Described Radix Betae base modified dimethyl polysiloxane satisfies the structure formula V.R in the formula V
1, R
2Independently be selected from separately: the alkyl of saturated or undersaturated long-chain or short chain or alkoxyl or thiazolinyl, branched alkyl or thiazolinyl, and C
5～C
8The ring-type system; R
3Be selected from C
1～C
22Alkyl; M is 1～500 integer, and n is 1～200 integer, and a is 0～30 integer.
Described quaternary ammonium salt-modified polydimethylsiloxane satisfies structural formula (VI).R in the formula (VI)
1, R
2, R
3And R
4Be selected from C independently of one another
1～C
22Alkyl, OH or OC
1～C
20Alkoxyl, R
5, R
6Be selected from C
1～C
22Alkyl, a, c are 1～20 integers, and b is 0～20 integer, and x is 0～100 integer, and z is 1～100 integer, and y is 1～500 integer.
(iii) account for composition weight 0.6% to 8.0%, preferred 0.5% to 6.0% the suitable polydimethylsiloxane that is used on hair or the skin.Described polydimethylsiloxane is that polydimethylsiloxane exists with dispersed particles through pre-emulsified.Described emulsifying polydimethylsiloxane is that particle diameter is that small particle diameter polydimethylsiloxane and the particle diameter of 0.01 μ m to 5 μ m is the compositions of the big particle diameter polydimethylsiloxane of 10 μ m to 50 μ m.Described small particle diameter polydimethylsiloxane deposition on hair is little, and good flushing hands sense can be provided; The deposition of described big particle diameter polydimethylsiloxane on hair is bigger, can effectively improve the cardability of doing the back hair.Polydimethylsiloxane deposition on hair is too small, can not reach the conditioning effect of expection, deposition is excessive, can cause hair hardening, easily broken again, in order to reach best nursing efficacy, the polydimethylsiloxane of high inner phase viscosity and low inner phase viscosity must remain in the suitable proportion, and this ratio is 1:10 to 1:1, preferred 1:8 to 1:3.
(iv) account for the suitable cationic surfactant that is used on hair or the skin of composition weight 0.25% to 8.0%, 0.5% to 6.0%.Described sun is a quaternary ammonium salt cationic surfactant from surfactant, and described quaternary sun comprises from the indefiniteness embodiment of surfactant: alkyl benzyl dimethyl ammonium salt, natural oil base Propylamino benzyl dimethyl ammonium salt, alkyl trimethyl quaternary ammonium salt, two alkyl-dimethyl based quaternary ammonium salts etc.
Also contain in the shampoo composite for moderately removing dandruff of the present invention and account for composition weight 0.25% to 3.5%, preferred 0.5% to 3.0% the suitable pearling agent that is used on hair or the skin.Described pearling agent is selected from: at least a in ethylene glycol stearate monoesters and dibasic acid esters, fatty acid metal salts, monostearate nuclear Palmic acid propylene glycol ester, higher fatty acids alkylolamides, aliphatic alcohol, stearate acid zinc and magnesium stearate, fine dispersive zinc oxide and titanium dioxide, the Magnesiumaluminumsilicate, preferred ethylene glycol stearate monoesters and dibasic acid esters.
Shampoo composite for moderately removing dandruff of the present invention can also comprise other optional components, comprises chelating agen, pH regulator agent, antiseptic, pigment and spice etc.The non-limiting example of described chelating agen has: ethylenediaminetetraacetic acid, disodiumedetate, tetrasodium ethylenediamine tetraacetate, citric acid, phosphoric acid, ascorbic acid etc., preferred disodiumedetate; The non-limiting example of described pH regulator agent has: citric acid, phosphoric acid etc., optimization citric acid, the pH of regulation system are 5.0 to 8.0, and preferred 5.5 to 6.5; Choosing of described antiseptic, essence, pigment meets the regulation of hygienic standards for cosmetics, selects safe raw material for use.
In the shampoo composite for moderately removing dandruff of the present invention, except the above component, water is mended to aequum.
Compared with prior art, the present invention has the following advantages: adopt gentle anti-dandruff dose and composite conditioner, when effectively removing dandruff, also have the good conditioning performance.
Preparation method
Shampoo composite for moderately removing dandruff of the present invention can by any known or other effectively be applicable to the technology preparation that shampoo composite is provided, the method for preparing anti-dandruff shampoo composition of the present invention comprises conventional preparation and hybrid technology.
Using method
Shampoo composite for moderately removing dandruff of the present invention uses with the cleaning of routine and the mode of conditioning hair, mainly comprises following step:
(A) water is with the hair moistening;
(B) use the shampoo composite of aforementioned each claim of effective dose on described hair, the scope of described effective dose is generally 1 gram to 50 grams, preferred 2 to 20 grams;
(C) with the shampoo composite on the described hair of water rinse.
These steps can repeat repeatedly as required, to reach cleaning, conditioning and the anti-dandruff effect of looking for.
Embodiment
Be the non-limiting example of shampoo composite for moderately removing dandruff of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention, because without departing from the spirit and scope of the present invention, can carry out many changes to the present invention.In these embodiments, unless stated otherwise, all concentration all is percentage by weight.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, pH regulator agent, spice, pigment etc., the selection of these small amount of matter will change in order to the physics for preparing special component of the present invention and chemical characteristic along with selected.
Preparation example I-X
The suitable method for preparing shampoo composite for moderately removing dandruff described in example I-X is as follows: suitable quantity of water is joined in the retort, adding polyquaternary ammonium salt-10 under slowly stirring disperses, slowly be stirred and heated to 60 ℃ to 80 ℃, then add Laurel alkyl ammonium sulfate, polyoxyethylene lauryl ether ammonium sulfate, cocamido propyl betaine, dihydro Adeps Bovis seu Bubali phthalic acid amide, pearlescent flake, disodiumedetate (if using these materials), make these materials disperse the back cooling fully.Treat to add when temperature is reduced to 65 ℃ of left and right sides anti-dandruff dose of hexamidine two (hydroxyethylsulfonic acid .) salt, be cooled to after being uniformly dispersed and add polydimethylsiloxane, modified dimethyl polysiloxane and nourishing additive agent below 50 ℃ and be uniformly dispersed, add antiseptic, pigment, essence etc. again and continue to stir, guarantee to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, the viscosity and the pH that regulate product arrive suitable degree.Randomly can add low amounts of water at last supplies.
Example I-V
Example VI-X
The preferred embodiments of the present invention are:
| Component | Content (weight %) |
| Laurel alkyl ammonium sulfate (70%) | 8.0 |
| Polyoxyethylene lauryl ether ammonium sulfate (70%) | 12.0 |
| Cocamido propyl betaine | 5.0 |
| Dihydro Adeps Bovis seu Bubali phthalic acid amide | 1.0 |
| Polyquaternary ammonium salt-10 | 0.4 |
| Pearlescent flake | 1.3 |
| Disodiumedetate | 0.1 |
| Amino modified polydimethylsiloxane | 0.4 |
| Polydimethylsiloxane | 2.0 |
| Two ethyl palmitate alkyl dimethyl ammonium chlorides | 1.5 |
| Hexamidine two (hydroxyethylsulfonic acid .) salt | 0.02 |
| Citric acid, antiseptic, coloring agent, spice, sodium chloride | In right amount |
| Water | Add to 100% |
Claims (12)
1. shampoo composite for moderately removing dandruff, contain in this shampoo:
(A) account for the surfactant of at least a cleaning action of composition weight 5.0% to 50.0%;
(B) account for the moderately removing dandruff agent of composition weight 0.01% to 2.0%;
(C) account for the viscosity-controlling agent of composition weight 0.5% to 6.0%;
(D) conditioner composition composed of the following components,
(i) account for the cationic polymer of composition weight 0.02% to 1.5%;
(ii) account for the modified dimethyl polysiloxane of composition weight 0.05% to 4.0%;
(iii) account for the polydimethylsiloxane of composition weight 0.2% to 8.0%;
(iv) account for the cationic surfactant of composition weight 0.25% to 8.0%; With
(E) surplus is a water.
2. shampoo composite for moderately removing dandruff according to claim 1, wherein said surfactant are the compositionss of aliphatic alcohol sulfate, fatty alcohol polyoxyethylene ether sulfate and betanin derivative.
3. shampoo composite for moderately removing dandruff according to claim 2, wherein said aliphatic alcohol sulfate accounts for 2.0%～20.0% of composition weight, described fatty alcohol polyoxyethylene ether sulfate accounts for 2.0%～20.0% of composition weight, and described betanin derivative accounts for 1.0%～10.0% of composition weight.
4. according to the shampoo composite for moderately removing dandruff of aforementioned each claim, wherein said moderately removing dandruff agent is hexamidine two (hydroxyethylsulfonic acid .) salt.
5. according to the shampoo composite for moderately removing dandruff of aforementioned each claim, wherein said viscosity-controlling agent is selected from: at least a in electrolyte, dihydro Adeps Bovis seu Bubali phthalic acid amide, the polyoxyethylene carboxylate.
6. shampoo composite for moderately removing dandruff according to claim 5, wherein said viscosity-controlling agent are dihydro Adeps Bovis seu Bubali phthalic acid amide.
7. according to the shampoo composite for moderately removing dandruff of aforementioned each claim, wherein said cationic polymer is selected from: at least a in the polyammonium copolymer of cationic cellulose polymer, cation melon xanthan polymer, dimethyl dialkyl ammonia chloride/allylamine copolymer, ethenyl pyrrolidone alkane and dimethylamino isobutyl ester.
8. according to the shampoo composite for moderately removing dandruff of aforementioned each claim, wherein said modified dimethyl polysiloxane is selected from: a kind of in amino modified polydimethylsiloxane, polyether-modified polydimethylsiloxane, Radix Betae base modified dimethyl polysiloxane, the quaternary ammonium salt-modified polydimethylsiloxane.
9. according to the shampoo composite for moderately removing dandruff of aforementioned each claim, described polydimethylsiloxane is that polydimethylsiloxane exists with dispersed particles through pre-emulsified.
10. shampoo composite for moderately removing dandruff according to claim 9, described emulsifying polydimethylsiloxane are that particle diameter is that small particle diameter polydimethylsiloxane and the particle diameter of 0.01 μ m to 5 μ m is the compositions of the big particle diameter polydimethylsiloxane of 10 μ m to 50 μ m.
11. shampoo composite for moderately removing dandruff according to aforementioned each claim, it is characterized in that said composition also comprises the cationic surfactant that accounts for composition weight 0.25% to 8.0%, described cationic surfactant is a quaternary ammonium salt cationic surfactant.
12. shampoo composite for moderately removing dandruff according to claim 1, its component and content are as follows:
Constituent content weight %
Laurel alkyl ammonium sulfate (70%) 8.0
Polyoxyethylene lauryl ether ammonium sulfate (70%) 12.0
Cocamido propyl betaine 5.0
Dihydro Adeps Bovis seu Bubali phthalic acid amide 1.0
Polyquaternary ammonium salt-10 0.4
Pearlescent flake 1.3
Disodiumedetate 0.1
Amino modified polydimethylsiloxane 0.4
Polydimethylsiloxane 2.0
Two ethyl palmitate alkyl dimethyl ammonium chlorides 1.5
Hexamidine two (hydroxyethylsulfonic acid .) salt 0.02
Citric acid, antiseptic, coloring agent, spice, chlorine are an amount of
Water adds to 100%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102204722A CN101444462A (en) | 2008-12-26 | 2008-12-26 | Shampoo composite for moderately removing dandruff |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008102204722A CN101444462A (en) | 2008-12-26 | 2008-12-26 | Shampoo composite for moderately removing dandruff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101444462A true CN101444462A (en) | 2009-06-03 |
Family
ID=40740545
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008102204722A Pending CN101444462A (en) | 2008-12-26 | 2008-12-26 | Shampoo composite for moderately removing dandruff |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101444462A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605627A (en) * | 2012-03-05 | 2012-07-25 | 山东大易化工有限公司 | Wig treating agent and using method thereof |
| CN102989151A (en) * | 2012-11-21 | 2013-03-27 | 戴立斌 | Preparation process of aerosol for humidifying feather pieces of badminton |
| CN103445984A (en) * | 2013-08-26 | 2013-12-18 | 拉芳家化股份有限公司 | Mild shampoo containing alkyl glycoside-hydroxypropyl sodium phosphate copolymer |
| CN103520021A (en) * | 2013-08-02 | 2014-01-22 | 拉芳家化股份有限公司 | Conditioning shampoo containing cation-modified alkyl polyglycoside |
| CN104323929A (en) * | 2014-10-31 | 2015-02-04 | 重庆环驰科技有限公司 | Shampoo with controllable viscosity and preparation method thereof |
| CN104940071A (en) * | 2015-06-25 | 2015-09-30 | 广州保税区雅兰国际化妆品有限公司 | Mild antidandruff shampoo and preparation method thereof |
| CN106619271A (en) * | 2016-10-19 | 2017-05-10 | 重庆市五洁新材料有限公司 | Liquid shampoo for children and preparation method of liquid shampoo |
-
2008
- 2008-12-26 CN CNA2008102204722A patent/CN101444462A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605627A (en) * | 2012-03-05 | 2012-07-25 | 山东大易化工有限公司 | Wig treating agent and using method thereof |
| CN102989151A (en) * | 2012-11-21 | 2013-03-27 | 戴立斌 | Preparation process of aerosol for humidifying feather pieces of badminton |
| CN103520021A (en) * | 2013-08-02 | 2014-01-22 | 拉芳家化股份有限公司 | Conditioning shampoo containing cation-modified alkyl polyglycoside |
| CN103520021B (en) * | 2013-08-02 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of cation is modified the conditioner shampoo of alkyglycosides |
| CN103445984A (en) * | 2013-08-26 | 2013-12-18 | 拉芳家化股份有限公司 | Mild shampoo containing alkyl glycoside-hydroxypropyl sodium phosphate copolymer |
| CN103445984B (en) * | 2013-08-26 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer |
| CN104323929A (en) * | 2014-10-31 | 2015-02-04 | 重庆环驰科技有限公司 | Shampoo with controllable viscosity and preparation method thereof |
| CN104323929B (en) * | 2014-10-31 | 2017-08-29 | 重庆环驰科技有限公司 | Controllable shampoo of a kind of viscosity and preparation method thereof |
| CN104940071A (en) * | 2015-06-25 | 2015-09-30 | 广州保税区雅兰国际化妆品有限公司 | Mild antidandruff shampoo and preparation method thereof |
| CN106619271A (en) * | 2016-10-19 | 2017-05-10 | 重庆市五洁新材料有限公司 | Liquid shampoo for children and preparation method of liquid shampoo |
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Open date: 20090603 |