CN104353250B - A kind of bubble-water concentrated solution - Google Patents
A kind of bubble-water concentrated solution Download PDFInfo
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- CN104353250B CN104353250B CN201410608064.XA CN201410608064A CN104353250B CN 104353250 B CN104353250 B CN 104353250B CN 201410608064 A CN201410608064 A CN 201410608064A CN 104353250 B CN104353250 B CN 104353250B
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Abstract
The invention discloses a kind of bubble-water concentrated solution, belong to field of household chemical.Its component consists of by mass percentage: tap water 50 80%, dicarboxyl methylalanine trisodium 1 6%, sodium polyacrylate 1 10%, alkyl polyglucoside 10 40%, glycerol 1 10%, essence 0.1 1%, preservative 0.1 1%.During use, described concentrated solution is diluted 5 10 times, make bubble-water solution.Bubble-water composition of the present invention is the green non-poisonous raw material of food stage, and degradability is good, with low cost；Product is concentrated liquid prescription, can save packed and transported cost, facilitates easy-to-use, froths effective.
Description
Technical field
The present invention relates to a kind of bubble-water concentrated solution, in particular to being the bubble-water concentrated solution with alkyl polyglucoside as foaming agent, belong to
In field of household chemical.
Background technology
The range of bubble-water is very extensive, the little toy to daily children, the big decoration to large-scale stage set, bubble
Using of water brings various enjoyment and color to our life, and the safety of bubble-water the most increasingly causes more pass
Note.
The know-why of bubble-water is under the effect of external air flow, by reducing the surface tension of water, and forms some
Continuous print bubble.The main component of bubble-water formula has: water, film former, surfactant, stabilizer etc..Use table
Face activating agent can significantly reduce the surface tension of solution, it is easy to bubble is formed, and the addition of film former and stabilizer can make bubble more
Abundant, the most fragile.
Application No. CN201210202456.7, a kind of bubble-water of Chinese patent application of Publication No. CN 103505890 A
Manufacture method lists several existing bubble-water formula:
1. tea+detergent+white sugar.
2. soap+tea+Saccharum Sinensis Roxb..
3. liquid detergent+water+white sugar.
4. glue: water: liquid detergent: handwashing liquid (shampoo)=1:4:2:2.
Meanwhile, this patent application document discloses the manufacture method of a kind of bubble-water, and it is mainly composed of liquid detergent and water.Deposit
In a certain degree of safety issue, the effect that froths is general, and bubble is abundant and fragile not.
Patent No. CN201210229443.9, the Chinese patent application one Novel bubble of Publication No. CN102743888A
Liquid product compositions and manufacture method thereof, disclose a kind of Novel bubble liquid compositions, including surfactant, thickening agent,
The raw materials such as water treatment agent, preservative, essence, pigment, PH regulator, deionized water, but the table used in this patent
Face activating agent, water treatment agent etc. is not admitted to green non-poisonous raw material, all there is some problems in terms of degradability and zest.
Existing recipe ingredient is not containing detergent, liquid detergent or soap, it is simply that raw material does not reaches green safety requirement, exists certain
The safety issue of degree, the effect that froths is general, and bubble is abundant and fragile not, is very restricted in actual applications.
Summary of the invention
The component security performance that it is an object of the invention to solve existing bubble-water is not enough, the defect of the poor-performing that froths, it is provided that
Froth after a kind of dilution excellent performance, the bubble-water concentrated liquid prescription of Environmental Safety, particularly do not contain detergent, liquid detergent,
Soap, all uses the bubble-water concentrated solution of the green non-poisonous raw material of food stage.
For achieving the above object, the bubble-water concentrated solution designed by the present invention, its component by mass percentage, by following component
Composition: tap water 50-80%, dicarboxyl methylalanine trisodium 1-6%, sodium polyacrylate 1-10%, alkyl polyglucoside 10-40%,
Glycerol 1-10%, spice 0.1-1%, preservative 0.1-1%.
Wherein the molecular weight of sodium polyacrylate is 10W-500W；Alkyl polyglucoside be carbon number be that the alkyl polyglucoside of 8-10, carbon number are
Arbitrary or both combinations in the alkyl polyglucoside of 12-14.
When carbon number is alkyl polyglucoside and the combination of alkyl polyglucoside that carbon number is 12-14 of 8-10, carbon number is the alkyl sugar of 8-10
Glycosides and the mass ratio that carbon number is 12-14 alkyl polyglucoside are 1:9-9:1.Wherein be preferably in a proportion of alkyl polyglucoside that carbon number is 8-10 and
Carbon number be the mass ratio of 12-14 alkyl polyglucoside be 2:8,5:5,6:4,7:3, or 8:2.Carbon number be 8-10 alkyl polyglucoside and
Carbon number is that both combinations of the alkyl polyglucoside of 12-14 are the alkyl polyglucoside that carbon number is 8-14.
Wherein carbon number be 8-10, carbon number be that the preparation method of 12-14 alkyl polyglucoside is the fatty alcohol of glucose and corresponding carbon number and leads to
Cross one-step method reaction to be prepared, (list of references: Dong Wantian, Geng Tao, Yao Xuezhu. the through engineering approaches of alkyl polyglucoside and industry
Change [J]. household chemicals science, 2008,31 (5): 15-17.).
Wherein preservative is potassium sorbate or sodium benzoate.
Present invention also offers the application process of a kind of above-mentioned bubble-water concentrated solution, the method is: by above-mentioned bubble-water concentrated solution
Add by the mass percent of 10%-20% and make bubble-water solution to water, at normal temperatures, froth with the instrument of frothing.
Wherein the instrument of frothing is: model is the full-automatic bubble generating machine of the star (manufacturer: Haiyang, Shantou City trade in Haiyang of S998-14
Company limited).
The innovation of the present invention is: bubble-water component newly developed is reasonable, and selected alkyl polyglucoside is green safety table
Face activating agent, to environment and the person non-hazardous, easily biological-degradable, little to skin irritation；Other selected raw material components
Also food stage, safety nuisance free it are；In the present invention, the production of product is simple, and froth excellent effect；The present invention prepares
The bubble-water concentrated solution become, can largely reduce cost of transportation, pack, the cost such as handling.
Beneficial effects of the present invention:
1. the Surfactants Alkyl that the present invention selects is green safety raw material, nontoxic, non-stimulated, safety is good, presses
OECD directive/guide NO.406 method test result shows, no matter which kind of alkyl polyglucoside, Cavia porcellus is not caused contact dermatitis,
This point is by have also been obtained checking to the test of human body skin.
2. other raw material that the present invention selects is food grade materials, green safety.
Compound method the most of the present invention is simple, the highest to equipment requirements, and preparation cost is relatively low；Meanwhile, it is made into concentrated solution and can reduce bag
Dress and cost of transportation.
Product the most of the present invention, froth excellent effect, and bubble is abundant, stable.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
Take from water 54% by mass percentage, dicarboxyl methylalanine trisodium 2%, sodium polyacrylate (molecular weight 10W) 1%,
Alkyl polyglucoside (carbon number 8-14) (alkyl polyglucoside used be carbon number be alkyl polyglucoside and alkyl that carbon number the is 12-14 sugar of 8-10
Glycosides compounds with the mass ratio of 7:3 and forms, and each alkyl polyglucoside used is the product of Shanghai Fakai Chemical Co., Ltd., carbon number
Batch for the alkyl polyglucoside of 8-10 is APG0810-13-39, and carbon number is that the batch of the alkyl polyglucoside of 12-14 is
APG1214-13-79) 40%, glycerol 1%, essence (fragrant citrus) (purchased from Taizhou City gold Fragrant food additive factory, model:
JX22123) 1%, potassium sorbate 1%, after above-mentioned raw materials is sequentially added in stirred tank uniformly mixing, i.e. prepare bubble-water
Concentrated solution 1.
Above-mentioned bubble-water concentrated solution 1 is added according to the mass percent of every 10%-20% to water, makes bubble-water solution,
Under room temperature, frothing with the full-automatic bubble generating machine of star in Haiyang that model is S998-14, the rate that froths is about up to 42/second, and Shen
Number please only have 20/second for the patent disclosed embodiment 1 bubble-water rate of frothing of CN 201210202456.7, Patent No.
The bubble liquid rate of frothing disclosed in embodiment 1 patent of CN201210229443.9 is only 35/second.
Froth as stated above, the bubble-water of the present embodiment, calculated by bubble quantity after frothing 5 seconds, broken bubble rate is 5%,
And the patent disclosed embodiment 1 of Application No. CN201210202456.7 and Patent No. CN201210229443.9 is special
The bubble-water of technical scheme gained in profit disclosed embodiment 1, the broken bubble rate after frothing 5 seconds is respectively 13% and 10%.
Embodiment 2
Take from water 80%, dicarboxyl methylalanine trisodium 1%, sodium polyacrylate (molecular weight 100W) by mass percentage
3.8%, (alkyl polyglucoside used is the product of Shanghai Fakai Chemical Co., Ltd. to alkyl polyglucoside (carbon number 8-10), and batch is
APG0810-13-39) 10%, glycerol 5%, essence (Fructus Fragariae Ananssae) (purchased from Taizhou City gold Fragrant food additive factory, model:
JX22067) 0.1%, sodium benzoate 0.1%, after above-mentioned raw materials is sequentially added in stirred tank uniformly mixing, i.e. prepare bubble
Concentrated liquid 2.
Above-mentioned bubble-water concentrated solution 2 is added according to the mass percent of every 10%-20% to water, makes bubble-water solution,
Under room temperature, frothing with the full-automatic bubble generating machine of star in Haiyang that model is S998-14, the rate that froths is about up to 43/second.Froth 5
Being calculated by bubble quantity after Miao, broken bubble rate is 4%.Detection method is with embodiment 1.
Embodiment 3
Take from water 62%, dicarboxyl methylalanine trisodium 6%, sodium polyacrylate (molecular weight 400W) by mass percentage
10%, (alkyl polyglucoside used is that carbon number is the alkyl polyglucoside of 8-10 and carbon number is 12-14's to alkyl polyglucoside (carbon number 8-14)
Alkyl polyglucoside compounds with the mass ratio of 2:8 and forms, and each alkyl polyglucoside used is the product of Shanghai Fakai Chemical Co., Ltd.,
Carbon number be the batch of the alkyl polyglucoside of 8-10 be APG0810-13-39, carbon number is that the batch of the alkyl polyglucoside of 12-14 is
APG1214-13-79) 20%, glycerol 1%, essence (fragrant citrus) (purchased from Taizhou City gold Fragrant food additive factory, model:
JX22123) 0.5%, potassium sorbate 0.5%, after above-mentioned raw materials is sequentially added in stirred tank uniformly mixing, i.e. prepare bubble
Concentrated liquid 3.
Above-mentioned bubble-water concentrated solution 3 is added according to the mass percent of every 10%-20% to water, makes bubble-water solution,
Under room temperature, frothing with the full-automatic bubble generating machine of star in Haiyang that model is S998-14, the rate that froths is about up to 45/second.Froth 5
Being calculated by bubble quantity after Miao, broken bubble rate is 5%.Detection method is with embodiment 1.
Embodiment 4
Take from water 50%, dicarboxyl methylalanine trisodium 4.5%, sodium polyacrylate (molecular weight 500W) by mass percentage
8%, (alkyl polyglucoside used is the product of Shanghai Fakai Chemical Co., Ltd. to alkyl polyglucoside (carbon number 12-14), and batch is
APG1214-13-79) 26%, glycerol 10%, essence (honey peach) is (purchased from Taizhou City gold Fragrant food additive factory, type
Number: JX62090) 0.5%, sodium benzoate 1%, after above-mentioned raw materials is sequentially added in stirred tank uniformly mixing, i.e. prepare bubble
Soaked concentrated solution 4.
Above-mentioned bubble-water concentrated solution 4 is added according to the mass percent of every 10%-20% to water, makes bubble-water solution,
Under room temperature, frothing with the full-automatic bubble generating machine of star in Haiyang that model is S998-14, the rate that froths is about up to 41/second.Froth 5
Being calculated by bubble quantity after Miao, broken bubble rate is 4%.Detection method is with embodiment 1.
Embodiment 5
Take from water 70%, dicarboxyl methylalanine trisodium 1%, sodium polyacrylate (molecular weight 100W) by mass percentage
3%, (alkyl polyglucoside used is that carbon number is the alkyl polyglucoside of 8-10 and carbon number is 12-14's to alkyl polyglucoside (carbon number 8-14)
Alkyl polyglucoside compounds with the mass ratio of 9:1 and forms, and each alkyl polyglucoside used is the product of Shanghai Fakai Chemical Co., Ltd.,
Carbon number be the batch of the alkyl polyglucoside of 8-10 be APG0810-13-39, carbon number is that the batch of the alkyl polyglucoside of 12-14 is
APG1214-13-79) 20%, glycerol 5.8%, essence (Fructus Fragariae Ananssae) (purchased from Taizhou City gold Fragrant food additive factory, model:
JX22067) 0.1%, sodium benzoate 0.1%, after above-mentioned raw materials is sequentially added in stirred tank uniformly mixing, i.e. prepare bubble
Concentrated liquid 5.
Above-mentioned bubble-water concentrated solution 5 is added according to the mass percent of every 10%-20% to water, makes bubble-water solution,
Under room temperature, frothing with the full-automatic bubble generating machine of star in Haiyang that model is S998-14, the rate that froths is about up to 39/second.Froth 5
Being calculated by bubble quantity after Miao, broken bubble rate is 6%.Detection method is with embodiment 1.
Embodiment 6
Take from water 65%, dicarboxyl methylalanine trisodium 2%, sodium polyacrylate (molecular weight 200W) by mass percentage
4%, (alkyl polyglucoside used is that carbon number is the alkyl polyglucoside of 8-10 and carbon number is 12-14's to alkyl polyglucoside (carbon number 8-14)
Alkyl polyglucoside compounds with the mass ratio of 1:9 and forms, and each alkyl polyglucoside used is the product of Shanghai Fakai Chemical Co., Ltd.,
Carbon number be the batch of the alkyl polyglucoside of 8-10 be APG0810-13-39, carbon number is that the batch of the alkyl polyglucoside of 12-14 is
APG1214-13-79) 25%, glycerol 3.8%, essence (honey peach) is (purchased from Taizhou City gold Fragrant food additive factory, type
Number: JX62090) 0.1%, sodium benzoate 0.1%, after above-mentioned raw materials is sequentially added in stirred tank uniformly mixing, the most prepared
Bubble-water concentrated solution 6.
Above-mentioned bubble-water concentrated solution 6 is added according to the mass percent of every 10%-20% to water, makes bubble-water solution,
Under room temperature, frothing with the full-automatic bubble generating machine of star in Haiyang that model is S998-14, the rate that froths is about up to 40/second.Froth 5
Being calculated by bubble quantity after Miao, broken bubble rate is 7%.Detection method is with embodiment 1.
Comparative example
The formula of comparative example 1-5 is as follows, the application process of bubble-water concentrated solution such as embodiment 1, the bubble-water after the dilution obtained
At normal temperatures, froth, such as table 1 below with the full-automatic bubble generating machine of star in Haiyang that model is S998-14:
Table 1 comparative example and testing result thereof
The alkyl polyglucoside of above carbon number 8-14 be alkyl polyglucoside be that carbon number is the alkyl polyglucoside of 8-10 and carbon number is the alkane of 12-14
Base glucosides compounds with the mass ratio of 2:8 and forms, and each alkyl polyglucoside is the product of Shanghai Fakai Chemical Co., Ltd.；
Above essence is purchased from Taizhou City gold Fragrant food additive factory, model: JX62090；Preservative is potassium sorbate；
The detection method of the rate that more than froths and broken bubble rate is with embodiment 1.
Result shows, the component ratio that in the present invention, embodiment lists is preferably component ratio.By comparative example and embodiment
Testing result show add alkyl polyglucoside amount very few, the rate that froths reduce；Add or be added without sodium polyacrylate or glycerol less,
The rate that froths of joined bubble-water is deteriorated, and broken bubble rate raises.
Below preferred embodiment to the invention is illustrated, but the invention is not limited to described enforcement
Example, those of ordinary skill in the art also can make on the premise of the invention spirit all equivalents modification or
Replacing, modification or the replacement of these equivalents are all contained in the application claim limited range.
Claims (7)
1. a bubble-water concentrated solution, its component by mass percentage, consists of the following composition: tap water 50-80%, dicarboxyl
Methylalanine trisodium 1-6%, sodium polyacrylate 1-10%, alkyl polyglucoside 10-40%, glycerol 1-10%, essence 0.1-1%,
Preservative 0.1-1%；
Wherein the molecular weight of sodium polyacrylate is 10W-500W.
A kind of bubble-water concentrated solution the most according to claim 1, it is characterised in that wherein alkyl polyglucoside is selected from: carbon number is
The alkyl polyglucoside of 8-10, carbon number are arbitrary or both combinations in the alkyl polyglucoside of 12-14.
A kind of bubble-water concentrated solution the most according to claim 2, it is characterised in that wherein alkyl polyglucoside selected from carbon number is
During both combinations of the alkyl polyglucoside of 8-10 and alkyl polyglucoside that carbon number is 12-14, carbon number is alkyl polyglucoside and the carbon number of 8-10
Mass ratio for 12-14 alkyl polyglucoside is 1:9-9:1.
A kind of bubble-water concentrated solution the most according to claim 3, it is characterised in that wherein carbon number is the alkyl polyglucoside of 8-10
It is 2:8,5:5,6:4,7:3 or 8:2 with the mass ratio that carbon number is 12-14 alkyl polyglucoside.
A kind of bubble-water concentrated solution the most according to claim 1, it is characterised in that wherein preservative is potassium sorbate or benzene
Sodium formate.
6. an application process for the bubble-water concentrated solution as described in any one of claim 1 to 5, the method is: by above-mentioned bubble
Soaked concentrated solution is added by the mass percent of 10%-20% makes bubble-water solution, at normal temperatures, with the instrument of frothing to water
Froth.
The application process of bubble-water concentrated solution the most according to claim 6, it is characterised in that wherein the instrument of frothing is: model
The full-automatic bubble generating machine of star for Haiyang of S998-14.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| MX2019002119A (en) * | 2016-08-24 | 2019-09-18 | Q Tran Dat | Formulations for edible bubble solution. |
| CN106362420A (en) * | 2016-08-31 | 2017-02-01 | 陈雄 | Home-made bubble water composition |
| CN106139619A (en) * | 2016-08-31 | 2016-11-23 | 陈雄 | A kind of stage preparation method rendering stage property |
| CN106422372A (en) * | 2016-09-26 | 2017-02-22 | 宁波美乐雅荧光科技股份有限公司 | Environment-friendly foaming liquid and preparation method thereof |
| CN107661639A (en) * | 2017-10-16 | 2018-02-06 | 山西大学 | A kind of colourless bubble liquid that can be developed the color automatically in atmosphere |
| CN110327633A (en) * | 2019-03-11 | 2019-10-15 | 湖北文理学院 | A kind of bubble-water compound film former and preparation method thereof |
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| CN1847381A (en) * | 2006-04-30 | 2006-10-18 | 北京市航天焊接材料厂 | Multifunctional environment-friendly cleaning agent and preparation method thereof |
| JP2009091396A (en) * | 2007-10-04 | 2009-04-30 | Dai Ichi Kogyo Seiyaku Co Ltd | Soap bubble composition |
| CN201301039Y (en) * | 2008-10-29 | 2009-09-02 | 卓雄玩具有限公司 | Package bag for containing condensing or non-condensing hubble-bubble water |
| CN101810555B (en) * | 2010-04-13 | 2011-07-27 | 陈振华 | Concentrated foam liquid soap |
| CN103445984B (en) * | 2013-08-26 | 2016-05-11 | 拉芳家化股份有限公司 | A kind of mild shampoo containing APG hydroxypropyl sodium phosphate copolymer |
| CN103820229A (en) * | 2014-03-20 | 2014-05-28 | 祝一鸣 | Natural antibacterial mould proofing detergent without petrochemical components |
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