CN109837141A - Concentrated type detergent and its production method - Google Patents
Concentrated type detergent and its production method Download PDFInfo
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- CN109837141A CN109837141A CN201711225951.9A CN201711225951A CN109837141A CN 109837141 A CN109837141 A CN 109837141A CN 201711225951 A CN201711225951 A CN 201711225951A CN 109837141 A CN109837141 A CN 109837141A
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- polyoxyethylene ether
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- type detergent
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Abstract
The present invention provides a kind of concentrated type detergent and its production methods, wherein the raw material of concentrated type detergent includes the component of following parts by weight: 2~6 parts of α-sodium olefin sulfonate；9~13 parts of isomerous tridecanol polyoxyethylene ether sodium sulphate；12~19 parts of isomerous tridecanol polyoxyethylene ether；21~25 parts of heterogeneous ten alcohol polyoxyethylene ethers；6~10 parts of alkyl glycosides；35~43 parts of water.Concentrated type detergent active content provided by the invention can be up to 50% or more, have many advantages, such as to save packaging material, reduce transportation cost and reduce storage space；The rational proportion of isomerous tridecanol polyoxyethylene ether sodium sulphate, isomerous tridecanol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether, ensure that concentrated type detergent at low temperatures has excellent low temperature flow and excellent instant capacity, and decontamination emulsifiability is very superior；Product is mixed when in use, with water with arbitrary proportion, is not in gel area；Product have good fluidity, easily topple over, single wash dosage is less, foam is low, it is easy float, dissolution in low temperature it is good.
Description
Technical field
The present invention relates to detergent composition technical fields, specifically, being a kind of concentrated type detergent and its producer
Method.
Background technique
Detergent, the product by cleaning process for the special configuration of cleaning, by surfactant, builder, synergy
The Multiple components such as agent composition.The high speed development of national economy has brought the life of high quality, while also causing to environment
Certain pressure.Nowadays the life idea of environmentally friendly low-carbon and mode have become generally total for people's lives and with social development
Know, as the easy consumption product in daily life, the development of detergent also greenization increasingly.Concentrated type detergent is with its water-saving section
Main product of the features such as energy, decontamination are efficiently, ecology is friendly as the whole world especially developed country's detergent market, and at me
State, it is also higher and higher to the acceptance level of concentrated cleaning with the raising of people's environmental consciousness.Dish washing detergent is thousand ten thousand
The essential articles for washing in family, the dish washing detergent for developing concentrated type is the inexorable trend of industry value chain.
The tableware detergent in China has the production history in more than 40 years.Tableware washes agent by liquid and has become to be sold in the market
The maximum liquid detergent kind of the amount of selling.For many years, tableware detergent compositions form substantially without significant change, mostly yin from
Sub- surfactant, nonionic surfactant, cosolvent, thickener, essence etc. provide in dish washing detergent in national standard
Active matter content be greater than or equal to 15%, concentration is lower, largely waste packaging material, transportation cost and
Labour cost.
Currently, concentrated type cleaning solution viscosity in the market is big, causes its flow resistance big, be not suitable for automatic dilutor
Or be inconvenient to topple over；Mixing with water will appear gelatin phenomenon, and product dissolubility is caused to be deteriorated, especially at low ambient temperatures, from
And lead to residual of the product on tableware, the service efficiency of product is reduced, is difficult to give full play to the performance of highly enriched detergent.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of concentrated type detergent and its production method, mobility and low temperature
Dissolubility is good.
In order to solve the above technical problems, raw material includes following parts by weight the present invention provides a kind of concentrated type detergent
Several component: 2~6 parts of α-sodium olefin sulfonate；9~13 parts of isomerous tridecanol polyoxyethylene ether sodium sulphate；12~19 parts
Isomerous tridecanol polyoxyethylene ether；21~25 parts of heterogeneous ten alcohol polyoxyethylene ethers；6~10 parts of alkyl glycosides；35~43 parts of water.
Further, raw material includes the component of following parts by weight: 3~5 parts of α-sodium olefin sulfonate；10~12 parts
Isomerous tridecanol polyoxyethylene ether sodium sulphate；13~18 parts of isomerous tridecanol polyoxyethylene ether；22~24 parts of ten alcohol of isomery are poly-
Ethylene oxide ether；7~9 parts of alkyl glycosides；38~40 parts of water.
Further, raw material includes the component of following parts by weight: 4 parts of α-sodium olefin sulfonate；11 parts of isomery ten
Triol polyethenoxy ether sodium sulfate；15 parts of isomerous tridecanol polyoxyethylene ether；；23 parts of heterogeneous ten alcohol polyoxyethylene ethers；8 parts of alkane
Base glucosides；39 parts of water.
Further, raw material further includes the component of following parts by weight: 0.05 part of essence and 0.1 part of preservative.
Further, the water is deionized water.
The present invention also provides the production methods of above-mentioned concentrated type detergent, include the following steps:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: it is molten to its that stirring in the resulting mixture of step C is added in the isomerous tridecanol polyoxyethylene ether sodium sulphate
Solution；
E: it is molten to its that stirring in the resulting mixture of step D is added in the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides
Solution；
F: after the resulting mixture of step E is heated to 90~98 DEG C, heat preservation 15~25 minutes, 30~55 DEG C are cooled to.
Further, in the step F, the resulting mixture of step E is heated to 95 DEG C, heat preservation after twenty minutes, cools down
To 45 DEG C.
Further, further include step G after the step F: the essence and the preservative are added to step F
It is stirred evenly in resulting mixture.
Further, in described step B, C, D and E, environment temperature is 50~70 DEG C, and mixing speed is 200~500r/
min。
Further, in described step B, C, D and E, environment temperature is 60 DEG C, mixing speed 350r/min.
Concentrated type detergent active content provided by the invention can be up to 50% or more, have save packaging material,
The advantages that reducing transportation cost and reducing storage space；
Isomerous tridecanol polyoxyethylene ether sodium sulphate, isomerous tridecanol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether
Rational proportion, ensure that concentrated type detergent at low temperatures has excellent low temperature flow and excellent instant capacity, goes
Dirty emulsifiability is very superior；
Product is mixed when in use, with water with arbitrary proportion, is not in gel area；
Product have good fluidity, easily topple over, single wash dosage is less, foam is low, it is easy float, dissolution in low temperature it is good.
Detailed description of the invention
Fig. 1 is each component content of concentrated type detergent embodiment one to five of the present invention；
Fig. 2 is concentrated type detergent detergency verification result of the present invention；
Fig. 3 is the test result that concentrated type detergent of the present invention places test；
Fig. 4 is the test result of concentrated type detergent diffusion test of the present invention.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings and specific examples, so that those skilled in the art can be with
It more fully understands the present invention and can be practiced, but illustrated embodiment is not as a limitation of the invention.
Embodiment one:
A kind of concentrated type detergent, the dosage of each component of raw material is as shown in figure 1 shown in serial number one, it is preferable that the water is
Deionized water.α-sodium olefin sulfonate is a kind of low-down anionic surfactant of irritation in the formula, is dispersed in water
Speed is exceedingly fast, and soil release performance is good, emulsibility is good.Isomerous tridecanol polyoxyethylene ether sodium sulphate and isomerous tridecanol polyoxyethylene ether are
Surfactant with low temperature flow, decontamination emulsifiability are very superior.
Its production method includes the following steps:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: it is molten to its that stirring in the resulting mixture of step C is added in the isomerous tridecanol polyoxyethylene ether sodium sulphate
Solution；
E: it is molten to its that stirring in the resulting mixture of step D is added in the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides
Solution；
F: after the resulting mixture of step E is heated to 90 DEG C, heat preservation 25 minutes, 30 DEG C are cooled to.
Wherein, in described step B, C, D and E, environment temperature is 50 DEG C, mixing speed 500r/min.
The wash temperature of China's majority Area Inhabitants differs greatly in winter and in summer, generally at normal temperature (i.e. originally
The temperature of water) washing, this requires detergent, and dissolution is easily dispersed in low temperature.The active matter content of conventional detergent compared with
It is low, it is generally not present water-soluble dispersion problem.But active matter content is more than that 30% concentrated type detergent product tends to out
It the problem of existing poor dispersion, pours into and easily forms bulk in the water of room temperature, and be difficult to scatter, on the one hand detergent is caused to remain
It on to washing articles, makes troubles to consumer's use, reduces the service efficiency of product, on the other hand, it is difficult to be suitable for
Automatic dilutor.Isomeric alcohol polyethenoxy ether (abbreviation isomery alcohol ether) is the non-ionic of the pure and mild reacting ethylene oxide generation of isomery
Surfactant.Compared with typical straight chain AEO such as Lauryl Alcohol, branched chain type AEO is there are difficult point in stability of solution difference and water
Scattered problem.The better cleaning effect of isomeric alcohol polyethenoxy ether Environmental compatibility, it is also more satisfactory to the emulsifying effectiveness of grease, and
Lower moles of ethylene oxide addition product has better wettability than the straight chain alcohol ethylene oxide adduct of identical molecular mass.
The high surface activity of isomerous tridecanol polyoxyethylene ether, Environmental compatibility are good, are the preferable productions for replacing alkylphenol ethoxylate
Product.
Embodiment two:
A kind of concentrated type detergent, the dosage of each component of raw material is as shown in figure 1 shown in serial number two, it is preferable that the water is
Deionized water.
Its production method includes the following steps:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: it is molten to its that stirring in the resulting mixture of step C is added in the isomerous tridecanol polyoxyethylene ether sodium sulphate
Solution；
E: it is molten to its that stirring in the resulting mixture of step D is added in the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides
Solution；
F: after the resulting mixture of step E is heated to 98 DEG C, heat preservation 15 minutes, 55 DEG C are cooled to.Preferably, between use
Steam is connect to heat the resulting mixture of step E.
Wherein, in described step B, C, D and E, environment temperature is 70 DEG C, mixing speed 200r/min.
Embodiment three:
A kind of concentrated type detergent, the dosage of each component of raw material is as shown in figure 1 shown in serial number three, it is preferable that the water is
Deionized water.Preferably, the preservative is Kathon.
Its production method includes the following steps:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: it is molten to its that stirring in the resulting mixture of step C is added in the isomerous tridecanol polyoxyethylene ether sodium sulphate
Solution；
E: it is molten to its that stirring in the resulting mixture of step D is added in the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides
Solution；
F: after the resulting mixture of step E is heated to 98 DEG C, heat preservation 15 minutes, 55 DEG C are cooled to.
G: the preservative and essence are added in the resulting mixture of step F and stirred evenly.
Wherein, in described step B, C, D and E, environment temperature is 60 DEG C, mixing speed 350r/min.
Example IV:
A kind of concentrated type detergent, the dosage of each component of raw material is as shown in figure 1 shown in serial number four, it is preferable that the water is
Deionized water.Preferably, the preservative is Kathon, and the essence is sweet orange oil.
Its production method includes the following steps:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: it is molten to its that stirring in the resulting mixture of step C is added in the isomerous tridecanol polyoxyethylene ether sodium sulphate
Solution；
E: it is molten to its that stirring in the resulting mixture of step D is added in the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides
Solution；
F: the resulting mixture of step E is heated to 95 DEG C, heat preservation after twenty minutes, is cooled to 45 DEG C.
G: the preservative and essence are added in the resulting mixture of step F and stirred evenly.
Wherein, in described step B, C, D and E, environment temperature is 65 DEG C, mixing speed 250r/min.
Embodiment five:
A kind of concentrated type detergent, the dosage of each component of raw material is as shown in figure 1 shown in serial number five, it is preferable that the water is
Deionized water.Preferably, the preservative is Kathon, and the essence is sweet orange oil.
Its production method includes the following steps:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: it is molten to its that stirring in the resulting mixture of step C is added in the isomerous tridecanol polyoxyethylene ether sodium sulphate
Solution；
E: it is molten to its that stirring in the resulting mixture of step D is added in the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides
Solution；
F: after the resulting mixture of step E is heated to 93 DEG C, heat preservation 18 minutes, 50 DEG C are cooled to.
G: the preservative and the sweet orange oil are added in the resulting mixture of step F and stirred evenly.
Wherein, in described step B, C, D and E, environment temperature is 55 DEG C, mixing speed 450r/min.
Experimental verification:
Detergency verifying:
The concentrated type detergent of Example one~five and commercially available concentrated type detergent A, B and C with deionized water (or from
Water) in proportion dilute after, number consecutively 1~8, with GB9985-2000 " the People's Republic of China's national standard manual dishwashing use
Detergent " Appendix B detergency measuring method carry out detergency measurement, as shown in Fig. 2, concentrated type detergent of the invention is gone
Dirty power is above national standard (national standard, 3.0 minimums), and is higher than similar commercial product.
Place test:
The concentrated type detergent of Example one~five and commercially available concentrated type detergent A, B and C respectively take a certain amount of sample,
Number consecutively 1~8, is placed in the transparent plastic bottle of PE material and plastic packaging, the dosage of sample are the 1/3 to 2/ of plastic bottle capacity
3.It places it at room temperature, observes it respectively at 0 day, 7 days, 1 month and 12 months and whether be layered and whether be uniformly dispersed.Such as
Shown in Fig. 3, concentrated type detergent of the invention and commercial like product Monodispersed uniformly and are long placed in and do not find lamination.
Diffusion verifying:
The concentrated type detergent of Example one~five and commercially available concentrated type detergent A, B and C respectively take 2g, number consecutively
1~8, it is stood in water, until being completely dissolved, records the time being completely dissolved.Different water temperatures do multiple groups test.Test result is such as
Shown in Fig. 4, diffusivity is more preferable at low temperature compared with commercial like product for concentrated type detergent of the invention.
The scope of protection of the present invention is not limited to this.Those skilled in the art are made equivalent on the basis of the present invention
Substitution or transformation, it is within the scope of the present invention.Protection scope of the present invention is subject to claims.
Claims (10)
1. a kind of concentrated type detergent, which is characterized in that its raw material includes the component of following parts by weight: 2~6 parts of α-alkenyl
Sodium sulfonate；9~13 parts of isomerous tridecanol polyoxyethylene ether sodium sulphate；12~19 parts of isomerous tridecanol polyoxyethylene ether；21
~25 parts of heterogeneous ten alcohol polyoxyethylene ether；6~10 parts of alkyl glycosides；35~43 parts of water.
2. concentrated type detergent as described in claim 1, which is characterized in that its raw material includes the component of following parts by weight: 3
~5 parts of α-sodium olefin sulfonate；10~12 parts of isomerous tridecanol polyoxyethylene ether sodium sulphate；13~18 parts of isomerous tridecanol
Polyoxyethylene ether；22~24 parts of heterogeneous ten alcohol polyoxyethylene ether；7~9 parts of alkyl glycosides；38~40 parts of water.
3. concentrated type detergent as claimed in claim 2, which is characterized in that its raw material includes the component of following parts by weight: 4
α-the sodium olefin sulfonate of part；11 parts of isomerous tridecanol polyoxyethylene ether sodium sulphate；15 parts of isomerous tridecanol polyoxyethylene ether；
23 parts of heterogeneous ten alcohol polyoxyethylene ether；8 parts of alkyl glycosides；39 parts of water.
4. the concentrated type detergent as described in claims 1 to 3 is any, which is characterized in that its raw material further includes following parts by weight
Several component: 0.05 part of essence and 0.1 part of preservative.
5. concentrated type detergent as claimed in claim 4, which is characterized in that the water is deionized water.
6. the production method of any concentrated type detergent of Claims 1 to 5, which comprises the steps of:
A: each component of the material of concentrated type detergent is weighed in proportion；
B: the α-sodium olefin sulfonate is added in the water and is stirred to its dissolution；
C: the isomerous tridecanol polyoxyethylene ether is added in the resulting mixture of step B and is stirred to its dissolution；
D: the isomerous tridecanol polyoxyethylene ether sodium sulphate is added in the resulting mixture of step C and is stirred to its dissolution；
E: the heterogeneous ten alcohol polyoxyethylene ether and alkyl glycosides are added in the resulting mixture of step D and stirred to its dissolution；
F: after the resulting mixture of step E is heated to 90~98 DEG C, heat preservation 15~25 minutes, 30~55 DEG C are cooled to.
7. the production method of concentrated type detergent as claimed in claim 6, which is characterized in that in the step F, by step E
Resulting mixture is heated to 95 DEG C, and heat preservation after twenty minutes, is cooled to 45 DEG C.
8. the production method of concentrated type detergent as claimed in claim 6, which is characterized in that after the step F, further include
Step G: the essence and the preservative are added in the resulting mixture of step F and stirred evenly.
9. the production method of the concentrated type detergent as described in claim 6~8 is any, which is characterized in that described step B, C, D
In E, environment temperature is 50~70 DEG C, and mixing speed is 200~500r/min.
10. the production method of concentrated type detergent as claimed in claim 9, which is characterized in that in described step B, C, D and E,
Environment temperature is 60 DEG C, mixing speed 350r/min.
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| CN201711225951.9A CN109837141A (en) | 2017-11-29 | 2017-11-29 | Concentrated type detergent and its production method |
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| CN201711225951.9A CN109837141A (en) | 2017-11-29 | 2017-11-29 | Concentrated type detergent and its production method |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111304017A (en) * | 2020-03-24 | 2020-06-19 | 万华化学集团股份有限公司 | Mild low-foam washing gel bead and preparation method thereof |
| CN113373006A (en) * | 2021-06-08 | 2021-09-10 | 四川海辰日用化工有限公司 | Super-concentrated laundry detergent and preparation method thereof |
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| CN106318686A (en) * | 2016-08-16 | 2017-01-11 | 中轻日化科技有限公司 | Efficient and environment-friendly concentrated hard surface cleaning agent |
| CN106635471A (en) * | 2016-10-08 | 2017-05-10 | 肇庆市科捷人力资源服务有限公司 | Hyper-concentrated laundry detergent and preparation method thereof |
| CN107338122A (en) * | 2017-06-29 | 2017-11-10 | 传化智联股份有限公司 | A kind of multi-functional emulsifier and its application |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643725A (en) * | 2012-04-25 | 2012-08-22 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
| CN103695197A (en) * | 2013-12-04 | 2014-04-02 | 佛山市新战略知识产权文化有限公司 | High-concentration laundry detergent |
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| CN106635471A (en) * | 2016-10-08 | 2017-05-10 | 肇庆市科捷人力资源服务有限公司 | Hyper-concentrated laundry detergent and preparation method thereof |
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| CN111304017A (en) * | 2020-03-24 | 2020-06-19 | 万华化学集团股份有限公司 | Mild low-foam washing gel bead and preparation method thereof |
| CN111304017B (en) * | 2020-03-24 | 2022-09-20 | 万华化学集团股份有限公司 | Mild low-foam washing gel bead and preparation method thereof |
| CN113373006A (en) * | 2021-06-08 | 2021-09-10 | 四川海辰日用化工有限公司 | Super-concentrated laundry detergent and preparation method thereof |
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Application publication date: 20190604 |