CN109971561A - A kind of concentrated cleaning and preparation method thereof based on modified grease anionic surfactant - Google Patents
A kind of concentrated cleaning and preparation method thereof based on modified grease anionic surfactant Download PDFInfo
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- CN109971561A CN109971561A CN201711438910.8A CN201711438910A CN109971561A CN 109971561 A CN109971561 A CN 109971561A CN 201711438910 A CN201711438910 A CN 201711438910A CN 109971561 A CN109971561 A CN 109971561A
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- modified grease
- anionic surfactant
- grease
- concentrated cleaning
- modified
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Abstract
The present invention provides the concentrated cleanings and preparation method thereof based on a kind of modified grease anionic surfactant, the raw material for preparing the concentrated cleaning solution includes modified grease anionic surfactant, modified grease nonionic surfactant, alkyl glycosides, carboxylate, isomeric alcohol polyethenoxy ether, auxiliary agent, enzyme preparation, essence and deionization, the High-concentration laundry detergent being made into, it is good without gel phase region, low temperature flow, Low-foam and easily rinsing, to grease strong detergency, good frost resistance；Meanwhile raw material selected by the present invention is the raw material of natural reproducible, performance is mild, non-stimulated to skin；In addition, detergent of the present invention is highly concentrated miniature, active matter content reaches 45% ~ 90%, can greatly reduce packing cost and production cost, be conducive to environmental protection.
Description
Technical field
The invention belongs to fabric washing technical field, in particular to based on a kind of modified grease anionic surfactant
Concentrated cleaning and preparation method thereof.
Background technique
Attention of the recent years due to people to environmental protection, the dynamics that especially close one or two years carrys out environmental protection are more next
It is bigger.For washing industry, it is also faced with great challenge, either to the content of detergent or packaging material,
Strict requirements are proposed, especially some environmental protection raw material not up to standard, packaging material manufacturer are shut down, rectified, just made
At the raising of raw material, packing cost.It increases the cost of downstream producer also, in order to seek to develop, forces down
Producer is swum, when researching and developing new product, will preferentially select some easily biological-degradables, environmental requirement raw material up to standard, and
The highly enriched product of development & production, to reduce packaging material rise in price bring increased costs.Therefore research and development are a natural highly concentrated
The product of contracting just becomes inevitable trend.
Summary of the invention
In view of the above-mentioned problems, the object of the present invention is to provide the concentrations based on a kind of modified grease anionic surfactant
Detergent and preparation method thereof, used in primary raw material be modified oil lipid surfactant, including modified grease yin from
Sub- surfactant, modified grease nonionic surfactant, such surfactant are to utilize official using natural oil as raw material
Grafting and modification technology, a natural oil surfactant of exploitation can be rolled into a ball.This surfactant water-soluble is good, not gel,
Pour point is low, low bubble, resistance to hard water is good, compatibility is good.The High-concentration laundry detergent being made into, no gel phase region, low temperature flow
It is good, Low-foam and easily rinsing, to grease strong detergency, good frost resistance.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of concentrated cleaning based on modified grease anionic surfactant, the raw material for preparing the concentrated cleaning include
Modified grease anionic surfactant, modified grease nonionic surfactant, alkyl glycosides, carboxylate, isomery alcohol polyoxy
Vinethene, auxiliary agent, enzyme preparation, essence and deionized water, the weight part ratio of each raw material are as follows:
Modified grease anionic surfactant 10-40
Modified grease nonionic surfactant 10-55
Alkyl glycosides 3-18
Carboxylate 0-20
Isomeric alcohol polyethenoxy ether 0-20
Auxiliary agent 5-15
Enzyme preparation 0-5
Essence 0.3-2
Deionized water polishing is to 100.
Further, the modified grease anionic surfactant is modified grease ethoxylation sulfonate.
Further, the modified grease nonionic surfactant is modified grease ethoxylate.
Further, the R of the isomeric alcohol polyethenoxy ether is C10-C13；The isomeric alcohol polyethenoxy ether that EO number is 7 or 9.
Further, the carboxylate is AEO carboxylic acid sodium/sylvite.
Further, the auxiliary agent includes organic additive and inorganic assistant.
Further, the enzyme preparation is that protease, amylase, lipase, cellulase are one such or several
Mixture.
The preparation method of the concentrated cleaning the following steps are included:
Modified grease nonionic surfactant, modified grease anionic surfactant, isomery are sequentially added in a kettle
Alcohol polyoxyethylene ether, carboxylate, alkyl glycosides, auxiliary agent, stirring and dissolving add enzyme preparation, essence stirs evenly, polishing go from
Sub- water to get arrive the concentrated cleaning.
The present invention having the beneficial effect that compared with prior art
1, the concentrated cleaning based on modified grease anionic surfactant of the present invention is a kind of highly concentrated miniature product,
Wherein the content of active matter reaches 45% ~ 90%, and active quantities are high, reduces packing cost and production cost, is conducive to environmental protection；
2, the concentrated cleaning based on modified grease anionic surfactant of the present invention, used in primary raw material
For modified oil lipid surfactant, including modified grease anionic surfactant, modified grease nonionic surfactant,
Such surfactant is to utilize functional group's grafting and modification technology, a natural oil table of exploitation using natural oil as raw material
Face activating agent.This surfactant water-soluble is good, not gel, pour point it is low, it is low bubble, resistance to hard water is good, compatibility is good, preparation obtains
The concentrated cleaning it is good without gel phase region, low temperature flow, Low-foam and easily rinsing, to grease strong detergency, good frost resistance；
3, the concentrated cleaning based on modified grease anionic surfactant of the present invention, selected raw material is day
Right reproducible raw material, performance is mild, non-stimulated to skin.
Specific embodiment
Embodiment 1
A kind of concentrated cleaning based on modified grease anionic surfactant, the raw material for preparing the concentrated cleaning include
Modified grease anionic surfactant, modified grease nonionic surfactant, alkyl glycosides, carboxylate, isomery alcohol polyoxy
Vinethene, auxiliary agent, enzyme preparation, essence and deionized water, the weight part ratio of each raw material are as follows:
Modified grease anionic surfactant 10-40
Modified grease nonionic surfactant 10-55
Alkyl glycosides 3-18
Carboxylate 0-20
Isomeric alcohol polyethenoxy ether 0-20
Auxiliary agent 5-15
Enzyme preparation 0-5
Essence 0.3-2
Deionized water polishing is to 100.
Further, the modified grease anionic surfactant is modified grease ethoxylation sulfonate.
Further, the modified grease nonionic surfactant is modified grease ethoxylate.
Further, the R of the isomeric alcohol polyethenoxy ether is C10-C13；The isomeric alcohol polyethenoxy ether that EO number is 7 or 9.
Further, the carboxylate is AEO carboxylic acid sodium/sylvite.
Further, the auxiliary agent includes organic additive and inorganic assistant.
Further, the enzyme preparation is that protease, amylase, lipase, cellulase are one such or several
Mixture.
The preparation method of the concentrated cleaning the following steps are included:
Modified grease nonionic surfactant, modified grease anionic surfactant, isomery are sequentially added in a kettle
Alcohol polyoxyethylene ether, carboxylate, alkyl glycosides, auxiliary agent, stirring and dissolving adds enzyme preparation, essence stirs evenly to get to institute
The concentrated cleaning stated.
Unit of weight used in the present embodiment is kilogram, or gram；
Each raw material described in the present embodiment is the conventional products sold in the market；
In the present embodiment, each raw material in the concentrated cleaning can in the ratio range provided flexible combination, herein
It does not enumerate one by one.
Embodiment 2
The present embodiment is preferred embodiment on that basis of example 1, and raw materials used quality is same as Example 1, which washes
Wash the weight fraction ratio of each raw material of agent are as follows:
Modified grease polyethenoxy ether sulphonate 17
Modified grease polyoxyethylene ether 35
Aliphatic alcohol polyethenoxy ether carboxylate 18
Isomeric alcohol polyethenoxy ether 18
Alkyl glycosides 3
Propylene glycol 5
Enzyme preparation 1.3
Essence 0.8
Deionized water polishing is to 100；
The concentrated cleaning the preparation method comprises the following steps: sequentially adding modified grease polyoxyethylene ether, modified grease in a kettle
Polyethenoxy ether sulphonate, isomeric alcohol polyethenoxy ether, aliphatic alcohol polyethenoxy ether carboxylate, alkyl glycosides, propylene glycol stirring
Dissolution, addition enzyme preparation, essence stir evenly, and polishing deionized water stands and obtains the concentrated cleaning.
Embodiment 3
The present embodiment is preferred embodiment on that basis of example 1, and raw materials used quality is same as Example 1, which washes
Wash the weight fraction ratio of each raw material of agent are as follows:
Modified grease polyethenoxy ether sulphonate 24
Modified grease polyoxyethylene ether 33
Aliphatic alcohol polyethenoxy ether carboxylate 13
Isomeric alcohol polyethenoxy ether 20
Alkyl glycosides 4
Propylene glycol 3
Enzyme preparation 1.5
Essence 1.0
Deionized water polishing is to 100.
Embodiment 4
The present embodiment is preferred embodiment on that basis of example 1, and raw materials used quality is same as Example 1, which washes
Wash the weight fraction ratio of each raw material of agent are as follows:
Modified grease polyethenoxy ether sulphonate 25
Modified grease polyoxyethylene ether 35
Aliphatic alcohol polyethenoxy ether carboxylate 18
Isomeric alcohol polyethenoxy ether 10
Propylene glycol 4.0
Enzyme preparation 2.0
Essence 0.6
Deionized water polishing is to 100.
Embodiment 5
The present embodiment is preferred embodiment on that basis of example 1, and raw materials used quality is same as Example 1, which washes
Wash the weight fraction ratio of each raw material of agent are as follows:
Modified grease polyethenoxy ether sulphonate 30
Modified grease polyoxyethylene ether 42
Aliphatic alcohol polyethenoxy ether carboxylate 10
Isomeric alcohol polyethenoxy ether 8
Alkyl glycosides 5
Enzyme preparation 0.8
Essence 1.0
Deionized water polishing is to 100.
Embodiment 6
The present embodiment is preferred embodiment on that basis of example 1, and raw materials used quality is same as Example 1, which washes
Wash the weight fraction ratio of each raw material of agent are as follows:
Modified grease polyethenoxy ether sulphonate 29
Modified grease polyoxyethylene ether 38
Isomeric alcohol polyethenoxy ether 15
Alkyl glycosides 3
Aliphatic alcohol polyethenoxy ether carboxylate 10
Propylene glycol 2
Enzyme preparation 1.6
Essence 0.8
Deionized water polishing is to 100.
Experimental result:
1, standard stain release power:
This High-concentration laundry detergent its standard stain release power under the premise of diluting 8-10 times can be above standard liquid detergent.
Experiment is the detergency done in the case that sample dilutes 8 times below.
| Sample | Standard liquid detergent (0.2%) | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Commercially available 1 |
| JB-01 | 1.0 | 1.02 | 1.05 | 1.30 | 1.05 | 1.22 | 0.98 |
| JB-02 | 1.0 | 2.37 | 2.54 | 2.72 | 2.66 | 3.71 | 1.75 |
| JB-03 | 1.0 | 1.43 | 1.46 | 2.33 | 1.54 | 2.27 | 1.50 |
Experiment is the detergency that sample is done in the case where diluting 10 times below.
| Soiled cotton | Standard liquid detergent (0.2%) | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Commercially available 1 |
| JB-01 | 1.0 | 0.98 | 1.0 | 1.16 | 1.02 | 1.13 | 0.94 |
| JB-02 | 1.0 | 2.20 | 2.45 | 2.62 | 2.42 | 3.05 | 1.53 |
| JB-03 | 1.0 | 1.26 | 1.23 | 2.02 | 1.32 | 2.01 | 1.38 |
By experiment it can be proved that embodiment is that can pass through standard stain release when sample extension rate is 8-10 times
, but show outstanding for embodiment 4 and embodiment 6.
2, practical detergency:
Practical detergency is washed according to international standard IEC-60456, and wash result is as follows: removing standard liquid detergent
Outside, remaining sample is the wash result diluted after 8 times；
Detergency result of the sample when diluting 10 times is as follows:
By experiment it is found that it is also outstanding that embodiment 4 and embodiment 6, which show, on practical soiled cotton.
Claims (8)
1. the concentrated cleaning based on a kind of modified grease anionic surfactant, which is characterized in that prepare the concentration and wash
The raw material for washing agent includes modified grease anionic surfactant, modified grease nonionic surfactant, alkyl glycosides, carboxylic acid
Salt, isomeric alcohol polyethenoxy ether, auxiliary agent, enzyme preparation, essence and deionized water, the weight part ratio of each raw material are as follows:
Modified grease anionic surfactant 10-40
Modified grease nonionic surfactant 10-55
Alkyl glycosides 3-18
Carboxylate 0-20
Isomeric alcohol polyethenoxy ether 0-20
Auxiliary agent 5-15
Enzyme preparation 0-5
Essence 0.3-2
Deionized water polishing is to 100.
2. the concentrated cleaning based on modified grease anionic surfactant according to claim 1, which is characterized in that
The modified grease anionic surfactant is modified grease ethoxylation sulfonate.
3. the concentrated cleaning based on modified grease anionic surfactant according to claim 1, which is characterized in that
The modified grease nonionic surfactant is modified grease ethoxylate.
4. the concentrated cleaning based on modified grease anionic surfactant according to claim 1, which is characterized in that
The R of the isomeric alcohol polyethenoxy ether is C10-C13；The isomeric alcohol polyethenoxy ether that EO number is 7 or 9.
5. the concentrated cleaning based on modified grease anionic surfactant according to claim 1, which is characterized in that
The carboxylate is AEO carboxylic acid sodium/sylvite.
6. the concentrated cleaning based on modified grease anionic surfactant according to claim 1, which is characterized in that
The auxiliary agent includes organic additive and inorganic assistant.
7. the concentrated cleaning based on modified grease anionic surfactant according to claim 1, which is characterized in that
The enzyme preparation is the one such or several mixture of protease, amylase, lipase, cellulase.
8. a kind of preparation method of the concentrated cleaning based on modified grease anionic surfactant, which is characterized in that preparation
The raw material of the concentrated cleaning includes modified grease anionic surfactant, modified grease nonionic surfactant, alkane
Base glucosides, carboxylate, isomeric alcohol polyethenoxy ether, auxiliary agent, enzyme preparation, essence and deionized water, the parts by weight of each raw material
Number ratio are as follows:
Modified grease anionic surfactant 10-40
Modified grease nonionic surfactant 10-55
Alkyl glycosides 3-18
Carboxylate 0-20
Isomeric alcohol polyethenoxy ether 0-20
Auxiliary agent 5-15
Enzyme preparation 0-5
Essence 0.3-2
Deionized water polishing is to 100；
The preparation method comprises the following steps:
Modified grease nonionic surfactant, modified grease anionic surfactant, isomery are sequentially added in a kettle
Alcohol polyoxyethylene ether, carboxylate, alkyl glycosides, auxiliary agent, stirring and dissolving add enzyme preparation, essence stirs evenly, polishing go from
Sub- water to get arrive the concentrated cleaning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711438910.8A CN109971561A (en) | 2017-12-27 | 2017-12-27 | A kind of concentrated cleaning and preparation method thereof based on modified grease anionic surfactant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711438910.8A CN109971561A (en) | 2017-12-27 | 2017-12-27 | A kind of concentrated cleaning and preparation method thereof based on modified grease anionic surfactant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109971561A true CN109971561A (en) | 2019-07-05 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711438910.8A Pending CN109971561A (en) | 2017-12-27 | 2017-12-27 | A kind of concentrated cleaning and preparation method thereof based on modified grease anionic surfactant |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112251298A (en) * | 2020-10-22 | 2021-01-22 | 特丝丽化工有限公司 | Super-concentrated laundry detergent and preparation method of diluent thereof |
| CN113088407A (en) * | 2021-03-30 | 2021-07-09 | 中国日用化学研究院有限公司 | Washing powder containing modified grease-based ethoxylate sulfonate and preparation method thereof |
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| CN103215143A (en) * | 2013-03-15 | 2013-07-24 | 金红叶纸业集团有限公司 | Cleaning composition and facial tissue using the same |
| CN106479738A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of all purpose cleaner and preparation method thereof |
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| CN103215143A (en) * | 2013-03-15 | 2013-07-24 | 金红叶纸业集团有限公司 | Cleaning composition and facial tissue using the same |
| CN106479738A (en) * | 2016-09-22 | 2017-03-08 | 长兴净安环保科技有限公司 | A kind of all purpose cleaner and preparation method thereof |
| CN107502467A (en) * | 2017-09-01 | 2017-12-22 | 中国日用化学工业研究院 | A kind of transparent liquid detergent composition and preparation method with antiredeposition function |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112251298A (en) * | 2020-10-22 | 2021-01-22 | 特丝丽化工有限公司 | Super-concentrated laundry detergent and preparation method of diluent thereof |
| CN113088407A (en) * | 2021-03-30 | 2021-07-09 | 中国日用化学研究院有限公司 | Washing powder containing modified grease-based ethoxylate sulfonate and preparation method thereof |
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Application publication date: 20190705 |