CN101514307B - Transparent and high-concentration laundry detergent and preparation method thereof - Google Patents
Transparent and high-concentration laundry detergent and preparation method thereof Download PDFInfo
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- CN101514307B CN101514307B CN2008102474789A CN200810247478A CN101514307B CN 101514307 B CN101514307 B CN 101514307B CN 2008102474789 A CN2008102474789 A CN 2008102474789A CN 200810247478 A CN200810247478 A CN 200810247478A CN 101514307 B CN101514307 B CN 101514307B
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- polyoxyethylene polyoxypropylene
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Abstract
The invention provides a transparent and high-concentration laundry detergent and a preparation method thereof. The laundry detergent contains sodium fatty alcohol-polyoxyethyleneether sulfate (70 percent), fatty alcohol polyoxyethylene ether (9), vegetable oil polyoxyethylene polyoxypropylene ether (5), vegetable oil polyoxyethylene polyoxypropylene ether (7), vegetable oil polyoxyethylene polyoxypropylene ether (9), monoethanol amine, sodium alkyl diphenyl ether disulfonate, propylene glvcol, prolease and essence. The laundry detergent adopts an anionic surfactant with good hard water-resistant effect and a non-ionic surfactant with branched chains to compound with a functional surfactant with chelation and dispersion effects, and solves the unsteady problem of high concentration conditions; and the laundry detergent adopts preparation technology of a biological enzyme complex to ensure that biological enzyme is chronically and steadily compounded into a liquid with the surfactants in the form of a complex.
Description
Technical field
The invention belongs to the detergent composition field, specifically a kind of transparent high-concentration laundry detergent and preparation method thereof.
Background technology
Laundry detergent has become one of requisite in the daily life.Laundry detergent is because the product performance of its liquid has advantages such as cold washing, easy dissolving, easy rinsing.Enrichment is one of development trend of laundry detergent, and enrichment means that its development steps into the high-level stage.The laundry detergent of high density not only strong detergency, consumption is few, and saves a large amount of packings, stores and the expenses of management.So in order to satisfy the requirement in people's real life, the needs that response is energy-saving and cost-reducing need a kind of high-concentration laundry detergent on the market.
Summary of the invention
The purpose of this invention is to provide a kind of transparent high-concentration laundry detergent and preparation method thereof, contain polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (9), vegetables oil polyoxyethylene poly-oxygen propylene aether (5), vegetables oil polyoxyethylene poly-oxygen propylene aether (7), vegetables oil polyoxyethylene poly-oxygen propylene aether (9), monoethanolamine, alkyl diphenyl ether disulphonic acid sodium, propylene glycol, proteolytic enzyme, essence among the present invention; The present invention adopts effective anion surfactant of anti-hard water and branched nonionogenic tenside, and is compound with the functional surface promoting agent with chelating dissemination, solved the problem of highly enriched conditional instability; The present invention adopts the technology of preparing of biological enzyme complex, and biological enzyme can be compound in the liquid with tensio-active agent steadily in the long term with the complex compound form.
The objective of the invention is to realize: contain polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (9), vegetables oil polyoxyethylene poly-oxygen propylene aether (5), vegetables oil polyoxyethylene poly-oxygen propylene aether (7), vegetables oil polyoxyethylene poly-oxygen propylene aether (9), monoethanolamine, alkyl diphenyl ether disulphonic acid sodium, propylene glycol, proteolytic enzyme, essence among the present invention by following technical proposals; The weight ratio of each component is in this washing composition:
Polyoxyethylenated alcohol sodium sulfate (70%) 15～40
Fatty alcohol-polyoxyethylene ether (9) 8～20
Vegetables oil polyoxyethylene poly-oxygen propylene aether (5) 0～10
Vegetables oil polyoxyethylene poly-oxygen propylene aether (7) 0～20
Vegetables oil polyoxyethylene poly-oxygen propylene aether (9) 0～15
Monoethanolamine 8～18
Alkyl diphenyl ether disulphonic acid sodium 0～15
Propylene glycol 2～5
Proteinase-10 .2～0.6
Essence 0.6～1.5;
Among the preparation method of this washing composition, steps in sequence is as follows:
A. successively described alkyl diphenyl ether disulphonic acid sodium, monoethanolamine, polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (9), vegetables oil polyoxyethylene poly-oxygen propylene aether (5), vegetables oil polyoxyethylene poly-oxygen propylene aether (7), vegetables oil polyoxyethylene poly-oxygen propylene aether (9) are mixed by the preparation weight ratio and stir, obtain mixed solution A;
B. in described propylene glycol, add proteolytic enzyme by the preparation weight ratio, obtain mixing solutions B;
C. described mixed solution A and described mixing solutions B are mixed, obtain mixed solution C;
D. in described mixed solution C, add described essence, mix and stir, obtain mixing solutions D by the preparation weight ratio;
F. described mixing solutions D is carried out filtration treatment, left standstill 2-4 hour, obtain described transparent high-concentration laundry scouring agent; In the described filtration treatment, the filtering net of employing is 200 orders.
The present invention uses after diluting 6 times, and detersive power detects the A level level that reaches by national sector standard QB1224-2007; Use after diluting 8 times, detersive power detects the C level level that reaches by national sector standard QB1224-2007.
Compared with the prior art the present invention has the following advantages:
1. the present invention is on the basis of the product performance that keeps common washing liquid, with the effective anion surfactant of anti-hard water, with branched nonionogenic tenside, compound with functional surface promoting agent with chelating dissemination, do not add common solubilizing agent; So both improve detersive power, solved the problem of highly enriched conditional instability again;
2. the present invention uses the technology of preparing of biological enzyme complex, and biological enzyme can be compound in the liquid with tensio-active agent steadily in the long term with the complex compound form, and the quality guaranteed period is more than 2 years;
3. product of the present invention uses after diluting 6 times, and detersive power detects the A level level that reaches by national sector standard QB1224-2007; Use after diluting 8 times, detersive power detects the C level level that reaches by national sector standard QB1224-2007;
4. the present invention can reduce packing, production, transportation cost, and save energy is had significance: then can save 5 packing bottle, 5 cover bottle subsides as concentrating by 6 times; 75% production cost, transportation cost have been reduced.
Embodiment
Embodiment 1:
A kind of transparent high-concentration laundry detergent, the weight ratio of each component that contains in this washing composition is:
Polyoxyethylenated alcohol sodium sulfate (70%) 15～40
Fatty alcohol-polyoxyethylene ether (9) 8～20
Vegetables oil polyoxyethylene poly-oxygen propylene aether (5) 0～10
Vegetables oil polyoxyethylene poly-oxygen propylene aether (7) 0～20
Vegetables oil polyoxyethylene poly-oxygen propylene aether (9) 0～15
Monoethanolamine 8～18
Alkyl diphenyl ether disulphonic acid sodium 0～15
Propylene glycol 2～5
Proteinase-10 .2～0.6
Essence 0.6～1.5;
The used weight unit of present embodiment is a kilogram, also can be gram;
Each component described in the present embodiment is technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each component in the described washing composition can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
The polyoxyethylenated alcohol sodium sulfate of selecting for use in the present embodiment (70%): be anti-hard water anion surfactant preferably, it is strong to remove the solid dirt
The fatty alcohol-polyoxyethylene ether of selecting for use in the present embodiment (9), vegetables oil polyoxyethylene poly-oxygen propylene aether (5), vegetables oil polyoxyethylene poly-oxygen propylene aether (7), vegetables oil polyoxyethylene poly-oxygen propylene aether (9) but greasy dirt is had well emulsify, solublization rapid permeability, peels off the greasy dirt on the fabric fibre
The propylene glycol of selecting for use in the present embodiment: as solvating agent, the stablizer of enzyme
The proteolytic enzyme of selecting for use in the present embodiment: strengthen removal ability to the albumen dirt
The alkyl diphenyl ether disulphonic acid sodium of selecting for use in the present embodiment: very strong infiltration decontamination promoter action is arranged, sebum class dirt is had strong removal power
The monoethanolamine of selecting for use in the present embodiment: increase detersive power, improve product appearance.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described transparent high-concentration laundry detergent:
Polyoxyethylenated alcohol sodium sulfate (70%) 37
Fatty alcohol-polyoxyethylene ether (9) 18.8
Vegetables oil polyoxyethylene poly-oxygen propylene aether (5) 5
Vegetables oil polyoxyethylene poly-oxygen propylene aether (7) 10
Vegetables oil polyoxyethylene poly-oxygen propylene aether (9) 5
Monoethanolamine 8
Alkyl diphenyl ether disulphonic acid sodium 10
Propylene glycol 5
Proteinase-10 .6
Essence 0.6;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described transparent high-concentration laundry detergent:
Polyoxyethylenated alcohol sodium sulfate (70%) 15
Fatty alcohol-polyoxyethylene ether (9) 20
Vegetables oil polyoxyethylene poly-oxygen propylene aether (3) 6
Vegetables oil polyoxyethylene poly-oxygen propylene aether (7) 13.5
Vegetables oil polyoxyethylene poly-oxygen propylene aether (9) 15
Monoethanolamine 15
Alkyl diphenyl ether disulphonic acid sodium 10
Propylene glycol 4
Proteinase-10 .5
Essence 0.9;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described transparent high-concentration laundry detergent:
Polyoxyethylenated alcohol sodium sulfate (70%) 25
Fatty alcohol-polyoxyethylene ether (9) 9
Vegetables oil polyoxyethylene poly-oxygen propylene aether (5) 9
Vegetables oil polyoxyethylene poly-oxygen propylene aether (7) 15
Vegetables oil polyoxyethylene poly-oxygen propylene aether (9) 5
Monoethanolamine 18
Alkyl diphenyl ether disulphonic acid sodium 14.3
Propylene glycol 3.5
Proteinase-10 .6
Essence 0.6;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and the quality of raw materials used (component) is identical with embodiment 1, and the weight ratio of each component is in the described transparent high-concentration laundry detergent:
Polyoxyethylenated alcohol sodium sulfate (70%) 30
Fatty alcohol-polyoxyethylene ether (9) 10
Vegetables oil polyoxyethylene poly-oxygen propylene aether (5) 6.4
Vegetables oil polyoxyethylene poly-oxygen propylene aether (7) 15
Vegetables oil polyoxyethylene poly-oxygen propylene aether (9) 10
Monoethanolamine 5
Alkyl diphenyl ether disulphonic acid sodium 18.5
Propylene glycol 3
Proteinase-10 .6
Essence 1.5;
The used weight unit of present embodiment is a kilogram, also can be gram.
Embodiment 6:
Present embodiment is the preparation method of embodiment 1-5.
A kind of preparation method of transparent high-concentration laundry detergent, this washing composition contains polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (9), vegetables oil polyoxyethylene poly-oxygen propylene aether (5), vegetables oil polyoxyethylene poly-oxygen propylene aether (7), vegetables oil polyoxyethylene poly-oxygen propylene aether (9), monoethanolamine, alkyl diphenyl ether disulphonic acid sodium, propylene glycol, proteolytic enzyme, essence; Among the preparation method of described transparent high-concentration laundry detergent, steps in sequence is as follows:
A. successively described alkyl diphenyl ether disulphonic acid sodium, monoethanolamine, polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (9), vegetables oil polyoxyethylene poly-oxygen propylene aether (5), vegetables oil polyoxyethylene poly-oxygen propylene aether (7), vegetables oil polyoxyethylene poly-oxygen propylene aether (9) are mixed by the preparation weight ratio and stir, obtain mixed solution A;
B. in described propylene glycol, add proteolytic enzyme by the preparation weight ratio, obtain mixing solutions B;
C. described mixed solution A and described mixing solutions B are mixed, obtain mixed solution C;
D. in described mixed solution C, add described essence, mix and stir, obtain mixing solutions D by the preparation weight ratio;
F. described mixing solutions D is carried out filtration treatment, left standstill 2-4 hour, obtain described transparent high-concentration laundry scouring agent; In the described filtration treatment, the filtering net of employing is 200 orders.
Claims (6)
1. a transparent high-concentration laundry detergent is characterized in that: contain 70% polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, vegetables oil polyoxyethylene polyoxypropylene (5) ether, vegetables oil polyoxyethylene polyoxypropylene (7) ether, vegetables oil polyoxyethylene polyoxypropylene (9) ether, monoethanolamine, alkyl diphenyl ether disulphonic acid sodium, propylene glycol, proteolytic enzyme, essence in this washing composition; The weight ratio of each component is in this washing composition:
70% polyoxyethylenated alcohol sodium sulfate 15～40
Aliphatic alcohol polyethenoxy (9) ether 8～20
Vegetables oil polyoxyethylene polyoxypropylene (5) ether 5～10
Vegetables oil polyoxyethylene polyoxypropylene (7) ether 10～20
Vegetables oil polyoxyethylene polyoxypropylene (9) ether 5～15
Monoethanolamine 8～18
Alkyl diphenyl ether disulphonic acid sodium 10～15
Propylene glycol 2～5
Proteinase-10 .2～0.6
Essence 0.6～1.5.
2. a kind of transparent high-concentration laundry detergent according to claim 1, it is characterized in that: the weight ratio of each component is in this washing composition:
70% polyoxyethylenated alcohol sodium sulfate 37
Aliphatic alcohol polyethenoxy (9) ether 18.8
Vegetables oil polyoxyethylene polyoxypropylene (5) ether 5
Vegetables oil polyoxyethylene polyoxypropylene (7) ether 10
Vegetables oil polyoxyethylene polyoxypropylene (9) ether 5
Monoethanolamine 8
Alkyl diphenyl ether disulphonic acid sodium 10
Propylene glycol 5
Proteinase-10 .6
Essence 0.6.
3. a kind of transparent high-concentration laundry detergent according to claim 1, it is characterized in that: the weight ratio of each component is in this washing composition:
70% polyoxyethylenated alcohol sodium sulfate 25
Aliphatic alcohol polyethenoxy (9) ether 9
Vegetables oil polyoxyethylene polyoxypropylene (5) ether 9
Vegetables oil polyoxyethylene polyoxypropylene (7) ether 15
Vegetables oil polyoxyethylene polyoxypropylene (9) ether 5
Monoethanolamine 18
Alkyl diphenyl ether disulphonic acid sodium 14.3
Propylene glycol 3.5
Proteinase-10 .6
Essence 0.6.
4. a transparent high-concentration laundry detergent is characterized in that: contain 70% polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, vegetables oil polyoxyethylene polyoxypropylene (5) ether, vegetables oil polyoxyethylene polyoxypropylene (7) ether, vegetables oil polyoxyethylene polyoxypropylene (9) ether, monoethanolamine, alkyl diphenyl ether disulphonic acid sodium, propylene glycol, proteolytic enzyme, essence in this washing composition; The weight ratio of each component is in this washing composition:
70% polyoxyethylenated alcohol sodium sulfate 30
Aliphatic alcohol polyethenoxy (9) ether 10
Vegetables oil polyoxyethylene polyoxypropylene (5) ether 6.4
Vegetables oil polyoxyethylene polyoxypropylene (7) ether 15
Vegetables oil polyoxyethylene polyoxypropylene (9) ether 10
Monoethanolamine 5
Alkyl diphenyl ether disulphonic acid sodium 18.5
Propylene glycol 3
Proteinase-10 .6
Essence 1.5.
5. the preparation method of a transparent high-concentration laundry detergent is characterized in that: contain 70% polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, vegetables oil polyoxyethylene polyoxypropylene (5) ether, vegetables oil polyoxyethylene polyoxypropylene (7) ether, vegetables oil polyoxyethylene polyoxypropylene (9) ether, monoethanolamine, alkyl diphenyl ether disulphonic acid sodium, propylene glycol, proteolytic enzyme, essence in this washing composition; The weight ratio of each component is in this washing composition:
70% polyoxyethylenated alcohol sodium sulfate 15～40
Aliphatic alcohol polyethenoxy (9) ether 8～20
Vegetables oil polyoxyethylene polyoxypropylene (5) ether 5～10
Vegetables oil polyoxyethylene polyoxypropylene (7) ether 10～20
Vegetables oil polyoxyethylene polyoxypropylene (9) ether 5～15
Monoethanolamine 8～18
Alkyl diphenyl ether disulphonic acid sodium 10～15
Propylene glycol 2～5
Proteinase-10 .2～0.6
Essence 0.6～1.5;
Among the preparation method of described transparent high-concentration laundry detergent, steps in sequence is as follows:
A. successively described alkyl diphenyl ether disulphonic acid sodium, monoethanolamine, 70% polyoxyethylenated alcohol sodium sulfate, aliphatic alcohol polyethenoxy (9) ether, vegetables oil polyoxyethylene polyoxypropylene (5) ether, vegetables oil polyoxyethylene polyoxypropylene (7) ether, vegetables oil polyoxyethylene polyoxypropylene (9) ether are mixed by the preparation weight ratio and stir, obtain mixed solution A;
B. in described propylene glycol, add proteolytic enzyme by the preparation weight ratio, obtain mixing solutions B;
C. described mixed solution A and described mixing solutions B are mixed, obtain mixed solution C;
D. in described mixed solution C, add described essence, mix and stir, obtain mixing solutions D by the preparation weight ratio;
F. described mixing solutions D is carried out filtration treatment, left standstill 2-4 hour, obtain described transparent high-concentration laundry scouring agent.
6. according to the preparation method of a kind of transparent high-concentration laundry detergent described in the claim 5, it is characterized in that: in the described filtration treatment, the filtering net of employing is 200 orders.
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| CN2008102474789A CN101514307B (en) | 2008-12-31 | 2008-12-31 | Transparent and high-concentration laundry detergent and preparation method thereof |
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| CN2008102474789A CN101514307B (en) | 2008-12-31 | 2008-12-31 | Transparent and high-concentration laundry detergent and preparation method thereof |
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| CN101514307A CN101514307A (en) | 2009-08-26 |
| CN101514307B true CN101514307B (en) | 2011-07-20 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011213992A (en) * | 2010-03-15 | 2011-10-27 | Kao Corp | Liquid detergent composition |
| CN101857824B (en) * | 2010-04-23 | 2012-08-29 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
| CN102242022B (en) * | 2011-06-15 | 2012-12-19 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102533465B (en) * | 2011-12-30 | 2013-03-13 | 北京绿伞化学股份有限公司 | Low foam fabric liquid detergent and preparation method thereof |
| CN102643725B (en) * | 2012-04-25 | 2014-03-26 | 中国日用化学工业研究院 | Hyper-concentrated liquid detergent and preparation technique thereof |
| EP2925844B1 (en) * | 2012-11-30 | 2022-06-29 | OTI Greentech Group AG | Cleaning composition and use thereof |
| CN106833925A (en) * | 2015-12-04 | 2017-06-13 | 深圳市芭格美生物科技有限公司 | Collar biology enzyme cleaning fluid and its preparation method and application |
| CN106318678A (en) * | 2016-07-25 | 2017-01-11 | 广州普爱生物科技有限公司 | Protease hyperconcentration laundry detergent with no water or corrosion remover or alcohol |
| CN106350279A (en) * | 2016-08-28 | 2017-01-25 | 广州舒雪健康科技有限公司 | Laundry detergent formulation |
| CN107828532A (en) * | 2017-11-08 | 2018-03-23 | 深圳市前海荣格生物技术有限公司 | A kind of hyperconcetration milky biology enzyme liquid detergent and preparation method thereof |
| CN109797054A (en) * | 2019-02-21 | 2019-05-24 | 党峰 | A kind of ferment High-concentration laundry detergent |
| CN109825377A (en) * | 2019-03-21 | 2019-05-31 | 福建省纯杰绿色科技有限公司 | A kind of plant cleaning agent using small molecule depth cleaning technique |
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Denomination of invention: Transparent and high-concentration laundry detergent and preparation method thereof Effective date of registration: 20120502 Granted publication date: 20110720 Pledgee: Standard Chartered Bank (China) Co., Ltd. Beijing branch Pledgor: Beijing Lusan Chemical Co., Ltd. Registration number: 2012990000183 |
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Date of cancellation: 20141209 Granted publication date: 20110720 Pledgee: Standard Chartered Bank (China) Co., Ltd. Beijing branch Pledgor: Beijing Lusan Chemical Co., Ltd. Registration number: 2012990000183 |
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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee after: Beijing green umbrella Technology Co.,Ltd. Address before: 100094, No. 3, North Road, Yongfeng industrial base, Beijing, Haidian District Patentee before: Beijing Lvsan Chemistry Co.,Ltd. |
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