CN102533465A - Low foam fabric liquid detergent and preparation method thereof - Google Patents
Low foam fabric liquid detergent and preparation method thereof Download PDFInfo
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- CN102533465A CN102533465A CN2011104538289A CN201110453828A CN102533465A CN 102533465 A CN102533465 A CN 102533465A CN 2011104538289 A CN2011104538289 A CN 2011104538289A CN 201110453828 A CN201110453828 A CN 201110453828A CN 102533465 A CN102533465 A CN 102533465A
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Abstract
The invention provides a low foam fabric liquid detergent and a preparation method thereof. The detergent comprises fatty alcohol polyoxyethylene lauryl ether sulfate sodium, sodium alpha-olefin sulfonate, fatty alcohol polyoxyethylene (7) ether, coconut oil amide propyl betaine, fatty acid alkanolamide, palm kernel oil fatty acid, fatty oil coconut oil, sodium hydroxide, sodium citrate, 1, 2-benzisothiazoline-3-ketone, essence and deionized water. The low foam fabric liquid detergent and the preparation method of the low foam fabric liquid detergent are strong in dirt-removing power, friendly to environment, small irritation to the skin during usage, low in foam during usage and small in water consumption during rinsing.
Description
Technical field
The present invention relates to chemical field, particularly a kind of low bubble fabric liquid washing agent and preparation method thereof.It is strong lowly to steep the fabric detergency of liquid detergent, and pungency is little.
Background technology
Along with the raising of expanding economy and people's income level, people are also improving the requirement of cleaning product.For cleaning supplies, people not only require high-efficiency cleaning, and require cleaning supplies little to the pungency of skin, require cleaning supplies safety, health.
At present China is used for the water of clothing rinsing every year the chances are 60 ~ 8,000,000,000 tons; If one time rinsing effect is equivalent to three rinsing effect of standard washing powder; Then the rinsing water amount is merely 1/3rd of washing powder washing, can practice thrift the water about 1,500,000,000 tons so at least.China is lack of water property country, therefore need provide a kind of and have the high-efficiency cleaning ability, be prone to rinsing, simultaneously to gentle, the low fabric liquid washing agent that stimulates of skin.
Summary of the invention
The object of the present invention is to provide a kind ofly have the high-efficiency cleaning ability, be prone to rinsing, to gentle, the low low bubble fabric liquid washing agent that stimulates of skin.Should select for use negatively charged ion and zwitterionics as the major surfaces promoting agent by low bubble fabric liquid washing agent; Selected fatty acid ester class low-foaming surfactant and natural, the green composite use of lipid acid reach decontamination, fall the bubble purpose; And select solubilizing agent and sequestrant as washing assistant, improve the resistance to hard water of this washing composition.
Another object of the present invention is to provide a kind of preparation method of low bubble fabric liquid washing agent.
The objective of the invention is to realize by following technical proposals:
A kind of low bubble fabric liquid washing agent; Contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, 1 in the raw material of this washing composition, 2-benzisothiazole-3-ketone, essence, deionized water; Each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 55.9～76.5.
Another object of the present invention realizes through following technical scheme:
This preparing method's preparation process is following:
(1) 20 ~ 40% of said deionized water total amount is heated to 50～60 ℃, and in the placing material still, adds sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to dissolving fully according to said ratio while stirring then, obtain mixed solution A; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component;
(2) deionized water at normal temperature of adding about 20 ~ 40% in mixed solution A; After being stirred to dissolving fully according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide while stirring then, obtain mixed liquid B; When preparing this mixing solutions B, need stir successively when adding described each component;
(3) in mixing solutions B, add Trisodium Citrate, 1,2-benzisothiazole-3-ketone, essence, residue deionized water stir, and leave standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid washing agent.
The invention has the beneficial effects as follows:
The feedstock fat polyoxyethylenated alcohol sodium sulfate that 1 the present invention selects for use, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether all have good soil release characteristics, calcium soap dispersiveness and emulsifying property; The selected fatty acid alkylolamide carries out composite as auxiliary agent and polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, improve the solubilizing power of low bubble fabric liquid washing agent of the present invention, is more conducive to dirt and removes.
The low amphoterics AMONYL 380LC that stimulates of the raw material that 2 the present invention select for use and other tensio-active agent synergy in decontamination, cleaning, reduce the pungency of system, can be used for the washing of underclothes.
Raw material palm kernel oil lipid acid, lipid acid Oleum Cocois and sodium hydroxide that 3 the present invention select for use are used, and except soil removability is provided, have more given the performance of system " low bubble ".
The material auxiliary agent Trisodium Citrate that 4 the present invention select for use can play sequestering action, improves the resistance to hard water of low bubble fabric liquid washing agent of the present invention.
5 the present invention are environmentally friendly, and are little to skin irritation during use, improve the Ross-Miles method according to the mensuration of GB/T 7462-94 tensio-active agent foaming power, and the foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment
Below in conjunction with embodiment the present invention is described further.
Embodiment 1:
A kind of low bubble fabric liquid washing agent; Contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, 1 in the raw material of this washing composition, 2-benzisothiazole-3-ketone, essence, deionized water; Each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 55.9～76.5.
The used weight unit of present embodiment is a kilogram, also can be gram;
Essence described in the present embodiment is food grade essence, and all the other each components are technical grade;
Each component described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each component in the described low bubble fabric liquid washing agent can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
Feedstock fat polyoxyethylenated alcohol sodium sulfate in the present embodiment, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether all have good soil release characteristics, calcium soap dispersiveness and emulsifying property, and the soil removability that is used each component is stronger; The selected fatty acid alkylolamide carries out composite as auxiliary agent and polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, improve the solubilizing power of low bubble fabric liquid washing agent of the present invention, is more conducive to dirt and removes; The low amphoterics AMONYL 380LC that stimulates and other tensio-active agent synergy in decontamination, cleaning, reduce the pungency of washing composition, can be used for the washing of underclothes; Palm kernel oil lipid acid, lipid acid Oleum Cocois and sodium hydroxide are used, and except having soil-removing action, washing composition of the present invention especially has the performance of " low bubble "; The auxiliary agent Trisodium Citrate can play sequestering action, improves the resistance to hard water of low bubble fabric liquid washing agent of the present invention.
Detersive power of the present invention reaches national sector standard QB/T1224-2007 requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method, and the foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
The preparation method of described a kind of low bubble fabric liquid washing agent, its preparation process is following:
(1) 20 ~ 40% (preferred 30%) with said deionized water total amount are heated to 50～60 ℃; And in the placing material still; Add sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to dissolving fully according to said ratio while stirring then, obtain mixed solution A; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component; Heating temperature is preferably 55 ℃ in this step;
(2) deionized water at normal temperature of adding about 20 ~ 40% (preferred 30%) in mixed solution A; After being stirred to dissolving fully according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide while stirring then, obtain mixed liquid B; When preparing this mixing solutions B, need stir successively when adding described each component; Described normal temperature is room temperature, is generally 20 ~ 25 ℃;
(3) in mixing solutions B, add Trisodium Citrate, 1,2-benzisothiazole-3-ketone, essence, residue deionized water stir, and leave standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid washing agent.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 6
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2.5
Sodium hydroxide 0.3
Trisodium Citrate 1.5
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 70.4.
The low bubble fabric detergent product that will meet industry standard is packed, vanning after the product outer packaging detects.
The used weight unit of present embodiment is a kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid washing agent of the present invention reaches the industry standard requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method; The foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 15
α-sodium olefin sulfonate 5
Aliphatic alcohol polyethenoxy (7) ether 4
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5
Lipid acid Oleum Cocois 3
Sodium hydroxide 0.3
Trisodium Citrate 3
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 63.9.
The used weight unit of present embodiment is a kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid washing agent of the present invention reaches the industry standard requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method; The foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.3
Trisodium Citrate 2.5
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 64.4.
The used weight unit of present embodiment is a kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid washing agent of the present invention reaches the industry standard requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method; The foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 1
Sodium hydroxide 0.2
Trisodium Citrate 2
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 68.
The used weight unit of present embodiment is a kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid washing agent of the present invention reaches the industry standard requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method; The foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 6:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 12
α-sodium olefin sulfonate 8
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.2
Trisodium Citrate 3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 65.5.
The used weight unit of present embodiment is a kilogram, also can be gram.
The preparation method of present embodiment sees embodiment 1 for details.
According to industry standard QB/T1224-2007 the product of present embodiment is detected: the soil removability of low bubble fabric liquid washing agent of the present invention reaches the industry standard requirement; Mensuration according to GB/T 7462-94 tensio-active agent foaming power is improved the Ross-Miles method; The foam of low bubble fabric liquid washing agent of the present invention is starkly lower than the commercially available prod, and rinsing gets final product for 1 time.
Embodiment 7:
Present embodiment is the preparation method of low bubble fabric liquid washing agent.
A kind of preparation method of low bubble fabric liquid washing agent; Contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, 1 in the raw material of this washing composition, 2-benzisothiazole-3-ketone, essence, deionized water; Each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 55.9～76.5
This preparing method's preparation process is following:
(1) 20 ~ 40% of said deionized water total amount is heated to 50～60 ℃, and in the placing material still, adds sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to dissolving fully according to said ratio while stirring then, obtain mixed solution A; This mixed solution A is formulated in changing the material still, need stir successively when adding described each component;
(2) deionized water at normal temperature of adding about 20 ~ 40% in mixed solution A; After being stirred to dissolving fully according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide while stirring then, obtain mixed liquid B; When preparing this mixing solutions B, need stir successively when adding described each component;
(3) in mixing solutions B, add Trisodium Citrate, 1,2-benzisothiazole-3-ketone, essence, residue deionized water stir, and leave standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid washing agent.
In above-mentioned process for preparation, should note entire operation clean environment health, dustproof.
The equipment that adopts in the present embodiment is conventional equipment, all can on market, buy to obtain.
Claims (7)
1. one kind low is steeped the fabric liquid washing agent; It is characterized in that: contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, 1 in the raw material of this washing composition, 2-benzisothiazole-3-ketone, essence, deionized water; Each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8～15
α-sodium olefin sulfonate 5～10
Aliphatic alcohol polyethenoxy (7) ether 2～4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 55.9～76.5.
2. low bubble fabric liquid washing agent according to claim 1 is characterized in that: each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 6
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2.5
Sodium hydroxide 0.3
Trisodium Citrate 1.5
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 70.4.
3. low bubble fabric liquid washing agent according to claim 1 is characterized in that: each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 15
α-sodium olefin sulfonate 5
Aliphatic alcohol polyethenoxy (7) ether 4
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5
Lipid acid Oleum Cocois 3
Sodium hydroxide 0.3
Trisodium Citrate 3
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 63.9.
4. low bubble fabric liquid washing agent according to claim 1 is characterized in that: each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 10
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 2
AMONYL 380LC 5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.3
Trisodium Citrate 2.5
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 64.4.
5. low bubble fabric liquid washing agent according to claim 1 is characterized in that: each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8
α-sodium olefin sulfonate 10
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 4
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1.5
Lipid acid Oleum Cocois 1
Sodium hydroxide 0.2
Trisodium Citrate 2
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 68.
6. low bubble fabric liquid washing agent according to claim 1 is characterized in that: each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 12
α-sodium olefin sulfonate 8
Aliphatic alcohol polyethenoxy (7) ether 3
AMONYL 380LC 3
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 1
Lipid acid Oleum Cocois 2
Sodium hydroxide 0.2
Trisodium Citrate 3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 65.5.
7. one kind is hanged down the preparation method who steeps the fabric liquid washing agent; It is characterized in that: contain polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide, palm kernel oil lipid acid, lipid acid Oleum Cocois, sodium hydroxide, Trisodium Citrate, 1 in the raw material of this washing composition, 2-benzisothiazole-3-ketone, essence, deionized water; Each raw materials in part by weight ratio of this washing composition is:
Polyoxyethylenated alcohol sodium sulfate 8 ~ 15
α-sodium olefin sulfonate 5.0 ~ 10.0
Aliphatic alcohol polyethenoxy (7) ether 2 ~ 4
AMONYL 380LC 3～5
Fatty acid alkyl amide 2
Palm kernel oil lipid acid 0.5～1.5
Lipid acid Oleum Cocois 1～3
Sodium hydroxide 0.2～0.3
Trisodium Citrate 1.5～3.0
1,2-benzisothiazole-3-ketone 0.1
Essence 0.2
Deionized water 55.9～76.5
This preparing method's preparation process is following:
(1) 20 ~ 40% of said deionized water total amount is heated to 50～60 ℃, and in the placing material still, adds sodium hydroxide, palm kernel oil lipid acid, lipid acid Oleum Cocois to dissolving fully according to said ratio then, obtain mixed solution A; (2) deionized water at normal temperature of adding about 20 ~ 40% in mixed solution A; After being stirred to dissolving fully according to said ratio adding polyoxyethylenated alcohol sodium sulfate, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, AMONYL 380LC, fatty acid alkyl amide then, obtain mixed liquid B;
(3) in mixing solutions B, add Trisodium Citrate, 1,2-benzisothiazole-3-ketone, essence, residue deionized water left standstill 100 ~ 120 minutes, can obtain described low bubble fabric liquid washing agent.
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| CN104313883A (en) * | 2014-10-20 | 2015-01-28 | 陕西科技大学 | Preparation method of environment-friendly multifunctional textile washing and finishing agent |
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| CN111440674A (en) * | 2020-05-13 | 2020-07-24 | 杭州炫墨生物科技有限公司 | Liquid detergent with mite removing effect |
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| CN104313883B (en) * | 2014-10-20 | 2016-05-04 | 陕西科技大学 | A kind of preparation method of green multifunctional textile washing finishing agent |
| CN105602769A (en) * | 2014-11-21 | 2016-05-25 | 刘建华 | Compound laundry soap solution and preparation method thereof |
| CN106318734A (en) * | 2015-06-19 | 2017-01-11 | 镇江市润州金山包装厂 | Cloth wrapper cleaning compound |
| US11104865B2 (en) | 2016-02-17 | 2021-08-31 | Conopeo, Inc. | Dishwash composition comprising rinse-activatable antifoam |
| CN108467803A (en) * | 2017-12-19 | 2018-08-31 | 苏州纳贝通环境科技有限公司 | A kind of environment-friendly type natural liquid detergent and preparation method thereof |
| CN108395941A (en) * | 2018-04-11 | 2018-08-14 | 岳圳 | A kind of liquid detergent and preparation method thereof of low bubble sterilization |
| CN109706002A (en) * | 2018-12-28 | 2019-05-03 | 诺而曼环保科技（江苏）有限公司 | A kind of degradable aqueous cleaning agent and preparation method thereof |
| CN110157551A (en) * | 2019-06-26 | 2019-08-23 | 广州市淳烨生物科技有限公司 | A kind of High-concentration laundry detergent |
| CN111440674A (en) * | 2020-05-13 | 2020-07-24 | 杭州炫墨生物科技有限公司 | Liquid detergent with mite removing effect |
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