CN104313883B - A kind of preparation method of green multifunctional textile washing finishing agent - Google Patents
A kind of preparation method of green multifunctional textile washing finishing agent Download PDFInfo
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- CN104313883B CN104313883B CN201410554402.6A CN201410554402A CN104313883B CN 104313883 B CN104313883 B CN 104313883B CN 201410554402 A CN201410554402 A CN 201410554402A CN 104313883 B CN104313883 B CN 104313883B
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Abstract
The invention discloses a kind of preparation method of green multifunctional textile washing finishing agent, first poly glycol monomethyl ether and hydroxy silicon oil and animal oleic acid are carried out to esterification, obtain the complex ester that animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil form, then wash finishing agent taking complex ester as Main Components with the composite Green Textiles that obtains of soluble chitosan, lauryl sodium sulfate, natrium citricum, isopropyl alcohol and lasting agent. The inventive method is prepared green multifunctional textile washing finishing agent, has that washing detergency ability is good, comfortable, antistatic a, sterilization of fabric sofetening after washing, the feature such as mothproof, is applicable to natural, synthetic fibers class textile.
Description
Technical field
The invention belongs to textile washing finishing agent technical field, be specifically related to a kind of preparation method of green multifunctional textile washing finishing agent.
Background technology
Indispensable role is being played the part of in textile washing agent in daily life, along with improving constantly of quality of life, people have been not only washing decontamination to the requirement of washing agent, also need it to there are some additional functions, such as can increase and keep the soft comfort of the textile such as clothing, bedding after washing, improve the abilities such as antistatic, sterilization is mothproof. Conventionally in use to keep the functions such as its softness is comfortable, antistatic, sterilization with textile, need to after textile washing, use special auxiliary agent to process it, or delivering to special washing dressing mechanism uses special assistant to process, must expend time in like this and increase financial cost, and the mainly source taking petrochemicals as primary raw material of current textile treating agent used, there is the degraded of being not easy and can produce the feature that more serious water pollutes after use. Therefore, need to developing a kind of process at washing textile, just can to reach the textile washing finishing agent that increases flexibility and comfortableness, improves the functions such as antistatic and sterilization is mothproof necessary, if can use the pollution to environment with minimizing as main component of environmental type surfactant, will inevitably produce good social benefit.
Application number in China's application is 201110453828.9, invention and created name is a kind of low bubble fabric liquid detergent and preparation method thereof, the applying date is 2011.12.30, application publication number be CN102533465A Patent Application Publication a kind of low bubble fabric liquid detergent, in the raw material of this washing agent, contain sodium sulfate of polyethenoxy ether of fatty alcohol, α-sodium olefin sulfonate, aliphatic alcohol polyethenoxy (7) ether, Cocoamidopropyl betaine, fatty acid alkanol amides, palm kernel oil aliphatic acid, aliphatic acid coconut oil, NaOH, natrium citricum, 1, 2-benzisothiazole-3-ketone, essence, deionized water, the ratio of weight and number of each raw material of this washing agent is: sodium sulfate of polyethenoxy ether of fatty alcohol 8-15, α-sodium olefin sulfonate 5-10, aliphatic alcohol polyethenoxy (7) ether 2-4, Cocoamidopropyl betaine 3-5, fatty acid alkanol amides 2, palm kernel oil aliphatic acid 0.5-1.5, aliphatic acid coconut oil 1-3, NaOH 0.2-0.3, natrium citricum 1.5-3.0, BIT 0.1, essence 0.2, deionized water 55.9-76.5, unit of weight used is kilogram, can be also gram.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of Green Textiles washing finishing agent, to there is the soluble chitosan of sterilizing effect and there is washing, arrange, the reasonable coordination of the complex ester that the oleic acid of the functions such as softness and poly glycol monomethyl ether and hydroxy silicon oil form etc. has obtained a kind of green multifunctional textile washing finishing agent, long chain hydrocarbon groups in soft function dependence complex ester in oleic acid segment and organosilicon radical are coated on fiber surface and realize the effect of softening fluffy fiber, gained washing finishing agent main component derive from natural material as shitosan and animal oleic acid, there is pollution little, easily degrade and the feature without environmental protections such as harm to human body.
For achieving the above object, the technical solution used in the present invention is:
The preparation method who the invention provides a kind of green multifunctional textile washing finishing agent, realizes by following steps:
(1) preparation of animal oil acid polyethylene glycol monomethyl ether and hydroxy silicon oil complex ester: 0.6 ~ 0.8 part of 26 ~ 30 parts of animal oleic acid and 30 ~ 35 parts of poly glycol monomethyl ethers, 1 ~ 3 part of hydroxy silicon oil, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 110 DEG C ~ 120 DEG C in dry, anhydrous reactor according to weight portion, be incubated 3 ~ 3.5 hours, be down to room temperature, obtain the complex ester that animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil form;
(2) preparation of green multifunctional textile washing finishing agent: 6 ~ 10 parts of complex ester prepared by step (1) and soluble chitosans, 8 ~ 12 parts of lauryl sodium sulfate, 2 ~ 5 parts of natrium citricums, 4 ~ 8 parts of isopropyl alcohols, 0.5 ~ 1 part of lasting agent, 100 ~ 130 parts of mixing and stirring of water, obtain green functional type textile washing finishing agent.
In such scheme, the outward appearance of described animal oleic acid is faint yellow bright oily liquids, and acid number is 190 ~ 202mgKOH/g, and saponification number is 195 ~ 205mgKOH/g, and iodine number is 80 ~ 100gI2/100g, and freezing point is less than 4 DEG C, and water content is less than 0.5%.
In such scheme, the average molecular mass of described poly glycol monomethyl ether is 2100 ~ 2200.
In such scheme, described hydroxy silicon oil is hydroxy-end capped poly-methyl-silicone oil, and outward appearance is colourless transparent liquid, and the kinematic viscosity 25 DEG C time is less than 30mm2/s, hydroxy radical content >=8.5%.
In such scheme, the deacetylation of described soluble chitosan is greater than 85%, and viscosity is 250mPa.s ~ 200mPa.s, water soluble.
In such scheme, described lasting agent adopts the lasting agent of floral type or Fruity type or composite fragrant or banksia rose type or delicate fragrance type.
Compared with prior art, beneficial effect of the present invention:
The present invention prepares nonionic surface active agent with animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil by esterification, again with the composite a kind of Green Textiles washing finishing agent that obtains of soluble chitosan, lauryl sodium sulfate, natrium citricum, isopropyl alcohol and lasting agent, have that washing detergency ability is good, comfortable and antistatic, the sterilizing of fabric sofetening after washing, the feature such as mothproof, and have the advantages that environmental pollution is little, be applicable to natural, synthetic fibers class textile.
Detailed description of the invention
Below the specific embodiment of the present invention is elaborated.
The embodiment of the present invention is put forward the preparation method to a kind of green multifunctional textile washing finishing agent, realizes by following steps:
(1) preparation of animal oil acid polyethylene glycol monomethyl ether and hydroxy silicon oil complex ester: 0.6 ~ 0.8 part of 26 ~ 30 parts of animal oleic acid and 30 ~ 35 parts of poly glycol monomethyl ethers, 1 ~ 3 part of hydroxy silicon oil, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 110 DEG C ~ 120 DEG C in dry, anhydrous reactor according to weight portion, be incubated 3 ~ 3.5 hours, be down to room temperature, obtain the complex ester that animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil form;
(2) preparation of green multifunctional textile washing finishing agent: 6 ~ 10 parts of complex ester prepared by step (1) and soluble chitosans, 8 ~ 12 parts of lauryl sodium sulfate, 2 ~ 5 parts of natrium citricums, 4 ~ 8 parts of isopropyl alcohols, 0.5 ~ 1 part of lasting agent, 100 ~ 130 parts of mixing and stirring of water, obtain green functional type textile washing finishing agent.
The outward appearance of described animal oleic acid is faint yellow bright oily liquids, and acid number is 190 ~ 202mgKOH/g, and saponification number is 195 ~ 205mgKOH/g, and iodine number is 80 ~ 100gI2/ 100g, freezing point is less than 4 DEG C, and water content is less than 0.5%.
The average molecular mass of described poly glycol monomethyl ether is 2100 ~ 2200.
The deacetylation of described soluble chitosan is greater than 85%, and viscosity is 250mPa.s ~ 200mPa.s, water soluble.
Described hydroxy silicon oil is hydroxy-end capped poly-methyl-silicone oil, and outward appearance is colourless transparent liquid, and the kinematic viscosity 25 DEG C time is less than 30mm2/ s, hydroxy radical content >=8.5%.
The lasting agent of different flavor is selected in described lasting agent as required, as odor types such as floral type, Fruity type, composite fragrant, banksia rose type, delicate fragrance types.
Embodiment 1：
0.6 part of 26 parts of animal oleic acid and 30 parts of poly glycol monomethyl ethers, 1 part of hydroxy silicon oil, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 110 DEG C in dry, anhydrous reactor, insulation is reacted 3 hours, obtain the compound ester type surfactant of animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil, then with obtained green multifunctional textile washing finishing agent with 6 parts of soluble chitosans, 8 parts of lauryl sodium sulfate, 2 parts of natrium citricums, 4 parts of isopropyl alcohols, 0.5 part of lasting agent, 100 parts of mixing and stirring of water.
Embodiment 2：
0.7 part of 27 parts of animal oleic acid and 31 parts of poly glycol monomethyl ethers, 2 parts of hydroxy silicon oils, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 115 DEG C in dry, anhydrous reactor, insulation is reacted 3 hours, obtain the compound ester type surfactant of animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil, then obtained the agent of green multifunctional textile washing with 8 parts of soluble chitosans, 10 parts of lauryl sodium sulfate, 3 parts of natrium citricums, 4 parts of isopropyl alcohols, 0.5 part of lasting agent, 110 parts of mixing and stirring of water.
Embodiment 3：
0.7 part of 28 parts of animal oleic acid and 32 parts of poly glycol monomethyl ethers, 3 parts of hydroxy silicon oils, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 120 DEG C in dry, anhydrous reactor, insulation is reacted 3.5 hours, obtain the compound ester type surfactant of animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil, then obtained green multifunctional textile washing finishing agent with 8 parts of soluble chitosans, 10 parts of lauryl sodium sulfate, 4 parts of natrium citricums, 5 parts of isopropyl alcohols, 0.5 part of lasting agent, 110 parts of mixing and stirring of water.
Embodiment 4：
0.8 part of 29 parts of animal oleic acid and 33 parts of poly glycol monomethyl ethers, 2 parts of hydroxy silicon oils, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 120 DEG C in dry, anhydrous reactor, insulation is reacted 3.5 hours, obtain the compound ester type surfactant of animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil, then obtained green multifunctional textile washing finishing agent with 10 parts of soluble chitosans, 10 parts of lauryl sodium sulfate, 5 parts of natrium citricums, 8 parts of isopropyl alcohols, 0.5 part of lasting agent, 120 parts of mixing and stirring of water.
Embodiment 5：
0.8 part of 30 parts of animal oleic acid and 34 parts of poly glycol monomethyl ethers, 2 parts of hydroxy silicon oils, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 120 DEG C in dry, anhydrous reactor, insulation is reacted 3.5 hours, obtain the compound ester type surfactant of animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil, then obtained green green multifunctional textile washing finishing agent with 10 parts of soluble chitosans, 12 parts of lauryl sodium sulfate, 5 parts of natrium citricums, 8 parts of isopropyl alcohols, 0.5 part of lasting agent, 130 parts of mixing and stirring of water.
Embodiment 6:
0.8 part of 30 parts of animal oleic acid and 35 parts of poly glycol monomethyl ethers, 3 parts of hydroxy silicon oils, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 110 DEG C in dry, anhydrous reactor, insulation is reacted 3.5 hours, obtain the compound ester type surfactant of animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil, then obtained green multifunctional textile washing finishing agent with 8 parts of soluble chitosans, 12 parts of lauryl sodium sulfate, 3 parts of natrium citricums, 6 parts of isopropyl alcohols, 0.5 part of lasting agent, 120 parts of mixing and stirring of water.
Claims (6)
1. a preparation method for green multifunctional textile washing finishing agent, is characterized in that: realize by following steps:
(1) preparation of animal oil acid polyethylene glycol monomethyl ether and hydroxy silicon oil complex ester: 0.6 ~ 0.8 part of 26 ~ 30 parts of animal oleic acid and 30 ~ 35 parts of poly glycol monomethyl ethers, 1 ~ 3 part of hydroxy silicon oil, p-methyl benzenesulfonic acid are mixed and are stirred and heated to 110 DEG C ~ 120 DEG C in dry, anhydrous reactor according to weight portion, be incubated 3 ~ 3.5 hours, be down to room temperature, obtain the complex ester that animal oleic acid and poly glycol monomethyl ether and hydroxy silicon oil form;
(2) preparation of green multifunctional textile washing finishing agent: 6 ~ 10 parts of complex ester prepared by step (1) and soluble chitosans, 8 ~ 12 parts of lauryl sodium sulfate, 2 ~ 5 parts of natrium citricums, 4 ~ 8 parts of isopropyl alcohols, 0.5 ~ 1 part of lasting agent, 100 ~ 130 parts of mixing and stirring of water, obtain green functional type textile washing finishing agent.
2. the preparation method of green multifunctional textile washing finishing agent according to claim 1, it is characterized in that: the outward appearance of described animal oleic acid is faint yellow bright oily liquids, acid number is 190 ~ 202mgKOH/g, and saponification number is 195 ~ 205mgKOH/g, and iodine number is 80 ~ 100gI2/ 100g, freezing point is less than 4 DEG C, and water content is less than 0.5%.
3. the preparation method of green multifunctional textile washing finishing agent according to claim 1, is characterized in that: the average molecular mass of described poly glycol monomethyl ether is 2100 ~ 2200.
4. the preparation method of green multifunctional textile washing finishing agent according to claim 1, is characterized in that: described hydroxy silicon oil is hydroxy-end capped poly-methyl-silicone oil, and outward appearance is colourless transparent liquid, and the kinematic viscosity 25 DEG C time is less than 30mm2/ s, hydroxy radical content >=8.5%.
5. the preparation method of green multifunctional textile washing finishing agent according to claim 1, is characterized in that: the deacetylation of described soluble chitosan is greater than 85%, viscosity is 250mPa.s ~ 200mPa.s, water soluble.
6. the preparation method of green multifunctional textile washing finishing agent according to claim 1, is characterized in that: described lasting agent adopts the lasting agent of floral type or Fruity type or composite fragrant or banksia rose type or delicate fragrance type.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104711854B (en) * | 2015-03-23 | 2016-09-21 | 苏州陈恒织造有限公司 | A kind of combed cotton and soybean protein fiber blended fabric finishing agent |
| CN106801337B (en) * | 2016-12-25 | 2019-07-02 | 佛山市柏丁达家居用品有限公司 | A kind of high preparation method for receiving greasy dirt Wiping material |
| CN111329786B (en) * | 2020-03-25 | 2023-06-23 | 深圳市施尔洁生物工程有限公司 | Multifunctional hand sanitizer containing aminopropanesulfonic acid inner salt type amphoteric structure and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086562A (en) * | 1992-11-04 | 1994-05-11 | 上海海飞日用化工厂 | Collar and sleeve cleaning agent and using method thereof |
| CN1129459A (en) * | 1993-07-08 | 1996-08-21 | 普罗格特-甘布尔公司 | Detergent compositions comprising soil release agents |
| KR100323253B1 (en) * | 1999-04-30 | 2002-02-04 | 정용식 | The chitosan fiber having high degree of strength and elasticity |
| CN102533465A (en) * | 2011-12-30 | 2012-07-04 | 北京绿伞化学股份有限公司 | Low foam fabric liquid detergent and preparation method thereof |
| CN102787032A (en) * | 2012-08-14 | 2012-11-21 | 中国民航大学 | Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086562A (en) * | 1992-11-04 | 1994-05-11 | 上海海飞日用化工厂 | Collar and sleeve cleaning agent and using method thereof |
| CN1129459A (en) * | 1993-07-08 | 1996-08-21 | 普罗格特-甘布尔公司 | Detergent compositions comprising soil release agents |
| KR100323253B1 (en) * | 1999-04-30 | 2002-02-04 | 정용식 | The chitosan fiber having high degree of strength and elasticity |
| CN102533465A (en) * | 2011-12-30 | 2012-07-04 | 北京绿伞化学股份有限公司 | Low foam fabric liquid detergent and preparation method thereof |
| CN102787032A (en) * | 2012-08-14 | 2012-11-21 | 中国民航大学 | Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent |
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Effective date of registration: 20191106 Address after: 450000 Suzhuang Village, Yingyang Town, Xiangcheng County, Xuchang City, Henan Province Patentee after: Li Shuangfeng Address before: 710021 Shaanxi city of Xi'an province Weiyang University City Patentee before: Shaanxi University of Science and Technology |
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