CN102787032A - Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent - Google Patents
Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent Download PDFInfo
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- CN102787032A CN102787032A CN2012102881673A CN201210288167A CN102787032A CN 102787032 A CN102787032 A CN 102787032A CN 2012102881673 A CN2012102881673 A CN 2012102881673A CN 201210288167 A CN201210288167 A CN 201210288167A CN 102787032 A CN102787032 A CN 102787032A
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Abstract
The invention relates to an environment-friendly cleaning agent containing orange oil and a preparation method of the environment-friendly cleaning agent. The cleaning agent consists of the following ingredients in parts by weight: 20 to 30 parts of orange oil, 30 to 50 parts of lauryl sodium sulfate, 10 to 20 parts of fatty alcohol-polyoxyethylene ether, 10 to 20 parts of alkyl glycoside, 10 to 20 parts of ethanol and 100 parts of deionized water. The cleaning agent provided by the invention is characterized in that the orange oil containing more than 80 percent of limonene is used as major ingredients to be compounded with various kinds of surfactants, the cleaning agent has low surface tension, has fragrance and sterilization effects and can effectively remove organic oil stain without corroding the surface of a cleaned object, and in addition, the orange oil is refined and extracted from natural plant orange peels, so the orange oil is harmless to the environment and the human body health, in addition, the biodegradation can be realized, in addition, non-combustion and nonexplosive performance is realized, the use is very safe, and the cleaning agent can be widely applied to the fields of industry, daily use life, medical care and the like.
Description
Technical field
The invention belongs to the fine chemical technology field, particularly relate to a kind of environment-friendly type sanitising agent and preparation method who contains mandarin oil.
Background technology
Be usually used in removing the smeary sanitising agent at present and can be divided into flammable sanitising agent and non-inflammability sanitising agent two big classes, they are widely used in all respects of national economy:
Wherein flammable sanitising agent mainly includes machine hydro carbons and alcohols, and wherein the hydro carbons sanitising agent is gasoline, the kerosene that obtains through the crude oil fractionation, and this type sanitising agent is along with carbon number increases and the flash-point raising, and security increases.The alcohol clean agent has big, the characteristics such as flash-point is lower, easy burning of volatility, so poor stability.The flammable clean agent does not mainly comprise hydrochloric ether and fluorinated hydrocarbon (like HCFC and HFC class) etc.; Little, the high volatility of wherein hydrogenous fluorochlorohydrocarbon vaporization heat; In atmosphere, decompose easily, belong to ODS (ODS), so international community pays special attention to this problem.On December 31st, 1996, all inactive ODS of developed country, 10 years tolerances of developing country; China has promised to undertake and had all eliminated ODS in 2009; Because such material has the greatest impact to environment, and the toxicity of chlorinated hydrocarbon is big, so safety-problems pays particular attention to.
At present the researchist of countries in the world is seeking to environment, to the substituting solvent of human security.From containing PC 560 in the natural mandarin oil, therefore begin to receive people's attention with premium properties.The U.S., Japan, Britain have just carried out development research to the PC 560 in the mandarin oil as far back as the nineties, and have been applied to clean in the field of washing of grease, circuit card cleaning, automobile component cleaning and government utility.The health assessment report that the lemon smell PC 560 solvent to comfortable that the researchist of U.S. Atlanta CDC makes substitutes most of toxic solvents shows, does not find its insalubrity, and there is potential hazard in the user.Among the GRAS (" generally recognized as safe material ") of U.S. food Drug Administration (FDA) approval, the PC 560 in the mandarin oil can be widely used in the various products safely and effectively.But,, so need its modification be become water-insoluble solvent, can directly use, but up to the present not find as yet with the relevant report of mandarin oil as the sanitising agent of main raw material because mandarin oil is a kind of oil-dissolving solvent.
Summary of the invention
In order to address the above problem, the object of the present invention is to provide a kind of with natural phant as main raw material, have biological degradation property fully, environment is not had the environment-friendly type sanitising agent that contains mandarin oil of secondary pollution.
Another object of the present invention is to provide a kind of above-mentioned preparation method who contains the environment-friendly type sanitising agent of mandarin oil.
In order to achieve the above object, the environment-friendly type sanitising agent that contains mandarin oil provided by the invention is made up of the following raw materials according in weight part:
PC 560 content is more than 80% in the described mandarin oil.
Described AEO is selected from any among AEO3, AEO4, AEO5, AEO6, AEO7, AEO8 and the AEO9.
The preparation method who contains the environment-friendly type sanitising agent of mandarin oil provided by the invention comprises the following step that carries out in order:
1) will mix in container with AEO and APG according to the mandarin oil of above-mentioned weight meter, under the rotating speed of 40-50 ℃ temperature and 6000rpm, stirred 20-30 minute;
2) will join according to the sodium lauryl sulphate of above-mentioned weight meter in the container, under the rotating speed of 1000rpm, stir 10 minutes, under the rotating speed of 6000rpm, stir 10-20 minute then;
3) will join in the container according to the deionized water of above-mentioned weight meter speed with 10ml/10mins; Add ethanol then according to above-mentioned weight meter; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
The environment-friendly type sanitising agent that contains mandarin oil provided by the invention is to utilize the mandarin oil contain 80% above PC 560 as staple, and composite and process with the kinds of surface promoting agent, and it has lower surface tension; The delicate fragrance sterilization; Can remove organic greasy dirt effectively, and not corrode the surface that is cleaned thing, and because mandarin oil is to be subordinated to refine in the orange skin of natural phant to form; So it is harmless to environment and HUMAN HEALTH; And biodegradable and do not burn, do not explode, thereby use fool proofly, can be widely used in fields such as industry, daily life and medical treatment.In addition, employed tensio-active agent does not have cloud point, is easy to dilution, and the gel-free phenomenon is easy to use, and anti-highly basic, salt resistance are strong.In addition, this preparation method simple, be convenient to operation.
Embodiment
Below in conjunction with specific embodiment environment-friendly type sanitising agent and the preparation method who contains mandarin oil provided by the invention is elaborated.
Embodiment 1:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 30 kilograms of mandarin oils is mixed in container with 10 kilograms of AEOs (AEO3) and 10 kilograms of APGs, under the rotating speed of 40 ℃ temperature and 6000rpm, stirred 30 minutes;
2) 30 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 10 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 10 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 2:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 25 kilograms of mandarin oils is mixed in container with 15 kilograms of AEOs (AEO3) and 20 kilograms of APGs, under the rotating speed of 45 ℃ temperature and 6000rpm, stirred 25 minutes;
2) 40 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 20 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 3:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 20 kilograms of AEOs (AEO3) and 10 kilograms of APGs, under the rotating speed of 40 ℃ temperature and 6000rpm, stirred 30 minutes;
2) 35 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 10 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 4:
1) 20 kilograms of mandarin oils is mixed in container with 16 kilograms of AEOs (AEO3) and 15 kilograms of APGs, under the rotating speed of 40 ℃ temperature and 6000rpm, stirred 30 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 10 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 5:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 16 kilograms of AEOs (AEO4) and 15 kilograms of APGs, under the rotating speed of 45 ℃ temperature and 6000rpm, stirred 25 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 6:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 10 kilograms of AEOs (AEO5) and 15 kilograms of APGs, under the rotating speed of 40 ℃ temperature and 6000rpm, stirred 30 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 7:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 15 kilograms of AEOs (AEO6) and 15 kilograms of APGs, under the rotating speed of 40 ℃ temperature and 6000rpm, stirred 30 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 10 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 8:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 16 kilograms of AEOs (AEO7) and 15 kilograms of APGs, under the rotating speed of 45 ℃ temperature and 6000rpm, stirred 25 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 9:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 16 kilograms of AEOs (AEO8) and 15 kilograms of APGs, under the rotating speed of 45 ℃ temperature and 6000rpm, stirred 25 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Embodiment 10:
The preparation method of the environment-friendly type sanitising agent that contains mandarin oil that present embodiment provides comprises the following step that carries out in order:
1) 20 kilograms of mandarin oils is mixed in container with 10 kilograms of AEOs (AEO9) and 15 kilograms of APGs, under the rotating speed of 40 ℃ temperature and 6000rpm, stirred 30 minutes;
2) 50 kilograms of sodium lauryl sulphate are joined in the container, under the rotating speed of 1000rpm, stirred 10 minutes, under the rotating speed of 6000rpm, stirred 15 minutes then;
3) speed of 100 kilograms of deionized waters according to 10ml/10mins is joined in the container; Add 15 kilograms of ethanol then; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
In order to verify the biological degradability that contains the environment-friendly type sanitising agent of mandarin oil provided by the invention; The inventor has carried out the biological degradation index determining by the biological degradation measuring method to the environment-friendly type sanitising agent of being prepared by the foregoing description that contains mandarin oil; The result shows; In biodegradation process, every 70mg sanitising agent carbon dioxide releasing amount is 113.58mg, and theoretical carbon dioxide releasing amount is 120.16mg.Therefore, this sanitising agent biological degradation percentage D
T=113.58/120.168 * 100%=94.52%.It is thus clear that this sanitising agent biological degradation rate is higher; Trace it to its cause is because mandarin oil, sodium lauryl sulphate and AEO all have very high biodegradability; Can all be degraded by biology, so sanitising agent provided by the invention is a totally biodegradable.
Claims (4)
1. environment-friendly type sanitising agent that contains mandarin oil, it is characterized in that: the described environment-friendly type sanitising agent that contains mandarin oil is made up of the following raw materials according in weight part:
2. the environment-friendly type sanitising agent that contains mandarin oil according to claim 1 is characterized in that: PC 560 content is more than 80% in the described mandarin oil.
3. the environment-friendly type sanitising agent that contains mandarin oil according to claim 1, it is characterized in that: described AEO is selected from any among AEO3, AEO4, AEO5, AEO6, AEO7, AEO8 and the AEO9.
4. preparation method who contains the environment-friendly type sanitising agent of mandarin oil as claimed in claim 1, it is characterized in that: said preparation method comprises the following step that carries out in order:
1) will mix in container with AEO and APG according to the mandarin oil of above-mentioned weight meter, under the rotating speed of 40-50 ℃ temperature and 6000rpm, stirred 20-30 minute;
2) will join according to the sodium lauryl sulphate of above-mentioned weight meter in the container, under the rotating speed of 1000rpm, stir 10 minutes, under the rotating speed of 6000rpm, stir 10-20 minute then;
3) will join in the container according to the deionized water of above-mentioned weight meter speed with 10ml/10mins; Add ethanol then according to above-mentioned weight meter; Under the rotating speed of 6000rpm, stirred 30 minutes, and at last solution was cooled to 20-25 ℃ temperature and promptly processes the described environment-friendly type sanitising agent that contains mandarin oil.
Priority Applications (1)
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| CN 201210288167 CN102787032B (en) | 2012-08-14 | 2012-08-14 | Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent |
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| CN 201210288167 CN102787032B (en) | 2012-08-14 | 2012-08-14 | Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent |
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| CN102787032A true CN102787032A (en) | 2012-11-21 |
| CN102787032B CN102787032B (en) | 2013-06-12 |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103320242A (en) * | 2013-07-19 | 2013-09-25 | 北方民族大学 | Dry cleaning agent and its preparation method |
| CN103468424A (en) * | 2013-09-26 | 2013-12-25 | 陈理敬 | Environmentally-friendly multifunctional cleanser formula |
| CN104293516A (en) * | 2014-09-30 | 2015-01-21 | 苏州长盛机电有限公司 | Cow-dung oil containing detergent and preparation method thereof |
| CN104313883A (en) * | 2014-10-20 | 2015-01-28 | 陕西科技大学 | Preparation method of environment-friendly multifunctional textile washing and finishing agent |
| CN104560426A (en) * | 2014-11-21 | 2015-04-29 | 杭州洛合科技有限公司 | Environment-friendly degradable cleaning agent and preparation process thereof |
| CN104789391A (en) * | 2015-03-25 | 2015-07-22 | 苏州绿朗新材料科技有限公司 | Fully-biodegradable detergent containing orange oil and preparation method thereof |
| CN104877778A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for cooking utensil cleaning agent |
| CN105733859A (en) * | 2016-01-28 | 2016-07-06 | 中国民航大学 | Cleaning agent capable of eliminating dirt on heat exchanger of aircraft air conditioner system and preparation method |
| CN105821428A (en) * | 2016-06-04 | 2016-08-03 | 罗浩 | Low-corrosiveness medical vessel cleaning agent and preparation method thereof |
| CN106118896A (en) * | 2016-06-07 | 2016-11-16 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
| CN106352734A (en) * | 2016-09-23 | 2017-01-25 | 中国民航大学 | Off-location ultrasonic cleaning method of heat exchanger of aircraft air conditioning system |
| CN107699377A (en) * | 2017-09-06 | 2018-02-16 | 冯伟强 | A kind of non-toxic, multifunctional cleaning agent non-stimulated to skin and eyes, environmentally safe safe to the human body |
| CN107699378A (en) * | 2017-10-19 | 2018-02-16 | 谭志华 | A kind of cleaner in environmental protection and preparation method thereof |
| CN110564521A (en) * | 2019-09-30 | 2019-12-13 | 武汉九珑人福药业有限责任公司 | Cleaning agent composition, preparation method and application thereof |
| CN111187680A (en) * | 2020-01-06 | 2020-05-22 | 康丽莱(山东)环境科技有限公司 | Novel antibacterial and degerming range hood cleaning agent and preparation method thereof |
| CN112980601A (en) * | 2019-12-17 | 2021-06-18 | 中国石油天然气股份有限公司 | Heavy oil pollution oil pipeline cleaning agent and application thereof |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320242A (en) * | 2013-07-19 | 2013-09-25 | 北方民族大学 | Dry cleaning agent and its preparation method |
| CN103468424A (en) * | 2013-09-26 | 2013-12-25 | 陈理敬 | Environmentally-friendly multifunctional cleanser formula |
| CN104293516A (en) * | 2014-09-30 | 2015-01-21 | 苏州长盛机电有限公司 | Cow-dung oil containing detergent and preparation method thereof |
| CN104313883A (en) * | 2014-10-20 | 2015-01-28 | 陕西科技大学 | Preparation method of environment-friendly multifunctional textile washing and finishing agent |
| CN104313883B (en) * | 2014-10-20 | 2016-05-04 | 陕西科技大学 | A kind of preparation method of green multifunctional textile washing finishing agent |
| CN104560426A (en) * | 2014-11-21 | 2015-04-29 | 杭州洛合科技有限公司 | Environment-friendly degradable cleaning agent and preparation process thereof |
| CN104789391B (en) * | 2015-03-25 | 2018-02-16 | 苏州绿朗新材料科技有限公司 | A kind of biological degradable type cleaning agent and preparation method containing citrus seed oil |
| CN104789391A (en) * | 2015-03-25 | 2015-07-22 | 苏州绿朗新材料科技有限公司 | Fully-biodegradable detergent containing orange oil and preparation method thereof |
| CN104877778A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for cooking utensil cleaning agent |
| CN105733859A (en) * | 2016-01-28 | 2016-07-06 | 中国民航大学 | Cleaning agent capable of eliminating dirt on heat exchanger of aircraft air conditioner system and preparation method |
| CN105821428A (en) * | 2016-06-04 | 2016-08-03 | 罗浩 | Low-corrosiveness medical vessel cleaning agent and preparation method thereof |
| CN106118896A (en) * | 2016-06-07 | 2016-11-16 | 安徽普瑞普勒传热技术有限公司 | A kind of plate type heat exchanger complex cleaning and washing agent and its preparation method and application |
| CN106352734A (en) * | 2016-09-23 | 2017-01-25 | 中国民航大学 | Off-location ultrasonic cleaning method of heat exchanger of aircraft air conditioning system |
| CN107699377A (en) * | 2017-09-06 | 2018-02-16 | 冯伟强 | A kind of non-toxic, multifunctional cleaning agent non-stimulated to skin and eyes, environmentally safe safe to the human body |
| CN107699378A (en) * | 2017-10-19 | 2018-02-16 | 谭志华 | A kind of cleaner in environmental protection and preparation method thereof |
| CN110564521A (en) * | 2019-09-30 | 2019-12-13 | 武汉九珑人福药业有限责任公司 | Cleaning agent composition, preparation method and application thereof |
| CN112980601A (en) * | 2019-12-17 | 2021-06-18 | 中国石油天然气股份有限公司 | Heavy oil pollution oil pipeline cleaning agent and application thereof |
| CN112980601B (en) * | 2019-12-17 | 2022-10-04 | 中国石油天然气股份有限公司 | Heavy oil pollution oil pipeline cleaning agent and application thereof |
| CN111187680A (en) * | 2020-01-06 | 2020-05-22 | 康丽莱(山东)环境科技有限公司 | Novel antibacterial and degerming range hood cleaning agent and preparation method thereof |
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