CN104877778A - Preparation method for cooking utensil cleaning agent - Google Patents
Preparation method for cooking utensil cleaning agent Download PDFInfo
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- CN104877778A CN104877778A CN201510344044.0A CN201510344044A CN104877778A CN 104877778 A CN104877778 A CN 104877778A CN 201510344044 A CN201510344044 A CN 201510344044A CN 104877778 A CN104877778 A CN 104877778A
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- limonene
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Abstract
The invention discloses a preparation method for a cooking utensil cleaning agent. The preparation method for the cooking utensil cleaning agent is characterized in that the cooking utensil cleaning agent is composed of high carbon acid polyethylene glycol ester, high carbon acid diethanolamine and natural plant extract limonene. The cooking utensil cleaning agent is strong in fat-dissolving capacity, and the particularly strong cleaning effect on heavy oil strain and heavy glue strain of the surface of cooking utensil is achieved. The cooking utensil cleaning agent is yellow transparent low-vicidity liquid, the pH value is 6-8, and the happy lemon fragrance is achieved.
Description
Technical field
The present invention relates to a kind of preparation method of clean-out system, especially a kind of preparation method of kitchen tools clean-out system.
Background technology
Along with improving constantly of people's living standard, living conditions are also constantly perfect, kitchen has become the important component part of modern house environment, the requirement of people to kitchen is also more and more higher, the kitchen range top, smoke exhaust ventilator, washing platform, locker, integral cabinet, electric equipment products for cooking, clean series products and security alarm series products and the various materials etc. for kitchen finishing, make kitchen cleaning agent consumption increasing, bring huge ski-jump flow to the research of kitchen cleaning agent.The surfacing that current kitchen utensils adopt and coating varied, as cold-rolled steel, the toughened glass of stainless steel, teflon coating, marble, PLASTIC LAMINATED, PVC etc., the plurality of advantages such as these surfacings are beautiful, handsome in appearance with its color, easy to clean are subject to many human consumers and like, but these material self performance vary, higher requirement is proposed to its cleaning, series of problems is brought to the exploitation of kitchen cleaning agent.
Due to food habits and cooking method aspect, not only oil smoke weight in China's residential kitchen, and also on kitchen tools and periphery article surface, grease is very heavy, especially lampblack absorber surface and impeller sticks a thick layer of heavy oil stain.This heavy oil stain at high temperature to be gasified condensation by animals and plants edible oil and other condiment, and even carbonization postadhesion is formed in solid surface; Also can be attached to solid surface by other physics or chemical action, as the consaturated oil in edible oil be oxidized, polyreaction, formed and there is the film-type dirt of strong tack and toughness.In addition, the small-particles such as tiny dust floating in environment and fiber fines on these greases, more increase the difficulty that it is removed by sedimentation and physical adsorption.Main flow heavy oil stain clean-out system many employings high solvent that Vehicles Collected from Market adopts, high pH value or high-alkali formula, cause its security and the feature of environmental protection not good enough.How for the feature of lampblack absorber heavy oil stain, development is efficient, Environmental Safety, neutral sanitising agent are a great problems in civilian cleaning field.
The cleaning technique 1. strong base of tradition kitchen tools: counterweight dirt (as coking wet goods) removal ability is strong, its shortcoming is that corrodibility is comparatively strong, there is larger corrodibility and injury to the skin of tool face and user; 2. solvent-borne type: organic solvent has excellent dissolution effect to grease and grease is removed, but due to organic solvent inflammable, explosive and poisonous, be not too applicable in kitchen environment; 3. surfactant type: this clean-out system is easy to use, action temperature and, cost is low, but the removal effect of counterweight dirt is not ideal, need the long period (about 1 hours) in the solution that substrate product are immersed in containing washing composition in actual use, cause the limitation that clean-out system uses.
Add up according to market survey result, the kitchen utensils of more than 70% explicitly call for and use mild detergent cleaning in operation instruction, and the high grease soil detergent for kitchen use that domestic market is sold is alkaline cleaner, is not suitable with the requirement of kitchen utensils cleaning; Therefore, utilize waste grease and the neutral heavy dirty cleaning agent for kitchen of natural plant extracts development, make it also can reach good degreasing result in neutral conditions, both solved strong basicity clean-out system to the highly corrosive of kitchen tools with to human injury's problem, also solution leaning solvent is inflammable, explosive, poisonous, cost is high, use unsafe problem; In addition, neutral products can increase use range, is applicable to the various kitchen tools in kitchen, articles for use and electrical equipment; Be actually and lead high grease soil detergent by strong basicity to mildness, neutralisation future development.
The formulating of recipe of kitchen utensils sanitising agent needs to consider following four aspects, 1. dirts: comprise the sex change grease, carbon distribution, dust etc. from producing in the food (hydrocarbon polymer, fat, protein and pigment) of many different sourcess, vegetables oil, animal oil and cooking process; 2. material: typical kitchen tackle material has metal (stainless steel, aluminium alloy, copper), glass, ceramic tile, pottery, polyethylene, polypropylene, polyvinyl chloride, marble, coating, timber and pottery etc.3. safety: sanitising agent in use contacts in one's hands unavoidably or splashes on skin, remains in sanitising agent on utensil simultaneously on a small quantity after cleaning, likely with Food Contact, therefore to the nonirritant of human body and nontoxic, be the important indicator of this series products; 4. environmental protection: sanitising agent can flow into underground after using, and this material brings pollution should to environment (water body, soil etc.), have higher biological degradability, meet the requirement of National Environmental famous special product; Therefore design kitchen high grease soil detergent, first will consider efficient wipe oil, and material will be kept not to be damaged, sanitising agent remains minimum, will consider the impact of health on human body and environment simultaneously.
According to molecule composite theory, utilize tensio-active agent to the infiltration of grease, wetting, emulsifying effect, the infiltration of solvent, solubility property, and the solubilising of auxiliary agent, disperse and help emulsifying effect, utilize natural plant extracts to the solvability of oil, glue and the effect supporting antiredeposition simultaneously, combination is optimized to each component, thus meets above-mentioned requirements.
Waste grease is actually the concept of a general reference, is people's common names for all kinds of poor quality oil in life; Abendoned oil can be divided into following a few class: one is the abendoned oil of narrow sense, by the greasy floating matter in water drain or by the leftovers of hotel, restaurant, leftovers (common name swill) oil through simply processing, extracting; Two is pork inferior, haslet, pigskin processing and the oil of output after refining; Three is after exceeding specified requirement for the oily access times of fried food product, then is reused or toward the oil reused after wherein adding some fresh oils.
Utilizing waste grease and manufacturing high carbon acid macrogol ester and high carbon acid diglycollic amide by ester-interchange method is solve one of extraordinary approach of abendoned oil outlet; Recycle these two kinds of nonionogenic tensides and natural plant extracts limonene composite, completely solve the dirty cleaning problems of dirty, the heavy glue of kitchen tools heavy oil
Limonene another name limonene, limonene, belong to monoterpenes compound, colourless oil liquid, have the lemonish fragrance of class, be extensively present in the monocyclic terpene in natural phant, in the thick oil of orange peel, content can reach 60-70%; Limonene has multiple physiologically active and biological function, is widely used in medicine, food, essence and flavoring agent, makeup, clean-out system, pesticide industry; The physical property of limonene, flash-point: 46 DEG C, fusing point :-74.3 DEG C, boiling point: 177 DEG C.Be dissolved in ethanol and most of nonvolatile oil, be slightly soluble in glycerine, water insoluble and propylene glycol; Limonene is nontoxic, nuisanceless, the various chemical solventss used at present can be substituted in industry and civilian cleaning, detrimentally affect is not had to environment, and has good biological degradability, be environmental protection cleaning-type solvent, in a lot of daily chemical essence, food flavor(ing), have application simultaneously; Limonene has the feature of prevention and prohibition tumor promotion, has obvious preventive and therapeutic action, have restraining effect, have solvency action to gallbladdergallstonecholetithiasis to carcinoma of the pancreas cancer of the stomach, lung cancer, liver cancer etc.
Limonene has extraordinary cleansing power to crust body in Industrial products, but the wetting ability of limonene is very bad, and this have impact on the post-processed of limonene to cleaning object.
High carbon acid macrogol ester and high carbon acid diglycollic amide are important class nonionogenic tensides, such tensio-active agent is not easily destroyed by acid, alkali, stability is higher, better water-soluble, electrolyte-resistant, be easy to biological degradation, foam is little, can manufacture efficient kitchen tools clean-out system with limonene is composite.
It is composite that the present invention passes through high carbon acid macrogol ester and high carbon acid diglycollic amide and limonene, also changes this feature of limonene non-hydrophilic, solve the water solubility problems of limonene; Substantially increase the post-processed problem of limonene cleaning kitchen surfaces body, make the present invention after cleaning crust body, then carry out later stage cleaning with water, dirty, the heavy glue dirt of its heavy oil can clean well.
Summary of the invention
The present invention relates to a kind of preparation method of kitchen tools clean-out system, it is characterized in that being made up of high carbon acid macrogol ester, high carbon acid diglycollic amide and natural plant extracts limonene.
Material and proportioning (weight percent):
High carbon acid macrogol ester 10-90%
High carbon acid diglycollic amide 10-90%
Limonene 10-90%.
Wherein, high carbon acid macrogol ester be by waste grease through esterification again with PEG400 transesterify gained; High carbon acid diglycollic amide be by waste grease through esterification again with diethanolamine transesterify gained.
Preparation technology is: with in temperature controlled stainless steel or enamel material reactor, add high carbon acid macrogol ester, high carbon acid diglycollic amide and crude limonene successively, be warming up to 20-60 DEG C, stir, react after 0.5-2 hour, overall material be the low liquid of vicidity of yellow transparent, and be down to normal temperature discharging after qualified after testing, finished product need be placed on preservation in stainless steel vessel.
The finished appearance of preparation is the low liquid of vicidity of yellow transparent, pH value 6-8, has citris aromas.
Embodiment
Embodiment one:
Throwing raw materials ratio (weight percent): high carbon acid macrogol ester 10%, high carbon acid diglycollic amide 10% and crude limonene 80%.
Embodiment two:
Throwing raw materials ratio (weight percent): high carbon acid macrogol ester 10%, high carbon acid diglycollic amide 90% and crude limonene 10%.
Embodiment three:
Throwing raw materials ratio (weight percent): high carbon acid macrogol ester 90%, high carbon acid diglycollic amide 10% and crude limonene 10%.
Embodiment four:
Throwing raw materials ratio (weight percent): high carbon acid macrogol ester 20%, high carbon acid diglycollic amide 20% and crude limonene 60%.
Embodiment five:
Throwing raw materials ratio (weight percent): high carbon acid macrogol ester 30%, high carbon acid diglycollic amide 30% and crude limonene 40%.
Embodiment six:
Throwing raw materials ratio (weight percent): high carbon acid macrogol ester 40%, high carbon acid diglycollic amide 40% and crude limonene 20%.
Kitchen tools clean-out system of the present invention, can be prepared from by following steps according to the proportioning of above 6 embodiments.
Preparation process is: with in temperature controlled stainless steel or enamel material reactor, add high carbon acid macrogol ester, high carbon acid diglycollic amide and crude limonene successively, be warming up to 20-60 DEG C, stir, react after 0.5-2 hour, overall material be the low liquid of vicidity of yellow transparent, and be down to normal temperature discharging after qualified after testing, finished product need be placed on preservation in stainless steel vessel.
Preferably, temperature of reaction is 30 DEG C, 40 DEG C, 50 DEG C.
Preferably, the reaction times is 1 hour-1.5 hours.
Above embodiment, for understanding method of the present invention and core concept, for a person skilled in the art, without departing from the inventive concept of the premise, is carried out any possible change or replacement, is all belonged to protection scope of the present invention.
Claims (5)
1. a preparation method for kitchen tools clean-out system, is characterized in that: be made up of high carbon acid macrogol ester, high carbon acid diglycollic amide and limonene.
2. the preparation method of a kind of kitchen tools clean-out system according to claim 1, is characterized in that: the amount per-cent proportioning of material is:
High carbon acid macrogol ester 10-90%
High carbon acid diglycollic amide 10-90%
Limonene 10-90%.
3. the preparation method of a kind of kitchen tools clean-out system according to claim 1, is characterized in that: high carbon acid macrogol ester be by waste grease through esterification again with PEG400 transesterify gained.
4. the preparation method of a kind of kitchen tools clean-out system according to claim 1, is characterized in that: high carbon acid diglycollic amide be by waste grease through esterification again with diethanolamine transesterify gained.
5. the preparation method of a kind of kitchen tools clean-out system according to claim 1, it is characterized in that: preparation process is: with in temperature controlled stainless steel or enamel material reactor, add high carbon acid macrogol ester, high carbon acid diglycollic amide and crude limonene successively, be warming up to 20-60 DEG C, stir, react after 0.5-2 hour, overall material is the low liquid of vicidity of yellow transparent, be down to normal temperature discharging after qualified after testing, finished product need be placed in stainless steel vessel and preserve.
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Citations (8)
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CN1789398A (en) * | 2005-12-13 | 2006-06-21 | 张刚 | Natural plant type detergent |
CN1993455A (en) * | 2004-06-10 | 2007-07-04 | 布瑞林斯知识产权有限公司 | Cleaning composition |
CN101768530A (en) * | 2010-03-17 | 2010-07-07 | 天津鎏虹科技发展有限公司 | Natural plant cleaning agent |
CN102277239A (en) * | 2011-07-20 | 2011-12-14 | 天津鎏虹科技发展有限公司 | Natural plant aqueous cleaning agent and preparation method thereof |
CN102604761A (en) * | 2012-01-19 | 2012-07-25 | 任航 | All natural fruit and vegetable tableware cleaning agent and preparation method thereof |
CN102787032A (en) * | 2012-08-14 | 2012-11-21 | 中国民航大学 | Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent |
CN103373935A (en) * | 2012-04-13 | 2013-10-30 | 天津博克尼科技发展有限公司 | Method for preparing aliphatic alcohol amide by utilizing waste oil through ester exchange process |
CN103387882A (en) * | 2012-05-11 | 2013-11-13 | 天津博克尼科技发展有限公司 | Method for preparing fatty acid polyethylene glycol ester by utilizing waste oil through ester exchange process |
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2015
- 2015-06-22 CN CN201510344044.0A patent/CN104877778A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1993455A (en) * | 2004-06-10 | 2007-07-04 | 布瑞林斯知识产权有限公司 | Cleaning composition |
CN1789398A (en) * | 2005-12-13 | 2006-06-21 | 张刚 | Natural plant type detergent |
CN101768530A (en) * | 2010-03-17 | 2010-07-07 | 天津鎏虹科技发展有限公司 | Natural plant cleaning agent |
CN102277239A (en) * | 2011-07-20 | 2011-12-14 | 天津鎏虹科技发展有限公司 | Natural plant aqueous cleaning agent and preparation method thereof |
CN102604761A (en) * | 2012-01-19 | 2012-07-25 | 任航 | All natural fruit and vegetable tableware cleaning agent and preparation method thereof |
CN103373935A (en) * | 2012-04-13 | 2013-10-30 | 天津博克尼科技发展有限公司 | Method for preparing aliphatic alcohol amide by utilizing waste oil through ester exchange process |
CN103387882A (en) * | 2012-05-11 | 2013-11-13 | 天津博克尼科技发展有限公司 | Method for preparing fatty acid polyethylene glycol ester by utilizing waste oil through ester exchange process |
CN102787032A (en) * | 2012-08-14 | 2012-11-21 | 中国民航大学 | Environment-friendly cleaning agent containing orange oil and preparation method of environment-friendly cleaning agent |
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Application publication date: 20150902 |