CN105238602A - Degreasing agent and preparation method therefor - Google Patents
Degreasing agent and preparation method therefor Download PDFInfo
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- CN105238602A CN105238602A CN201510735351.1A CN201510735351A CN105238602A CN 105238602 A CN105238602 A CN 105238602A CN 201510735351 A CN201510735351 A CN 201510735351A CN 105238602 A CN105238602 A CN 105238602A
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Abstract
In order to solve problems that an existing degreasing product in the prior art damages human skin, corrodes cleaned appliances, has a relatively strong irritating odor and is not ideal in degreasing effect, the invention provides a degreasing agent and a preparation method therefor. The degreasing agent provided by the present invention is characterized by comprising the following components in percentage by weight: 0.1-5% of edible essence, 0.2-10% of a solubilizing agent, 10-35% of a surfactant, 0.2-8% of a cosolvent, 0.2-8% of a builder, 0.05-1% of dilute hydrochloric acid and the balance of deionized water. The degreasing agent and the preparation method therefor provided by the present invention have the beneficial technical effects of high degreasing rate and fast cleaning speed, mildness, no irritating odor and no damage to human skin and no corrosion to the cleaned appliances.
Description
Technical field
The present invention relates to filed of daily-use chemical industry, particularly relate to a kind of degreaser and preparation method thereof.
Background technology
Kitchen is as formation aspect important in modern house environment, and its sanitation degree is more and more subject to people's attention, and this also makes the proportion of clean-out system in household detergent consumption being suitable for Fouling Cleaning in kitchen appliance and surrounding enviroment thereof be in critical role always.For now, be applicable to the high grease soil detergent of hard surface cleaning in kitchen environment and relate generally to 3 types: 1) be strong acid alkaline, this clean-out system counterweight dirt (as coking wet goods) removal ability is stronger, but corrode also stronger, in use not only larger corrodibility is existed to tool face, comparatively major injury is also existed to the skin of user simultaneously; 2) be solvent-borne type, this clean-out system impels dirt to remove mainly through the excellent dissolution effect of organic solvent to grease, but this kind of degreaser contains the chemicals of irritating smell, make us be difficult to stand when using this product cleaning kitchen tools such as lampblack absorber, also can produce some intense stimulus to respiratory tract; 3) be surfactant type, this clean-out system is easy to use, action temperature and, use cost is low, but the removal effect of counterweight dirt (coking wet goods) is not bery desirable, in actual use for improving the result of use of clean-out system, the long period (generally at about 1h) in the solution that need cleaned article are immersed in containing clean-out system, or under higher temperature conditions (30 DEG C-60 DEG C), the deoiling effect that competence exertion is stronger.Visible, prior art is damaged human body skin except strong acid alkaline degreaser in oil production also exists, is corroded cleaned articles for use; Solvent-borne type degreaser has also existed comparatively strong and stimulating smell; Surfactant type degreaser also exists the undesirable problem of deoiling effect.
Summary of the invention
For solving damage human body skin that prior art exists except oil production, corroding cleaned articles for use, having the problem undesirable compared with strong and stimulating smell, deoiling effect, the present invention proposes a kind of degreaser and preparation method thereof.
A kind of degreaser of the present invention, is characterized in that, be made up of by weight percentage following material:
Food flavour 0.1%-5%
Solubilizing agent 0.2%-10%
Tensio-active agent 10%-35%
Solubility promoter 0.2%-8%
Washing assistant 0.2%-8%
Dilute hydrochloric acid 0.05%-1%
Deionized water surplus.
Further, the food flavour of degreaser of the present invention be spearmint oil, green tea oil one or more, the add-on of described food flavour in degreaser is 0.5-2% weight ratio.
Further, the solubilizing agent of a kind of degreaser of the present invention is one or more of toluenesulfonic acid sodium salt or hydrogenated castor oil, and the add-on of described solubilizing agent in degreaser is 0.5-4% weight ratio.
Further, the add-on of the tensio-active agent of a kind of degreaser of the present invention in degreaser is 12-25% weight ratio.
Further, the tensio-active agent of a kind of degreaser of the present invention consists of the following composition by mass parts: sodium carbonate 1-20, fatty alcohol-polyoxyethylene ether 2-10, alkylolamide 2-10, Trisodium Citrate 10-15, metasilicate pentahydrate sodium 10-20, disodium ethylene diamine tetraacetate 1-5.
Further, the tensio-active agent of a kind of degreaser of the present invention consists of the following composition by mass parts: sodium carbonate 3-10, fatty alcohol-polyoxyethylene ether 2-6, alkylolamide 3-5, Trisodium Citrate 12-15, metasilicate pentahydrate sodium 12-15, disodium ethylene diamine tetraacetate 2-3.
Further, the solubility promoter of a kind of degreaser of the present invention is one or more in phenylcarbinol or butyl glycol ether, and the add-on of described solubility promoter in degreaser is 0.5-5% weight ratio.
Further, the washing assistant of a kind of degreaser of the present invention is one or more in nitrilotriacetic acid NTA or edta edta, and the add-on of described washing assistant in degreaser is 0.5-5% weight ratio.
The present invention also provides the preparation method of above degreaser, comprises the following steps:
1, under rotating speed is 50 ~ 70r/min stirring, sodium carbonate, fatty alcohol-polyoxyethylene ether, alkylolamide, Trisodium Citrate, metasilicate pentahydrate sodium, disodium ethylene diamine tetraacetate are added in a mixing bowl after cleaning, stir 1-2 little of uniform state, obtained self-control tensio-active agent, for subsequent use;
2, under rotating speed is 50 ~ 70r/min stirring, food flavour, solubilizing agent are added in the stirring tank after cleaning, stirs 1-2 little of uniform state;
3, the stirring velocity in stirring tank is set to 80 ~ 100r/min, slowly adds the tensio-active agent prepared by step 1, solubility promoter, washing assistant, deionized water, stir 0.5-1 little of uniform state;
4, dilute hydrochloric acid is used to regulate the pH to 8-10.5 of degreaser in stirring tank;
Wherein, described degreaser is made up of following material by mass percentage:
Food flavour 0.1%-5%
Solubilizing agent 0.2%-10%
Tensio-active agent 10%-35%
Solubility promoter 0.2%-8%
Washing assistant 0.2%-8%
Dilute hydrochloric acid 0.05%-1%
Deionized water surplus.
The Advantageous Effects of a kind of degreaser of the present invention and preparation method thereof is that oily waste degradation rate is high, and cleaning speed is fast, gentle, has no irritating odor and does not damage human body skin, corrodes cleaned articles for use.
Embodiment
Embodiment 1:
A kind of degreaser, is made up of following material by mass percentage:
Spearmint oil 0.1%
Toluenesulfonic acid sodium salt 4%
Tensio-active agent 35%
Phenylcarbinol 5%
NTA0.5%
Dilute hydrochloric acid 0.05%
Deionized water 55.35%.
Wherein tensio-active agent consists of the following composition by mass parts: 1 part, sodium carbonate, fatty alcohol-polyoxyethylene ether 10 parts, alkylolamide 2 parts, Trisodium Citrate 15 parts, metasilicate pentahydrate sodium 10 parts, disodium ethylene diamine tetraacetate 5 parts.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 98.4%.The pH value of this degreaser is 8.5, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
Embodiment 2:
A kind of degreaser, is made up of following material by mass percentage:
Green tea oil 5%
Toluenesulfonic acid sodium salt 0.2%
Tensio-active agent 12%
Phenylcarbinol 0.5%
EDTA8%
Dilute hydrochloric acid 0.5%
Deionized water 73.8%.
Wherein tensio-active agent consists of the following composition by mass parts: 20 parts, sodium carbonate, fatty alcohol-polyoxyethylene ether 2 parts, alkylolamide 5 parts, Trisodium Citrate 10 parts, metasilicate pentahydrate sodium 10 parts, disodium ethylene diamine tetraacetate 5 parts.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 98.9%.The pH value of this degreaser is 8, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
Embodiment 3:
A kind of degreaser, is made up of following material by mass percentage:
Spearmint oil 0.5%
Hydrogenated castor oil 10%
Tensio-active agent 10%
Butyl glycol ether 0.2%
NTA5%
Dilute hydrochloric acid 0.2%
Deionized water 74.1%.
Wherein tensio-active agent is made up of following material by mass parts: 10 parts, sodium carbonate, fatty alcohol-polyoxyethylene ether 5 parts, alkylolamide 10 parts, Trisodium Citrate 12 parts, metasilicate pentahydrate sodium 15 parts, disodium ethylene diamine tetraacetate 1 part.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 99.2%.The pH value of this degreaser is 10.5, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
Embodiment 4:
A kind of degreaser, is made up of following material by mass percentage:
Phenylcarbinol 1%
Green tea oil 1%
Toluenesulfonic acid sodium salt 2%
Tensio-active agent 20%
Butyl glycol ether 8%
EDTA0.2%
Dilute hydrochloric acid 1%
Deionized water 66.8%.
Wherein tensio-active agent is made up of following material by mass parts: 5 parts, sodium carbonate, fatty alcohol-polyoxyethylene ether 8 parts, alkylolamide 3 parts, Trisodium Citrate 11 parts, metasilicate pentahydrate sodium 20 parts, disodium ethylene diamine tetraacetate 2 parts.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 99.5%.The pH value of this degreaser is 10, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
Embodiment 5:
A kind of degreaser, is made up of following material by mass percentage:
Green tea oil 2%
Hydrogenated castor oil 0.5%
Self-control tensio-active agent 25%
Phenylcarbinol 1%
Butyl glycol ether 1%
NTA1%
Dilute hydrochloric acid 0.3%
Deionized water 69.2%.
Wherein tensio-active agent is made up of following material by mass parts: 8 parts, sodium carbonate, fatty alcohol-polyoxyethylene ether 3 parts, alkylolamide 4 parts, Trisodium Citrate 14 parts, metasilicate pentahydrate sodium 12 parts, disodium ethylene diamine tetraacetate 3 parts.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 98.6%.The pH value of this degreaser is 9, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
Embodiment 6:
A kind of degreaser, is made up of following material by mass percentage:
Spearmint oil 1%
Toluenesulfonic acid sodium salt 1%
Hydrogenated castor oil 2%
Tensio-active agent 15%
Butyl glycol ether 3%
NTA1.5%
EDTA1.5%
Dilute hydrochloric acid 0.6%
Deionized water 74.4%.
Wherein tensio-active agent is made up of following material by mass parts: 3 parts, sodium carbonate, fatty alcohol-polyoxyethylene ether 6 parts, alkylolamide 6 parts, Trisodium Citrate 13 parts, metasilicate pentahydrate sodium 14 parts, disodium ethylene diamine tetraacetate 4 parts.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 99.1%.The pH value of this degreaser is 9.5, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
Embodiment 7:
The preparation method of degreaser, comprises the following steps:
1, under rotating speed is 50 ~ 70r/min stirring, sodium carbonate, fatty alcohol-polyoxyethylene ether, alkylolamide, Trisodium Citrate, metasilicate pentahydrate sodium, disodium ethylene diamine tetraacetate are added in a mixing bowl after cleaning, stir 1 little of uniform state, obtained tensio-active agent, for subsequent use;
2, under rotating speed is 50 ~ 70r/min stirring, food flavour, solubilizing agent are added in the stirring tank after cleaning, stirring 2 is little of uniform state;
3, the stirring velocity in stirring tank is set to 80 ~ 100r/min, slowly adds the tensio-active agent prepared by step 1, solubility promoter, washing assistant, deionized water, stirring 1 is little of uniform state;
4, dilute hydrochloric acid is used to regulate the pH to 8-10.5 of degreaser in stirring tank;
Wherein, described degreaser is made up of following material by mass percentage:
Food flavour 0.1%-5%
Solubilizing agent 0.2%-10%
Tensio-active agent 10%-35%
Solubility promoter 0.2%-8%
Washing assistant 0.2%-8%
Dilute hydrochloric acid 0.05%-1%
Deionized water surplus.
The degreaser that the present embodiment obtains is with reference to the experimental technique of QB/T4348-2012 kitchen oil scale washing agent, and test the viscous crude dirt detersive power of sample, when the drying temperature of greasy dirt is 200 DEG C, its detersive power is 98.8%.The pH value of this degreaser is 9.2, does not damage human body skin, corrodes cleaned articles for use and have no irritating odor.
The Advantageous Effects of a kind of degreaser of the present invention and preparation method thereof is that oily waste degradation rate is high, and cleaning speed is fast, gentle, has no irritating odor and does not damage human body skin, corrodes cleaned articles for use.
The foregoing is only the preferred embodiments of the present invention; be not limited to the present invention, for a person skilled in the art, within the spirit and principles in the present invention all; any amendment of doing, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (9)
1. a degreaser, is characterized in that, is made up of by weight percentage following material:
Food flavour 0.1%-5%
Solubilizing agent 0.2%-10%
Tensio-active agent 10%-35%
Solubility promoter 0.2%-8%
Washing assistant 0.2%-8%
Dilute hydrochloric acid 0.05%-1%
Deionized water surplus.
2. degreaser according to claim 1, is characterized in that, described food flavour be spearmint oil, green tea oil one or more, the add-on of described food flavour in degreaser is 0.5-2% weight ratio.
3. degreaser according to claim 1, is characterized in that, described solubilizing agent is one or more of toluenesulfonic acid sodium salt or hydrogenated castor oil, and the add-on of described solubilizing agent in degreaser is 0.5-4% weight ratio.
4. degreaser according to claim 1, it is characterized in that, the add-on of described tensio-active agent in degreaser is 12-25% weight ratio.
5. degreaser according to claim 1, it is characterized in that, described tensio-active agent consists of the following composition by mass parts: sodium carbonate 1-20, fatty alcohol-polyoxyethylene ether 2-10, alkylolamide 2-10, Trisodium Citrate 10-15, metasilicate pentahydrate sodium 10-20, disodium ethylene diamine tetraacetate 1-5.
6. degreaser according to claim 1, it is characterized in that, described tensio-active agent consists of the following composition by mass parts: sodium carbonate 3-10, fatty alcohol-polyoxyethylene ether 2-6, alkylolamide 3-5, Trisodium Citrate 12-15, metasilicate pentahydrate sodium 12-15, disodium ethylene diamine tetraacetate 2-3.
7. degreaser according to claim 1, is characterized in that, described solubility promoter is one or more in phenylcarbinol or butyl glycol ether, and the add-on of described solubility promoter in degreaser is 0.5-5% weight ratio.
8. degreaser according to claim 1, it is characterized in that, described washing assistant is one or more in nitrilotriacetic acid NTA or edta edta, and the add-on of described washing assistant in degreaser is 0.5-5% weight ratio.
9. the preparation method of degreaser described in claim 1 to 8, is characterized in that, described preparation method comprises the following steps:
A () is under 50 ~ 70r/min stirs at rotating speed, sodium carbonate, fatty alcohol-polyoxyethylene ether, alkylolamide, Trisodium Citrate, metasilicate pentahydrate sodium, disodium ethylene diamine tetraacetate are added in a mixing bowl after cleaning, stir 1-2 little of uniform state, obtained self-control tensio-active agent, for subsequent use;
B () is under 50 ~ 70r/min stirs at rotating speed, food flavour, solubilizing agent are added in the stirring tank after cleaning, stir 1-2 little of uniform state;
C stirring velocity in stirring tank is set to 80 ~ 100r/min by (), slowly add the tensio-active agent prepared by step 1, solubility promoter, washing assistant, deionized water, stirs 0.5-1 little of uniform state;
D () uses dilute hydrochloric acid to regulate the pH to 8-10.5 of degreaser in stirring tank;
Wherein, described degreaser is made up of following material by mass percentage:
Food flavour 0.1%-5%
Solubilizing agent 0.2%-10%
Tensio-active agent 10%-35%
Solubility promoter 0.2%-8%
Washing assistant 0.2%-8%
Dilute hydrochloric acid 0.05%-1%
Deionized water surplus.
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Cited By (5)
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CN106635492A (en) * | 2016-12-05 | 2017-05-10 | 天津天狮生物发展有限公司 | Range hood cleaning agent and preparation method thereof |
CN106957737A (en) * | 2017-04-06 | 2017-07-18 | 湖南中大中雅医药科技有限公司 | A kind of greasy dirt detergent and preparation method thereof |
CN107227210A (en) * | 2017-06-20 | 2017-10-03 | 合肥尚涵装饰工程有限公司 | A kind of deoiling method of workpiece |
CN107629890A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of heavy oil sewage based cleaning agent |
CN111849647A (en) * | 2020-08-13 | 2020-10-30 | 程坤 | Oil removing agent |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN107629890A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of heavy oil sewage based cleaning agent |
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Application publication date: 20160113 |