CN104531402A - Neutral toilet cleaner - Google Patents

Neutral toilet cleaner Download PDF

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Publication number
CN104531402A
CN104531402A CN201410749440.7A CN201410749440A CN104531402A CN 104531402 A CN104531402 A CN 104531402A CN 201410749440 A CN201410749440 A CN 201410749440A CN 104531402 A CN104531402 A CN 104531402A
Authority
CN
China
Prior art keywords
toilet cleaner
fatty alcohol
neutral
cleaner according
carbon chain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410749440.7A
Other languages
Chinese (zh)
Inventor
张世林
陈树旭
陈文�
蔡熙扬
侯君辉
赵建红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LANGQI INDUSTRY Co Ltd GUANGZHOU
Original Assignee
LANGQI INDUSTRY Co Ltd GUANGZHOU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LANGQI INDUSTRY Co Ltd GUANGZHOU filed Critical LANGQI INDUSTRY Co Ltd GUANGZHOU
Priority to CN201410749440.7A priority Critical patent/CN104531402A/en
Publication of CN104531402A publication Critical patent/CN104531402A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a neutral toilet cleaner. The neutral toilet cleaner is prepared from the following components in percentage by weight: 0.5-30 percent of a surfactant, 0.1-5 percent of a thickener, 0.05-10 percent of a chelating additive, 2-20 percent of a solvent, 0.03-0.2 percent of a preservative, 0-1 percent of essence, 0-0.1 percent of a pigment, 0-1 percent of a pH regulator, 0-0.1 percent of a preservative and the balance of water. The toilet cleaner is a neutral product, is strong in decontamination ability and is capable of very lightly and conveniently removing fouling including soap scales and urine scales.

Description

A kind of neutral toilet cleaner
Technical field
The present invention relates to a kind of washing composition, particularly relate to a kind of neutral toilet cleaner.
Background technology
Along with standard of living is more and more higher, human consumer is also more and more concerned about the security of cleaning toilet product, mildness.Now toilet cleaner is on the market substantially all be bulk composition by strong acid, tensio-active agent, thickening material.Strong acid energy fast decoupled bathroom in toilet cleaner and the dirt composition such as urine dirt, soap scum, rust stain in lavatory.Although detersive power is very strong, owing to adding strong acid, while clean porcelain facing, opponent, porcelain facing also have severe corrosive, and use range is also narrow, can not be used for metal hand basin, bathtub etc. clean.
Summary of the invention
The object of the present invention is to provide a kind of strong detergency, non-corrosive neutral toilet cleaner.
Object of the present invention is achieved through the following technical solutions: a kind of neutral toilet cleaner, comprises the component of following mass percent:
Tensio-active agent 0.5%-30%
Thickening material 0.1%-5%
Chelating auxiliary agent 0.05%-10%
Solvent 2%-20%
Sanitas 0.03-0.2%
Essence 0%-1%
Pigment 0-0.1%
PH adjusting agent 0 ~ 1%
Sanitas 0 ~ 0.1%
Water surplus.
In the present invention, described tensio-active agent is one or both the mixing in nonionogenic tenside and anion surfactant.Described nonionogenic tenside is fatty alcohol-polyoxyethylene ether or alkyl glycoside.Wherein, the fatty alcohol carbon chain lengths of described fatty alcohol-polyoxyethylene ether is 8C-16C, and carbon-chain structure is straight or branched, and EO number is 3-10.The alkyl carbon chain of described alkyl glycoside is long is 8C-16C.Described anion surfactant is one or more the mixing in linear alkylbenzene sulfonate, α alkenyl sulphonate, fatty alcohol polyoxyethylene ether sulfate, alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, secondary alkyl sulfonate, ethoxylated fatty-acid methyl ester sulfonate, alcohol ether carboxylate and fatty acid methyl ester sulfonate.Wherein, the alkyl carbon chain of described linear alkylbenzene sulfonate is long is 12C-14C.The fatty alcohol carbon chain lengths of described fatty alcohol polyoxyethylene ether sulfate is 8C-16C.The fatty alcohol carbon chain lengths of described ethoxylated fatty-acid methyl ester sulfonate is 12C-18C.The fatty alcohol carbon chain lengths of described fatty acid methyl ester sulfonate is 12C-18C.
Described chelating auxiliary agent is one or more the mixing in Sunmorl N 60S, Trisodium Citrate and edetate.Sequestrant by calcium ions and magnesium ions, the metal ion in chelating dirt, thus makes dirt peel off, is separated.
Described thickening material is one or more the mixing in cellulose derivative, guar gum or derivatives thereof and xanthan gum or derivatives thereof.
Described solvent is one or both the mixing in 2-methyl-2,4-pentanediol, propandiol butyl ether, dipropylene and tripropylene glycol butyl ether.
Described pH adjusting agent is citric acid or sodium hydroxide.
The present invention compared with prior art has the following advantages:
(1) toilet cleaner provided by the invention is neutral products, and soil removability is strong, can remove the dirt such as soap scum and urine dirt very easily.
The present invention is not containing strong acid, and do not have corrodibility, pH value is 4 ~ 9, close to human body skin, can not damage, also can not corroding metal device, and use range is wide.Chelant ties dispersion urine dirt wherein and soap scum, and dissolution with solvents urine dirt and soap scum.Tensio-active agent then can play wetting and osmosis, urine dirt and soap scum is more easily disintegrated, contributes to improving clean effect.
(2) the present invention can also increase perfume ingredient, to remove peculiar smell.
(3) in use can't there is acid-base reaction in the present invention, in use can not can produce bad smell as existing toilet cleaner.
Embodiment
The preparation method of the neutral toilet cleaner of following examples:
1. add softening water, open and stir, add sequestrant, be warming up to 50 DEG C ~ 80 DEG C, and add thickening material, stir half an hour to thickening material and all disperse, dissolve.
2. cool to less than 45 DEG C, add solvent and tensio-active agent successively, be stirred to and dissolve completely.
3. add essence, sanitas and pigment.
4. be adjusted to pH value to 4 ~ 9 with appropriate citric acid or sodium hydroxide, obtain neutral toilet cleaner.
Tensio-active agent is one or both the mixing in nonionogenic tenside and anion surfactant.Nonionogenic tenside is fatty alcohol-polyoxyethylene ether or alkyl glycoside.Wherein, the fatty alcohol carbon chain lengths of fatty alcohol-polyoxyethylene ether is 8C-16C, and carbon-chain structure is straight or branched, and EO number is 3-10.The alkyl carbon chain of described alkyl glycoside is long is 8C-16C.Anion surfactant is one or more the mixing in linear alkylbenzene sulfonate, α alkenyl sulphonate, fatty alcohol polyoxyethylene ether sulfate, alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, secondary alkyl sulfonate, ethoxylated fatty-acid methyl ester sulfonate, alcohol ether carboxylate and fatty acid methyl ester sulfonate.Wherein, the alkyl carbon chain of linear alkylbenzene sulfonate is long is 12C-14C.The fatty alcohol carbon chain lengths of fatty alcohol polyoxyethylene ether sulfate is 8C-16C.The fatty alcohol carbon chain lengths of ethoxylated fatty-acid methyl ester sulfonate is 12C-18C.The fatty alcohol carbon chain lengths of fatty acid methyl ester sulfonate is 12C-18C.
Chelating auxiliary agent is one or more the mixing in Sunmorl N 60S, Trisodium Citrate and edetate.Sequestrant by calcium ions and magnesium ions, the metal ion in chelating dirt, thus makes dirt peel off, is separated.
Thickening material is one or more the mixing in cellulose derivative, guar gum or derivatives thereof and xanthan gum or derivatives thereof.
Solvent is one or both the mixing in 2-methyl-2,4-pentanediol, propandiol butyl ether, dipropylene and tripropylene glycol butyl ether.

Claims (9)

1. a neutral toilet cleaner, is characterized in that, comprises the component of following mass percent:
Tensio-active agent 0.5%-30%
Thickening material 0.1%-5%
Chelating auxiliary agent 0.05%-10%
Solvent 2%-20%
Sanitas 0.03-0.2%
Essence 0%-1%
Pigment 0-0.1%
PH adjusting agent 0 ~ 1%
Sanitas 0 ~ 0.1%
Water surplus.
2. neutral toilet cleaner according to claim 1, is characterized in that, described tensio-active agent is one or both the mixing in nonionogenic tenside and anion surfactant.
3. neutral toilet cleaner according to claim 2, is characterized in that, described nonionogenic tenside is fatty alcohol-polyoxyethylene ether or alkyl glycoside.
4. neutral toilet cleaner according to claim 3, is characterized in that, the fatty alcohol carbon chain lengths of institute's fatty alcohol-polyoxyethylene ether is 8C-16C, and carbon-chain structure is straight or branched, and EO number is 3-10; The alkyl carbon chain of described alkyl glycoside is long is 8C-16C.
5. neutral toilet cleaner according to claim 2, it is characterized in that, described anion surfactant is one or more the mixing in linear alkylbenzene sulfonate, α alkenyl sulphonate, fatty alcohol polyoxyethylene ether sulfate, alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, secondary alkyl sulfonate, ethoxylated fatty-acid methyl ester sulfonate, alcohol ether carboxylate and fatty acid methyl ester sulfonate.
6. neutral toilet cleaner according to claim 5, is characterized in that, the alkyl carbon chain of described linear alkylbenzene sulfonate is long is 12C-14C; The fatty alcohol carbon chain lengths of described fatty alcohol polyoxyethylene ether sulfate is 8C-16C; The fatty alcohol carbon chain lengths of described ethoxylated fatty-acid methyl ester sulfonate is 12C-18C; The fatty alcohol carbon chain lengths of described fatty acid methyl ester sulfonate is 12C-18C.
7. neutral toilet cleaner according to claim 1, is characterized in that, described chelating auxiliary agent is one or more the mixing in Sunmorl N 60S, Trisodium Citrate and edetate.
8. neutral toilet cleaner according to claim 1, is characterized in that, described thickening material is one or more the mixing in cellulose derivative, guar gum or derivatives thereof and xanthan gum or derivatives thereof.
9. neutral toilet cleaner according to claim 1, is characterized in that, described solvent is one or both the mixing in 2-methyl-2,4-pentanediol, propandiol butyl ether, dipropylene and tripropylene glycol butyl ether.
CN201410749440.7A 2014-12-10 2014-12-10 Neutral toilet cleaner Pending CN104531402A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410749440.7A CN104531402A (en) 2014-12-10 2014-12-10 Neutral toilet cleaner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410749440.7A CN104531402A (en) 2014-12-10 2014-12-10 Neutral toilet cleaner

Publications (1)

Publication Number Publication Date
CN104531402A true CN104531402A (en) 2015-04-22

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410749440.7A Pending CN104531402A (en) 2014-12-10 2014-12-10 Neutral toilet cleaner

Country Status (1)

Country Link
CN (1) CN104531402A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062707A (en) * 2015-09-18 2015-11-18 上海升阶化工科技有限公司 Formula for household healthy environment-friendly detergent
CN105505593A (en) * 2016-01-13 2016-04-20 于景成 Environment-friendly toilet cleaning agent
CN105754739A (en) * 2016-03-15 2016-07-13 王玉兴 Environment-friendly cleaning agent for toilets
CN106591007A (en) * 2016-11-03 2017-04-26 铜陵桂生生态养殖有限公司 Cleaning agent for honeycomb-like scorpion nest for breeding scorpions
CN108117936A (en) * 2016-11-30 2018-06-05 黎凯华 A kind of low foam detergent for toilet
CN111575125A (en) * 2020-04-21 2020-08-25 中国铁道科学研究院集团有限公司金属及化学研究所 Cleaning agent for train toilet wastewater collector and preparation method thereof
CN112029593A (en) * 2020-07-21 2020-12-04 名臣健康用品股份有限公司 Foam type toilet cleaning liquid composition and preparation method thereof
CN112251299A (en) * 2020-10-21 2021-01-22 沈阳脱普生活用品服务有限公司上海分公司 High-concentration detergent and preparation method thereof
CN112391240A (en) * 2020-11-21 2021-02-23 英德市东鸿化工科技有限公司 Toilet cleaner and preparation method thereof
CN115895796A (en) * 2022-11-17 2023-04-04 江苏腾旷生物科技有限公司 Environment-friendly acid-free toilet cleaning liquid

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183463A (en) * 1997-03-31 1998-06-03 白志信 Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof
CN1443235A (en) * 2000-07-12 2003-09-17 约翰逊父子公司 Lavatory freshening and/or cleaning system and method
CN103060114A (en) * 2013-01-07 2013-04-24 洛娃科技实业集团有限公司 Detergent with quick-drying effect
CN103131546A (en) * 2013-02-26 2013-06-05 金红叶纸业集团有限公司 Cleaning composition
CN103540444A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Mild non-irritating detergent for skin

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183463A (en) * 1997-03-31 1998-06-03 白志信 Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof
CN1443235A (en) * 2000-07-12 2003-09-17 约翰逊父子公司 Lavatory freshening and/or cleaning system and method
CN103060114A (en) * 2013-01-07 2013-04-24 洛娃科技实业集团有限公司 Detergent with quick-drying effect
CN103131546A (en) * 2013-02-26 2013-06-05 金红叶纸业集团有限公司 Cleaning composition
CN103540444A (en) * 2013-09-27 2014-01-29 安徽华印机电股份有限公司 Mild non-irritating detergent for skin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王慎敏主编: "《洗涤剂配方设计、制备工艺与配方实例》", 30 April 2003, 化学工业出版社 *

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062707A (en) * 2015-09-18 2015-11-18 上海升阶化工科技有限公司 Formula for household healthy environment-friendly detergent
CN105505593A (en) * 2016-01-13 2016-04-20 于景成 Environment-friendly toilet cleaning agent
CN105754739A (en) * 2016-03-15 2016-07-13 王玉兴 Environment-friendly cleaning agent for toilets
CN106591007A (en) * 2016-11-03 2017-04-26 铜陵桂生生态养殖有限公司 Cleaning agent for honeycomb-like scorpion nest for breeding scorpions
CN108117936A (en) * 2016-11-30 2018-06-05 黎凯华 A kind of low foam detergent for toilet
CN111575125B (en) * 2020-04-21 2021-10-15 中国铁道科学研究院集团有限公司金属及化学研究所 Cleaning agent for train toilet wastewater collector and preparation method thereof
CN111575125A (en) * 2020-04-21 2020-08-25 中国铁道科学研究院集团有限公司金属及化学研究所 Cleaning agent for train toilet wastewater collector and preparation method thereof
CN112029593A (en) * 2020-07-21 2020-12-04 名臣健康用品股份有限公司 Foam type toilet cleaning liquid composition and preparation method thereof
CN112029593B (en) * 2020-07-21 2022-08-30 名臣健康用品股份有限公司 Low-viscosity foam type toilet cleaning liquid composition with foam spraying effect and preparation method thereof
CN112251299A (en) * 2020-10-21 2021-01-22 沈阳脱普生活用品服务有限公司上海分公司 High-concentration detergent and preparation method thereof
CN112391240A (en) * 2020-11-21 2021-02-23 英德市东鸿化工科技有限公司 Toilet cleaner and preparation method thereof
CN112391240B (en) * 2020-11-21 2021-11-30 英德市东鸿化工科技有限公司 Toilet cleaner and preparation method thereof
CN115895796A (en) * 2022-11-17 2023-04-04 江苏腾旷生物科技有限公司 Environment-friendly acid-free toilet cleaning liquid

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SE01 Entry into force of request for substantive examination
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Application publication date: 20150422