CN105505593A - Environment-friendly toilet cleaning agent - Google Patents
Environment-friendly toilet cleaning agent Download PDFInfo
- Publication number
- CN105505593A CN105505593A CN201610020055.8A CN201610020055A CN105505593A CN 105505593 A CN105505593 A CN 105505593A CN 201610020055 A CN201610020055 A CN 201610020055A CN 105505593 A CN105505593 A CN 105505593A
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- Prior art keywords
- environment
- cleaning agent
- friendly type
- type cleaning
- environmental protection
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses an environment-friendly toilet cleaning agent which is prepared from, by weight, 15-25% of environment-friendly ferment, 1.5-2.5% of methyl ester sulfonate, 15-25% of citric acid and 47.5-68.5% of deionized water. A preparation method comprises the steps that the needed deionized water is heated to 30-40 DEG C, the methyl ester sulfonate is slowly added with stirring, the citric acid is added to be mixed with the methyl ester sulfonate after the methyl ester sulfonate is completely dissolved, stirring is stopped after the mixture is mixed to be uniform, the environment-friendly ferment is added after the solution is cooled to normal temperature, then the mixture is stirred to be uniform, and the environment-friendly toilet cleaning agent is obtained. The environment-friendly toilet cleaning agent has the strong decontamination detergency, does not pollute environment and is the environment-friendly product.
Description
Technical field
The present invention relates to cleaning agent, be specifically related to a kind of environment-friendly type cleaning agent being applicable to communal bathroom, belong to cleaning supplies technical field.
Background technology
At present, the cleaning agent kind on market is a lot, divides, can be divided into third gear from price, high-grade, middle-grade and low-grade; From use region zones, can be divided into, between domestic hygiene, hotels toilet and communal bathroom.But nearly all cleaning agent is all the tensio-active agent that synthesized by chemical industry and chemical substance is composite forms, communal bathroom cleaning agent mostly be mineral acid add chemosynthesis tensio-active agent composition, mineral acid is generally hydrochloric acid, and tensio-active agent is Sodium dodecylbenzene sulfonate or sodium laurylsulfonate.As everyone knows, hydrochloric acid is strong acid, and corrodibility is large, has strong impulse smell, so use this kind of cleaning agent can cause corrosion damage to the facility of communal bathroom, slows down the work-ing life of facility; If people breathes hydrochloric acid smell, respiratory mucosa can be destroyed; In addition, the excrement and urine water containing hydrochloric acid flows into water body, decomposes and releases chlorion, also can work the mischief to environment.Sodium dodecylbenzene sulfonate or sodium laurylsulfonate are syntheticses, show according to epidemiologic data: a large amount of contact can cause the abnormal immune reactions such as fash, pharyngalgia, asthma.
" a kind of environment-protective toilet cleanser " of publication number CN101412947A is made up of penetrating agent JFC 2 parts, sodium laurylsulfonate 3 parts, tripoly phosphate sodium STPP 0.8 part, 30 parts, water, can find out that other all components is in addition to water all chemical substance.Application number be 201410701182.5 " a kind of toilet sterilizing agent " be by fatty alcohol-polyoxyethylene ether 8-10 part, Sodium Benzoate 1.8-2.2 part, ethylene glycol stearate 5-6 part, citric acid 3-5 part, sodium lauryl sulphate 4-8 part, sodium carbonate 10-12 part, sodium aluminate 3-5 part, negatively charged ion or nonionogenic tenside 2-5 part, Moxifloxacin 1-5 part, Triclosan 0.5-1 part, lauric acid 2-3 part, ethanol 70-85 part, the compositions such as bromine 0.05-0.1 part, wherein most of material or chemical substance, be unfavorable for environmental protection.
Summary of the invention
In order to overcome above-mentioned Problems existing, the invention provides a kind of environment-friendly type cleaning agent being applicable to communal bathroom.In order to complete the goal of the invention of the application, the application by the following technical solutions:
A kind of environment-friendly type cleaning agent of the present invention, wherein: this environment-friendly type cleaning agent is made up of the raw material of following weight percent: the environmental protection ferment of 15%-25%, the methyl sodiosul foaliphatate of 1.5%-2.5%, the citric acid of 15%-25% and the deionized water of 47.5%-68.5%, preparation method is: required deionized water is heated to 30 DEG C-40 DEG C, under agitation, first, slowly add above-mentioned methyl sodiosul foaliphatate, after methyl sodiosul foaliphatate dissolves completely, add after above-mentioned citric acid mixes, stop stirring, after above-mentioned solution is cooled to normal temperature, add above-mentioned environmental protection ferment, stir again, obtain environment-friendly type cleaning agent,
A kind of environment-friendly type cleaning agent of the present invention, wherein: this environment-friendly type cleaning agent is made up of the raw material of following weight percent: the environmental protection ferment of 20%, the methyl sodiosul foaliphatate of 2%, the citric acid of 20% and 58% deionized water;
A kind of environment-friendly type cleaning agent of the present invention, wherein: to be the commercially available EM bacterium that adds 10 parts of deionized waters and 0.014 part with 3 parts of fruits and vegetables rubbish, 1 part of molasses obtain described environmental protection ferment through the time indirect fermentation of more than 90 days to described environmental protection ferment;
A kind of environment-friendly type cleaning agent of the present invention, wherein: the preparation method of described environmental protection ferment comprises the following steps:
1) deionized water of 70L is added in nontoxic PE plastic tank that be with blind nut to 120L, that can seal;
2) in the PE plastic tank described in step 1), add the molasses of 7kg, add the EM bacterium that 98mL is commercially available, stir;
3) by collect from the market of farm produce without rot 21kg fruits and vegetables rubbish clean up, be cut into the block that particle diameter is less than or equal to 50mm, add step 2) described in PE plastic tank in;
4) cover tightly above-mentioned PE plastic tank bung, be put into shady and cool ventilation place, carry out the fermentation of more than 90 days time, wherein, the gas that the bung release fermentation that needs for the 2nd day to the 30th day to outward winding gently every day produces 1-2 times;
5), after 90 days, filtered by the solution fermented in step 4) 60 object plate filters, filtered liquid is environmental protection ferment, by airtight for the environmental protection ferment barrelling obtained put for subsequent use in the cool;
A kind of environment-friendly type cleaning agent of the present invention, wherein: described fermentation time is 90-100 days;
A kind of environment-friendly type cleaning agent of the present invention, wherein: described fruits and vegetables rubbish is fruit rubbish and vegetable waste, wherein fruit rubbish: the part by weight of vegetable waste is 2:1;
A kind of environment-friendly type cleaning agent of the present invention, wherein: described fruit rubbish is one or more of orange peel, pineapple peel and Watermelon rind; Vegetable waste is one or both of leaf of Herba Apii graveolentis and Chinese cabbage leaf;
A kind of environment-friendly type cleaning agent of the present invention, wherein: described methyl sodiosul foaliphatate be with crude vegetal or with the sewer oil reclaimed in kitchen of eating for raw material, make through over-churning, transesterify and sulfonation.
The cleaning agent of the application, compared with existing cleaning agent, has following useful implementation result:
1, after testing, except containing except the organic acids such as gallic acid, oxysuccinic acid, pyruvic acid and succsinic acid in environmental protection ferment, also containing 8 × 10
2u/mg amylase, 700U/mg cellulase, 80U/mg catalase and a certain amount of lipase and protease, so environmental protection ferment has stronger cleansing power, decomposes dirt ability and sterilizing ability;
2, methyl sodiosul foaliphatate is bio-surfactant, and soil release performance, calcium soap dispersiveness, emulsifying property, lyotropy and biological degradability are all better than Sodium dodecylbenzene sulfonate;
3, citric acid is without chemical hazard, has lyotropy, deodorizing, oxidation-resistance and biological degradability.
3, owing to adding fruit rubbish in the making of environmental protection ferment, so the environmental protection ferment made has with the fruit rubbish added the fruital taste adapted, owing to adding the environmental protection ferment of 15%-20% in this product, so this product has light pleasant fruital taste, there is broad-spectrum detersive power, the urine alkali in urinal can not only be removed, and dirt and the grease of hand basin and ceramic tile can also be removed.
4, this product is made up of bio-surfactant, biotechnological formulation and water, has stronger synergy, and not only decontamination de-sludging, de-sludging, deodorizing power are strong, and free from environmental pollution, are a kind of environmentally friendly property products.
5, this Product Process is simple, cheap, solves communal bathroom consumption problem greatly, costly.
Embodiment
A kind of environment-friendly type of the present invention cleaning agent is made up of the raw material of following weight percent: the deionized water of the environmental protection ferment of 15%-25%, the methyl sodiosul foaliphatate of 1.5%-2.5%, the citric acid of 15%-25% and 47.5%-68.5%, and preferably environment-friendly type cleaning agent is made up of the raw material of following weight percent: the environmental protection ferment of 20%, the methyl sodiosul foaliphatate of 2%, the citric acid of 20% and 58% deionized water.
Its preparation method is: required deionized water is heated to 30 DEG C-40 DEG C, under agitation, first, above-mentioned methyl sodiosul foaliphatate is slowly added, after methyl sodiosul foaliphatate dissolves completely, add after above-mentioned citric acid mixes, stop stirring, after above-mentioned solution is cooled to normal temperature, add above-mentioned environmental protection ferment, stir again, obtain environment-friendly type cleaning agent.
To be the commercially available EM bacterium that adds 10 parts of deionized waters and 0.014 part with 3 parts of fruits and vegetables rubbish, 1 part of molasses obtain described environmental protection ferment through the time indirect fermentation of 90 days-100 days to environmental protection ferment.
The preparation method of environmental protection ferment comprises the following steps:
1) deionized water of 70L is added in nontoxic PE plastic tank that be with blind nut to 120L, that can seal;
2) in the PE plastic tank in step 1), add the molasses of 7kg, add the EM bacterium that 98mL is commercially available, stir; The unit weight of EM bacterium is 1g/mL.
3) by collect from the market of farm produce without rot 21kg fruits and vegetables rubbish clean up, be cut into the block that particle diameter is less than or equal to 50mm, add step 2) described in PE plastic tank in;
4) cover tightly 3) in above-mentioned PE plastic tank bung, be put into shady and cool ventilation place, carry out the fermentation of 90-100 days, wherein, the gas that the bung release fermentation that needs for the 2nd day to the 30th day to outward winding gently every day produces 1-2 times;
5) after 90 days, the solution fermented in step 4) 60 object plate filters are filtered, filtered liquid is environmental protection ferment, by airtight for the environmental protection ferment barrelling obtained put for subsequent use in the cool, at the bottom of residue continues to be left to barrel, the bacterial classification fermented as next time or taking-up are dried, and are used for the plantation of flowers and vegetables as fertilizer.
Fruits and vegetables rubbish is fruit rubbish and vegetable waste, wherein fruit rubbish: vegetable waste part by weight is 2:1, and fruit rubbish is one or more of orange peel, pineapple peel and Watermelon rind; Vegetable waste is one or both of leaf of Herba Apii graveolentis and Chinese cabbage leaf.Methyl sodiosul foaliphatate be with crude vegetal or with the sewer oil reclaimed in kitchen of eating for raw material, make through over-churning, transesterify and sulfonation.
Citric acid is the organic acid that a kind of acidity is stronger, and the product of decomposition is carbonic acid gas and water, can extract and obtain from the fruit such as lemon, oranges and tangerines, pineapple.Commercially easily buy.
It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.The all available prior art of each integral part not clear and definite in the present embodiment is realized.
Claims (8)
1. an environment-friendly type cleaning agent, it is characterized in that: this environment-friendly type cleaning agent is made up of the raw material of following weight percent: the environmental protection ferment of 15%-25%, the methyl sodiosul foaliphatate of 1.5%-2.5%, the citric acid of 15%-25% and the deionized water of 47.5%-68.5%, preparation method is: required deionized water is heated to 30 DEG C-40 DEG C, under agitation, first, slowly add above-mentioned methyl sodiosul foaliphatate, after methyl sodiosul foaliphatate dissolves completely, add after above-mentioned citric acid mixes, stop stirring, after above-mentioned solution is cooled to normal temperature, add above-mentioned environmental protection ferment, stir again, obtain environment-friendly type cleaning agent.
2. environment-friendly type cleaning agent as claimed in claim 1, is characterized in that: this environment-friendly type cleaning agent is made up of the raw material of following weight percent: the environmental protection ferment of 20%, the methyl sodiosul foaliphatate of 2%, the citric acid of 20% and 58% deionized water.
3. environment-friendly type cleaning agent as claimed in claim 1 or 2, is characterized in that: to be the commercially available EM bacterium that adds 10 parts of deionized waters and 0.014 part with 3 parts of fruits and vegetables rubbish, 1 part of molasses obtain described environmental protection ferment through the time indirect fermentation of more than 90 days to described environmental protection ferment.
4. environment-friendly type cleaning agent as claimed in claim 3, is characterized in that: the preparation method of described environmental protection ferment comprises the following steps:
1) deionized water of 70L is added in nontoxic PE plastic tank that be with blind nut to 120L, that can seal;
2) in the PE plastic tank described in step 1), add the molasses of 7kg, add the EM bacterium that 98mL is commercially available, stir;
3) by collect from the market of farm produce without rot 21kg fruits and vegetables rubbish clean up, be cut into the block that particle diameter is less than or equal to 50mm, add step 2) described in PE plastic tank in;
4) cover tightly above-mentioned PE plastic tank bung, be put into shady and cool ventilation place, carry out the fermentation of more than 90 days time, wherein, the gas that the bung release fermentation that needs for the 2nd day to the 30th day to outward winding gently every day produces 1-2 times;
5), after 90 days, filtered by the solution fermented in step 4) 60 object plate filters, filtered liquid is environmental protection ferment, by airtight for the environmental protection ferment barrelling obtained put for subsequent use in the cool.
5. environment-friendly type cleaning agent as claimed in claim 4, is characterized in that: described fermentation time is 90-100 days.
6. environment-friendly type cleaning agent as claimed in claim 5, is characterized in that: described fruits and vegetables rubbish is fruit rubbish and vegetable waste, wherein fruit rubbish: the weight ratio of vegetable waste is 2:1.
7. the environment-friendly type cleaning agent as described in claim 5 or 6, is characterized in that: described fruit rubbish is one or more of orange peel, pineapple peel and Watermelon rind; Vegetable waste is one or both of leaf of Herba Apii graveolentis and Chinese cabbage leaf.
8. environment-friendly type cleaning agent as claimed in claim 7, is characterized in that: described methyl sodiosul foaliphatate be with crude vegetal or with the sewer oil reclaimed in kitchen of eating for raw material, make through over-churning, transesterify and sulfonation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610020055.8A CN105505593A (en) | 2016-01-13 | 2016-01-13 | Environment-friendly toilet cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610020055.8A CN105505593A (en) | 2016-01-13 | 2016-01-13 | Environment-friendly toilet cleaning agent |
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| CN105505593A true CN105505593A (en) | 2016-04-20 |
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| CN201610020055.8A Pending CN105505593A (en) | 2016-01-13 | 2016-01-13 | Environment-friendly toilet cleaning agent |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635560A (en) * | 2016-12-24 | 2017-05-10 | 叶宗瑞 | Environment-friendly antibacterial toilet detergent and preparation method thereof |
| CN106939261A (en) * | 2017-03-17 | 2017-07-11 | 长沙协浩吉生物工程有限公司 | A kind of compound method of urinal ferment cleaning agent |
| CN110484375A (en) * | 2019-09-07 | 2019-11-22 | 阜阳洁平日化有限公司 | One kind is high performance to be quantitatively sustained bottled detergent for toilet and preparation method thereof |
| CN112457924A (en) * | 2020-12-09 | 2021-03-09 | 四川同庆南风洗涤用品有限责任公司 | Peculiar smell removing ferment bathroom cleaner and preparation method thereof |
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| CN103695214A (en) * | 2013-12-30 | 2014-04-02 | 深圳先进技术研究院 | Detergent containing ginkgo enzyme and preparation method of detergent |
| CN103897812A (en) * | 2012-12-27 | 2014-07-02 | 海安县亚太助剂有限公司 | Deodorizing toilet cleaner |
| CN104187731A (en) * | 2014-09-22 | 2014-12-10 | 北海市东雨农业科技有限公司 | Preparation method of environment-friendly enzyme taking lychee exocarp as principal raw material |
| CN104531402A (en) * | 2014-12-10 | 2015-04-22 | 广州市浪奇实业股份有限公司 | Neutral toilet cleaner |
-
2016
- 2016-01-13 CN CN201610020055.8A patent/CN105505593A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101463293A (en) * | 2007-12-21 | 2009-06-24 | 上海和黄白猫有限公司 | Perfuming viscous type acidic closestool cleanser |
| CN103897812A (en) * | 2012-12-27 | 2014-07-02 | 海安县亚太助剂有限公司 | Deodorizing toilet cleaner |
| CN103695214A (en) * | 2013-12-30 | 2014-04-02 | 深圳先进技术研究院 | Detergent containing ginkgo enzyme and preparation method of detergent |
| CN104187731A (en) * | 2014-09-22 | 2014-12-10 | 北海市东雨农业科技有限公司 | Preparation method of environment-friendly enzyme taking lychee exocarp as principal raw material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635560A (en) * | 2016-12-24 | 2017-05-10 | 叶宗瑞 | Environment-friendly antibacterial toilet detergent and preparation method thereof |
| CN106939261A (en) * | 2017-03-17 | 2017-07-11 | 长沙协浩吉生物工程有限公司 | A kind of compound method of urinal ferment cleaning agent |
| CN110484375A (en) * | 2019-09-07 | 2019-11-22 | 阜阳洁平日化有限公司 | One kind is high performance to be quantitatively sustained bottled detergent for toilet and preparation method thereof |
| CN112457924A (en) * | 2020-12-09 | 2021-03-09 | 四川同庆南风洗涤用品有限责任公司 | Peculiar smell removing ferment bathroom cleaner and preparation method thereof |
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Application publication date: 20160420 |
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