CN1789398A - Natural plant type detergent - Google Patents
Natural plant type detergent Download PDFInfo
- Publication number
- CN1789398A CN1789398A CN 200510122330 CN200510122330A CN1789398A CN 1789398 A CN1789398 A CN 1789398A CN 200510122330 CN200510122330 CN 200510122330 CN 200510122330 A CN200510122330 A CN 200510122330A CN 1789398 A CN1789398 A CN 1789398A
- Authority
- CN
- China
- Prior art keywords
- natural plant
- parts
- cleaning agent
- solvent
- emulsifying agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 18
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229940087305 limonene Drugs 0.000 claims abstract description 7
- 235000001510 limonene Nutrition 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims abstract description 6
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 6
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims abstract description 6
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 6
- 229940116411 terpineol Drugs 0.000 claims abstract description 6
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims abstract description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 18
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 abstract description 17
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 229940043350 citral Drugs 0.000 abstract description 3
- 244000248349 Citrus limon Species 0.000 abstract description 2
- 235000005979 Citrus limon Nutrition 0.000 abstract description 2
- 150000001555 benzenes Chemical class 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000012459 cleaning agent Substances 0.000 abstract 5
- LOJHHQNEBFCTQK-UHFFFAOYSA-N 2-phenoxypropan-1-ol Chemical compound OCC(C)OC1=CC=CC=C1 LOJHHQNEBFCTQK-UHFFFAOYSA-N 0.000 abstract 1
- 239000001293 FEMA 3089 Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- GPTJTTCOVDDHER-UHFFFAOYSA-N cyclononane Chemical compound C1CCCCCCCC1 GPTJTTCOVDDHER-UHFFFAOYSA-N 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates the natural plant cleaning agent, comprising the following steps: mixing 60-80 parts limonene, 10-20 parts turpentine oil, 10-15 parts methyl ethylene glycol phenyl ether, 5-10 parts terpineol, and 1-3 parts citral to form natural plant solvent; mixing the natural plant solvent and emulsifying agent whose proportion is 1:0.125-0.25 at the 50-80Deg.C and getting the product. The emulsifying agent is polyoxyethylene nonylphenol or sodium dodecylbenzene sulfonate or the mixture of them. The main constituents are extracted by natural plant, such as orange peel and lemon peel. The cleaning agent can substitute the bergol accessory, specially the organic cleaning agent of benzene series chemical materials. The cleaning agent has strong dissolving power, high flash point, high burning point, storage safety, simple technology and easy operation. The raw material is circulating renewable resources, so the cleaning agent is widely used in industry and family.
Description
Technical field
The present invention relates to a kind of clean-out system, particularly a kind of natural plant type detergent.
Background technology
At present, on the market and the chemical solvents of every profession and trade widespread usage mostly be the organic solvent that contains benzene,toluene,xylene or cyclononane etc., the clean-out system of making as main ingredient by this solvent, wherein contain in a large number the poisonous and hazardous material of human body, therefore the eubiosis that when serious infringement people are healthy, will endanger the Nature.The above-mentioned industrial chemicals multi-source for preparing this clean-out system is in the oil fittings, because oil is Nonrenewable resources, so cost of material will constantly rise, and will face the condition of the constantly deficient exhaustion of resource.Drawbacks such as preparation industrial chemicals ubiquity flash-point of clean-out system and burning-point are lower are arranged again, thereby in preparation and use all potential potential safety hazard, security for ensureing that operation is produced will have stricter requirement to production unit and environment, thereby strengthen input and the production cost of implementing.In addition, though existing clean-out system kind is more, because various clean-out systems contain the limitation of component, make range of application narrower, versatility is relatively poor.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point, a kind of cyclic regeneration aboundresources, simple, of many uses, the environment friendly and pollution-free natural plant type detergent of technology are provided.
The technical solution adopted in the present invention is for achieving the above object: a kind of natural plant type detergent, it is characterized in that by 60～80 parts of limonene, 10～20 parts in turps, 10～15 parts of propylene glycol phenylates, 5～10 parts of Terpineol 350s, 1～3 part of citral natural plant solvent that uniform mixing is formulated and emulsifier mix are formed; The proportioning of natural plant solvent and emulsifying agent is 1: 0.125～0.25, is to mix under 50～80 ℃ of conditions in temperature.
Described emulsifying agent adopts polyoxyethylene nonylphenol ether, Sodium dodecylbenzene sulfonate or both mixtures respectively.
The invention has the beneficial effects as follows: the main component of this clean-out system is a smart distillation extraction from natural plant such as orange skin, lemon peel, Pericarpium citri sinensis, and environment-protecting asepsis is pollution-free.Main ingredient limonene wherein has stronger solvency power, and the propylene glycol phenylate can further improve solvency power, strengthens the dissolution with solvents scope; Turps balance solvent evaporates speed, but the miscible degree of citral balance.This clean-out system does not contain benzene,toluene,xylene, cyclononane etc. to the human body hazardous and noxious substances, heavy metal such as yet not leaded, chromium, cadmium, antimony and barium.Non-secondary pollution of the present invention, its residue can be by biological decomposition; Its flash-point height, being more than 60 ℃, the burning-point height, is more than 237 ℃, uses storage safe reliable.Become water solvent as clean-out system by distinctive component of solvent and emulsifier ratio modification.Technology is simple, easy to operate, and the production environment condition is loose, need not specific equipment and the supporting facility that decontaminates, and has significant practical value and economic benefit.Adopting raw material is the recyclable regenerative resource, and the source is abundant and extensive; Reach the removing source of pollution in utilization of waste material, when turning waste into wealth, effectively implement resource integration; Organic chemical industry's clean-out system of benzene class thing as an alternative cleans, decontamination, can generally be used for industry, family and public place etc., as airfield runway, shut down the cleaning of berth, oil field heavy oil stain; And for example airframe, train, automobile machine parts etc.; Also can be used for the cleaning of the required all respects of the fragrant carbohydrate gum of Butterworth Hatch, non-setting adhesive and family.Cleaning performance is remarkable, uses very extensive.
Embodiment
Below in conjunction with preferred embodiment, to details are as follows according to embodiment provided by the invention:
Embodiment 1
With 70 kilograms of limonene, 15 kilograms in turps, 12.5 kilograms of propylene glycol phenylates, 7.5 kilograms of Terpineol 350s, 2 kilograms of citrals, natural plant solvent that uniform mixing is formulated and emulsifier mix are formed; The proportioning of natural plant solvent and emulsifying agent is 1: 0.1875, and promptly emulsifying agent adopts 20.06 kilograms in polyoxyethylene nonylphenol ether, Sodium dodecylbenzene sulfonate or both mixtures respectively, is to mix under 50～80 ℃ of conditions in temperature.
Embodiment 2
With 60 kilograms of limonene, 10 kilograms in turps, 10 kilograms of propylene glycol phenylates, 5 kilograms of Terpineol 350s, 1 kilogram of citral, natural plant solvent that uniform mixing is formulated and emulsifier mix are formed; The proportioning of natural plant solvent and emulsifying agent is 1: 0.125, and promptly emulsifying agent adopts 10.75 kilograms in polyoxyethylene nonylphenol ether, Sodium dodecylbenzene sulfonate or both mixtures respectively, is to mix under 50～80 ℃ of conditions in temperature.
Embodiment 3
With 80 kilograms of limonene, 20 kilograms in turps, 15 kilograms of propylene glycol phenylates, 10 kilograms of Terpineol 350s, 3 kilograms of citrals, natural plant solvent that uniform mixing is formulated and emulsifier mix are formed; The proportioning of natural plant solvent and emulsifying agent is 1: 0.25, and promptly emulsifying agent adopts 32 kilograms in polyoxyethylene nonylphenol ether, Sodium dodecylbenzene sulfonate or both mixtures respectively, is to mix under 50～80 ℃ of conditions in temperature.
Above-mentioned detailed description of the present invention being carried out with reference to embodiment; be illustrative rather than determinate; can enumerate several embodiment according to set of dispense than qualification scope,, should belong within protection scope of the present invention therefore in the variation and the modification that do not break away under the general plotting of the present invention.
Claims (2)
1, a kind of natural plant type detergent, it is characterized in that by 60～80 parts of limonene, 10～20 parts in turps, 10～15 parts of propylene glycol phenylates, 5～10 parts of Terpineol 350s, 1～3 part of citral natural plant solvent that uniform mixing is formulated and emulsifier mix are formed; The proportioning of natural plant solvent and emulsifying agent is 1: 0.125～0.25, is to mix under 50～80 ℃ of conditions in temperature.
2, natural plant type detergent according to claim 1 is characterized in that described emulsifying agent adopts polyoxyethylene nonylphenol ether, Sodium dodecylbenzene sulfonate or both mixtures respectively.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101223309A CN100351360C (en) | 2005-12-13 | 2005-12-13 | Natural plant type detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005101223309A CN100351360C (en) | 2005-12-13 | 2005-12-13 | Natural plant type detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1789398A true CN1789398A (en) | 2006-06-21 |
| CN100351360C CN100351360C (en) | 2007-11-28 |
Family
ID=36787524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005101223309A Expired - Fee Related CN100351360C (en) | 2005-12-13 | 2005-12-13 | Natural plant type detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100351360C (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225346B (en) * | 2007-12-21 | 2010-06-16 | 中航材航空新材料有限公司 | Water-based type environment protection cleaning agent and preparation method thereof |
| CN101768530A (en) * | 2010-03-17 | 2010-07-07 | 天津鎏虹科技发展有限公司 | Natural plant cleaning agent |
| CN101962601A (en) * | 2010-10-31 | 2011-02-02 | 无锡龙腾画材有限公司 | Environment-friendly orange peel extract limonene degumming and decontaminating agent and preparation method thereof |
| CN101974376A (en) * | 2010-10-31 | 2011-02-16 | 无锡龙腾画材有限公司 | Adhesive removing soft capsule by extracting limonene from orange peel and preparation method thereof |
| CN102051272A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Multifunctional environmental-protection cleaning agent |
| CN102277239A (en) * | 2011-07-20 | 2011-12-14 | 天津鎏虹科技发展有限公司 | Natural plant aqueous cleaning agent and preparation method thereof |
| CN101735894B (en) * | 2008-11-11 | 2012-05-23 | 3M创新有限公司 | Medical adhesive residue remover |
| WO2013010337A1 (en) * | 2011-07-20 | 2013-01-24 | 天津鎏虹科技发展有限公司 | Method for fabricating wet tissue by using natural plant cleaning agent |
| CN103525584A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Efficient cleaning agent for cleaning printing machinery and preparation method thereof |
| CN103643250A (en) * | 2013-12-19 | 2014-03-19 | 青岛聚蚨源机电有限公司 | Environment-friendly paraffin cleaner |
| CN104877778A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for cooking utensil cleaning agent |
| CN104877833A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for automobile engine cleaning agent |
| CN106367235A (en) * | 2016-08-26 | 2017-02-01 | 广州市博林机械设备有限公司 | Application of rutaceous plant extract serving as decontaminant |
| CN106590139A (en) * | 2016-12-11 | 2017-04-26 | 钦州学院 | Natural plant type cleaning agent and preparation method thereof |
| CN107227211A (en) * | 2017-06-19 | 2017-10-03 | 苏州永创达电子有限公司 | A kind of plant environment-friendly type cleaning agent |
| CN108822995A (en) * | 2018-06-11 | 2018-11-16 | 太仓双赢电子电气成套设备有限公司 | Washing agent for electronic materials |
| CN109576080A (en) * | 2018-12-28 | 2019-04-05 | 北京绿伞化学股份有限公司 | A kind of kitchen heavy oil dirt micro emulsion cleaning agent and preparation method thereof |
| US10638769B2 (en) | 2014-10-20 | 2020-05-05 | Arysta Lifescience Benelux Sprl | Method for anti-sprouting tuber treatment with reduced amount of CIPC |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242797A (en) * | 1997-01-06 | 2000-01-26 | 雷克特和科尔曼公司 | Improved blooming type disinfecting cleaning compostions |
| CN1580145A (en) * | 2003-08-01 | 2005-02-16 | 张刚 | Natural plant type solvent and its preparing method |
-
2005
- 2005-12-13 CN CNB2005101223309A patent/CN100351360C/en not_active Expired - Fee Related
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225346B (en) * | 2007-12-21 | 2010-06-16 | 中航材航空新材料有限公司 | Water-based type environment protection cleaning agent and preparation method thereof |
| CN101735894B (en) * | 2008-11-11 | 2012-05-23 | 3M创新有限公司 | Medical adhesive residue remover |
| CN101768530A (en) * | 2010-03-17 | 2010-07-07 | 天津鎏虹科技发展有限公司 | Natural plant cleaning agent |
| WO2011113221A1 (en) * | 2010-03-17 | 2011-09-22 | 天津鎏虹科技发展有限公司 | Natural plant detergent |
| CN101962601A (en) * | 2010-10-31 | 2011-02-02 | 无锡龙腾画材有限公司 | Environment-friendly orange peel extract limonene degumming and decontaminating agent and preparation method thereof |
| CN101974376A (en) * | 2010-10-31 | 2011-02-16 | 无锡龙腾画材有限公司 | Adhesive removing soft capsule by extracting limonene from orange peel and preparation method thereof |
| CN101974376B (en) * | 2010-10-31 | 2013-07-03 | 无锡龙腾画材有限公司 | Adhesive removing soft capsule by extracting limonene from orange peel and preparation method thereof |
| CN102051272A (en) * | 2011-01-24 | 2011-05-11 | 北京洛娃日化有限公司 | Multifunctional environmental-protection cleaning agent |
| CN102051272B (en) * | 2011-01-24 | 2012-11-07 | 北京洛娃日化有限公司 | Multifunctional environmental-protection cleaning agent |
| CN102277239A (en) * | 2011-07-20 | 2011-12-14 | 天津鎏虹科技发展有限公司 | Natural plant aqueous cleaning agent and preparation method thereof |
| WO2013010337A1 (en) * | 2011-07-20 | 2013-01-24 | 天津鎏虹科技发展有限公司 | Method for fabricating wet tissue by using natural plant cleaning agent |
| WO2013010338A1 (en) * | 2011-07-20 | 2013-01-24 | 天津鎏虹科技发展有限公司 | Natural plant water-based cleaning agent and preparation method therefor |
| CN103525584A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Efficient cleaning agent for cleaning printing machinery and preparation method thereof |
| CN103643250A (en) * | 2013-12-19 | 2014-03-19 | 青岛聚蚨源机电有限公司 | Environment-friendly paraffin cleaner |
| CN103643250B (en) * | 2013-12-19 | 2015-11-11 | 青岛聚蚨源机电有限公司 | A kind of Environment-friendlyparaffin paraffin cleaner |
| US10638769B2 (en) | 2014-10-20 | 2020-05-05 | Arysta Lifescience Benelux Sprl | Method for anti-sprouting tuber treatment with reduced amount of CIPC |
| US11344039B2 (en) | 2014-10-20 | 2022-05-31 | Arysta Lifescience Benelux Sprl | Method for anti-sprouting tuber treatment with reduced amount of CIPC |
| CN104877778A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for cooking utensil cleaning agent |
| CN104877833A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for automobile engine cleaning agent |
| CN106367235A (en) * | 2016-08-26 | 2017-02-01 | 广州市博林机械设备有限公司 | Application of rutaceous plant extract serving as decontaminant |
| CN106590139A (en) * | 2016-12-11 | 2017-04-26 | 钦州学院 | Natural plant type cleaning agent and preparation method thereof |
| CN107227211A (en) * | 2017-06-19 | 2017-10-03 | 苏州永创达电子有限公司 | A kind of plant environment-friendly type cleaning agent |
| CN108822995A (en) * | 2018-06-11 | 2018-11-16 | 太仓双赢电子电气成套设备有限公司 | Washing agent for electronic materials |
| CN109576080A (en) * | 2018-12-28 | 2019-04-05 | 北京绿伞化学股份有限公司 | A kind of kitchen heavy oil dirt micro emulsion cleaning agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100351360C (en) | 2007-11-28 |
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Owner name: ZHANG GANG Free format text: FORMER OWNER: ZHANG GANG; LI SHUGUI Effective date: 20080725 |
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Effective date of registration: 20080725 Address after: Tianjin New Technology Industrial Park, Wuhua Avenue No. 2 Haitai torch Pioneering Park A block 102 zip code: 300384 Patentee after: Zhang Gang Address before: Tianjin New Technology Industrial Park, Wuhua Avenue No. 2 Haitai torch Pioneering Park A block 102 zip code: 300384 Co-patentee before: Li Shugui Patentee before: Zhang Gang |
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Denomination of invention: Natural plant cleaning agent for cleaning heavy oil in kitchen and preparation method of natural plant cleaning agent Effective date of registration: 20141102 Granted publication date: 20071128 Pledgee: Bank of Shanghai Limited by Share Ltd Tianjin branch Pledgor: Tianjin Liuhong Sci. & Tech. Dev. Co., Ltd. Registration number: 2014120000058 |
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