CN107652749A - A kind of UV ink environment-friendly cleaning agent and preparation method thereof - Google Patents
A kind of UV ink environment-friendly cleaning agent and preparation method thereof Download PDFInfo
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- CN107652749A CN107652749A CN201710964400.8A CN201710964400A CN107652749A CN 107652749 A CN107652749 A CN 107652749A CN 201710964400 A CN201710964400 A CN 201710964400A CN 107652749 A CN107652749 A CN 107652749A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of UV ink environment-friendly cleaning agent and preparation method thereof, the UV ink environment-friendly cleaning agent is made up of the raw material of following parts by weight：Environmentally friendly solvent 20 40, surfactant 15, solubilizer 5 25, preservative 0.5 3, water 30 70；Preparation method is by weight, environmentally friendly solvent to be added into reactor, after stirring 5 minutes, adds surfactant and stirs 10 minutes, add solubilizer and preservative, stir to each component after being completely dissolved, add water, continues to stir 15 minutes；Obtained UV ink environment-friendly cleaning agents flash-point is high, volatilization is few, it is nonflammable explosive, discharged with extremely low VOC, pollution to environment is extremely low, and solvent is not degradable to be oxidized to acid, aldehyde, ketone corrosion ink roller and blanket, ink roller is not easy to expand, deformed, the field such as clean with printing plate in the cleaning of UV ink and UV ink has larger Social benefit and economic benefit, is advantageous to printing industry towards green, the direction sound development of environmental protection.
Description
Technical field
The present invention relates to a kind of printing consumable material, particularly a kind of UV detergent for ink.
Background technology
UV detergent for ink of the prior art removes using gasoline, kerosene as main solvent although can be very good cleaning
UV ink, but solvent flash-point is low, inflammable and explosive, high volatility, influences the health of staff in workshop, while can cause
Serious environmental pollution.Also there is substantial amounts of arene compounds in gasoline and kerosene, these compounds are to plate and rubber
The corrosivity of roller is strong.
The patent document of Publication No. " CN102888140B " discloses a kind of environment-friendlyprinting printing ink cleaning agent and preparation technology, should
Scheme is prepared using phosphate or enuatrol as main solvent, then with surfactant and emulsifying agent mixing, stirring.The ink is clear
Lotion is free of petroleum solvent, and smell is low, and cleaning efficiency is high, but has used expensive in the invention, and water body is caused
The phosphoric acid ester solvent polluted extensively limits its application as main solvent.
The patent document of Publication No. " CN101434764B " discloses a kind of environment-friendlyprinting printing ink cleaning agent, and the program employs
Aliphatic acid monoalkyl ester is main solvent, compounds, is prepared with nonionic surface active agent and anionic surfactant
Detergent for ink with good cleaning capacity, but the detergent for ink of the program is not suitable for UV ink, and cleaning agent be present
The problem of emulsion system is unstable and is furnished with corrosion to rubber, limit its large-scale promotion application.
These problems hampers UV detergent for ink is unfavorable for printing industry towards environmental protection, the direction progress of green
Develop in a healthy way.
The content of the invention
For overcome the deficiencies in the prior art, of the invention to provide a kind of flash-point height, volatilization is few, nonflammable explosive, reduction pair
The UV ink cleaner in environmental protection of ink roller corrosion.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of UV ink environment-friendly cleaning agent, is made up of the raw material of following parts by weight：Environmentally friendly solvent 20-40, surfactant 1-5,
Solubilizer 5-25, preservative 0.5-3, water 30-70.
The environmentally friendly solvent is methylated vegetable oil（Main chain carbon number is 8-30）With the mixture of terpene compound, its
In, the weight of terpene compound is 50%-90%, methylated vegetable oil（Main chain carbon number is 8-30）Weight be 10%-50%.
The terpene compound is selected from australene, nopinene, limonene, (+)-α-longipinene, α-carypohyllene
The mixture of one or two kinds of and two or more arbitrary proportions.
The methylated vegetable oil（Main chain carbon number is 8-30）Selected from methyl caprylate, methyl laurate, methyl hexadecanoate, Asia
The mixture of one or both of methyl oleate, methyl stearate and two or more arbitrary proportions.
The surfactant is the Compositional type table that nonionic surface active agent and anionic surfactant mix
Face activating agent, wherein, the weight ratio of nonionic surface active agent and anionic surfactant is 1:5—5:1.
The nonionic surface active agent is one or both of APES, alkylolamides and two
The mixture of kind any of the above ratio.
The anion surfactant be Brij 35 sodium sulphate, aliphatic acid sodium isethionate,
The mixture of one or both of ethoxylated dodecyl alcohol carboxylic acid sodium and two or more arbitrary proportions.
The solubilizer is MMB.
The preservative is the mixture of sodium benzoate and Nipasol, wherein, the weight of sodium benzoate and Nipasol
Than for 10:1—1:1.
A kind of preparation method of described UV ink environment-friendly cleaning agents, comprises the following steps（Without special in making step
Temperature and pressure is emphasized, temperature and pressure refers under normal temperature and pressure environment）：
（1）, the environmentally friendly solvents of above-mentioned parts by weight added in reactor, persistently stir 5 minutes, then add above-mentioned weight
The surfactant of part persistently stirs 10 minutes, obtains the solution of homogeneous transparent；
（2）, add the solubilizer and preservative of above-mentioned parts by weight, stir to each component and be completely dissolved, then add above-mentioned
The water of parts by weight, continue stirring 15 minutes, obtain the UV ink environment-friendly cleaning agent.
The beneficial effects of the invention are as follows：UV ink environment-friendly cleaning agents prepared by the present invention, flash-point is high, and volatilization is few, is not easy
Fire explosive, there is extremely low VOC to discharge, the pollution to environment is extremely low, is environmentally friendly product；It is contained
Preservative can effectively prevent degrading solvent to be oxidized to acid, aldehyde, ketone, reduce the corrosion to ink roller and blanket, be not easy ink roller swollen
Swollen, deformation, extends its service life；The field such as cleaning with printing plate in the cleaning of UV ink and UV ink has larger society
Benefit and economic benefit, be advantageous to printing industry and developed in a healthy way towards the direction of green, environmental protection.
Embodiment
A kind of UV ink environment-friendly cleaning agent, is made up of the raw material of following parts by weight：Environmentally friendly solvent 20-40, surfactant
1-5, solubilizer 5-25, preservative 0.5-3, water 30-70.
The environmentally friendly solvent is methylated vegetable oil（Main chain carbon number is 8-30）With the mixture of terpene compound, its
In, the weight of terpene compound is 50%-90%, methylated vegetable oil（Main chain carbon number is 8-30）Weight be 10%-50%.
The terpene compound is selected from australene, nopinene, limonene, (+)-α-longipinene, α-carypohyllene
The mixture of one or two kinds of and two or more arbitrary proportions.
The methylated vegetable oil（Main chain carbon number is 8-30）Selected from methyl caprylate, methyl laurate, methyl hexadecanoate, Asia
The mixture of one or both of methyl oleate, methyl stearate and two or more arbitrary proportions.
The surfactant is the Compositional type table that nonionic surface active agent and anionic surfactant mix
Face activating agent, wherein, the weight ratio of nonionic surface active agent and anionic surfactant is 1:5—5:1.
The nonionic surface active agent is one or both of APES, alkylolamides and two
The mixture of kind any of the above ratio.
The anion surfactant be Brij 35 sodium sulphate, aliphatic acid sodium isethionate,
The mixture of one or both of ethoxylated dodecyl alcohol carboxylic acid sodium and two or more arbitrary proportions.
The solubilizer is MMB.
The preservative is the mixture of sodium benzoate and Nipasol, wherein, the weight of sodium benzoate and Nipasol
Than for 10:1—1:1.
Solvent for use flash-point of the present invention is high, and volatilization is few, and can extract from plant or be obtained by plant oil modified；Institute
All it is the material of difficult volatilization with surfactant, solubilizer, preservative, and toxicity is extremely low, will not endanger shop personnel
Health.Possess hydroxyl and methoxyl group simultaneously in the molecule of MMB, this makes it in intramolecular and divided
Very strong hydrogen bond is formed between son, there is prominent solvability.The solvent of the present invention is free of without using kerosene, vapour oil based solvent
Arene compounds, and preservative can protect the solvent of the present invention, avoid solvent from being degraded and be oxidized to the corrosion of acid, aldehyde, ketone
Ink roller, ink roller is not easy to expand, deformed, extend its service life.
Embodiment 1
UV ink environment-friendly cleaning agent is made up of the raw material of following parts by weight：Environmentally friendly solvent is from australene 10, limonene 10, palm
Sour methyl esters 5, methyl stearate 3, surfactant from NPE 2, cocoanut fatty acid diethanolamide 1,
Brij 35 sodium sulphate 1, solubilizer are MMB 25, and preservative includes benzoic acid
Sodium 2.5, Nipasol 0.5, water 40（Water does not specially require, distilled water, deionized water or meet standard for drinking running water it is equal
Can）.
Embodiment 2
UV ink environment-friendly cleaning agent is made up of the raw material of following parts by weight：Environmentally friendly solvent is from nopinene 10, limonene 15, palm
Sour methyl esters 5, methyl laurate 3, surfactant is from NPE 2, Brij 35 sulfuric acid
Sodium 1, ethoxylated dodecyl alcohol carboxylic acid sodium 2, solubilizer are MMB 20, and preservative includes benzoic acid
Sodium 2, Nipasol 1, water 50.
Embodiment 3
UV ink environment-friendly cleaning agent is made up of the raw material of following parts by weight：Environmentally friendly solvent is from australene 15, limonene 15, palm
Sour methyl esters 5, methyl laurate 5, surfactant is from OPEO 3, Brij 35 sulfuric acid
Sodium 1, ethoxylated dodecyl alcohol carboxylic acid sodium 1, solubilizer are MMB 25, and preservative includes benzoic acid
Sodium 0.5, Nipasol 0.5, water 35.
Embodiment 4
UV ink environment-friendly cleaning agent is made up of the raw material of following parts by weight：Environmentally friendly solvent is from (+)-α-longipinene 15, sub- oil
Sour methyl esters 5, surfactant is from NPE 0.5, Brij 35 sodium sulphate 0.5, solubilising
Agent is MMB 8, and preservative includes sodium benzoate 1, Nipasol 1, water 30.
Embodiment 5
UV ink environment-friendly cleaning agent is made up of the raw material of following parts by weight：Environmentally friendly solvent is from australene 10, nopinene 5, lemon
Alkene 10, α-carypohyllene 5, methyl hexadecanoate 3, methyl stearate 3, surfactant is from NPE 2, coconut oil
Fatty diglycollic amide 1, Brij 35 sodium sulphate 1, solubilizer are MMB
25, preservative includes sodium benzoate 2, Nipasol 1, water 60.
The preparation method of the UV ink environment-friendly cleaning agent, comprises the following steps（Do not emphasized especially in making step temperature and
Pressure, temperature and pressure refers under normal temperature and pressure environment）：
（1）, the environmentally friendly solvents of above-mentioned parts by weight added in reactor, persistently stir 5 minutes, then add above-mentioned parts by weight
Surfactant persistently stirs 10 minutes, obtains the solution of homogeneous transparent.
（2）, add the solubilizer and preservative of above-mentioned parts by weight, stir to each component and be completely dissolved（Persistently stir 15 points
Clock）, the water of above-mentioned parts by weight is then added, continues stirring 15 minutes, obtains UV ink environment-friendly cleaning agents.
Each component in above-described embodiment is product generally in the art, is not particularly limited, and is commercially available.
Cleaning capacity compares：
Sample is embodiment 1, embodiment 2, embodiment 3, embodiment 4, embodiment 5, Dongguan cent STQX, Guangzhou domino WL-
200 .By blanket（The precious spring UV blankets of Suzhou Jun Xiang printing apparatus Co., Ltd production）It is cut into 30cm*30cm, each sample
Product prepare 3 pieces, weigh 50 grams of UV ink（The German high 950-UV of enlightening）Uniformly it is applied on the blanket cut out, solidifies 10 under sunlight
Minute, ask skilled worker operating personnel's use above each sample to clean the blanket for speckling with UV ink, record every kind of sample
It is the total time that product clean up 3 pieces of blankets, as a result as follows：
| Sample | Clean up the used time |
| Embodiment 1 | 132 seconds |
| Embodiment 2 | 135 seconds |
| Embodiment 3 | 130 seconds |
| Embodiment 4 | 142 seconds |
| Embodiment 5 | 127 seconds |
| STQX | 128 seconds |
| WL-200 | 140 seconds |
It follows that the cleaning capacity of the UV ink environment-friendly cleaning agents of the present invention cleans with gasoline, the volatile UV ink of kerosene type
The cleaning capacity of agent is suitable.The present invention can high-efficient cleaning except residual UV ink while, can accomplish it is nonflammable, it is difficult volatilization, it is low
Toxicity, be advantageous to the health of safeguard work personnel, it is ensured that the production safety in workshop.
Claims (10)
1. a kind of UV ink environment-friendly cleaning agent, it is characterised in that be made up of the raw material of following parts by weight：Environmentally friendly solvent 20-40, table
Face activating agent 1-5, solubilizer 5-25, preservative 0.5-3, water 30-70.
2. UV ink environment-friendly cleaning agent according to claim 1, it is characterised in that the environmentally friendly solvent is esterification plant
Oil（Main chain carbon number is 8-30）With the mixture of terpene compound, wherein, the weight of terpene compound is 50%-90%, first
Esterified vegetable oil（Main chain carbon number is 8-30）Weight be 10%-50%.
3. UV ink environment-friendly cleaning agent according to claim 2, it is characterised in that the terpene compound is selected from australene
One or both of alkene, nopinene, limonene, (+)-α-longipinene, α-carypohyllene and two or more arbitrary proportions it is mixed
Compound.
4. UV ink environment-friendly cleaning agent according to claim 2, it is characterised in that the methylated vegetable oil（Main chain carbon number
For 8-30）Selected from one or both of methyl caprylate, methyl laurate, methyl hexadecanoate, methyl linoleate, methyl stearate
And the mixture of two or more arbitrary proportions.
5. UV ink environment-friendly cleaning agent according to claim 1, it is characterised in that the surfactant is nonionic
Surfactant and the built surfactant of anionic surfactant mixing, wherein, nonionic surface active agent
Weight ratio with anionic surfactant is 1:5—5:1.
6. UV ink environment-friendly cleaning agent according to claim 5, it is characterised in that the nonionic surface active agent is
The mixture of one or both of APES, alkylolamides and two or more arbitrary proportions.
7. UV ink environment-friendly cleaning agent according to claim 5, it is characterised in that the anion surfactant is ten
Dialkyl group alcohol polyethenoxy ether sodium sulfate, aliphatic acid sodium isethionate, one kind in ethoxylated dodecyl alcohol carboxylic acid sodium or
Two kinds and the mixture of two or more arbitrary proportions.
8. UV ink environment-friendly cleaning agent according to claim 1, it is characterised in that the solubilizer is 3- methoxyl group -3- first
Base-n-butyl alcohol.
9. UV ink environment-friendly cleaning agent according to claim 1, it is characterised in that the preservative is sodium benzoate and hydroxyl
The mixture of phenylpropyl alcohol ester, wherein, the weight ratio of sodium benzoate and Nipasol is 10:1—1:1.
A kind of 10. preparation method of UV ink environment-friendly cleaning agents as described in claim 1 to 9 is any, it is characterised in that including
Following steps（Do not have especially to emphasize temperature and pressure in making step, temperature and pressure refers under normal temperature and pressure environment）：
（1）, the environmentally friendly solvents of above-mentioned parts by weight added in reactor, persistently stir 5 minutes, then add above-mentioned weight
The surfactant of part persistently stirs 10 minutes, obtains the solution of homogeneous transparent；
（2）, add the solubilizer and preservative of above-mentioned parts by weight, stir to each component and be completely dissolved, then add above-mentioned
The water of parts by weight, continue stirring 15 minutes, obtain the UV ink environment-friendly cleaning agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710964400.8A CN107652749A (en) | 2017-10-17 | 2017-10-17 | A kind of UV ink environment-friendly cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710964400.8A CN107652749A (en) | 2017-10-17 | 2017-10-17 | A kind of UV ink environment-friendly cleaning agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107652749A true CN107652749A (en) | 2018-02-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710964400.8A Pending CN107652749A (en) | 2017-10-17 | 2017-10-17 | A kind of UV ink environment-friendly cleaning agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727895A (en) * | 2018-05-04 | 2018-11-02 | 南京信息工程大学 | A kind of half detergent for water-based print ink of environment-friendly type and preparation method thereof |
| CN113969220A (en) * | 2021-11-26 | 2022-01-25 | 中山市富日印刷材料有限公司 | Water-based UV ink cleaning agent and preparation method thereof |
| CN115433638A (en) * | 2022-09-15 | 2022-12-06 | 中山市富日印刷材料有限公司 | Rubber blanket cleaning agent and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525174A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Emulsion type ink cleaning agent and preparation method thereof |
| CN106147372A (en) * | 2016-09-27 | 2016-11-23 | 合肥天翔环境工程有限公司 | Detergent for ink containing D limonene and preparation method thereof |
-
2017
- 2017-10-17 CN CN201710964400.8A patent/CN107652749A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525174A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Emulsion type ink cleaning agent and preparation method thereof |
| CN106147372A (en) * | 2016-09-27 | 2016-11-23 | 合肥天翔环境工程有限公司 | Detergent for ink containing D limonene and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108727895A (en) * | 2018-05-04 | 2018-11-02 | 南京信息工程大学 | A kind of half detergent for water-based print ink of environment-friendly type and preparation method thereof |
| CN108727895B (en) * | 2018-05-04 | 2022-04-08 | 南京信息工程大学 | Environment-friendly semi-water-based printing ink cleaning agent and preparation method thereof |
| CN113969220A (en) * | 2021-11-26 | 2022-01-25 | 中山市富日印刷材料有限公司 | Water-based UV ink cleaning agent and preparation method thereof |
| CN115433638A (en) * | 2022-09-15 | 2022-12-06 | 中山市富日印刷材料有限公司 | Rubber blanket cleaning agent and preparation method and application thereof |
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Application publication date: 20180202 |
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