CN108048234A - A kind of degradable cleaning agent of building roof special bio and preparation method thereof - Google Patents
A kind of degradable cleaning agent of building roof special bio and preparation method thereof Download PDFInfo
- Publication number
- CN108048234A CN108048234A CN201810031746.7A CN201810031746A CN108048234A CN 108048234 A CN108048234 A CN 108048234A CN 201810031746 A CN201810031746 A CN 201810031746A CN 108048234 A CN108048234 A CN 108048234A
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- Prior art keywords
- cleaning agent
- ether
- agent according
- alkyl ether
- alcohol
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
Abstract
The present invention provides a kind of degradable cleaning agent of building roof special bio and preparation method thereof, which is made by including nonionic surfactant, polyol alkyl ether, mineral oil dispersion, polysiloxane emulsion, anion surfactant, the ingredient of alcamine compound and deionized water.The degradable cleaning agent of building roof special bio provided by the invention can quickly and effectively, targetedly remove needed for washing oily dirt, in water can quick emulsification, scattered, dissolving, it is and nontoxic or less toxic, it has no irritating odor, it is environmentally protective, there is biodegradability, it is easy to operate.
Description
Technical field
The present invention relates to a kind of degradable cleaning agents of building roof special bio and preparation method thereof, are mainly used for building
The cleaning decontamination of roofing.
Background technology
Removing the common method of greasy dirt has physics, chemistry and biological ablution.Wherein chemical cleaning method is current using most
A kind of extensive cleaning method, it is cleaned using the reaction of chemicals or other solvents and dirt, it passes through
The effects that dissolving, emulsification, scattered, absorption and achieve the purpose that take out stains, the dead angle with high, the capable of washing equipment of cleaning efficiency
The advantages that.
At present, with the improvement of people's life quality, gradually recognize environmental protection importance, so coming into being just
Aqueous cleaning agent is generated, but there are following defect or deficiencies for current aqueous-base cleaning：On the one hand, the ability to degrease compared with
Difference, the more not easy cleanings of bubble are, it is necessary to which substantial amounts of water can just clean up；On the other hand, environmental pollution is serious, biological non-degradable.
The content of the invention
It is an object of the invention to provide a kind of degradable cleaning agents of building roof special bio and preparation method thereof, this is clear
Lotion is by including nonionic surfactant, polyol alkyl ether, mineral oil dispersion, polysiloxane emulsion, anionic surface
Activating agent, the ingredient and deionized water of alcamine compound are made.Cleaning agent provided by the invention can quickly and effectively, pointedly
The oily dirt of washing needed for removing, in water can quick emulsification, scattered, dissolving, it is and nontoxic or less toxic, have no irritating odor,
It is environmentally protective, there is biodegradability, it is easy to operate.
According to the present invention on one side, a kind of degradable cleaning agent of building roof special bio is provided, including following quality
The raw material of number：
In the present invention, contain alkyl glycosides in the structure of the nonionic surfactant, be readily biodegradable as water
And carbon dioxide, effectively prevent the pollution to environment.
In the present invention, 3 are preferably comprised in the structure of the nonionic surfactant containing 1~8 oxyethylene group ,~
5 oxyethylene groups, the oxyethylene group generally refer to the group with alcohol ehter bond.
According to the present invention, in non-limiting manner, the specific example of the nonionic surfactant includes：Cetostearyl alcohol Portugal
Polyglycoside polyoxyethylene ether (alcohol ehter bond contains 3),
Ten alcohol glucoside polyoxyethylene ether of isomery (alcohol ehter bond contains 7), fatty alcohol glucoside polyoxyethylene ether (alcohol ether
Key contains 9), aliphatic amine polyoxyethylene ether glucoside (alcohol ehter bond contains 5), it is preferred to use commercial goods, such as Aksu are public
Take charge of the APG-AEO-3 of production.
In the present invention, the polyol alkyl ether can reach optimal cleaning effect with cosurfactant.
In non-limiting manner, the polyol alkyl ether can be dihydric alcohol alkyl ether, trihydroxylic alcohol alkyl ether, tetrahydroxylic alcohol alkyl
The lower alkyl ether of ether, preferably more than polyalcohol, such as dihydric alcohol methyl ether, dihydric alcohol ether, trihydroxylic alcohol methyl ether, trihydroxylic alcohol second
Ether, tetrahydroxylic alcohol methyl ether, tetrahydroxylic alcohol ether etc. are most preferably dipropylene glycol methyl ether.There are many its commercial product, such as the good China in Xingtai helps
Dipropylene glycol methyl ether of agent Co., Ltd production etc..
In the present invention, using mineral oil as dispersion, mineral oil is also white oil, alias paraffin oil, white oil, be by
The cycloalkane and alkane mixture of the mixture, predominantly saturation of refining liquid hydrocarbon obtained by oil, crude oil is through normal pressure and decompression
Fractionation, solvent extraction and dewaxing, hydrofinishing and obtain.
According to the present invention, the mineral oil dispersion is preferably modified it to more preferably play a role, and especially adopts
With organic-silicon-modified mineral oil dispersion.It can use commercial goods, such as extra large name this productionMade products can also be used, such as are modified as follows：It utilizes：2- (second sulfidomethyl) benzene
Base-N- methyl carbamates and 3- glycidylpropyl trimethoxy silanes, make solvent, bismuth chloride makees catalyst with ethyl alcohol,
In 20 DEG C of temperature and N2In the case of protection, 12h is reacted, is extracted using deionized water, anhydrous sodium sulfate drying, filtering obtains mesh
Mark product.
In the present invention, when the mineral oil dispersion and polysiloxane emulsion are used cooperatively, can eliminate inside system
The bubble generated, while inhibit to generate bubble in whipping process, and optimal bubble defoaming effect can be reached.
The polysiloxane emulsion can use commercial goods, such as extra large name this production
The degradable cleaning agent of building roof special bio provided by the invention further includes the raw material of following mass fraction：
Anion surfactant, 0.5~10 part, preferably 1~5 part,
Alcamine compound, preferably 5~35 parts, 11~20 parts.
In the present invention, the anion surfactant is fat soap, is preferably line style fat soap, and line style is fatty
Soaps are easy to degrade, and degradability is better than other anion surfactants.Through measuring：Anion surfactant biology drop
The high and low level of solution property is substantially：Line style fat soap>Higher aliphatic sulfuric acid>Line style alcohol ethers sulfuric ester>Line style alkane
Base or alkenyl sulfonate>Linear alkyl benzene sulfonate sodium>Branch higher alcohol sulfate and soaps>Branch ethers sulfuric ester>Branch
Alkylsulfonate.Commercial goods, such as the LATEMUL E-118B of BASF AG's production can be used.
In the present invention, the alcamine compound is triethanolamine, diethanol amine, one kind or more in monoethanolamine etc.
Kind, it is preferably triethanolamine and the composition of monoethanolamine, more preferably triethanolamine and matter of the mass fraction for 4.5~25 parts
Measure number be 0.5~10 part monoethanolamine composition, especially preferably mass fraction be 10~15 parts triethanolamine and
Mass fraction is the composition of 1~5 part of monoethanolamine.There are many its commercial product, such as the life of Xingtai Jia Hua auxiliary agents Co., Ltd
The triethanolamine of production and monoethanolamine etc..
In the present invention, the alcamine compound is used for the pH value of regulation system, such as pH value is adjusted to 9-10's
Scope.
According to a further aspect of the invention, the preparation side of the above-mentioned degradable cleaning agent of building roof special bio is additionally provided
Method comprises the following steps：
Step 1, add water in blender, then add in mineral oil dispersion and polysiloxane emulsion；
Step 2, nonionic surfactant, anion surfactant and polyol alkyl ether are sequentially added, 600 turns/
Minute, persistently stir 20 minutes；
Step 3, alcamine compound is added in, and is stirred, 400 revs/min, is persistently stirred 25 minutes, system pH
Scope is 9-10.
In the present invention, the cleaning agent can be used for carrying out building roof cleaning decontamination, and washing performance is more than 95%,
COD/BOD values are more than 4.
The degradable cleaning agent of building roof special bio prepared according to the method for the present invention has following beneficial technique effect：
1) oily dirt of washing needed for quickly and effectively, targetedly removing, in water can quick emulsification, it is scattered,
Dissolving.
2) reply washing object and environment are nontoxic or less toxic, have no irritating odor, the stringent addition for controlling APEO, green ring
It protects.
3) cleaning raw material used should be cheap and easily-available, based on production domesticization, makes cleaning cost relatively low.
4) there is biodegradability, less have enrichment.
5) easy to operate, cleaning condition is mild, to all no requirement (NR)s such as wash temperature, pressure, machinery, is easily flush with water dry
Only.
Specific embodiment
Below by embodiment, the present invention is described in more detail.Pass through these explanations, the features and advantages of the invention
It will become more apparent from clearly.
Raw material：
Nonionic surfactant is the APG-AEO-3 of Aksu company production；
Triethanolamine, monoethanolamine and dipropylene glycol methyl ether produce for Xingtai Jia Hua auxiliary agents Co., Ltd；
Anion surfactant is the LATEMUL E-118B20g of BASF AG's production；
Organic-silicon-modified mineral oil dispersion and polysiloxane emulsion are respectively extra large this production of nameWith
Embodiment 1：
150g water is added in blender, then adds in 5gAnd 15g
Sequentially add 100g APG-AEO-3,20g LATEMUL E-118B and 60g dipropylene glycol methyl ethers, 600 revs/min
Clock persistently stirs 20 minutes；
100g triethanolamines and 30g monoethanolamine are added in, and is stirred, 400 revs/min, is persistently stirred 25 minutes, body
It is that pH value range is 9-10, obtains target cleaning agent.
Embodiment 2：
180g water is added in blender, then adds in 3gAnd 10g
Sequentially add 150g APG-AEO-3,40g LATEMUL E-118B and 100g dipropylene glycol methyl ethers, 600 revs/min
Clock persistently stirs 20 minutes；
150g triethanolamines and 40g ethanolamines are added in, and is stirred, 400 revs/min, is persistently stirred 25 minutes, system
PH value range is 9-10, obtains target cleaning agent.Experimental example
Normative reference：
JB/T 4323-1999 water base metal cleaning agents are mainly used for measuring the washability and defoaming capacity of cleaning agent；
The measure dichromate titration of the water chemical oxygen demands of HJ828-2017, this standard are suitable for surface water, sanitary sewage
With the measure of COD in industrial wastewater；
The measure dilution of HJ 505-2009 water quality five-day BODs (BOD5) and inocalation method, this standard are suitable for ground
The measure of BOD in table water, sanitary sewage and industrial wastewater.
To embodiment 1 and it is that the degradable cleaning agent of building roof special bio is tested for the property made from embodiment 2, point
Do not test its COD, BOD, COD/BOD value, washing performance, defoaming and pH, embodiment 1 and 2 test result of embodiment are respectively such as
Shown in Tables 1 and 2.
Table 1
Table 2
Above in association with preferred embodiment, the present invention is described, but these embodiments are only exemplary
, only play the role of illustrative.On this basis, a variety of replacements and improvement can be carried out to the present invention, these each fall within this
In the protection domain of invention.
Claims (10)
1. a kind of degradable cleaning agent of building roof special bio, it is characterised in that：Include the raw material of following mass fraction：
2. cleaning agent according to claim 1, which is characterized in that contain alkane in the structure of the nonionic surfactant
Base glucosides.
3. cleaning agent according to claim 1, which is characterized in that contain 1 in the structure of the nonionic surfactant
~8 oxyethylene groups preferably comprise 3~5 oxyethylene groups.
4. cleaning agent according to claim 1, which is characterized in that
The mineral oil dispersion is organic-silicon-modified mineral oil dispersion,
The polyol alkyl ether is dihydric alcohol alkyl ether, trihydroxylic alcohol alkyl ether, tetrahydroxylic alcohol alkyl ether, is preferably more than polyalcohol
Lower alkyl ether, such as dihydric alcohol methyl ether, dihydric alcohol ether, trihydroxylic alcohol methyl ether, trihydroxylic alcohol ether, tetrahydroxylic alcohol methyl ether, quaternary
Alcohol ether etc. is most preferably dipropylene glycol methyl ether.
5. the cleaning agent according to one of Claims 1-4, which is characterized in that further include the raw material of following mass fraction：
Anion surfactant, 0.5~10 part, preferably 1~5 part,
Alcamine compound, preferably 5~35 parts, 11~20 parts.
6. cleaning agent according to claim 5, which is characterized in that the anion surfactant is fat soap, excellent
Elect line style fat soap as.
7. cleaning agent according to claim 5, which is characterized in that the alcamine compound is triethanolamine, diethanol
One or more in amine, monoethanolamine etc. are preferably triethanolamine and the composition of monoethanolamine, more preferably mass fraction
For the composition of monoethanolamine that 4.5~25 parts of triethanolamines and mass fraction are 0.5~10 part, especially preferably mass parts
The composition for the monoethanolamine that number is 10~15 parts of triethanolamine and mass fraction is 1~5 part.
8. the preparation method of the cleaning agent according to one of claim 1 to 7, which is characterized in that comprise the following steps：
Step 1, add water in blender, then add in mineral oil dispersion and polysiloxane emulsion,
Step 2, nonionic surfactant, anion surfactant and polyol alkyl ether are sequentially added,
Step 3, alcamine compound is added in, and is stirred, such as is persistently stirred 10 minutes to 40 minutes, preferably 20-30
Minute, more preferably 25 minutes.
9. preparation method according to claim 8, which is characterized in that
In step 2, nonionic surfactant, anion surfactant and polyol alkyl ether are sequentially added, 600 revs/min
Clock persistently stirs 20 minutes；
In step 3, alcamine compound is added in, 400 revs/min, is persistently stirred 25 minutes, system pH scope is 9-10.
10. the purposes of the cleaning agent according to one of claim 1 to 7 decontaminates, washing performance for the cleaning of building roof
It is more than 4 more than 95%, COD/BOD values.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810031746.7A CN108048234B (en) | 2018-01-12 | 2018-01-12 | Biodegradable cleaning agent special for building roof and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810031746.7A CN108048234B (en) | 2018-01-12 | 2018-01-12 | Biodegradable cleaning agent special for building roof and preparation method thereof |
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| Publication Number | Publication Date |
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| CN108048234A true CN108048234A (en) | 2018-05-18 |
| CN108048234B CN108048234B (en) | 2020-04-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810031746.7A Active CN108048234B (en) | 2018-01-12 | 2018-01-12 | Biodegradable cleaning agent special for building roof and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304012A (en) * | 2020-04-16 | 2020-06-19 | 武汉东方聚仁防水保温有限公司 | Concrete base surface cleaning alkali-resistant material and preparation method thereof |
| CN115216369A (en) * | 2022-06-15 | 2022-10-21 | 联盛纸业（龙海）有限公司 | Multi-disc concentrated filter bag cleaning agent, cleaning method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833993A (en) * | 2016-12-27 | 2017-06-13 | 东莞市先飞电子材料有限公司 | A kind of aqueous cleaning agent and preparation method thereof |
| CN107418763A (en) * | 2017-06-16 | 2017-12-01 | 苏州永创达电子有限公司 | A kind of iundustrial oil pollution cleanser |
-
2018
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106833993A (en) * | 2016-12-27 | 2017-06-13 | 东莞市先飞电子材料有限公司 | A kind of aqueous cleaning agent and preparation method thereof |
| CN107418763A (en) * | 2017-06-16 | 2017-12-01 | 苏州永创达电子有限公司 | A kind of iundustrial oil pollution cleanser |
Non-Patent Citations (1)
| Title |
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| 李德旺: "《最新工厂常用清洗剂、脱脂剂、萃取剂操作控制与管理控制及典型案例剖析实务全书》", 30 April 2005, 中国化工出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304012A (en) * | 2020-04-16 | 2020-06-19 | 武汉东方聚仁防水保温有限公司 | Concrete base surface cleaning alkali-resistant material and preparation method thereof |
| CN115216369A (en) * | 2022-06-15 | 2022-10-21 | 联盛纸业（龙海）有限公司 | Multi-disc concentrated filter bag cleaning agent, cleaning method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN108048234B (en) | 2020-04-07 |
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