CN107699383A - Water base without phosphorus, normal temperature low temperature aircraft carrier or warship deck weight greasy dirt detergent - Google Patents
Water base without phosphorus, normal temperature low temperature aircraft carrier or warship deck weight greasy dirt detergent Download PDFInfo
- Publication number
- CN107699383A CN107699383A CN201610646520.9A CN201610646520A CN107699383A CN 107699383 A CN107699383 A CN 107699383A CN 201610646520 A CN201610646520 A CN 201610646520A CN 107699383 A CN107699383 A CN 107699383A
- Authority
- CN
- China
- Prior art keywords
- phosphorus
- low temperature
- aircraft carrier
- greasy dirt
- normal temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 28
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 19
- 239000011574 phosphorus Substances 0.000 title claims abstract description 19
- 239000003599 detergent Substances 0.000 title claims abstract description 17
- 239000012459 cleaning agent Substances 0.000 claims abstract description 29
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 24
- -1 almag Inorganic materials 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 230000007797 corrosion Effects 0.000 claims abstract description 15
- 238000005260 corrosion Methods 0.000 claims abstract description 15
- 239000002738 chelating agent Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 229930006000 Sucrose Natural products 0.000 claims description 10
- 239000005720 sucrose Substances 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 229920000805 Polyaspartic acid Polymers 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 108010064470 polyaspartate Proteins 0.000 claims description 6
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 235000019864 coconut oil Nutrition 0.000 claims description 5
- 239000003240 coconut oil Substances 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000001509 sodium citrate Substances 0.000 claims description 4
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 3
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 3
- 239000000176 sodium gluconate Substances 0.000 claims description 3
- 235000012207 sodium gluconate Nutrition 0.000 claims description 3
- 229940005574 sodium gluconate Drugs 0.000 claims description 3
- 239000011684 sodium molybdate Substances 0.000 claims description 3
- 235000015393 sodium molybdate Nutrition 0.000 claims description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003876 biosurfactant Substances 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 231100000252 nontoxic Toxicity 0.000 abstract description 5
- 230000003000 nontoxic effect Effects 0.000 abstract description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract description 4
- 239000006260 foam Substances 0.000 abstract description 4
- 239000002360 explosive Substances 0.000 abstract description 3
- 239000000295 fuel oil Substances 0.000 abstract description 3
- 229910000838 Al alloy Inorganic materials 0.000 abstract description 2
- 229910000975 Carbon steel Inorganic materials 0.000 abstract description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000881 Cu alloy Inorganic materials 0.000 abstract description 2
- 229910000861 Mg alloy Inorganic materials 0.000 abstract description 2
- 230000000711 cancerogenic effect Effects 0.000 abstract description 2
- 239000010962 carbon steel Substances 0.000 abstract description 2
- 231100000357 carcinogen Toxicity 0.000 abstract description 2
- 239000003183 carcinogenic agent Substances 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 230000003750 conditioning effect Effects 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000005556 hormone Substances 0.000 description 4
- 229940088597 hormone Drugs 0.000 description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 235000011083 sodium citrates Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241001272567 Hominoidea Species 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 230000007123 defense Effects 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000015424 sodium Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920005479 Lucite® Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
- C23G1/16—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions using inhibitors
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/721—End blocked ethers
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Abstract
The invention discloses a kind of water base without phosphorus, normal temperature low temperature aircraft carrier or warship deck weight greasy dirt detergent, the cleaning agent to be made up of water, nonionic surfactant, auxiliary agent, chelating agent, corrosion inhibiter, conditioning agent.Cleaning agent anacidity, the alkali-free（Or low alkali）, it is without phosphorus, no chlorate, without sulfate, nitrate-free, floride-free compound, without oxious components such as aromatic hydrocarbon solvents, it is corrosion-free to carbon steel, aluminium alloy, magnesium alloy, almag, copper and copper alloy；It is nontoxic（Rat footpath mouth LD50 >=1000mg/kg）, no carcinogen.Normal temperature/low temperature can high-efficient cleaning remove runway, heavy oil particularly on aircraft carrier runway is dirty.Meet EU criteria, U.S. MIL PR 8670E.With energy-conservation（Low temperature, Low-foam and easily rinsing）, safety（Flash-point is high, without inflammable and explosive composition）, environmental protection, easily biological-degradable feature.
Description
Technical field
The invention discloses a kind of water base without phosphorus, normal temperature/low temperature（0~15℃）Aircraft carrier（Warship）Deck weight greasy dirt detergent,
Belong to national defense industry and extraordinary cleaning agent field.
Background technology
Military cleaning agent species is various, wide, amount is big, and technical indicator is rigorous（It is harsh）.Based on meet efficiently, safety,
The multiple targets such as ecology, the military cleaning agent in China far lag behind the space flight and aviation of fast development, naval, particularly aircraft carrier and carrier-borne
The regular maintenance demand such as machine.
To on June 20th, 2016 only, the U.S. is related to agent for cleaning airplane patent 7245, wherein nearly 3 years patents are more than 1200
Bar.And Chinese patent only 118.
In recent years national defense industry development is swift and violent, particularly naval vessels, submarine, aircraft carrier and carrier-borne aircraft, to ensure its marine severe ring
Normal, the safe operation in border, it is badly in need of matched efficient, ecological, less toxic cleaning agent, such as：Carrier-borne aircraft surface cleaning agent, zero
Part cleaning agent, carbon deposit cleaning agent, deck cleaning agent, aircraft carrier runway rubber trace cleaning agent, cabin cleaning agent, glass are antifog
Cleaning agent etc..
For a long time in the harsh sea navigation of environment, deck is directly exposed to that air humidity is big, salt content for aircraft carrier and carrier-borne aircraft
In high salt mist environment, it is easy in external surface area salt, cause the corrosion damage of housing construction, system, annex etc., reduce body
Life-span.
Research show clean deck can substantially reduce type aircraft carrier deck Korrosionsmedium concentration, wherein chlorion, nitrate,
Sulfate concentration substantially reduces, and can effectively slow down deck corrosion rate, therefore the cleaning to type aircraft carrier deck just seems increasingly important.
However, the military cleaning agent now used both at home and abroad, due to its particular/special requirement, even American-European countries, is changed in recent years
Military cleaning agent standard in, also still need to use substantial amounts of aromatic hydrocarbon solvent（Aromatic hydrocarbon is not degradable）.And it is compareed in standard specimen,
Still using has the APEO that potential hazard has widely been studied and proved to environment（APES class compound）.
Some countries of Europe have formulated regulation limitation production from 1976 and using APEO.APEO can be summarized in following to ecology influence
Four aspects：Toxicity, biological degradability, environmental hormone, harmful side product is produced in process of production.Some domestic and international cleaning agents
Product and patent still with using APEP such as：
Chinese Patent Application No. CN201310752646.0 discloses a kind of aqua type deck cleaning agent（Authorize effective）, contain ten
Dialkyl benzene sulfonic acids, its sulfonic group have corrosiveness to metal；" environmental hormone " composition nonyl particularly containing European Union's disabling
Phenol polyethenoxy ether.
A kind of efficiently preparation methods of airfield runway cleaning agent of Chinese Patent Application No. CN96100959.4 and runway cleaning
Method, contain APEO（OP-10）Composition, and contain low-flash solvent（Toluene, No. 2 solvent naphthas, dichloroethanes etc.）, inflammable and explosive substances
Matter.
United States Patent (USP) 7,270,131, for including clean deck, mainly by the nonylphenol class surface with " environmental hormone "
Activating agent and sodium tripolyphosphate composition.
I types comparative formula is also using " environmental hormone " APEO containing European Union's disabling in U.S. army mark MIL-PRF-85570E
（APES class compound）Composition.
And Chinese Patent Application No. CN201110034848.2 discloses a kind of cleaning agent for airplane runways, containing low-flash
The inflammable and explosive composition such as methanol, dichloropropane, dimethylbenzene, and have containing the sulfonic acid for having larger corrosion to metal, and to metal
There is the anion surfactant of corrosiveness.
Naval vessels ride the sea, and often meet high temperature, microthermal climate, about 60 DEG C of naval vessels deck temperature, grease on deck during high temperature
Through being exposed to the sun and " hardening ", cause cleaning difficult, need to generally use cleaned containing solvent formula both at home and abroad.And low temperature（0~15℃）
Grease solidifies on environment lower decks, causes oil removing difficult, thus existing cleaning agent both at home and abroad is difficult in low temperature（0~15℃）Under the conditions of
It is dirty to remove heavy oil.
The content of the invention
It is an object of the invention to provide a kind of anacidity, alkali-free（Or weak base PH ＜ 10）, without phosphorus, no chlorate, without sulfate, nothing
The water base without phosphorus, normal temperature-low temperature aircraft carrier of nitrate, fluoride-free, solvent-free one kind or warship deck weight greasy dirt detergent.
It is an object of the invention to provide a kind of normal temperature/low temperature（0~15℃）Efficiently except the dirty cleaning agent of heavy oil；
The purpose of the present invention is to carbon steel, aluminium alloy, magnesium alloy, almag, copper and copper alloy；And paint（Coating）, rubber,
The free from corrosion cleaning agent of lucite, fluid sealant；
It is an object of the invention to provide a kind of efficient removal aircraft carrier of easily biological-degradable（Warship）Deck weight greasy dirt detergent；
It is an object of the invention to provide one kind nontoxic（Rat footpath mouth LD50 >=10000mg/kg）Aircraft carrier（Warship）Deck is efficient
Cleaning agent；
To achieve the above object, the present invention is according to the performance possessed needed for cleaning basic theory and warship deck：Deck cleaning agent
The principal element that need to be considered has：Dirt composition and solubility parameter, surface tension, HLB value, cloud point, freezing point, flash-point, burn into
Biodegradable, toxicity（LD50, three cause）Deng.Therefore, the present invention is by water, compound nonionic surfactant, auxiliary agent, chelating
Agent, corrosion inhibiter, conditioner composition.Wherein：
Compound nonionic surfactant of the present invention by：Organosilicon nonionic surfactant, APG class biology
Surfactant, sucrose fatty ester nonionic surfactant, fatty acid distribution of coconut oil alkylolamides（6501、6502）Non-ionic surface
Activating agent and the two or more compositions of isomery alcohol ethers nonionic surfactant.Its dosage is 3 ~ 45%.
Organosilicon nonionic surfactants have that volatility is small, and after using discharging, they can drop in nature
Solve as CO2, water and silicic acid, biological accumulation is not produced, to waters, land animals and plants without any pollution.The very high spy of surface-active
Point, it is mainly used in strengthening wetting；The present invention uses polysiloxanes -ol ether copolymer nonionic surfactant, under mainly including
Row two types：
Wherein：PXO=- (CH2)3-O(C2H4O)dH or：-(CH2)3-O(C2H4O)a-(C3H6O)b-(C2H4O)cH
In polysiloxane molecule polyether structure is introduced in part silica chain link.Content is bigger in the molecule by PXO, and water solubility is got over
Good, wherein EO (C O) ratio is bigger, and the hydrophilic lipophilic balance (HLB) of product is also bigger, and solubility increases in water, turbid
Point also corresponding increase.In addition, from alkoxy chemical property, their quantitative hydrolysis generate alcohol radicals, i.e. silanol group, thus
Stable silicon oxygen bond can be generated with oxide or the hydroxyl effect of metal surface, so as to form the network of densification in metal surface
The organosilan film of shape.It can be that metal surface acquisition good protection is laid a good foundation, play corrosion-resisting function.Its dosage is straight
Connect using formula 0 ~ 0.5%；To save transport, carrying cost, the present invention, which devises, can dilute 30 ~ 50 times of Concentrated formulations, concentration
Organosilicon nonionic surfactant dosage is 0.5 ~ 1.5% in formula.
It by natural reproducible resource starch or its hydrolysis sugar is raw material that APG, which is, with fatty alcohol occur dehydrating condensation and
The gentle new non-ionic surfactants of obtained one kind.It is nontoxic that APG is used as surfactant itself, biodegradable rapid complete
Entirely, it is a kind of natural green surfactant.APG has the advantages of conventional nonionic and anion surfactant concurrently, its
Special construction determines that it has many significant properties：Surface-active height, strong detergency, good water solubility, action temperature and, biology drop
It is good to solve performance, degraded is pacified soon, compound property is splendid.Its dosage is 0.5 ~ 5%.
Sucrose fatty ester is a kind of nonionic surfactant, the simple substance generated by sucrose and aliphatic acid through esterification
Or mixture.Using-OH the bases of sucrose as hydrophilic group, the carbon chain moiety of aliphatic acid is lipophilic group, commonly uses stearic acid, oleic acid, palm
The higher fatty acids such as acid.With nontoxic（Rat footpath mouth LD50=39000mg/kg）, easily biological-degradable and good surface property
Feature.Surface tension can be reduced, have it is good emulsify, scattered solubilising, lubrication, infiltration, foaming, viscosity regulation, prevent aging,
The performances such as antibacterial.According to the esterification number of sucrose hydroxyl, can obtain by lipophile to hydrophily difference HLB value（1~16）Sucrose Fatty Acid Ester
Fat acid esters series of products.The present invention using the specification of HLB=12 ~ 15 sucrose fatty ester.Usage amount is 0.5 ~ 5%.
Fatty acid distribution of coconut oil amide-type（6501、6502）For nonionic surfactant, there is good foaming, foam stabilizing, ooze
The function such as saturating decontamination, hard water resistance, can be with a variety of surfactant compatibilities.Cleaning effect can be strengthened, can be used as additive, foam peace
Determine agent, thickener.Dosage of the present invention is 0 ~ 5%.
The fatty alcohol of side chain is carried in isomery aliphatic alcohols molecular structure, compared with the derivative of straight-chain fatty alcohol, in property
Can on have its specificity.For example, isomery alcohol type surfactant have good wetting, emulsification, decontamination, detergency, solubilising, rise
The performances such as bubble, antistatic, scattered and antirust and lubrication, and be easy to use with other additive compatibilities, nontoxic and excitant is small, raw
Thing degradability is preferable, and the characteristic such as relatively low dynamic surface tension.With it is low bubble, efficiently, with various surfactants, help
Agent, additive, solvent compatibility are good, acidproof, alkaline-resisting, anti-oxidant.The present invention is using the isomery AEO of C10 ~ 13
Nonionic surfactant, the dosage of different size is respectively 0.5 ~ 15%.
Auxiliary agent of the present invention is by sodium metasilicate, sodium carbonate, detersive enzyme, SODIUM PERCARBONATE, high-purity stearic acid monoglycerides, carboxylic first
Base cellulose, by two of which composition described above, its dosage is 1 ~ 10%.
Chelating agent of the present invention by sodium citrate, sodium gluconate, chitosan, stearic acid monoglycerides, EDTA and
EDTA-2Na sodium metasilicate（It can act also as corrosion inhibiter）, salt of poly aspartic acid（It can act also as corrosion inhibiter）, polycarboxylate, poly- amber
Acid imide, by least two composition described above, its dosage is 1 ~ 5%.
Corrosion inhibiter of the present invention is by BTA, salt of poly aspartic acid（Chelating agent can be made simultaneously）, imidazoline
Quaternary ammonium salt, sodium molybdate, sodium metasilicate（Chelating agent can be made simultaneously）Two of which composition described above.Its dosage is 0.05 ~ 2%.
Conditioner of the present invention is made up of the acetic acid of regulation pH value and the essence of regulation smell.
Embodiment
For the present invention by embodiment come further description objects and advantages of the present invention, described is only exemplary
And illustrative, rather than the restriction of the claims in the present invention.
Embodiment 1
Weigh 5g APGs（AGP-1000）, 5g sucrose fatty esters, 2g fatty acid distribution of coconut oil diglycollic amide, 0.5g isomery fat
Fat alcohol polyoxyethylene XP-70,0.5g isomery aliphatic alcohol polyethenoxy TO-50,0.2g isomery aliphatic alcohol polyethenoxy XL-60,
0.6g isomery aliphatic alcohol polyethenoxy E-1308,500g water is added, after being uniformly mixed, add 10g glucose while stirring
Sour sodium, 10g sodium citrates, 5g metasilicate pentahydrate sodiums, 0.05g essence, then mend and add water to 1000g, continue to be stirred until homogeneous transparent
Solution.
Embodiment 2,3,4,5,6
Preparation method see the table below with embodiment 1, formula and performance.
Embodiment 1 is formulated to embodiment 6 and cleaning performance table
Explanation：II type formulas in cleaning efficiency foundation U.S. army mark MIL-PRF-85570E, in addition to being cleaned by standard dirt piece, and with
Control formula is contrasted.Provide, PH=7 ~ 10, adjusted with acetic acid according to II types formula in MIL-PRF-85570E.PH is with vinegar in table
Acid regulation.
Its main performance has passed through the detection of MIL-PRF-85570E standard test method.With U.S. army mark MIL-PRF-
85570E is compared, and is had the characteristics that：
1st, normal temperature/low temperature（0~15℃）Efficient degreasing, degreasing；
2nd, it is biodegradable fast；
3rd, it is in most cases, special " slow without adding because this technology is without the harmful ion that various materials are caused with corrosion
Lose agent "（Embodiment 1）, you can reach the requirement of MIL-PRF-85570E standards；
4th, Low-foam and easily rinses.
Embodiment 7
A kind of water base without phosphorus, normal temperature-low temperature aircraft carrier of the present embodiment or warship deck weight greasy dirt detergent, the cleaning agent is by nonionic
Surfactant, auxiliary agent, chelating agent, corrosion inhibiter, conditioner and water composition.Cleaning agent anacidity, the alkali-free（Or weak base）, it is without phosphorus,
Without chlorate, without sulfate, nitrate-free, fluoride-free, without aluminate, without the oxious components such as aromatic hydrocarbon solvent, rat footpath mouth
LD50 >=10000mg/kg, no carcinogen, easily biological-degradable.
As more preferably embodiment, the nonionic surface active agent is：
A. organosilicon nonionic surfactant（Polysiloxanes -ol ether copolymer）；
B. APG nonionic biosurfactant（APG AGP-1000）；
C. sucrose fatty ester nonionic surfactant（HLB-12 ~ 15, surface tension ＜ 31.5mN/m）；
D. fatty acid distribution of coconut oil acid amides（6501、6502）Nonionic surfactant
E. the isomery alcohol nonionic surface active agent of C10 ~ 13；
The two or more mixtures of above-mentioned nonionic surfactant.Its dosage is 3 ~ 45%.
As more preferably embodiment, the auxiliary agent, by sodium carbonate, detersive enzyme, stearic acid monoglycerides, one or more groups
Into its dosage is 0.5 ~ 5%.
As more preferably embodiment, the chelating agent by sodium gluconate, sodium citrate, chitosan, poly-aspartic-acid,
The two or more compoundings of sodium metasilicate form, and its dosage is 1 ~ 8%.
As more preferably embodiment, the corrosion inhibiter is by BTA, poly-aspartic-acid, sodium molybdate, sodium metasilicate two
Compounding forms more than kind, and its dosage is 0.05 ~ 1%.
As more preferably embodiment, for the cleaning agent using water as solvent, its dosage is the surplus after above-mentioned formula.
Claims (10)
1. a kind of water base without phosphorus, normal temperature-low temperature aircraft carrier or warship deck weight greasy dirt detergent, it is characterised in that the cleaning agent bag
Include nonionic surfactant, auxiliary agent, chelating agent, corrosion inhibiter, conditioner and water.
2. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 1 or warship deck weight greasy dirt detergent, its feature
It is that the nonionic surface active agent is：
A. organosilicon nonionic surfactant（Polysiloxanes -ol ether copolymer）；
B. APG nonionic biosurfactant（APG AGP-1000）；
C. sucrose fatty ester nonionic surfactant（HLB-12 ~ 15, surface tension ＜ 31.5mN/m）；
D. fatty acid distribution of coconut oil acid amides（6501、6502）Nonionic surfactant
E. the isomery alcohol nonionic surface active agent of C10 ~ 13；
From the two or more mixtures of above-mentioned a, b, c, d, e nonionic surfactant.
3. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 2 or warship deck weight greasy dirt detergent, its feature
The dosage for being the nonionic surface active agent is 3 ~ 45%.
4. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 1 or warship deck weight greasy dirt detergent, its feature
In the one kind at least selected in the auxiliary agent in sodium carbonate, detersive enzyme, stearic acid monoglycerides.
5. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 4 or warship deck weight greasy dirt detergent, its feature
The dosage for being the auxiliary agent is 0.5 ~ 5%.
6. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 1 or warship deck weight greasy dirt detergent, its feature
Be the chelating agent by sodium gluconate, sodium citrate, chitosan, the two or more compoundings of poly-aspartic-acid, sodium metasilicate and
Into.
7. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 6 or warship deck weight greasy dirt detergent, its feature
It is 1 ~ 8% to be the amount of chelant.
8. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 1 or warship deck weight greasy dirt detergent, its feature
It is that the corrosion inhibiter is formed by BTA, poly-aspartic-acid, sodium molybdate, the two or more compoundings of sodium metasilicate.
9. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 8 or warship deck weight greasy dirt detergent, its feature
The dosage for being the corrosion inhibiter is 0.05 ~ 1%.
10. water base without phosphorus, normal temperature-low temperature aircraft carrier according to claim 1 or warship deck weight greasy dirt detergent, its feature
It is the cleaning agent using water as solvent.
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| CN110565104A (en) * | 2019-09-03 | 2019-12-13 | 湖南德莱恩新材料科技有限公司 | Environment-friendly spray cleaning agent and preparation method thereof |
| CN112921327A (en) * | 2019-12-07 | 2021-06-08 | 东莞市集田新材料科技有限公司 | Preparation method of environment-friendly degreasing agent |
| CN114806737A (en) * | 2022-04-28 | 2022-07-29 | 应急管理部天津消防研究所 | Special cleaning agent for extinguishing fire and protecting clothing PAHs pollution as well as preparation method and application thereof |
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| CN105063639A (en) * | 2015-05-20 | 2015-11-18 | 天津市澳路浦润滑油有限公司 | Water-based heavy-duty multifunction metal cleaning agent and preparation method thereof |
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