CN106590960A - Alkaline foam detergent for cleaning food stains, preparation method therefor and application of alkaline foam detergent - Google Patents
Alkaline foam detergent for cleaning food stains, preparation method therefor and application of alkaline foam detergent Download PDFInfo
- Publication number
- CN106590960A CN106590960A CN201611085955.7A CN201611085955A CN106590960A CN 106590960 A CN106590960 A CN 106590960A CN 201611085955 A CN201611085955 A CN 201611085955A CN 106590960 A CN106590960 A CN 106590960A
- Authority
- CN
- China
- Prior art keywords
- cleaning agent
- amine oxide
- alkaline foam
- dirt
- alkaline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006260 foam Substances 0.000 title claims abstract description 106
- 235000013305 food Nutrition 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 13
- 238000004140 cleaning Methods 0.000 title abstract description 19
- 239000003599 detergent Substances 0.000 title abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 48
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000001412 amines Chemical class 0.000 claims abstract description 20
- 239000002738 chelating agent Substances 0.000 claims abstract description 19
- 229930182478 glucoside Natural products 0.000 claims abstract description 17
- 150000008131 glucosides Chemical class 0.000 claims abstract description 17
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 17
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000012459 cleaning agent Substances 0.000 claims description 67
- 238000003756 stirring Methods 0.000 claims description 27
- -1 pentamethylene phosphonic acids Chemical class 0.000 claims description 26
- 238000010790 dilution Methods 0.000 claims description 20
- 239000012895 dilution Substances 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002689 soil Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000003760 tallow Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical class OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 claims description 3
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 3
- BRDJPCFGLMKJRU-UHFFFAOYSA-N DDAO Chemical compound ClC1=C(O)C(Cl)=C2C(C)(C)C3=CC(=O)C=CC3=NC2=C1 BRDJPCFGLMKJRU-UHFFFAOYSA-N 0.000 claims description 3
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 claims description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N monoethyl amine Natural products CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 26
- 238000001556 precipitation Methods 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 238000005187 foaming Methods 0.000 description 13
- 239000008233 hard water Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 10
- 239000012530 fluid Substances 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000006641 stabilisation Effects 0.000 description 8
- 238000011105 stabilization Methods 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical group [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- MLFIYYDKLNZLAO-UHFFFAOYSA-N 2-aminoethane-1,1-diol Chemical compound NCC(O)O MLFIYYDKLNZLAO-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 239000012488 sample solution Substances 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical class [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 244000137852 Petrea volubilis Species 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 125000003010 ionic group Chemical group 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 2
- AQFWNELGMODZGC-UHFFFAOYSA-N o-ethylhydroxylamine Chemical compound CCON AQFWNELGMODZGC-UHFFFAOYSA-N 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- 239000010773 plant oil Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- 239000010963 304 stainless steel Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DLEPCXYNAPUMDZ-UHFFFAOYSA-N butan-2-ylphosphonic acid Chemical compound CCC(C)P(O)(O)=O DLEPCXYNAPUMDZ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/361—Phosphonates, phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/365—Organic compounds containing phosphorus containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C11D2111/20—
-
- C11D2111/42—
Abstract
The invention relates to an alkaline foam detergent for cleaning food stains. The alkaline foam detergent contains the ingredients in percentage by mass: 4% to 7% of sodium hydroxide, 1% to 3% of chelating agent, 0.5% to 10% of thickener, 5% to 15% of amine oxide, 5% to 10% of glucoside nonionic surfactant, 1% to 5% of isopropanol and 50% to 82% of pure water. The invention further provides a method for preparing the alkaline foam detergent and an application of the alkaline foam detergent. The alkaline foam detergent is stable in foam, high in wall hanging capacity, high in cleaning efficiency and high in detergency.
Description
Technical field
The present invention relates to chemical, more particularly to a kind of imitate with colloid for cleaning food industrial equipment surface
The alkaline foam cleaning agent of fruit and its preparation.
Background technology
In recent years, countries in the world property safe to food requires constantly to increase.In food processing process, the cleaning of food machinery
Property has a major impact to the security of food.Food machinery usually produces in process of production oily dirt, burnt dirt.Cleaning is handle
The dirt of factory and process equipment removes, and these dirts are stored in food contacting surface, the nutrition for needed for bacterial growth is provided
Material.Thoroughly then sterilization can not reach good result for all surface free cleanings to be cleaned or cleaning.Therefore, oily dirt,
Burnt dirt is removed product quality can be had a negative impact not in time.
Foam cleaning is that foam cleaning agent is added in proportion in water, and solution is fully mixed in blender by compressed air
Make it foam after conjunction, then the cleaning fluid after foaming is sprayed at the surface of substrate, cleaning fluid by outlet hose and spray gun
After being kept for sufficient time of contact with dirt, dirt is processed by dispersion, absorption, dissolving, parcel mode, make dirt and object table
Face is completely separated, then just can be easy in the dirt in easily exfoliated state remove with clear water flushing, significantly there is provided cleaning
Efficiency.
Therefore, it is necessary to provide the alkalescence bubble that a kind of foam stabilization, wall built-up ability are strong, cleaning efficiency is high, dirt-removing power is strong
Foam cleaning agent.
The content of the invention
An object of the present invention is a kind of foam stabilization of offer, wall built-up ability is strong, cleaning efficiency is high, dirt-removing power is strong
The alkaline foam cleaning agent for washing foodstuff dirt,.
To realize the purpose, the present invention provides a kind of alkaline foam cleaning agent for washing foodstuff dirt, according to quality
Percentage is calculated, and the alkaline foam cleaning agent includes following components：NaOH 4%～7%；Chelating agent 1%～3%；Increase
Thick dose 0.5%～10%；Amine oxide 5%～15%；Glucosides class nonionic surfactant 5%～10%；Isopropanol 1%～
5%；And pure water 50%～82%.
It is preferred that the chelating agent be 2- phosphonobutane -1,2,4- tricarboxylic acids, or including ATMP, two
At least one and acrylic acid-acrylic ester-sulfonate terpolymer, carboxylic acid-sulphur in hexene triamine pentamethylene phosphonic acids
At least one in acid-acrylate terpolymer.
It is preferred that the thickener is the one kind in polyacrylamide, polyvinyl alcohol, sodium carboxymethylcellulose, xanthans
Or its mixture.
It is preferred that described amine oxide is the mixture of alkyl dimethyl amine oxide and alkyl dihydroxy ethyl amine oxide, its
Middle alkyl is the alkyl chain of C8～C20.Alkyl dimethyl amine oxide/alkyl dihydroxy ethyl amine oxide has relative to alkyl amine oxide
There is lower CMC value, it is easier to form micella.The molecular weight of thickener is big, and high molecular association is produced in aqueous,
Solution viscosity is set to increase.Alkyl dimethyl amine oxide/alkyl dihydroxy ethyl amine oxide and thickener compounding use so as to compared with
Can still make solution that there is higher viscosity under low concentration, i.e., viscosity is raised after alkaline foam cleaning agent dilution.
It is preferred that the alkyl dimethyl amine oxide is DDAO, the oxidation of dodecyldimethylamine base
One kind or its mixture in amine, cetyl dimethyl amine oxide；The alkyl dihydroxy ethyl amine oxide is octadecyl two
One kind or its mixture in ethoxy amine oxide, Cocoalkyl dihydroxy ethyl amine oxide, tallow alkyl dihydroxy ethyl amine oxide.
It is preferred that the glucosides class nonionic surfactant is C8～C10 APG class surfactants.
Another object of the present invention is to provide a kind of alkaline foam for preparing and being used for washing foodstuff dirt as above
The method of cleaning agent, the preparation method includes：
(1) by the amount weigh respectively thickener, pure water, amine oxide, glucosides class nonionic surfactant, chelating agent,
Isopropanol and NaOH；
(2) pure water is added in thickener, stirring and dissolving is uniform；
(3) isopropanol is added, stirring and dissolving is uniform；
(4) amine oxide, glucosides class nonionic surfactant are added, stirring and dissolving is uniform；
(5) chelating agent is added, stirring and dissolving is uniform；And
(6) NaOH is added, stirring and dissolving is uniform.
Add isopropanol to reduce solution viscosity after dissolving thickener, stir beneficial to solution, then add oxidation
Amine, glucosides class nonionic surfactant, solution still keeps low viscosity, adds chelating agent, is eventually adding NaOH, because
The addition of NaOH has heat release.
A further object of the present invention is to provide a kind of application of alkaline foam cleaning agent, using alkalescence bubble as above
Foam cleaning agent carrys out washing foodstuff dirt, and it is 2%～4% first the alkaline foam cleaning agent to be diluted to into mass fraction, then will be dilute
Described alkaline foam cleaning agent after releasing foams in food soil surface.Clean water is finally used, food soil and alkali is removed
Property foam cleaning agent.
Prior art is compared, the present invention relates to have the alkaline foam cleaning agent of colloid effect, its advantage includes：
(1) the alkaline foam cleaning agent viscosity is low, viscosity increase after dilution.The addition of isopropanol can reduce alkaline foam
The viscosity of cleaning agent, is easy to the production of product, filling and pump formulated product when using；When in use by alkaline foam cleaning agent
Dilution, the viscosity reduction effect of isopropanol is reduced, and dilution fluid viscosity is raised, and considerably increases product foam stability.Published increasing
In thick system, such as add cationic surfactant, colloidal magnesium aluminum silicate, polysaccharide and sodium chloride, under these formula systems
Can not reach makes the phenomenon of product dilution fluid viscosity increase.The present invention is compounded using certain thickener with amine oxide, here
Add other materials such as isopropanol under formula system and there is the viscosity that can reduce product, while with dilution fluid viscosity increase
Effect.
(2) consumption is saved.The alkaline foam cleaning agent can be foamed in cleaned material surface, due to foam by foamed system
There is certain mobility, cleaning agent is can penetrate in gap or the groove of food soil Non-smooth surface, prevent corner or spot as yet untouched by a clean-up campaign, save
The consumption of cleaning agent, there is provided cleaning efficiency.
(3) foam stabilization, wall built-up ability are strong.Glucosides class nonionic surfactant is compounded with amine oxide, enhances alkalescence
The foaming capacity and foam stability of foam cleaning agent.The principal element for affecting foam stabilization and wall built-up ability is that alkaline foam is clear
The viscosity of lotion dilution, the viscosity of alkaline foam cleaning agent dilution is higher, and boundary layer drain age velocity is slower after foaming, interface
Tension force is lower, and foam is more lasting；The viscosity of another alkalescence foam cleaning agent dilution is higher, and gas-premeable is just low, durable lather
Property also strengthens.Foam stabilization, wall built-up ability are strong so as to longer with surface to be cleaned dirt time of contact, with more excellent clear
Wash effect.
(4) cleaning capacity is strong.Chelating agent selects the compounding for organic phosphine series with organic carboxyl acid series, organic phosphine in formula
Serial chelating agent there is good chelating, lower bound to suppress and distortion of lattice effect.Scaling salt class in water can be prevented to form incrustation scale, it is special
It is not the formation of calcium carbonate scale, is particularly suited for winter severe cold area.Organic carboxyl acid series chelating agent is due to dividing in copolymer
Contain strong acid, weak acid and non-ionic group in subchain simultaneously, it be applied to high temperature, high pH, it is high firmly with it is high-alkali under the conditions of use, it is right
The deposition of iron oxide, calcium phosphate, trbasic zinc phosphate and calcium carbonate in water, with excellent inhibitory action.Will both compounding uses
It is better, can effectively prevent incrustation scale from being formed, suppress soil redeposition；NaOH can occur soap with the aliphatic acid in grease
Change reaction and form soap, while glucosides class nonionic surfactant has the effect of wetting, solubilising and high bubble, can be fast
The surface tension of the low aqueous solution of prompt drop, contributes to the removing of dirt, while its solubilization can make the dirt after saponification readily soluble
Yu Shui, prevents redeposition.
Description of the drawings
Fig. 1 is the design sketch after alkalescence foam cleaning agent foaming of the invention.
Fig. 2 is the design sketch after comparative example's foaming.
Specific embodiment
The several different most preferred embodiments of the present invention are illustrated below with reference to the accompanying drawings.
The present invention is intended to provide a kind of alkaline foam cleaning agent for washing foodstuff dirt, according to mass percentage
Calculate, the alkaline foam cleaning agent includes following components：NaOH 4%～7%；Chelating agent 1%～3%；Thickener 0.5%
～10%；Amine oxide 5～15%；Glucosides class nonionic surfactant 5～10%；Isopropanol 1～5%；And pure water 50%
～82%.
Wherein, the chelating agent be 2- phosphonobutane -1,2,4- tricarboxylic acids, or including ATMP, two oneself
At least one and acrylic acid-acrylic ester-sulfonate terpolymer, carboxylic acid-sulfonic acid in alkene triamine pentamethylene phosphonic acids-
At least one in acrylate terpolymer.
The thickener is the one kind in polyacrylamide, polyvinyl alcohol, sodium carboxymethylcellulose, xanthans or its mixing
Thing.
Described amine oxide is the mixture of alkyl dimethyl amine oxide and alkyl dihydroxy ethyl amine oxide, and wherein alkyl is
The alkyl chain of C8～C20.The alkyl dimethyl amine oxide is DDAO, the oxidation of dodecyldimethylamine base
One kind or its mixture in amine, cetyl dimethyl amine oxide；The alkyl dihydroxy ethyl amine oxide is octadecyl two
One kind or its mixture in ethoxy amine oxide, Cocoalkyl dihydroxy ethyl amine oxide, tallow alkyl dihydroxy ethyl amine oxide.
The glucosides class nonionic surfactant is C8～C10 APG class surfactants.
The present invention also provides a kind of method for preparing the alkaline foam cleaning agent for being used for washing foodstuff dirt as above,
The preparation method includes：
(1) by the amount weigh respectively thickener, pure water, amine oxide, glucosides class nonionic surfactant, chelating agent,
Isopropanol and NaOH；
(2) pure water is added in thickener, stirring and dissolving is uniform；
(3) isopropanol is added, stirring and dissolving is uniform；
(4) amine oxide, glucosides class nonionic surfactant are added, stirring and dissolving is uniform；
(5) chelating agent is added, stirring and dissolving is uniform；And
(6) NaOH is added, stirring and dissolving is uniform.
The present invention also provides a kind of application of alkaline foam cleaning agent, comes clear using alkalescence foam cleaning agent as above
Wash food soil, first the alkaline foam cleaning agent be diluted to into mass fraction for 2%～4%, then by dilution after the alkali
Property foam cleaning agent foams in food soil surface.Clean water is finally used, food soil and alkaline foam cleaning agent is removed.
Embodiment one
1. polyacrylamide 5g is taken, it is uniform with 500g water dissolves；
2. isopropanol 40g is added thereto to, is uniformly dissolved；
3. dodecyl amine oxide 20g, tallow alkyl dihydroxy ethyl amine oxide 60g, APG are separately added into thereto
Class surfactant 50g, stirring and dissolving is uniform；
4. amino trident phosphonic acids 20g is added thereto to, and stirring and dissolving is uniform；
5. NaOH 50g is added thereto to, and stirring and dissolving is uniform；Detection is qualified.
Embodiment two
1. polyvinyl alcohol 20g is taken, it is uniform with 700g water dissolves；
2. isopropanol 10g is added thereto to, is uniformly dissolved；
3. CH3-(CH2)13N(CH3)2-O 50g, tallow alkyl dihydroxy ethyl amine oxide 100g, alkane are separately added into thereto
Base sugar glycocide surfactant 100g, stirring and dissolving is uniform；
4. hydroxy ethylidene phosphonic acids 10g is added thereto to, and stirring and dissolving is uniform；
5. NaOH 70g is added thereto to, and stirring and dissolving is uniform；Detection is qualified.
Embodiment three
1. sodium carboxymethylcellulose 100g is taken, it is uniform with 820g water dissolves；
2. isopropanol 50g is added thereto to, is uniformly dissolved；
3. Cocoalkyl dihydroxy ethyl amine oxide 30g, tallow alkyl dihydroxy ethyl amine oxide 100g are separately added into thereto,
APG class surfactant 60g, stirring and dissolving is uniform；
3. 2- phosphonobutane -1 is added thereto to, and 2,4- tricarboxylic acids 30g, stirring and dissolving is uniform；
5. NaOH 70g is added thereto to, and stirring and dissolving is uniform；Detection is qualified.
Comparative example
The composition of conventional alkaline foam cleaning agent is as follows：
Below by the effect for testing alkaline foam cleaner more of the invention and contrast experiment's example.
1 foam stability is tested：Foaming properties according to《Surfactant detergent test method》(GB/T 13173-
2008) prescriptive procedure is carried out, and is determined using Roche foam meter.Foam is high when test determination sample initial foam height and 30min
Degree, to the foam performance and foam stability of observing embodiment 1～3, while being compared with comparative example's product.
The foaming properties of embodiment 1～3 and comparative experimental example are determined, experimental result is as follows：
The alkaline foam cleaning agent foaming properties measurement result of table 1
As known from Table 1, the foam of alkaline foam cleaning agent of the invention is more stable compared with comparative example.
2 viscosity tests：Detergent viscosimetric analysis according to《Surfactant and detergent rotary viscosity design determining fluid product
Viscosity》(GB/T 15357-2014) method is carried out.
Viscosimetric analysis adopts NDJ-8SN rotation viscometers, and condition determination is No. 2 rotors, and rotating speed is 60r/min, experiment knot
Fruit is as follows：
The alkaline foam cleaning agent viscosity experiment result of table 2
As known from Table 2, the viscosity after alkaline foam cleaning agent of the invention dilution increases, and the viscosity of comparative example becomes
Change less, or even reduce.
3 hard water resistance tests：The preparation of hard water according to《The preparation of calcium hardness water known to surfactant》(GB/T 6367-
2012) method is prepared.Weigh 16.7g anhydrous calcium chlorides and 24.7g magnesium sulfate prepares 10L, about 2500mg/L hard water.When using
It is diluted to different hardness water.The water of different hardness is prepared, then alkaline cleaner is diluted to concentration, experiment with hard water
Its stability in hard water energy.
The stability in hard water of embodiment 1～3 and comparative experimental example can result show, the alkaline cleaner of embodiment 1～3 it is dilute
Release concentration for 4% when, the tolerable hardness of the alkaline foam cleaning agent with antifreezing effect developed is 250mg/L～625mg/
The hard water of L；The resistance to hard water ability of comparative example is poor.
The resistance to hard water experimental result of the alkaline foam cleaning agent of table 3
| Hardness | 250mg/L | 375mg/L | 500mg/L | 625mg/L |
| Embodiment 1 | It is transparent, without precipitation | It is transparent, without precipitation | It is transparent, without precipitation | It is transparent, without precipitation |
| Embodiment 2 | It is transparent, without precipitation | It is transparent, without precipitation | It is transparent, without precipitation | It is transparent, without precipitation |
| Embodiment 3 | It is transparent, without precipitation | It is transparent, without precipitation | It is transparent, without precipitation | It is transparent, without precipitation |
| Comparative example | It is muddy, without precipitation | It is muddy, have precipitation | It is muddy, have precipitation | It is muddy, have precipitation |
4. detergency test：Alkaline foam colloid cleaning agent detergency determine according to《Food items and industrial equipment alkali
Property cleaning agent》(QBT 4314-2012) method is carried out.
The preparation of 4.1 test pieces
Test steels piece is 304 stainless steel substrates, and specification is 50mm × 25mm × 4mm.180# sand paper is first used by the table of test piece
Face is polished, and is then deposited in be washed in drier by parallel ridge orientation polishing light with 200# sand paper.Gripped with tweezers
The test piece that absorbent cotton is polished is scrubbed successively in acetone and absolute ethyl alcohol, is placed on clean filter paper, is blotted with filter paper, is put
It is stand-by after being dried 4h in drier.
The preparation of 4.2 hard water
Weigh 16.7g anhydrous calcium chlorides and 24.7g magnesium sulfate prepares 10L, about 2500mg/L hard water.Take 1L when using to fill
250mg/L hard water is to 10L.
The preparation of 4.3 sample solutions
Product concentration is pressed with 250mg/L hard water and prepare sample solution, to test.
The preparation of 4.4 artificial dirts
By butter：Lard：Refined plant oil：Glycerin monostearate：Sugar aqueous solution：Egg presses 16：16：3.2：30：
2.8 proportions, this is artificial dirt.
Butter, lard, refined plant oil, glycerin monostearate are mixed in beaker, heat value 180 on electric furnace are put
DEG C, stirring keeps this temperature stirring 10min, then beaker is moved to into magnetic stirrer, is cooled to 60 DEG C, adds syrup molten
Liquid, egg, are well mixed.It is now with the current.
The preparation of 4.5 dirty pieces
It is one group by the test piece three polished and cleaned, three groups is prepared altogether, weigh, now quality is with m0Represent.
Weighed test piece is sandwiched in one by one on film airing stand, shelf should be clipped in test piece more than 20mm lines, by film airing stand
To put prepare in enamel tray and defile, temperature of defiling is 60 DEG C.When dirt is maintained at 60 DEG C, one by one by test piece together with clip from the piece that dries in the air
Remove on frame；Hand-held clip immerses test piece in greasy dirt to 20mm 1～2s once along the line, slowly takes out, and treats to drip speed under greasy dirt
After slack-off, extension is returned on original film airing stand, once prepares dirty piece.After dirt solidification, dirty piece is removed with filter paper or absorbent cotton
The unnecessary dirt of dirty piece base and two avris is wiped, is hung at room temperature after 4h, accurate weighing is defiled quality m of test piece1.This
When each dirty piece the dirty amount of extension should ensure that in 0.3g～0.5g.
4.6 test procedure
Sample solution is poured in stainless steel water bath, is heated to (80 ± 2) DEG C, keep constant temperature.The pendulum of adjustment pendulum washing machine
It is (30 ± 2) DEG C secondary/min (coming and going as 1 time) to wash frequency, now clips in the clip that washing machine is put in the test piece of the known amount of defiling,
Note being clipped in test piece more than 20mm lines, test piece is totally immersed in detergent solution and soaks 1min, start pendulum washing machine, pendulum is washed
13min, takes out rapidly test piece, hangs the 3h that dries in the air and test piece is weighed, and now quality is m2。
4.7 results are calculated
Detergency D is expressed as a percentage, and is calculated as follows：
D (100%)=(m1-m2)/(m1-m0)×100
In formula：m0--- test piece quality before defiling, unit is gram (g)；
m1--- test piece quality after defiling, unit is gram (g)；
m2--- test piece quality after cleaning, unit is gram (g).
Detergency under the antifreeze alkaline cleaner difference concentration of 4.8 experiments, experimental result is as follows：
The alkaline foam cleaning agent detergency experimental result of table 4
As shown in Table 4, the detergency of alkaline bubble face cleaning agent of the invention is up to more than 93%, compared with the decontamination of comparative example
Ability is strong.
5. foaming test：Embodiment 1～3 is proportionally diluted to into 2% and uses solution, will be produced using portable foaming machine
Product foam is sprayed on body surface.For the wall built-up performance of test product, 1 square metre of corrosion resistant plate is vertically hung on into wall, will
Bubble jet thereon, observes the wall built-up situation and stability of foam.Meanwhile, using same procedure by comparative example's sample foams
Corrosion resistant plate is sprayed on, is contrasted.
The alkaline foam cleaning agent of embodiment 1～3 is carried out into foaming experiment with comparative example's sample, foam stability is observed
And wall built-up ability.As a result show, when cleaning agent foam is sprayed on into stainless steel surface 5min, the foam of embodiment 1～3 is more steady
Fixed, wall built-up ability is strong, and the foam of comparative experimental example starts rupture, and starts to glide, concrete as shown in Fig. 1～2.
Prior art is compared, the present invention relates to have the alkaline foam cleaning agent of colloid effect, its advantage includes：
(1) the alkaline foam cleaning agent viscosity is low, viscosity increase after dilution.The addition of isopropanol can reduce alkaline foam
The viscosity of cleaning agent, is easy to the production of product, filling and pump formulated product when using；When in use by alkaline foam cleaning agent
Dilution, the viscosity reduction effect of isopropanol is reduced, and dilution fluid viscosity is raised, and considerably increases product foam stability.Published increasing
In thick system, such as add cationic surfactant, colloidal magnesium aluminum silicate, polysaccharide and sodium chloride, under these formula systems
Can not reach makes the phenomenon of product dilution fluid viscosity increase.The present invention is compounded using certain thickener with amine oxide, here
Add other materials such as isopropanol under formula system and there is the viscosity that can reduce product, while with dilution fluid viscosity increase
Effect.
(2) consumption is saved.The alkaline foam cleaning agent can be foamed in cleaned material surface, due to foam by foamed system
There is certain mobility, cleaning agent is can penetrate in gap or the groove of food soil Non-smooth surface, prevent corner or spot as yet untouched by a clean-up campaign, save
The consumption of cleaning agent, there is provided cleaning efficiency.
(3) foam stabilization, wall built-up ability are strong.Glucosides class nonionic surfactant is compounded with amine oxide, enhances alkalescence
The foaming capacity and foam stability of foam cleaning agent.The principal element for affecting foam stabilization and wall built-up ability is that alkaline foam is clear
The viscosity of lotion dilution, the viscosity of alkaline foam cleaning agent dilution is higher, and boundary layer drain age velocity is slower after foaming, interface
Tension force is lower, and foam is more lasting；The viscosity of another alkalescence foam cleaning agent dilution is higher, and gas-premeable is just low, durable lather
Property also strengthens.Foam stabilization, wall built-up ability are strong so as to longer with surface to be cleaned dirt time of contact, with more excellent clear
Wash effect.
(4) cleaning capacity is strong.Chelating agent selects the compounding for organic phosphine series with organic carboxyl acid series, organic phosphine in formula
Serial chelating agent there is good chelating, lower bound to suppress and distortion of lattice effect.Scaling salt class in water can be prevented to form incrustation scale, it is special
It is not the formation of calcium carbonate scale, is particularly suited for winter severe cold area.Organic carboxyl acid series chelating agent is due to dividing in copolymer
Contain strong acid, weak acid and non-ionic group in subchain simultaneously, it be applied to high temperature, high pH, it is high firmly with it is high-alkali under the conditions of use, it is right
The deposition of iron oxide, calcium phosphate, trbasic zinc phosphate and calcium carbonate in water, with excellent inhibitory action.Will both compounding uses
It is better, can effectively prevent incrustation scale from being formed, suppress soil redeposition；NaOH can occur soap with the aliphatic acid in grease
Change reaction and form soap, while glucosides class nonionic surfactant has the effect of wetting, solubilising and high bubble, can be fast
The surface tension of the low aqueous solution of prompt drop, contributes to the removing of dirt, while its solubilization can make the dirt after saponification readily soluble
Yu Shui, prevents redeposition.
Above disclosed is only presently preferred embodiments of the present invention, can not limit the right of the present invention with this certainly
Scope, therefore the equivalent variations made according to scope of the present invention patent, still belong to the scope that the present invention is covered.
Claims (8)
1. a kind of alkaline foam cleaning agent for washing foodstuff dirt, it is characterised in that calculate according to mass percent, it is described
Alkaline foam cleaning agent includes following components：
2. the alkaline foam cleaning agent of washing foodstuff dirt is used for as claimed in claim 1, it is characterised in that the chelating agent
For 2- phosphonobutane -1,2,4- tricarboxylic acids, or including in ATMP, two hexene triamine pentamethylene phosphonic acids extremely
In few a kind of and acrylic acid-acrylic ester-sulfonate terpolymer, carboxylic acid-sulfonic-acrylic ester terpolymer extremely
Few one kind.
3. the alkaline foam cleaning agent of washing foodstuff dirt is used for as claimed in claim 1, it is characterised in that the thickener
For the one kind in polyacrylamide, polyvinyl alcohol, sodium carboxymethylcellulose, xanthans or its mixture.
4. the alkaline foam cleaning agent of washing foodstuff dirt is used for as claimed in claim 1, it is characterised in that described oxidation
Amine is the mixture of alkyl dimethyl amine oxide and alkyl dihydroxy ethyl amine oxide, and wherein alkyl is the alkyl chain of C8～C20.
5. the alkaline foam cleaning agent of washing foodstuff dirt is used for as claimed in claim 4, it is characterised in that the alkyl two
Methyl oxidation amine is in DDAO, CH3-(CH2)13N(CH3)2-O, cetyl dimethyl amine oxide
One kind or its mixture；The alkyl dihydroxy ethyl amine oxide is octadecyl dihydroxy ethyl amine oxide, Cocoalkyl dihydroxy
One kind or its mixture in ethyl amine oxide, tallow alkyl dihydroxy ethyl amine oxide.
6. the alkaline foam cleaning agent of washing foodstuff dirt is used for as claimed in claim 1, it is characterised in that the glucosides class
Nonionic surfactant is C8～C10 APG class surfactants.
7. a kind of side of the alkaline foam cleaning agent for washing foodstuff dirt prepared as described in any one of claim 1～6
Method, it is characterised in that the preparation method includes：
(1) thickener, pure water, amine oxide, glucosides class nonionic surfactant, chelating agent, isopropyl are weighed respectively by the amount
Alcohol and NaOH；
(2) pure water is added in thickener, stirring and dissolving is uniform；
(3) isopropanol is added, stirring and dissolving is uniform；
(4) amine oxide, glucosides class nonionic surfactant are added, stirring and dissolving is uniform；
(5) chelating agent is added, stirring and dissolving is uniform；And
(6) NaOH is added, stirring and dissolving is uniform.
8. washing foodstuff dirt is carried out using the alkaline foam cleaning agent as described in any one of claim 1～6, it is characterised in that
The alkaline foam cleaning agent is diluted to into mass fraction 2%～4%, by dilution after described alkaline foam cleaning agent foam in
Food soil surface.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110079402A (en) * | 2019-05-30 | 2019-08-02 | 陕西汉隆清洁消毒产品有限公司 | Compound alkaline foam cleaning agent of a kind of environment-friendly type and preparation method thereof |
| CN110791390A (en) * | 2019-11-15 | 2020-02-14 | 南京魄力倍清洁科技有限公司 | Composite alkaline cleaning agent |
| CN114686321A (en) * | 2022-04-28 | 2022-07-01 | 西安汉隆化工科技有限公司 | Low-foam environment-friendly efficient CIP alkaline cleaning agent for food processing and preparation method thereof |
| TWI787368B (en) * | 2017-10-17 | 2022-12-21 | 日商花王股份有限公司 | Liquid cleaner composition for hard surfaces |
| US11555162B2 (en) | 2019-04-24 | 2023-01-17 | The Procter & Gamble Company | Aqueous dishwashing composition containing dissolved polyvinyl alcohol and having improved sudsing |
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|---|---|---|---|---|
| CN1153526A (en) * | 1994-07-21 | 1997-07-02 | 美国3M公司 | Concentrated cleaner compositions capable of viscosity increase upon dilution |
| CN105400616A (en) * | 2015-12-15 | 2016-03-16 | 广东环凯微生物科技有限公司 | CIP alkaline cleaning agent with anti-freezing effect and preparation method therefor |
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2016
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1153526A (en) * | 1994-07-21 | 1997-07-02 | 美国3M公司 | Concentrated cleaner compositions capable of viscosity increase upon dilution |
| CN105400616A (en) * | 2015-12-15 | 2016-03-16 | 广东环凯微生物科技有限公司 | CIP alkaline cleaning agent with anti-freezing effect and preparation method therefor |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI787368B (en) * | 2017-10-17 | 2022-12-21 | 日商花王股份有限公司 | Liquid cleaner composition for hard surfaces |
| US11555162B2 (en) | 2019-04-24 | 2023-01-17 | The Procter & Gamble Company | Aqueous dishwashing composition containing dissolved polyvinyl alcohol and having improved sudsing |
| CN110079402A (en) * | 2019-05-30 | 2019-08-02 | 陕西汉隆清洁消毒产品有限公司 | Compound alkaline foam cleaning agent of a kind of environment-friendly type and preparation method thereof |
| CN110791390A (en) * | 2019-11-15 | 2020-02-14 | 南京魄力倍清洁科技有限公司 | Composite alkaline cleaning agent |
| CN114686321A (en) * | 2022-04-28 | 2022-07-01 | 西安汉隆化工科技有限公司 | Low-foam environment-friendly efficient CIP alkaline cleaning agent for food processing and preparation method thereof |
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|---|---|
| CN106590960B (en) | 2019-09-10 |
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