CN110862879A - Environment-friendly efficient degreasing industrial cleaning agent - Google Patents
Environment-friendly efficient degreasing industrial cleaning agent Download PDFInfo
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- CN110862879A CN110862879A CN201911144382.4A CN201911144382A CN110862879A CN 110862879 A CN110862879 A CN 110862879A CN 201911144382 A CN201911144382 A CN 201911144382A CN 110862879 A CN110862879 A CN 110862879A
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- 238000005238 degreasing Methods 0.000 title claims abstract description 54
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 53
- 241000894006 Bacteria Species 0.000 claims abstract description 46
- 230000000593 degrading effect Effects 0.000 claims abstract description 46
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000003094 microcapsule Substances 0.000 claims abstract description 30
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 25
- 239000013527 degreasing agent Substances 0.000 claims abstract description 25
- 238000005237 degreasing agent Methods 0.000 claims abstract description 25
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 25
- 239000002455 scale inhibitor Substances 0.000 claims abstract description 23
- 239000000945 filler Substances 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- 239000010881 fly ash Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 238000012545 processing Methods 0.000 claims abstract description 8
- 239000002738 chelating agent Substances 0.000 claims description 20
- 230000007797 corrosion Effects 0.000 claims description 20
- 238000005260 corrosion Methods 0.000 claims description 20
- 239000006184 cosolvent Substances 0.000 claims description 20
- 239000003995 emulsifying agent Substances 0.000 claims description 20
- 239000003112 inhibitor Substances 0.000 claims description 20
- 239000012528 membrane Substances 0.000 claims description 20
- 239000003599 detergent Substances 0.000 claims description 18
- 239000000047 product Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical group C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 239000011265 semifinished product Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 8
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 5
- 241000196324 Embryophyta Species 0.000 claims description 5
- 229920002907 Guar gum Polymers 0.000 claims description 5
- 241001465754 Metazoa Species 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 235000010489 acacia gum Nutrition 0.000 claims description 5
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 5
- 229940072056 alginate Drugs 0.000 claims description 5
- 235000010443 alginic acid Nutrition 0.000 claims description 5
- 229920000615 alginic acid Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000011162 core material Substances 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 238000005538 encapsulation Methods 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 235000010417 guar gum Nutrition 0.000 claims description 5
- 239000000665 guar gum Substances 0.000 claims description 5
- 229960002154 guar gum Drugs 0.000 claims description 5
- 238000012423 maintenance Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000011858 nanopowder Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 229920001529 polyepoxysuccinic acid Polymers 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920000136 polysorbate Polymers 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 abstract description 19
- 239000010865 sewage Substances 0.000 abstract description 10
- 150000003839 salts Chemical class 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000001556 precipitation Methods 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 3
- 230000003381 solubilizing effect Effects 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004945 emulsification Methods 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000233866 Fungi Species 0.000 description 2
- 238000006065 biodegradation reaction Methods 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/381—Microorganisms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C11D2111/20—
Abstract
The invention discloses an environment-friendly high-efficiency degreasing industrial cleaning agent, and particularly relates to the technical field of cleaning agent processing and preparation, wherein the cleaning agent comprises 55-65 parts of deionized water, 12-18 parts of an alkaline degreasing agent, 8-12 parts of a non-ionic surfactant, 8-12 parts of an anionic surfactant, 6-10 parts of an auxiliary agent, 2-4 parts of a purification filler and 1-3 parts of microcapsule COD degrading bacteria. According to the invention, the nonionic surfactant and the anionic surfactant are compounded and matched with the alkaline degreasing agent, so that oil stain can be separated, emulsified and dispersed in a low-temperature environment in a curling and solubilizing mode, the cleaning capability of polar oil stain is improved by matching with the auxiliary agent, the surface of a workpiece cannot be corroded in the cleaning process, meanwhile, the scale inhibitor can prevent salt precipitation on the surface of the workpiece and further soften and clean sewage, the fly ash and the active carbon effectively adsorb cleaning substances and peculiar smell, and the sewage is biologically degraded by COD degrading bacteria, so that the composite material is safe and efficient.
Description
Technical Field
The invention relates to the technical field of processing and preparation of cleaning agents, in particular to an environment-friendly efficient degreasing industrial cleaning agent.
Background
With the accelerated development of the industrialization process, the large-scale workshop treatment of the workpiece becomes the industrialization trend, and when the workpiece is processed, produced and maintained, the polar oil stain on the surface of the workpiece needs to be degreased, degreased and cleaned.
The polar oil stain cleaning needs to use an industrial cleaning agent, and the current global development trend of the detergent is low-temperature and water-saving cleaning. The low-temperature washing can save a large amount of energy and water resources, and is beneficial to environmental protection and sustainable development. At present, under the vigorous popularization of relevant national departments and the combined efforts of scientific research personnel, low-temperature washing has been primarily applied in a plurality of fields in China. The surfactant for low-temperature washing has the advantages that the surfactant conforms to the green development trend of global detergents, the commercial value and the application space of the surfactant for low-temperature washing are fully explored, but the existing low-temperature detergent has low degreasing efficiency, the COD (chemical oxygen demand) of sewage cannot be effectively reduced, and the problem of serious water resource pollution waste exists.
Therefore, it is necessary to develop an environment-friendly and efficient degreasing industrial cleaning agent to solve the above problems.
Disclosure of Invention
In order to overcome the defects in the prior art, the embodiment of the invention provides an environment-friendly high-efficiency degreasing industrial cleaning agent, the non-ionic surfactant and the anionic surfactant are compounded and are matched with the alkaline degreasing agent, so that oil stain can be separated, emulsified and dispersed in a curling and solubilizing mode in a low-temperature environment, the cleaning capability of polar oil stain is improved by matching with an auxiliary agent, the surface of a workpiece cannot be corroded in the cleaning process, meanwhile, the scale inhibitor can prevent salt precipitation on the surface of the workpiece and further soften and clean sewage, the fly ash and the activated carbon effectively adsorb cleaning substances and peculiar smell, and the microcapsule COD degrading bacteria are separated from the microcapsule COD degrading bacteria to biodegrade the sewage, so that the environment-friendly high-efficiency degreasing industrial cleaning agent is safe and high-efficiency, and the problems in the background art are solved.
In order to achieve the purpose, the invention provides the following technical scheme: an environment-friendly high-efficiency degreasing industrial cleaning agent, wherein the used main materials comprise the following components in parts by weight: 55-65 parts of deionized water, 12-18 parts of alkaline degreasing agent, 8-12 parts of non-ionic surfactant, 8-12 parts of anionic surfactant and 6-10 parts of auxiliary agent, wherein the auxiliary material comprises the following components in parts by weight: 2-4 parts of purifying filler and 1-3 parts of microcapsule COD degrading bacteria.
Preferably, the auxiliary agent consists of a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, and the proportion of the cosolvent, the emulsifier, the scale inhibitor, the chelating agent and the corrosion inhibitor is set to be 1:2-4:1:1-3: 1.
Preferably, the purification filler consists of fly ash and activated carbon, the fly ash and the activated carbon are both in a nano powder shape, and the ratio of the fly ash to the activated carbon is set to be 1: 1-2.
Preferably, the microcapsule COD degrading bacteria are made of COD degrading bacteria and isolating membrane, the COD degrading bacteria and the isolating membrane are respectively core material and wall material, and the isolating membrane is made of one of alginate, guar gum and Arabic gum and a composition thereof.
Preferably, the isolating membrane is wrapped outside the COD degrading bacteria through molecular encapsulation treatment, the release mode of the microcapsule COD degrading bacteria is dissolution release, and the release time is slow release.
Preferably, the alkaline degreasing agent is 15% sodium carbonate solution, the nonionic surfactant is OP-10 surfactant, and the anionic surfactant is fatty alcohol-polyoxyethylene ether sodium sulfate.
Preferably, the cosolvent is tween, the emulsifier is cellulose derivative, the scale inhibitor is polyepoxysuccinic acid, the chelating agent is organic phosphate, and the corrosion inhibitor is mercaptobenzothiazole.
A preparation method of an environment-friendly high-efficiency degreasing industrial cleaning agent comprises the following specific operation steps:
the method comprises the following steps: taking deionized water, an alkaline degreasing agent, a nonionic surfactant, an anionic surfactant and an auxiliary agent according to a certain proportion, mixing the mixture with a compound purifying filler, and preparing microcapsule COD degrading bacteria;
step two: dissolving an alkaline degreasing agent, a nonionic surfactant and an anionic surfactant in deionized water, adding a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, and uniformly stirring to prepare a semi-finished product of the emulsified detergent;
step three: adding a purifying filler and microcapsule COD degrading bacteria into the semi-finished product of the emulsified detergent prepared in the step two, uniformly stirring, and then carrying out ultrasonic defoaming treatment to prepare a finished product of the degreasing industrial detergent;
step four: and filling the prepared finished product of the degreasing industrial cleaning agent, and sealing and storing the finished product in a low-temperature environment.
The application of the environment-friendly high-efficiency degreasing industrial cleaning agent is used for removing oil stains and oil stains of various ores, animals and plants in machinery, equipment, vehicles, ships, manufacturing and processing and maintenance of parts.
The invention has the technical effects and advantages that:
through compounding nonionic surfactant and anionic surfactant, and compatible alkaline degreasing agent, can make the greasy dirt break away from and emulsify and disperse through the mode of crimpling and solubilization under low temperature environment, cooperation auxiliary agent improves the cleaning capacity to polar greasy dirt, can not cause the corruption to the workpiece surface in the clearance process, antisludging agent can prevent workpiece surface salt deposit simultaneously, and further soften the clearance sewage, fly ash and active carbon effective adsorption clearance thing and peculiar smell, and break away from COD degradation fungus by COD microcapsule degradation fungus and carry out the biodegradation to sewage, and is safe high-efficient, can clear up automatically and the organic matter in the biodegradation sewage, can high-efficient degrease the clearance under low temperature environment compared with prior art.
Detailed Description
The following will clearly and completely describe the technical solutions in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the invention provides an environment-friendly high-efficiency degreasing industrial cleaning agent, wherein the used main materials comprise the following components in parts by weight: 55 parts of deionized water, 12 parts of an alkaline degreasing agent, 8 parts of a non-ionic surfactant, 8 parts of an anionic surfactant and 6 parts of an auxiliary agent, wherein the auxiliary material comprises the following components in parts by weight: 2 parts of purifying filler and 1 part of microcapsule COD degrading bacteria.
Furthermore, the auxiliary agent consists of a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, wherein the ratio of the cosolvent to the emulsifier to the scale inhibitor to the chelating agent to the corrosion inhibitor is set to be 1:2:1:1: 1.
Further, the purifying filler is composed of fly ash and activated carbon, the fly ash and the activated carbon are both in a nano powder shape, and the ratio of the fly ash to the activated carbon is set to be 1: 1.
Further, the microcapsule COD degrading bacteria are made of COD degrading bacteria and an isolating membrane, the COD degrading bacteria and the isolating membrane are respectively a core material and a wall material, and the isolating membrane is set to be a composition of alginate and guar gum.
Further, the isolating membrane is wrapped outside the COD degrading bacteria through molecular encapsulation treatment, the release mode of the microcapsule COD degrading bacteria is dissolution release, and the release time is slow release.
Further, the alkaline degreasing agent is 15% sodium carbonate solution, the nonionic surfactant is OP-10 surfactant, and the anionic surfactant is fatty alcohol-polyoxyethylene ether sodium sulfate.
Further, the cosolvent is tween, the emulsifier is cellulose derivative, the scale inhibitor is polyepoxysuccinic acid, the chelating agent is organic phosphate, and the corrosion inhibitor is mercaptobenzothiazole.
A preparation method of an environment-friendly high-efficiency degreasing industrial cleaning agent comprises the following specific operation steps:
the method comprises the following steps: taking deionized water, an alkaline degreasing agent, a nonionic surfactant, an anionic surfactant and an auxiliary agent according to a certain proportion, mixing the mixture with a compound purifying filler, and preparing microcapsule COD degrading bacteria;
step two: dissolving an alkaline degreasing agent, a nonionic surfactant and an anionic surfactant in deionized water, adding a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, and uniformly stirring to prepare a semi-finished product of the emulsified detergent;
step three: adding a purifying filler and microcapsule COD degrading bacteria into the semi-finished product of the emulsified detergent prepared in the step two, uniformly stirring, and then carrying out ultrasonic defoaming treatment to prepare a finished product of the degreasing industrial detergent;
step four: and filling the prepared finished product of the degreasing industrial cleaning agent, and sealing and storing the finished product in a low-temperature environment.
The application of the environment-friendly high-efficiency degreasing industrial cleaning agent is used for removing oil stains and oil stains of various ores, animals and plants in machinery, equipment, vehicles, ships, manufacturing and processing and maintenance of parts.
The degreasing industry cleaning agent liquid phase emulsification of preparing in this embodiment is effectual, and each composition distributes evenly can carry out the degrease washing to the polarity greasy dirt on the work piece under low temperature environment, and cleaning efficiency is high, in addition, carries out physical properties and result of use test to the high-efficient degreasing industry cleaning agent of preparing in this mode in this embodiment, under 18 + -2 ℃ low temperature environment, dissolves this cleaner in aqueous and carries out the spray rinsing to the work piece and wipe, and the result shows: the surface tension of the aqueous solution is 27.9 percent, the comprehensive decontamination rate is 79.6 percent, the comprehensive deoiling rate is 94.2 percent, and the degreasing and cleaning effects are higher than those of the existing similar products in the market.
Example 2:
the invention provides an environment-friendly high-efficiency degreasing industrial cleaning agent, wherein the used main materials comprise the following components in parts by weight: 60 parts of deionized water, 15 parts of an alkaline degreasing agent, 10 parts of a non-ionic surfactant, 10 parts of an anionic surfactant and 8 parts of an auxiliary agent, wherein the auxiliary material comprises the following components in parts by weight: 3 parts of purifying filler and 2 parts of microcapsule COD degrading bacteria.
Furthermore, the auxiliary agent consists of a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, wherein the ratio of the cosolvent to the emulsifier to the scale inhibitor to the chelating agent to the corrosion inhibitor is set to be 1:3:1:2: 1.
Further, the purification filler is composed of fly ash and activated carbon, the fly ash and the activated carbon are both in a nano powder shape, and the ratio of the fly ash to the activated carbon is set to be 3: 2.
Further, the microcapsule COD degrading bacteria are prepared from COD degrading bacteria and an isolating membrane, the COD degrading bacteria and the isolating membrane are respectively a core material and a wall material, and the isolating membrane is a composition of alginate and Arabic gum.
Further, the isolating membrane is wrapped outside the COD degrading bacteria through molecular encapsulation treatment, the release mode of the microcapsule COD degrading bacteria is dissolution release, and the release time is slow release.
Further, the alkaline degreasing agent is 15% sodium carbonate solution, the nonionic surfactant is OP-10 surfactant, and the anionic surfactant is fatty alcohol-polyoxyethylene ether sodium sulfate.
Further, the cosolvent is tween, the emulsifier is cellulose derivative, the scale inhibitor is polyepoxysuccinic acid, the chelating agent is organic phosphate, and the corrosion inhibitor is mercaptobenzothiazole.
A preparation method of an environment-friendly high-efficiency degreasing industrial cleaning agent comprises the following specific operation steps:
the method comprises the following steps: taking deionized water, an alkaline degreasing agent, a nonionic surfactant, an anionic surfactant and an auxiliary agent according to a certain proportion, mixing the mixture with a compound purifying filler, and preparing microcapsule COD degrading bacteria;
step two: dissolving an alkaline degreasing agent, a nonionic surfactant and an anionic surfactant in deionized water, adding a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, and uniformly stirring to prepare a semi-finished product of the emulsified detergent;
step three: adding a purifying filler and microcapsule COD degrading bacteria into the semi-finished product of the emulsified detergent prepared in the step two, uniformly stirring, and then carrying out ultrasonic defoaming treatment to prepare a finished product of the degreasing industrial detergent;
step four: and filling the prepared finished product of the degreasing industrial cleaning agent, and sealing and storing the finished product in a low-temperature environment.
The application of the environment-friendly high-efficiency degreasing industrial cleaning agent is used for removing oil stains and oil stains of various ores, animals and plants in machinery, equipment, vehicles, ships, manufacturing and processing and maintenance of parts.
Comparative example 1, the degreasing industry cleaning agent liquid phase emulsification of preparing in this embodiment is effectual, and each composition distributes evenly can carry out the degrease washing to the polarity greasy dirt on the work piece under low temperature environment, and cleaning efficiency is high, in addition, carries out physical properties and result of use test to the high-efficient degreasing industry cleaning agent of preparing in this mode in this embodiment, under 18 ± 2 ℃ low temperature environment, dissolves this cleaning agent in aqueous and carries out the spray rinsing to the work piece and wipe, and the result shows: the surface tension of the aqueous solution is 25.3 percent, the comprehensive decontamination rate is 89.3 percent, the comprehensive deoiling rate is 99.9 percent, and the degreasing and cleaning effects are higher than those of the existing like products in the market.
Example 3:
the invention provides an environment-friendly high-efficiency degreasing industrial cleaning agent, wherein the used main materials comprise the following components in parts by weight: 65 parts of deionized water, 18 parts of an alkaline degreasing agent, 12 parts of a non-ionic surfactant, 12 parts of an anionic surfactant and 10 parts of an auxiliary agent, wherein the auxiliary material comprises the following components in parts by weight: 4 parts of purifying filler and 3 parts of microcapsule COD degrading bacteria.
Furthermore, the auxiliary agent consists of a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, wherein the ratio of the cosolvent to the emulsifier to the scale inhibitor to the chelating agent to the corrosion inhibitor is set to be 1:4:1:3: 1.
Further, the purifying filler is composed of fly ash and activated carbon, the fly ash and the activated carbon are both in a nano powder shape, and the ratio of the fly ash to the activated carbon is set to be 1: 2.
Further, the microcapsule COD degrading bacteria are made of COD degrading bacteria and an isolating membrane, the COD degrading bacteria and the isolating membrane are respectively a core material and a wall material, and the isolating membrane is a composition of guar gum and Arabic gum.
Further, the isolating membrane is wrapped outside the COD degrading bacteria through molecular encapsulation treatment, the release mode of the microcapsule COD degrading bacteria is dissolution release, and the release time is slow release.
Further, the alkaline degreasing agent is 15% sodium carbonate solution, the nonionic surfactant is OP-10 surfactant, and the anionic surfactant is fatty alcohol-polyoxyethylene ether sodium sulfate.
Further, the cosolvent is tween, the emulsifier is cellulose derivative, the scale inhibitor is polyepoxysuccinic acid, the chelating agent is organic phosphate, and the corrosion inhibitor is mercaptobenzothiazole.
A preparation method of an environment-friendly high-efficiency degreasing industrial cleaning agent comprises the following specific operation steps:
the method comprises the following steps: taking deionized water, an alkaline degreasing agent, a nonionic surfactant, an anionic surfactant and an auxiliary agent according to a certain proportion, mixing the mixture with a compound purifying filler, and preparing microcapsule COD degrading bacteria;
step two: dissolving an alkaline degreasing agent, a nonionic surfactant and an anionic surfactant in deionized water, adding a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, and uniformly stirring to prepare a semi-finished product of the emulsified detergent;
step three: adding a purifying filler and microcapsule COD degrading bacteria into the semi-finished product of the emulsified detergent prepared in the step two, uniformly stirring, and then carrying out ultrasonic defoaming treatment to prepare a finished product of the degreasing industrial detergent;
step four: and filling the prepared finished product of the degreasing industrial cleaning agent, and sealing and storing the finished product in a low-temperature environment.
The application of the environment-friendly high-efficiency degreasing industrial cleaning agent is used for removing oil stains and oil stains of various ores, animals and plants in machinery, equipment, vehicles, ships, manufacturing and processing and maintenance of parts.
Comparative example 1 and 2, the degreasing industry cleaner liquid phase emulsification of preparation is effectual in this embodiment, and each composition distributes evenly can carry out the degrease washing to the polarity greasy dirt on the work piece under low temperature environment, and cleaning efficiency is high, in addition, carries out physical properties and result of use test to the high-efficient degreasing industry cleaner of preparing in this mode in this embodiment, under 18 ± 2 ℃ low temperature environment, dissolves this cleaner in aqueous and carries out the spray rinsing to the work piece and wipe, and the result shows: the surface tension of the aqueous solution is 26.7%, the comprehensive decontamination rate is 84.1%, the comprehensive deoiling rate is 97.8%, and the degreasing and cleaning effects are higher than those of the existing like products in the market.
The following table is obtained according to examples 1 to 3:
as can be seen from the above table, in example 2, the raw materials have a moderate proportion and optimal components are prepared, the surface tension of the aqueous solution of the industrial cleaning agent prepared by the present embodiment is minimum, and the comprehensive decontamination rate and the comprehensive oil removal rate are highest when the industrial cleaning agent is used for cleaning a workpiece, so that the processing technology is most suitable for preparing the high-efficiency degreasing industrial cleaning agent in the technical scheme, the technical scheme combines the nonionic surfactant and the anionic surfactant, and is compatible with the alkaline degreasing agent, so that the oil stain can be separated, emulsified and dispersed in a curling and solubilizing manner in a low-temperature environment, the cleaning capability of the polar oil stain is improved by the aid, the surface of the workpiece cannot be corroded in the cleaning process, meanwhile, the scale inhibitor can prevent salt precipitation on the surface of the workpiece, and further soften the cleaned sewage, the fly ash and the activated carbon effectively adsorb the cleaning substances and peculiar smell, and the COD degrading bacteria are separated from the microcapsule COD degrading bacteria to biodegrade the sewage, is safe and efficient.
Finally, it should be noted that: the above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like that are within the spirit and principle of the present invention are intended to be included in the scope of the present invention.
Claims (9)
1. An environment-friendly high-efficiency degreasing industrial cleaning agent is characterized in that: the used main materials comprise the following components in parts by weight: 55-65 parts of deionized water, 12-18 parts of alkaline degreasing agent, 8-12 parts of non-ionic surfactant, 8-12 parts of anionic surfactant and 6-10 parts of auxiliary agent, wherein the auxiliary material comprises the following components in parts by weight: 2-4 parts of purifying filler and 1-3 parts of microcapsule COD degrading bacteria.
2. The environment-friendly efficient degreasing industrial cleaning agent as claimed in claim 1, wherein the environment-friendly efficient degreasing industrial cleaning agent comprises: the auxiliary agent consists of a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, wherein the proportion of the cosolvent, the emulsifier, the scale inhibitor, the chelating agent and the corrosion inhibitor is set to be 1:2-4:1:1-3: 1.
3. The environment-friendly efficient degreasing industrial cleaning agent as claimed in claim 1, wherein the environment-friendly efficient degreasing industrial cleaning agent comprises: the purifying filler is composed of fly ash and activated carbon, the fly ash and the activated carbon are both arranged in a nano powder shape, and the ratio of the fly ash to the activated carbon is 1: 1-2.
4. The environment-friendly efficient degreasing industrial cleaning agent as claimed in claim 1, wherein the environment-friendly efficient degreasing industrial cleaning agent comprises: the microcapsule COD degrading bacteria are prepared from COD degrading bacteria and an isolating membrane, the COD degrading bacteria and the isolating membrane are respectively a core material and a wall material, and the isolating membrane is made of one of alginate, guar gum and Arabic gum and a composition of the alginate, the guar gum and the Arabic gum.
5. The environment-friendly efficient degreasing industrial cleaning agent as claimed in claim 4, wherein the environment-friendly efficient degreasing industrial cleaning agent comprises: the isolating membrane is wrapped outside the COD degrading bacteria through molecular encapsulation treatment, the release mode of the microcapsule COD degrading bacteria is dissolution release, and the release time is slow release.
6. The environment-friendly efficient degreasing industrial cleaning agent as claimed in claim 1, wherein the environment-friendly efficient degreasing industrial cleaning agent comprises: the alkaline degreasing agent is 15% sodium carbonate solution, the nonionic surfactant is OP-10 surfactant, and the anionic surfactant is fatty alcohol-polyoxyethylene ether sodium sulfate.
7. The environment-friendly efficient degreasing industrial cleaning agent as claimed in claim 2, wherein the cleaning agent comprises: the cosolvent is Tween, the emulsifier is a cellulose derivative, the scale inhibitor is polyepoxysuccinic acid, the chelating agent is organic phosphate, and the corrosion inhibitor is mercaptobenzothiazole.
8. The preparation method of the environment-friendly high-efficiency degreasing industrial cleaning agent as claimed in any one of claims 1-7, wherein the preparation method comprises the following steps: the specific operation steps are as follows:
the method comprises the following steps: taking deionized water, an alkaline degreasing agent, a nonionic surfactant, an anionic surfactant and an auxiliary agent according to a certain proportion, mixing the mixture with a compound purifying filler, and preparing microcapsule COD degrading bacteria;
step two: dissolving an alkaline degreasing agent, a nonionic surfactant and an anionic surfactant in deionized water, adding a cosolvent, an emulsifier, a scale inhibitor, a chelating agent and a corrosion inhibitor, and uniformly stirring to prepare a semi-finished product of the emulsified detergent;
step three: adding a purifying filler and microcapsule COD degrading bacteria into the semi-finished product of the emulsified detergent prepared in the step two, uniformly stirring, and then carrying out ultrasonic defoaming treatment to prepare a finished product of the degreasing industrial detergent;
step four: and filling the prepared finished product of the degreasing industrial cleaning agent, and sealing and storing the finished product in a low-temperature environment.
9. The use of the environment-friendly high-efficiency degreasing industrial cleaning agent as claimed in any one of claims 1-7, wherein the cleaning agent comprises: the cleaning agent is used for removing oil stains and oil stains of various ores, animals and plants in machinery, equipment, vehicles, ships, manufacturing and processing and maintenance of parts.
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