CN102230182B - Water-based cleaning agent - Google Patents
Water-based cleaning agent Download PDFInfo
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- CN102230182B CN102230182B CN201110161242A CN201110161242A CN102230182B CN 102230182 B CN102230182 B CN 102230182B CN 201110161242 A CN201110161242 A CN 201110161242A CN 201110161242 A CN201110161242 A CN 201110161242A CN 102230182 B CN102230182 B CN 102230182B
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Abstract
The invention discloses a water-based cleaning agent, which comprises the following components in percentage by mass: 1 to 3 percent of sodium tripolyphosphate, 2 to 4 percent of disodium hydrogen phosphate, 0.5 to 1 percent of borax, 2 to 4 percent of nitrobenzoic acid, 0.5 to 2 percent of sodium hydroxide, 1 to 4 percent of surfactant, 2 to 5 percent of polyethylene glycol, 13 to 15 percent of triethanolamine, 0.01 to 0.1 percent of defoamer and the balance of water. The water-based cleaning agent is high in cleaning capacity of greasy dirt, avoids generating a large amount of foam in the cleaning process, is suitable for full-automatic cleaning and ultrasonic cleaning, has the good protective effect on cleaning machines, does not contain inflammable and explosive ingredients, is used safely, does not have influence on human bodies and does not pollution on environment.
Description
Technical field
The invention belongs to industrial field of washing, be specifically related to a kind of aqueous cleaning agent.
Background technology
Industrial cleaning agent is the allied industry that develops rapidly along with development of modern industry; Developing rapidly of present stage China's industry; Demand to industrial cleaning agent is also increasing year by year; And there is following deficiency mostly at present domestic industrial cleaning agent: (1) foam is excessive, is not suitable in the jetting machine; (2) can not satisfy the requirement that parts are cleaned in protection between matting, cause parts to get rusty.In addition, the raising of Along with people's environmental consciousness, the exploitation green cleaning agent has become cleaning industry inevitable development trend.
Aqueous cleaning agent is that a kind of natural environmental-protective material that uses---water is the clean-out system of base solvent, and it has low toxicity, and is little to human harm, does not burn, and can be degraded, and does not destroy superior characteristics such as environment.To environmental protection today of growing interest with safety, aqueous cleaning agent is that an ideal is selected in produced worldwide enterprise.
Present aqueous cleaning agent has following several types: 1, alkaline species aqueous cleaning agent (containing alkaline inorganics or organism); 2, surfactant-based aqueous cleaning agent (containing tensio-active agent); 3, heterogeneous aqueous cleaning agent (water, two-phase or multiphase solvent of oil); 4, single-phase neutral surfactant-free class aqueous cleaning agent.
Announced a kind of aqueous cleaning agent in the CN101538512 patent, formulated by surfactant primary washing part, alkaline auxiliary washing part, solvent part, sanitas and water.Wherein surfactant primary washing part is carried out composite with negatively charged ion and nonionic surfactant.Alkaline assistant is partly selected trolamine and metasilicate pentahydrate sodium, EDTA disodium.Solvent partly is chosen as ethanol, glycol ether, or natural orange oil extract D-limonene, and sanitas is then selected propylben for use.Though this clean-out system cleaning performance can, the ethanol that it is selected for use, glycol ether have irritating smell and human body are had toxicity.
Announced a kind of alkaline water-based cleaning agent in the CN101363125A patent, it contains Sodium Nitrite 0.1-0.3%, yellow soda ash 0.3-0.6%, tensio-active agent 0.1-0.3%, and surplus is a water.The tensio-active agent that this clean-out system is selected for use is liquid detergent or household laundry powder; In washing process, produce a large amount of foams; Be not suitable for automatic washing and ultrasonic cleaning, and contain Sodium Nitrite and have toxicity in its prescription, workers exposed hand, pedal skin can damage.
Summary of the invention
In view of this, in order to overcome the deficiency of prior art, the present invention provides a kind of cleansing power strong, does not corrode to be cleaned parts, and no significant foam produces in the cleaning process, the aqueous cleaning agent of safe in utilization, environmental protection.
Aqueous cleaning agent provided by the invention comprises following mass percent component:
Tripoly phosphate sodium STPP 1-3%, Sodium phosphate, dibasic 2-4%, borax 0.5-1%,
P-Nitrobenzenecarboxylic acid 2-4%, sodium hydroxide 0.5-2%,
Tensio-active agent 1-4%, polyoxyethylene glycol 2-5%,
Trolamine 13-15%, skimmer 0.01-0.1%, surplus is a water.
Further, said tensio-active agent is preferably the SULPHOSUCCINIC ACID ESTER AS, and said SULPHOSUCCINIC ACID ESTER AS is formed according to the mass ratio of 25:24:1 is composite by water, polyoxyethylene ether phosphate and phosphoric acid salt successively.
Further, said polyoxyethylene ether phosphate molecular structural formula is:
Wherein: N is a nitrogen,
M is a sodium salt,
R is C
12-C
14Alkyl or alkene,
The span of n is 4-9.
Further, described skimmer is preferably tributyl phosphate.
Further, the more preferably silicone based skimmer of described skimmer.
Further, described skimmer most preferably is the methyl polysiloxane skimmer.
Tripoly phosphate sodium STPP, Sodium phosphate, dibasic, borax and sodium hydroxide are as cleaning smeary host among the present invention; High temperature performance is stable; Have good decontamination, emulsification, wettability, stronger degreasing power, and cast iron quality equipment also had good provide protection.
Trolamine among the present invention, p-Nitrobenzenecarboxylic acid have certain rust inhibition to metal material, can strengthen antirust ability, the stable performance of assurance products obtained therefrom of this product, and biological degradability are good, meets environmental protection requirement.
Nontoxic, the nonirritant of polyoxyethylene glycol among the present invention has good water-solubility, has excellent lubrication property, moisture retention, dispersiveness.
The skimmer that adds among the present invention; Be selected from tributyl phosphate or silicone based skimmer, heat-resisting, the acid and alkali-resistance of this skimmer has stronger froth breaking effect; Make this clean-out system more be applicable to automatic washing and ultrasonic cleaning, to satisfy still or low foaming requirement in the cleaning process.
Polyoxyethylene ether phosphate among the present invention has higher surface tension, and oilness is good; Biodegradable; In alkaline environment, have good decontamination, emulsification, wettability, stronger degreasing power.
The preparation method of aqueous cleaning agent of the present invention is: the amount of aqueous cleaning agent total desired raw material of preparation as required, under the normal temperature condition, the raw material that takes by weighing is added in the entry successively, and be stirred to and transparently fully promptly get.
Its fundamental property of aqueous cleaning agent and reference standard are following at present:
Table 1 aqueous cleaning agent with reference to examination criteria
Beneficial effect of the present invention is:
Ability of cleaning greasy dirt of the present invention is strong, is specially adapted to clean in automatic washing and the ultrasonic cleaning greasy dirt on the parts.Do not corrode hardware, have no irritating odor in the use, safe in utilization, be a kind of non-ODS environment-friendly type water based cleaning agent.
Embodiment
The preparation of embodiment 1-7 aqueous cleaning agent of the present invention
At normal temperatures, according to the ratio shown in the table 1, required each constituent mass of aqueous cleaning agent total of preparation takes by weighing the each component raw material as required.Under the normal temperature condition, raw material is added in the entry, be stirred to transparent getting final product fully.
The composition of table 1 aqueous cleaning agent and schedule of proportion thereof
With 10 kilograms of the high pressure water based cleaning agents of the foregoing description preparation, be made into diluent with water with the thinning ratio of 1:4 and use, cleaning performance is by operator's comparation and assessment then and there, and the result sees table 2.
Two kinds of clean-out system contrast tables of table 2
See from above-mentioned experimental result, compare with external like product, the more effective removing parts surface and oil contaminant of aqueous cleaning agent ability of the present invention, and can prevent that parts from returning rust in the operation process; External like product has strong impulse property smell; Can work the mischief to the operator is healthy, the while contaminate environment, and do not contain harmful organic solvent class material in the clean-out system of the present invention; Have no irritating odor, the safety in utilization aspect is superior to external product greatly.In addition, aqueous cleaning agent cleaning process of the present invention does not have significant foam and produces, and more is applicable to automatic washing and ultrasonic cleaning.
Although through reference some preferred embodiment of the present invention; Invention has been described; But those of ordinary skill in the art is to be understood that; Can make various changes to it in form with on the details, and the spirit and scope of the present invention that do not depart from appended claims and limited.
Claims (5)
1. aqueous cleaning agent is characterized in that said aqueous cleaning agent comprises following mass percent component:
Tripoly phosphate sodium STPP 1-3%, Sodium phosphate, dibasic 2-4%, borax 0.5-1%,
P-Nitrobenzenecarboxylic acid 2-4%, sodium hydroxide 0.5-2%,
Tensio-active agent 1-4%, polyoxyethylene glycol 2-5%,
Trolamine 13-15%; Skimmer 0.01-0.1%; Surplus is a water, and described tensio-active agent is the SULPHOSUCCINIC ACID ESTER AS, and said SULPHOSUCCINIC ACID ESTER AS is formed according to the mass ratio of 25:24:1 is composite by water, polyoxyethylene ether phosphate and phosphoric acid salt successively.
2. according to the described aqueous cleaning agent of claim 1; It is characterized in that; Said polyoxyethylene ether phosphate molecular structural formula is:
wherein: N is a nitrogen
M is a sodium salt,
R is C
12-C
14Alkyl or alkene,
The span of n is 4-9.
3. according to the described aqueous cleaning agent of claim 1, it is characterized in that described skimmer is a tributyl phosphate.
4. according to the described aqueous cleaning agent of claim 1, it is characterized in that described skimmer is silicone based skimmer.
5. according to the described aqueous cleaning agent of claim 4, it is characterized in that described skimmer is the methyl polysiloxane skimmer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110161242A CN102230182B (en) | 2011-06-16 | 2011-06-16 | Water-based cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110161242A CN102230182B (en) | 2011-06-16 | 2011-06-16 | Water-based cleaning agent |
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| Publication Number | Publication Date |
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| CN102230182A CN102230182A (en) | 2011-11-02 |
| CN102230182B true CN102230182B (en) | 2012-10-10 |
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| CN201110161242A Active CN102230182B (en) | 2011-06-16 | 2011-06-16 | Water-based cleaning agent |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816660A (en) * | 2012-09-11 | 2012-12-12 | 广东普赛特电子科技股份有限公司 | Nano water-based cleaning agent and preparing method thereof |
| CN103668229B (en) * | 2013-12-17 | 2015-12-30 | 广西理工职业技术学院 | The treatment process of aluminium alloy extruded porous mold |
| CN104073830B (en) * | 2014-07-03 | 2016-05-11 | 北京科大中冶技术发展有限公司 | A kind of be applicable to high grade of steel steel pipe rolling except oxide agent and preparation method thereof |
| CN107630222A (en) * | 2016-07-18 | 2018-01-26 | 天津市澳路浦润滑科技股份有限公司 | A kind of low bubble water base metal cleaning agent |
| CN106011895B (en) * | 2016-07-18 | 2019-03-26 | 武汉钢铁有限公司 | Electrogalvanizing pre-treatment cleaning agent |
| CN106283088A (en) * | 2016-08-24 | 2017-01-04 | 威海翔宇环保科技股份有限公司 | A kind of for complex cleaning and washing agent cleaning metal surface greasy dirt and preparation method thereof |
| CN107365999A (en) * | 2017-07-25 | 2017-11-21 | 马鞍山联邦机电工程有限公司 | A kind of magnetic polyethylene glycol fixes the compound powder cleaning agent of degradation bacteria and cleaning |
| CN107779892A (en) * | 2017-11-03 | 2018-03-09 | 徐州工程学院 | A kind of environmentally-friendly water-based metal cleaner and preparation method thereof |
| CN108265306B (en) * | 2018-01-22 | 2020-02-18 | 北京中钞钞券设计制版有限公司 | Water-based cleaning agent and preparation method and application thereof |
| CN108660463A (en) * | 2018-06-29 | 2018-10-16 | 湖州织里宝丰铝业有限公司 | Alkaline defatting agent for aluminium alloy extrusions |
| CN111268879B (en) * | 2020-02-19 | 2022-02-08 | 成都科衡环保技术有限公司 | Oxidizing agent for harmless treatment of waste solid water-based mud in drilling, preparation method and application thereof |
| CN115161130A (en) * | 2022-07-15 | 2022-10-11 | 天津市光复科技发展有限公司 | Preparation method of efficient environment-friendly water-based deoiling cleaning agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101736353A (en) * | 2008-11-14 | 2010-06-16 | 沈阳晟豪化工有限公司 | Metal surface degreasing agent |
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Non-Patent Citations (2)
| Title |
|---|
| 杜青.新型磷酸酯两性表面活性剂的性能与应用.《清洗技术》.2004,第2卷(第10期),52-59. * |
| 杨亚莉.水基型油污清洗剂的配方设计.《大众科技》.2009,(第8期),114-116. * |
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Owner name: BEIJING BLUESTAR TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: BLUE STAR ENVIRONMENTAL ENGINEERING CO., LTD. Effective date: 20130304 |
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Effective date of registration: 20130304 Address after: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5 Patentee after: Beijing Bluestar Technology Co., Ltd. Address before: 101300, serenity Road 5, Shunyi District airport industry zone, Beijing, Patentee before: Blue Star Environmental Engineering Co., Ltd. |
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Owner name: BEIJING BLUESTAR WASHING CO., LTD. Free format text: FORMER NAME: BEIJING BLUESTAR TECHNOLOGY CO., LTD. |
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Address after: 101318 Beijing city B District Shunyi District Tianzhu Airport Industrial Zone Anxiang Street No. 5 Patentee after: BEIJING BLUESTAR CLEANING CO., LTD. Address before: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5 Patentee before: Beijing Bluestar Technology Co., Ltd. |