CN102230182A - Water-based cleaning agent - Google Patents

Water-based cleaning agent Download PDF

Info

Publication number
CN102230182A
CN102230182A CN 201110161242 CN201110161242A CN102230182A CN 102230182 A CN102230182 A CN 102230182A CN 201110161242 CN201110161242 CN 201110161242 CN 201110161242 A CN201110161242 A CN 201110161242A CN 102230182 A CN102230182 A CN 102230182A
Authority
CN
China
Prior art keywords
cleaning agent
percent
aqueous cleaning
defoamer
water
Prior art date
Application number
CN 201110161242
Other languages
Chinese (zh)
Other versions
CN102230182B (en
Inventor
文措杰
王双田
白剑利
单素灵
于湘云
沈妮
Original Assignee
蓝星环境工程有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 蓝星环境工程有限公司 filed Critical 蓝星环境工程有限公司
Priority to CN201110161242A priority Critical patent/CN102230182B/en
Publication of CN102230182A publication Critical patent/CN102230182A/en
Application granted granted Critical
Publication of CN102230182B publication Critical patent/CN102230182B/en

Links

Abstract

The invention discloses a water-based cleaning agent, which comprises the following components in percentage by mass: 1 to 3 percent of sodium tripolyphosphate, 2 to 4 percent of disodium hydrogen phosphate, 0.5 to 1 percent of borax, 2 to 4 percent of nitrobenzoic acid, 0.5 to 2 percent of sodium hydroxide, 1 to 4 percent of surfactant, 2 to 5 percent of polyethylene glycol, 13 to 15 percent of triethanolamine, 0.01 to 0.1 percent of defoamer and the balance of water. The water-based cleaning agent is high in cleaning capacity of greasy dirt, avoids generating a large amount of foam in the cleaning process, is suitable for full-automatic cleaning and ultrasonic cleaning, has the good protective effect on cleaning machines, does not contain inflammable and explosive ingredients, is used safely, does not have influence on human bodies and does not pollution on environment.

Description

A kind of aqueous cleaning agent
Technical field
The invention belongs to industrial cleaning field, be specifically related to a kind of aqueous cleaning agent.
Background technology
Industrial cleaning agent is the allied industry that develops rapidly along with development of modern industry, developing rapidly of present stage China's industry, demand to industrial cleaning agent is also increasing year by year, and there is following deficiency mostly in domestic industrial cleaning agent at present: (1) foam is excessive, is not suitable in the jetting machine; (2) can not satisfy the requirement that parts are cleaned in protection between matting, cause parts to get rusty.In addition, along with the raising of people's environmental consciousness, the exploitation green cleaning agent has become cleaning industry inevitable development trend.
Aqueous cleaning agent is that a kind of natural environmental-protective material that uses---water is the clean-out system of base solvent, and it has low toxicity, and is little to human body harm, do not burn, and can be degraded, and do not destroy superior characteristics such as environment.In produced worldwide enterprise today of growing interest to environmental protection and safety, aqueous cleaning agent is that an ideal is selected.
Present aqueous cleaning agent has following a few class: 1, alkaline species aqueous cleaning agent (containing alkaline inorganics or organism); 2, surfactant-based aqueous cleaning agent (containing tensio-active agent); 3, heterogeneous aqueous cleaning agent (water, two-phase or multiphase solvent of oil); 4, single-phase neutral surfactant-free class aqueous cleaning agent.
Announced a kind of aqueous cleaning agent in the CN101538512 patent, formulated by surfactant primary washing part, alkaline auxiliary washing part, solvent part, sanitas and water.Wherein surfactant primary washing part is carried out composite with negatively charged ion and nonionic surfactant.Alkaline assistant is partly selected trolamine and metasilicate pentahydrate sodium, EDTA disodium.Solvent partly is chosen as ethanol, glycol ether, or natural orange oil extract D-limonene, and sanitas is then selected propylben for use.Though this clean-out system cleaning performance can, the ethanol that it is selected for use, glycol ether have irritating smell and human body are had toxicity.
Announced a kind of alkaline water-based cleaning agent in the CN101363125A patent, it contains Sodium Nitrite 0.1-0.3%, yellow soda ash 0.3-0.6%, tensio-active agent 0.1-0.3%, and surplus is a water.The tensio-active agent that this clean-out system is selected for use is liquid detergent or household laundry powder, in washing process, produce a large amount of foams, be not suitable for automatic washing and ultrasonic cleaning, and contain Sodium Nitrite and have toxicity in its prescription, workers exposed hand, pedal skin can damage.
Summary of the invention
In view of this, in order to overcome the deficiencies in the prior art, it is strong to the invention provides a kind of cleansing power, does not corrode to be cleaned parts, and no a large amount of foams produce in the cleaning process, the aqueous cleaning agent of safe in utilization, environmental protection.
Aqueous cleaning agent provided by the invention comprises following mass percent component:
Tripoly phosphate sodium STPP 1-3%, Sodium phosphate dibasic 2-4%, borax 0.5-1%,
P-nitrobenzoic acid 2-4%, sodium hydroxide 0.5-2%,
Tensio-active agent 1-4%, polyoxyethylene glycol 2-5%,
Trolamine 13-15%, defoamer 0.01-0.1%, surplus is a water.
Further, described tensio-active agent is preferably the phosphoric acid ester anion surfactant, and described phosphoric acid ester anion surfactant is formed according to the mass ratio of 25:24:1 is composite successively by water, polyoxyethylene ether phosphate and phosphoric acid salt.
Further, described polyoxyethylene ether phosphate molecular structural formula is:
Wherein: N is a nitrogen,
M is a sodium salt,
R is C 12-C 14Alkyl or alkene,
The span of n is 4-9.
Further, described defoamer is preferably tributyl phosphate.
Further, the more preferably silicone based defoamer of described defoamer.
Further, described defoamer most preferably is the methyl polysiloxane defoamer.
Tripoly phosphate sodium STPP, Sodium phosphate dibasic, borax and sodium hydroxide are as cleaning smeary host among the present invention; high temperature performance is stable; have good decontamination, emulsification, wettability, stronger degreasing power, and cast iron quality equipment also had good provide protection.
Trolamine among the present invention, p-nitrobenzoic acid have certain rust inhibition to metal material, can strengthen antirust ability, the stable performance of assurance products obtained therefrom of this product, and biological degradability are good, meets environmental protection requirement.
Nontoxic, the nonirritant of polyoxyethylene glycol among the present invention has good water-solubility, has excellent lubrication, moisture retention, dispersiveness.
The defoamer that adds among the present invention, be selected from tributyl phosphate or silicone based defoamer, heat-resisting, the acid and alkali-resistance of this defoamer has stronger froth breaking effect, make this clean-out system more be applicable to automatic washing and ultrasonic cleaning, to satisfy still or low foaming requirement in the cleaning process.
Polyoxyethylene ether phosphate among the present invention has higher surface tension, and oilness is good; Biodegradable; In alkaline environment, have good decontamination, emulsification, wettability, stronger degreasing power.
The preparation method of aqueous cleaning agent of the present invention is: the amount of Zhi Bei aqueous cleaning agent total desired raw material as required, under the normal temperature condition, the raw material that takes by weighing is added in the entry successively, and be stirred to fully promptly transparent.
Its fundamental property of aqueous cleaning agent and reference standard are as follows at present:
Table 1 aqueous cleaning agent with reference to examination criteria
Beneficial effect of the present invention is:
Ability of cleaning greasy dirt of the present invention is strong, is specially adapted to clean in automatic washing and the ultrasonic cleaning greasy dirt on the parts.Do not corrode hardware, have no irritating odor in the use, safe in utilization, be a kind of non-ODS environment-friendly type water based cleaning agent.
Embodiment
The preparation of embodiment 1-7 aqueous cleaning agent of the present invention
At normal temperatures, according to the ratio shown in the table 1, required each constituent mass of Zhi Bei aqueous cleaning agent total takes by weighing the each component raw material as required.Under the normal temperature condition, raw material is added in the entry, be stirred to transparent getting final product fully.
The composition of table 1 aqueous cleaning agent and schedule of proportion thereof
With 10 kilograms of the high pressure water based cleaning agents of the foregoing description preparation, be made into diluent with water with the thinning ratio of 1:4 and use, cleaning performance the results are shown in Table 2 by operator's comparation and assessment then and there.
Two kinds of clean-out system contrast tables of table 2
From above-mentioned experimental result, compare with external like product, the more effective removing parts surface and oil contaminant of aqueous cleaning agent energy of the present invention, and can prevent that parts from returning rust in the operation process; External like product has the strong impulse smell, can work the mischief to the operator is healthy, the while contaminate environment, and do not contain harmful organic solvent class material in the clean-out system of the present invention, have no irritating odor, the safety in utilization aspect is better than external product greatly.In addition, aqueous cleaning agent cleaning process of the present invention does not have a large amount of foams and produces, and more is applicable to automatic washing and ultrasonic cleaning.
Although by reference some preferred embodiment of the present invention, invention has been described, but those of ordinary skill in the art is to be understood that, can make various changes to it in the form and details, and the spirit and scope of the present invention that do not depart from appended claims and limited.

Claims (6)

1. aqueous cleaning agent is characterized in that described aqueous cleaning agent comprises following mass percent component:
Tripoly phosphate sodium STPP 1-3%, Sodium phosphate dibasic 2-4%, borax 0.5-1%,
P-nitrobenzoic acid 2-4%, sodium hydroxide 0.5-2%,
Tensio-active agent 1-4%, polyoxyethylene glycol 2-5%,
Trolamine 13-15%, defoamer 0.01-0.1%, surplus is a water.
2. according to the described aqueous cleaning agent of claim 1, it is characterized in that, described tensio-active agent is the phosphoric acid ester anion surfactant, and described phosphoric acid ester anion surfactant is formed according to the mass ratio of 25:24:1 is composite successively by water, polyoxyethylene ether phosphate and phosphoric acid salt.
3. according to the described aqueous cleaning agent of claim 2, it is characterized in that described polyoxyethylene ether phosphate molecular structural formula is:
Wherein: N is a nitrogen,
M is a sodium salt,
R is C 12-C 14Alkyl or alkene,
The span of n is 4-9.
4. according to the described aqueous cleaning agent of claim 1, it is characterized in that described defoamer is a tributyl phosphate.
5. according to the described aqueous cleaning agent of claim 1, it is characterized in that described defoamer is silicone based defoamer.
6. according to the described aqueous cleaning agent of claim 5, it is characterized in that described defoamer is the methyl polysiloxane defoamer.
CN201110161242A 2011-06-16 2011-06-16 Water-based cleaning agent CN102230182B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110161242A CN102230182B (en) 2011-06-16 2011-06-16 Water-based cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110161242A CN102230182B (en) 2011-06-16 2011-06-16 Water-based cleaning agent

Publications (2)

Publication Number Publication Date
CN102230182A true CN102230182A (en) 2011-11-02
CN102230182B CN102230182B (en) 2012-10-10

Family

ID=44842782

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110161242A CN102230182B (en) 2011-06-16 2011-06-16 Water-based cleaning agent

Country Status (1)

Country Link
CN (1) CN102230182B (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102816660A (en) * 2012-09-11 2012-12-12 广东普赛特电子科技股份有限公司 Nano water-based cleaning agent and preparing method thereof
CN103668229A (en) * 2013-12-17 2014-03-26 广西理工职业技术学院 Processing technology of porous mold for aluminum alloy extrusion
CN104073830A (en) * 2014-07-03 2014-10-01 北京科大中冶技术发展有限公司 Oxide removal agent for high-grade steel pipe rolling as well as preparation method of oxide removal agent
CN106011895A (en) * 2016-07-18 2016-10-12 武汉钢铁股份有限公司 Cleaning agent for electrogalvanizing pretreatment
CN106283088A (en) * 2016-08-24 2017-01-04 威海翔宇环保科技股份有限公司 A kind of for complex cleaning and washing agent cleaning metal surface greasy dirt and preparation method thereof
CN107365999A (en) * 2017-07-25 2017-11-21 马鞍山联邦机电工程有限公司 A kind of magnetic polyethylene glycol fixes the compound powder cleaning agent of degradation bacteria and cleaning
CN107630222A (en) * 2016-07-18 2018-01-26 天津市澳路浦润滑科技股份有限公司 A kind of low bubble water base metal cleaning agent
CN107779892A (en) * 2017-11-03 2018-03-09 徐州工程学院 A kind of environmentally-friendly water-based metal cleaner and preparation method thereof
CN108265306A (en) * 2018-01-22 2018-07-10 北京中钞钞券设计制版有限公司 A kind of aqueous cleaning agent and its preparation method and application
CN108660463A (en) * 2018-06-29 2018-10-16 湖州织里宝丰铝业有限公司 Alkaline defatting agent for aluminium alloy extrusions

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101736353A (en) * 2008-11-14 2010-06-16 沈阳晟豪化工有限公司 Metal surface degreasing agent

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101736353A (en) * 2008-11-14 2010-06-16 沈阳晟豪化工有限公司 Metal surface degreasing agent

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
《大众科技》 20091231 杨亚莉 水基型油污清洗剂的配方设计 114-116 1-6 , 第8期 *
《清洗技术》 20041031 杜青 新型磷酸酯两性表面活性剂的性能与应用 52-59 1-6 第2卷, 第10期 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102816660A (en) * 2012-09-11 2012-12-12 广东普赛特电子科技股份有限公司 Nano water-based cleaning agent and preparing method thereof
CN103668229A (en) * 2013-12-17 2014-03-26 广西理工职业技术学院 Processing technology of porous mold for aluminum alloy extrusion
CN103668229B (en) * 2013-12-17 2015-12-30 广西理工职业技术学院 The treatment process of aluminium alloy extruded porous mold
CN104073830A (en) * 2014-07-03 2014-10-01 北京科大中冶技术发展有限公司 Oxide removal agent for high-grade steel pipe rolling as well as preparation method of oxide removal agent
CN106011895A (en) * 2016-07-18 2016-10-12 武汉钢铁股份有限公司 Cleaning agent for electrogalvanizing pretreatment
CN106011895B (en) * 2016-07-18 2019-03-26 武汉钢铁有限公司 Electrogalvanizing pre-treatment cleaning agent
CN107630222A (en) * 2016-07-18 2018-01-26 天津市澳路浦润滑科技股份有限公司 A kind of low bubble water base metal cleaning agent
CN106283088A (en) * 2016-08-24 2017-01-04 威海翔宇环保科技股份有限公司 A kind of for complex cleaning and washing agent cleaning metal surface greasy dirt and preparation method thereof
CN107365999A (en) * 2017-07-25 2017-11-21 马鞍山联邦机电工程有限公司 A kind of magnetic polyethylene glycol fixes the compound powder cleaning agent of degradation bacteria and cleaning
CN107779892A (en) * 2017-11-03 2018-03-09 徐州工程学院 A kind of environmentally-friendly water-based metal cleaner and preparation method thereof
CN108265306A (en) * 2018-01-22 2018-07-10 北京中钞钞券设计制版有限公司 A kind of aqueous cleaning agent and its preparation method and application
CN108660463A (en) * 2018-06-29 2018-10-16 湖州织里宝丰铝业有限公司 Alkaline defatting agent for aluminium alloy extrusions

Also Published As

Publication number Publication date
CN102230182B (en) 2012-10-10

Similar Documents

Publication Publication Date Title
US4528039A (en) Alkaline cleaning compositions non-corrosive toward aluminum surfaces
CA2345692C (en) Concentrated stripper composition and method
CA2218256C (en) Reduced residue hard surface cleaner comprising hydrotrope
CN103510100B (en) Metal cleaner
US4457322A (en) Alkaline cleaning compositions non-corrosive toward aluminum surfaces
AU719487B2 (en) Concentrated aqueous degreasing cleanser
JP4838350B2 (en) Acid cleaning agent for metal surfaces
CN102010806B (en) Rapid wax removing agent
US5834411A (en) General purpose aqueous cleaner
US9506017B2 (en) Aqueous cleaning compositions including an alkyl 3-hydroxybutyrate
US4048121A (en) Low temperature metal cleaning composition
AU727794B2 (en) Compositions and methods for removal of oils & fats from food preparation surfaces
CN105296177B (en) A kind of multifunctional meter surface cleaning agent and preparation method thereof
AU660546B2 (en) Pumpable alkaline cleaning concentrates
US7666264B2 (en) Aircraft cleaner formula
CN108315748B (en) Metal cleaning agent and preparation method thereof
US5902415A (en) Aqueous sodium salt metal cleaner and method of using same
CN102560515B (en) Efficient low-foam special cleaning agent for stainless steel plate
US5705472A (en) Neutral aqueous cleaning composition
CN102732363B (en) Semi-synthesis cutting fluid for magnesium alloy, preparation method and application method
US5614027A (en) Metal cleaner with novel anti-corrosion system
CN104498204A (en) Bio-enzyme bacteriostatic oil stain-emulsifying preparation
MXPA02007622A (en) Microemulsion detergent composition and method for removing hydrophobic soil from an article.
EP2638140B1 (en) Hard surface cleaning composition
MXPA06002490A (en) Aqueous compositions and method for cleaning gas turbine compressor blades.

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
GR01 Patent grant
C14 Grant of patent or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 101300 SHUNYI, BEIJING TO: 101318 SHUNYI, BEIJING

ASS Succession or assignment of patent right

Owner name: BEIJING BLUESTAR TECHNOLOGY CO., LTD.

Free format text: FORMER OWNER: BLUE STAR ENVIRONMENTAL ENGINEERING CO., LTD.

Effective date: 20130304

TR01 Transfer of patent right

Effective date of registration: 20130304

Address after: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5

Patentee after: Beijing Bluestar Technology Co., Ltd.

Address before: 101300, serenity Road 5, Shunyi District airport industry zone, Beijing,

Patentee before: Blue Star Environmental Engineering Co., Ltd.

C41 Transfer of patent application or patent right or utility model
C56 Change in the name or address of the patentee

Owner name: BEIJING BLUESTAR WASHING CO., LTD.

Free format text: FORMER NAME: BEIJING BLUESTAR TECHNOLOGY CO., LTD.

CP03 Change of name, title or address

Address after: 101318 Beijing city B District Shunyi District Tianzhu Airport Industrial Zone Anxiang Street No. 5

Patentee after: BEIJING BLUESTAR CLEANING CO., LTD.

Address before: 101318 Beijing City, Shunyi District Airport Industrial Zone B Anxiang Road No. 5

Patentee before: Beijing Bluestar Technology Co., Ltd.