CN102604761A - All natural fruit and vegetable tableware cleaning agent and preparation method thereof - Google Patents
All natural fruit and vegetable tableware cleaning agent and preparation method thereof Download PDFInfo
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- CN102604761A CN102604761A CN2012100167528A CN201210016752A CN102604761A CN 102604761 A CN102604761 A CN 102604761A CN 2012100167528 A CN2012100167528 A CN 2012100167528A CN 201210016752 A CN201210016752 A CN 201210016752A CN 102604761 A CN102604761 A CN 102604761A
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Abstract
The invention discloses an all natural fruit and vegetable tableware cleaning agent, which comprises disodium fatty acid amide sulfosuccinate, limonene, fatty alcohol polyoxyethylene ether sodium sulfate, an SFD thickener, an inorganic thickener, a complexant, and deionized water, Correspondingly, the invention also discloses a preparation method of the cleaning agent. The cleaning agent disclosed by the invention, of which the main components are all prepared from fatty acids extracted from natural animals and plants, is mild, safe, non-toxic and good in biodegradability. Through the addition of orange oil with good dissolving power and cleansing power, which is extracted from all natural plants such as orange peels, tangerine peels and lemon peels, the dissolving power for pesticide residues and tableware oil stains is enhanced to achieve an ideal cleaning effect. The cleaning agent disclosed by the invention is simple in operation process, safe and efficient, has environmental and economic benefits, and does not cause irritation or damage to human bodies.
Description
Technical field
The present invention relates to a kind of clean-out system, particularly a kind of clean-out system that is used to clean fruits and vegetables and tableware belongs to daily life cleaning supplies field.
Background technology
In modern times in the agricultural; For the purpose that reaches quick desinsection, effectively destroys plant diseases and insect pests; Thereby agricultural chemicals has played the effect that becomes more and more important as a kind of chemicals that are useful at aspects such as control fruit, vegetables disease and pest assurance fruit and vegetable high yields; But the excessive use of agricultural chemicals for many years and medicinal after diet kind such as fruit, vegetables of promptly not going on the market to Safe period often at its remained on surface a large amount of agricultural chemicals; This type of chemistry of pesticide composition is water-soluble low, and the method for washing that people are traditional is difficult to its washes clean, so the remains of pesticide on the fruits and vegetables brings very big hidden danger for people's diet health.
Based on the problems referred to above; Multiple rapid cleaning agent has appearred on the market; Product such as liquid detergent for example; There is following several problem in this series products more: the design of this series products is a purpose of design with daily life vessel such as washing bowl dish usually, and additional fruits and vegetables clean and are merely its additional function, and this series products is used to clean fruit and vegetable residual pesticide effect and bad; The part liquid detergent, though can decompose greasy dirt rapidly, residue is removed in the fast decontaminating degerming, this type of liquid detergent mostly is the chemical industry sintetics.Along with the quick consumption of world petroleum resource and coal resource and the growing tension of supply; The price of industrial chemicals rises day by day; Brought great cost pressure not only for washing composition enterprise; The more important thing is that also there is potential safety hazard in chemical industry synthetic liquid detergent in preparation and production use, caused threat for the Sustainable development of human beings'health and environment.Existing literature research confirms; The chemistry liquid detergent is residual all unfavorable to human body and environment; Cause people when using its cleaning fruits and vegetables and tableware, not only do not have to produce the effectively result of cleaning, brought the infringement of potential HUMAN HEALTH on the contrary; The skin aging problem that causes of life-time service chemistry liquid detergent for example, the secondary environmental pollution that the character that can't degrade causes etc.
As with people the live closely bound up tableware and the clean-out system of fruits and vegetables; How to remove greasy dirt to greatest extent and reduce the fruit and vegetable residual pesticide amount; Reduction is to the harm of human body; And guarantee that clean-out system itself can not cause the secondary pollution infringement to human body and environment, has become the technical problem that this area needs to be resolved hurrily.
Summary of the invention
Problem to the prior art existence; The applicant provides a kind of pure natural fruit and vegetable cleaning agent for dinnerware through a large amount of scientific research and experimental exploring, has solved that the fruit and vegetable surfaces pesticide residue cleans, the problem of the residual cleaning of tableware surface and oil contaminant; And disclosed clean-out system does not all have injury to human body and environment; Be a kind of safety, nontoxic, environment friendly and pollution-free pure natural fruit and vegetable cleaning agent for dinnerware.
For realizing above-mentioned purpose, the technical scheme that the present invention adopted is:
A kind of pure natural fruit and vegetable cleaning agent for dinnerware comprises fatty acid amide sulfo-succinic acid fat disodium, PC 560, polyoxyethylenated alcohol sodium sulfate (being AES), SFD thickening material, inorganic thickening agent, complexing agent, deionized water.
Above-mentioned composition can effectively clean fruits and vegetables and tableware, and is preferred, and in order better to remove the pesticide residue on the fruits and vegetables, said clean-out system also includes AEO.
Those skilled in the art can rationally adjust wherein each composition consumption as required, preferred proportion of composing, meter by weight; 15～25 parts of fatty acid amide sulfo-succinic acid fat disodiums, 1～3 part of PC 560,10～15 parts of polyoxyethylenated alcohol sodium sulfate (AES); 1～3 part of SFD thickening material; 2～5 parts of inorganic thickening agents, 0.1～0.5 part of complexing agent, 48.5～70.9 parts of deionized waters.
When its adding AEO was exclusively used in the pesticide residue of removing fruit and vegetable surfaces, the parts by weight of each composition were 15～20 parts of fatty acid amide sulfo-succinic acid fat disodiums, 1～3 part of PC 560; 2～5 parts of AEOs (AEO-3); 10～15 parts of polyoxyethylenated alcohol sodium sulfate (AES), 1～2 part of SFD thickening material, 2～5 parts of inorganic thickening agents; 0.1～0.2 part of complexing agent, 49.8～68.9 parts of deionized waters.
Wherein, described SFD thickening material is an alkylolamide type tensio-active agent, the alkylolamide type tensio-active agent that is preferably made by sunflower seed oil.
Wherein, described PC 560 extracts acquisition from natural phant, especially can be the orange oil that is obtained through squeezing or distillation by the pericarp of oranges and tangerines, orange, lemon.
Wherein, described AEO is a kind of nonionogenic tenside, and its oleophilic group and hydrophilic group are respectively to be made by Fatty Alcohol(C12-C14 and C12-C18) with reactive hydrogen and ethylene oxide polymerization; It is the mixture of the different multiple Soxylat A 25-7 of oxyethane adduct number; According to the difference of its polymerization degree, have multiple different sizes such as AEO-3, AEO-9, be AEO-3 used preferred of the present invention; As water-in-oil emulsifier, has good washing cleaning action.
In the present invention, described inorganic thickening agent comprises sodium-chlor and/or ammonium chloride.
In the present invention, described complexing agent is selected from carboxyl carboxylate salt or alcamines complexing agent, and preferably EDTA disodium salt or its verivate had both had complexing preferably, is easy to degraded again, can not work the mischief to environment.
In the present invention, the applicant has used deionized water as solvent, it will be appreciated by those skilled in the art that this is that those skilled in the art use common water, purified water etc. instead and still belong to protection scope of the present invention from the needs of avoiding impurity is brought into clean-out system.
On the basis of the above, clarify more when clean-out system is used, can add an amount of emulsifying agent therein, used emulsifying agent is any available liquid emulsifier pharmaceutically.
Accordingly, the invention also discloses the preparation method of said clean-out system, above-mentioned each component is processed for the solvent microemulsified with the deionized water, comprise the steps:
Mark by weight, earlier with inorganic thickening agent, complexing agent under agitation is dissolved in the deionized water fully; Then successively with fatty acid amide sulfo-succinic acid fat disodium, AEO, polyoxyethylenated alcohol sodium sulfate (AES); PC 560, the SFD thickening material mixes with deionized water; Under 40～60 ℃ of temperature, under the speed of 600-1000r/min, stirred 5～10 minutes with high speed dispersor, mix formulated.
Compare with existing clean-out system, clean-out system of the present invention has following technical superiority:
1. clean-out system of the present invention has added PC 560; Especially the orange oil that obtains through squeezing or distillation by the pericarps of oranges and tangerines, orange, lemon etc.; Be a kind of natural strong solvent sanitising agent that has, particularly clean food property oil stain, the cleaning effect of orange oil obviously is superior to other compositions; Under very low content, its cleaning performance is also very obvious; And contained essential oil has the natural disinfection effect in the orange oil, and the acid that it had and fresh aromatising flavour help to improve mood and alleviate anxiety, can make us in labout process, experiencing pure and fresh and spiritual releive happy as the sunlight.
2. clean-out system main active ingredient of the present invention is that the natural acid that from plant-animal, extracts is after alkylolamideization; Carry out the AS of the sulfosuccinic acid type that the esterification sulfonation obtains; And it is composite with nontoxic, natural fats and oils synthetic AES and AEO-3; Have significant synergy, significantly strengthened solvability, remove agricultural residual degreasing result thereby reached ideal to fat residue residual on fat-soluble agricultural chemicals residual on the fruits and vegetables and the tableware.Main active ingredient wherein, as the fat-based tensio-active agent, its raw material is from renewable resources; Low price, molecular structure is simple, and biological degradability is good; Low to skin irritation, and acid amide type is similar with the composition of peptide bond in the human body skin protein also because of containing in the molecule-the CONH-key; Thereby has an extraordinary water-soluble and mildness; Compare with traditional petroleum chemistry based surfactants (like LAS), have the characteristics of environmental protection and safety, meet the trend of washing composition to the green low-carbon Sustainable development.And since wherein used all be natural component, therefore can the taste of fruits and vegetables not had any impact.
3. compare with common on the market organophosphorus liquid detergent, clean-out system of the present invention does not contain organophosphate, has avoided the potential environmental hazard, helps environment protection, the environmental requirement of the increasingly stringent that is in conformity with law; Simultaneously, clean-out system is as general as neutrality, has alleviated when using the stimulation to human hands skin; Clean-out system with some single kind that occur in recent years; For example ginger extract clean-out system, glucose alkyl polyglycoside extract clean-out system etc. are compared; Clean-out system of the present invention utilizes the synergy of the mutual compound generation of multiple composition, and cleaning effect is better, and the clean-out system of single component is because active restriction need add an amount of chemical industry cleansing etc. toward contact; And can't accomplish effectively to avoid secondary environmental pollution, cleaning effect is also limited.
4. each component of clean-out system of the present invention is the pure natural product, does not contain benzene, and toluene etc. are to the organic solvent of toxic elements in human body, has avoided the secondary pollution that causes because of residual, and its biological degradability and degraded product safety have greatly reduced the influence to human body and environment.Clean-out system safety non-toxic of the present invention, the fruits and vegetables after the cleaning can directly eat.
5. clean-out system of the present invention makes it to become stable, gentle water miscible sanitising agent through the proportioning of regulating activeconstituents and ancillary component; Preparing method's technology is simple; Easy to operate, need not specific equipment and the supporting facility that decontaminates, have remarkable practical value and economic and environmental benefit.
In the clean-out system as the PC 560 of moity, adopt orange oil, come from the reprocessing of orange peel etc., this had both solved the refuse pollution problem that citrus peel residue brings, and turned waste into wealth to have protected environment, had enlarged product category again, had increased added value, effect is remarkable.
Embodiment
Embodiment 1:
By weight, earlier with inorganic thickening agent 2kg, complexing agent 0.1kg is dissolved in the deionized water, and stirring and dissolving is complete; Then successively with fatty acid amide sulfo-succinic acid fat disodium 15kg, AEO (AEO-3) 5kg, polyoxyethylenated alcohol sodium sulfate (AES) 12kg; PC 560 1kg, SFD thickening material 1kg, deionized water 63.9kg mixes; Under 40～60 ℃ of temperature, under the speed of 600-1000r/min, stirred 5～10 minutes with high speed dispersor, mix formulated.
Embodiment 2:
By weight, earlier with inorganic thickening agent 4kg, complexing agent 0.2kg is dissolved in the deionized water, and stirring and dissolving is complete; Then successively with fatty acid amide sulfo-succinic acid fat disodium 18kg, AEO (AEO-3) 2kg, polyoxyethylenated alcohol sodium sulfate (AES) 15kg; PC 560 3kg, SFD thickening material 2kg, deionized water 55.8kg mixes; Under 40～60 ℃ of temperature, under the speed of 600-1000r/min, stirred 5～10 minutes with high speed dispersor, mix formulated.
Embodiment 3:
By weight, earlier with inorganic thickening agent 2kg, complexing agent 0.1kg is dissolved in the deionized water; Stirring and dissolving is complete, then successively with fatty acid amide sulfo-succinic acid fat disodium 15kg, polyoxyethylenated alcohol sodium sulfate (AES) 15kg; PC 560 1kg, SFD thickening material 1kg, deionized water 65.9kg mixes; Under 40～60 ℃ of temperature, under the speed of 600-1000r/min, stirred 5～10 minutes with high speed dispersor, mix formulated.
Embodiment 4:
By weight, earlier with inorganic thickening agent 5kg, complexing agent 0.5kg is dissolved in the deionized water; Stirring and dissolving is complete, then successively with fatty acid amide sulfo-succinic acid fat disodium 25kg, polyoxyethylenated alcohol sodium sulfate (AES) 12kg; PC 560 3kg, SFD thickening material 3kg, deionized water 51.5kg mixes; Under 40～60 ℃ of temperature, under the speed of 600-1000r/min, stirred 5～10 minutes with high speed dispersor, mix formulated.
The clean-out system of getting the above embodiment respectively cleans the apple that pesticide residue are arranged of buying on the market, cleans once back water cleaning, detects the pesticide residue in the water, finds non agricultural chemical residuum, and do not have any peculiar smell that cleaning performance is excellent.
The clean-out system of getting the foregoing description is used to clean the residual service plate of spot, and very clean after service plate cleans, the no greasy dirt in surface is residual.
The above embodiment only be used to explain the preferred realization of technical scheme of the present invention, and unrestricted the present invention only adopts such scheme.The improvement that those skilled in the art carry out understanding on the basis of essence of the present invention, substitute, equivalents etc. still belongs to protection scope of the present invention.
Claims (10)
1. a pure natural fruit and vegetable cleaning agent for dinnerware is characterized in that comprising fatty acid amide sulfo-succinic acid fat disodium, PC 560, polyoxyethylenated alcohol sodium sulfate, SFD thickening material, inorganic thickening agent, complexing agent, deionized water.
2. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 1 is characterized in that also comprising AEO.
3. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 1 is characterized in that the wherein ratio of each component, by weight meter; 15～25 parts of fatty acid amide sulfo-succinic acid fat disodiums, 1～3 part of PC 560,10～15 parts of polyoxyethylenated alcohol sodium sulfate; 1～3 part of SFD thickening material; 2～5 parts of inorganic thickening agents, 0.1～0.5 part of complexing agent, 48.5～70.9 parts of deionized waters.
4. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 2 is characterized in that the wherein ratio of each component, by weight meter; 15～20 parts of fatty acid amide sulfo-succinic acid fat disodiums, 1～3 part of PC 560,2～5 parts of AEOs (AEO-3); 10～15 parts of polyoxyethylenated alcohol sodium sulfate (AES), 1～2 part of SFD thickening material, 2～5 parts of inorganic thickening agents; 0.1～0.2 part of complexing agent, 49.8～68.9 parts of deionized waters.
5. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 1 is characterized in that said PC 560 is the orange oil that is obtained through squeezing or distillation by the pericarp of oranges and tangerines, orange, lemon.
6. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 2 is characterized in that said AEO is AEO AEO-3.
7. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 1 is characterized in that said SFD thickening material is an alkylolamide type tensio-active agent.
8. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 1 is characterized in that said inorganic thickening agent is sodium-chlor and/or ammonium chloride.
9. pure natural fruit and vegetable cleaning agent for dinnerware according to claim 1 is characterized in that said complexing agent is EDTA disodium salt or its verivate.
10. the preparation method of above-mentioned arbitrary described pure natural fruit and vegetable cleaning agent for dinnerware processes with the deionized water each component for the solvent microemulsified, comprise the steps: by weight; With inorganic thickening agent, complexing agent under agitation is dissolved in the deionized water fully, then successively with fatty acid amide sulfo-succinic acid fat disodium earlier; AEO, polyoxyethylenated alcohol sodium sulfate, PC 560; The SFD thickening material mixes with deionized water, under 40～60 ℃ of temperature; Under the speed of 600-1000r/min, stirred 5～10 minutes with high speed dispersor, mix formulated.
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| CN2012100167528A CN102604761A (en) | 2012-01-19 | 2012-01-19 | All natural fruit and vegetable tableware cleaning agent and preparation method thereof |
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| CN2012100167528A CN102604761A (en) | 2012-01-19 | 2012-01-19 | All natural fruit and vegetable tableware cleaning agent and preparation method thereof |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827712A (en) * | 2012-09-21 | 2012-12-19 | 天津宏竹科技发展有限公司 | Natural environment-friendly kitchen cleaning agent and preparation method thereof |
| CN102876479A (en) * | 2012-09-18 | 2013-01-16 | 江苏雪豹日化有限公司 | Mild-odor kitchen oil cleaner and preparation method thereof |
| CN103320237A (en) * | 2013-07-19 | 2013-09-25 | 北方民族大学 | Laundry detergent and its preparation method |
| CN103897814A (en) * | 2012-12-30 | 2014-07-02 | 武永福 | Pure natural antibacterial detergent |
| CN104862131A (en) * | 2015-06-05 | 2015-08-26 | 浙江海洋学院 | Fruit and vegetable tableware detergent based on marine fish oil and preparation method thereof |
| CN104877778A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for cooking utensil cleaning agent |
| CN106479713A (en) * | 2015-08-27 | 2017-03-08 | 西南大学 | Citrus procession industrial detergent |
| CN106939223A (en) * | 2017-03-18 | 2017-07-11 | 长沙协浩吉生物工程有限公司 | A kind of compound method of sensitive flesh special ferment fruits and vegetables cleaning agent |
| CN106987321A (en) * | 2017-04-14 | 2017-07-28 | 福建广和堂生物科技有限公司 | A kind of natural fruit and vegetables detergent containing shaddock ped, lemon and Semen Coicis extract |
| CN109234064A (en) * | 2018-09-06 | 2019-01-18 | 山西涑涑净商贸有限公司 | One kind disappears cleaning and preparation method thereof |
| CN110452781A (en) * | 2019-08-29 | 2019-11-15 | 张卓 | Essential oil ferment environment friendly dishwashing liquid |
| CN110669596A (en) * | 2019-09-04 | 2020-01-10 | 张卓 | Environment-friendly heavy oil stain cleaning agent and preparation method thereof |
| WO2022077953A1 (en) * | 2020-10-15 | 2022-04-21 | 崔万哲 | Detergent and preparation method therefor |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102876479A (en) * | 2012-09-18 | 2013-01-16 | 江苏雪豹日化有限公司 | Mild-odor kitchen oil cleaner and preparation method thereof |
| CN102827712A (en) * | 2012-09-21 | 2012-12-19 | 天津宏竹科技发展有限公司 | Natural environment-friendly kitchen cleaning agent and preparation method thereof |
| CN102827712B (en) * | 2012-09-21 | 2014-01-22 | 天津宏竹科技发展有限公司 | Natural environment-friendly kitchen cleaning agent and preparation method thereof |
| CN103897814A (en) * | 2012-12-30 | 2014-07-02 | 武永福 | Pure natural antibacterial detergent |
| CN103320237A (en) * | 2013-07-19 | 2013-09-25 | 北方民族大学 | Laundry detergent and its preparation method |
| CN104862131A (en) * | 2015-06-05 | 2015-08-26 | 浙江海洋学院 | Fruit and vegetable tableware detergent based on marine fish oil and preparation method thereof |
| CN104877778A (en) * | 2015-06-22 | 2015-09-02 | 天津博克尼科技发展有限公司 | Preparation method for cooking utensil cleaning agent |
| CN106479713A (en) * | 2015-08-27 | 2017-03-08 | 西南大学 | Citrus procession industrial detergent |
| CN106939223A (en) * | 2017-03-18 | 2017-07-11 | 长沙协浩吉生物工程有限公司 | A kind of compound method of sensitive flesh special ferment fruits and vegetables cleaning agent |
| CN106987321A (en) * | 2017-04-14 | 2017-07-28 | 福建广和堂生物科技有限公司 | A kind of natural fruit and vegetables detergent containing shaddock ped, lemon and Semen Coicis extract |
| CN109234064A (en) * | 2018-09-06 | 2019-01-18 | 山西涑涑净商贸有限公司 | One kind disappears cleaning and preparation method thereof |
| CN110452781A (en) * | 2019-08-29 | 2019-11-15 | 张卓 | Essential oil ferment environment friendly dishwashing liquid |
| CN110669596A (en) * | 2019-09-04 | 2020-01-10 | 张卓 | Environment-friendly heavy oil stain cleaning agent and preparation method thereof |
| WO2022077953A1 (en) * | 2020-10-15 | 2022-04-21 | 崔万哲 | Detergent and preparation method therefor |
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Application publication date: 20120725 |