CN103242972A - Cleaning emulsion for daily kitchen care and preparation method thereof - Google Patents
Cleaning emulsion for daily kitchen care and preparation method thereof Download PDFInfo
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- CN103242972A CN103242972A CN 201310165628 CN201310165628A CN103242972A CN 103242972 A CN103242972 A CN 103242972A CN 201310165628 CN201310165628 CN 201310165628 CN 201310165628 A CN201310165628 A CN 201310165628A CN 103242972 A CN103242972 A CN 103242972A
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Abstract
The invention discloses a cleaning emulsion for daily kitchen care and a preparation method thereof. The cleaning emulsion comprises a natural citrus plant solvent, a plant oil derivative, fatty alcohol polyether phosphate, fatty alcohol polyether, an emulsifier and de-ionized water. The cleaning emulsion disclosed by the invention has a good cleaning effect, contains natural components, is safe, nontoxic, healthy and environment-friendly, does not have strong base, is mild and non-irritant to skin and non-corrosive to utensils, has citrus fragrance, is fragrant and pleasant, can dispel unpleasant smells, is safe and efficient in production process, and has an economic value.
Description
Technical field
The present invention relates to a kind of cleaning emulsion, the cleaning emulsion in particular in the daily nursing of kitchen belongs to chemical field.
Background technology
At people's decontamination demand in daily life, on the market various sanitising agents are arranged now, generally adopt Sodium dodecylbenzene sulfonate (LAS) or Oleum Cocois alcohol amide as the decontamination activeconstituents, be equipped with an amount of auxiliary material simultaneously.In the existing detergent product, some has the ability of stronger removal greasy dirt, in actual use since degreasing power cross by force and can produce hormesis to skin, gentle inadequately, skin is caused damage, and foam is also on the low side when using, and is difficult for rinsing; The more important thing is, in order to strengthen cleaning effect, reduce production costs again simultaneously, existing sanitising agent often uses strong detergency, cheap but sodium alkyl benzene sulfonate that biological degradability is relatively poor and the tensio-active agent of nonylphenol class, perhaps contain the strong alkaline substance of higher concentration to reach clean effect preferably, perhaps add organic solvents such as various ethers, even use pungent, poisonous chemical solvents.
When general sanitising agent was used in this situation of kitchen daily cleaning, the problems referred to above were more outstanding, because kitchen cleaning is concerning household's diet health, the cleaning of every day becomes headache and stubborn problem in the life.This special relatively place in the kitchen; the existing sanitising agent of life-time service can damage HUMAN HEALTH; and it is Clean-and except the heavy oil dirt product that most kitchen cleaning articles for use are not distinguished daily nursing, and the daily cleaning work of using the product that removes the heavy oil dirt to carry out the kitchen is inappropriate.
Summary of the invention
Still the defective that lacks the cleaning supplies that are exclusively used in the kitchen daily nursing at present this area; the invention discloses a kind of kitchen daily nursing with cleaning emulsion; can be used for the daily processing of the slight dirt of kitchen range, cabinet, vent fan, sink, ceramic tile wall, kitchen glass, kitchen tools surface, dining table etc.; and it is supporting for the dirty aftertreatment of removing of heavy oil with the dirty professional clean-out system of heavy oil; has good clean effect; pungency is little simultaneously, has no side effect.
For achieving the above object, the present invention is achieved through the following technical solutions:
A kind of kitchen daily nursing comprises following compositions: natural citrus solvent, vegetable oil derivatives, poly alkyl alcohol ether phosphate, aliphatic alcohol polyether, emulsifying agent, deionized water with the cleaning emulsion.
According to different decontamination index needs, can flexible the consumption of each composition wherein, preferably, each composition consumption is, calculate with mass fraction: 5～15 parts of natural citrus solvents, 10～20 parts of vegetable oil derivatives, 1～10 part of poly alkyl alcohol ether phosphate, 5～15 parts of aliphatic alcohol polyethers, 50～80 parts of 2～10 parts of emulsifying agents and deionized waters.
Cleaning emulsion of the present invention is a kind of product of microemulsified, has fabulous perviousness, and its particle diameter is 300-800nm usually.
In the present invention, described natural citrus solvent is through squeezing or distillation and the essential oil that obtains by the citrus fruit pericarp, used citrus fruit includes but not limited to citrus such as sweet orange, orange, lemon, shaddock, orange, belong to the Rutaceae Citrus in phytology, for having the hesperidium aurantium of keratin pericarp, resulting essential oil main component is the d-limonene, is a kind of known health, the natural plant solvent of safety, and greasy dirt is had extremely strong solvency power; And the natural component that wherein contains also has the effect that suppresses microorganism growth, thereby can reach natural antibiotic, bacteriostasis efficacy.
In the present invention, described vegetable oil derivatives is the representative examples of saturated aliphatic polymkeric substance that is obtained through hydrogenation by natural plant grease, using natural plant grease to derive obtains, raw material is from renewable resources, molecular structure is simple, biological degradability is good, and is low to skin irritation, stops the harm that petroleum chemicals may bring from the source; Natural citrus solvent mixes to greasy dirt is similar with vegetable oil derivatives, and the infiltration of synergistic surfactant, emulsification, solublization can reach rapid osmotic dissolving greasy dirt, greasy dirt is wrapped up be dissolved in water, thereby reach the desirable stain effect of deoiling.
Natural plant grease described above, for example sweet oil, Oleum Cocois, plam oil, soybean wet goods, carry out the hydrogenated vegetable oil that hydrogenation obtains, normally under 150-300 degree centigrade, carry out hydrogenation reaction 40-120min and get final product under the pressure of 0.5-3MPa, used catalyzer is this area vegetable oil and fat hydrogenation catalyzer commonly used.
In the present invention, described aliphatic alcohol polyether comprises AEO-2, AEO-3, AEO-5, AEO-7, the mixture of two or more among the AEO-9, as is known to the person skilled in the art, AEO (being fatty alcohol-polyoxyethylene ether) series compound is a kind of nonionogenic tenside, has good soil removability and anti-hard water, has the broad applicability under the multiple water condition, and it is very low to the human body skin pungency, its biological degradability is good, can not impact environment, with above-mentioned vegetable oil derivatives, natural citrus solvent etc. is used in combination has significant synergistic effect.
In the present invention, described poly alkyl alcohol ether phosphate is aliphatic alcohol polyether and P
2O
5Obtain through esterification under 70 ℃ with 2: 1 ratios.As tensio-active agent, the poly alkyl alcohol ether phosphate has good wettability, emulsifying property, lyotropy and perviousness, thereby improves clean effect better.
Preferably, used aliphatic alcohol polyether has the carbon chain lengths of C8-C10.
In the present invention, described emulsifying agent is triethanolamine oleate, and it has the good emulsifying performance, can stablize the foam that produces when cleaning, and improves the decontamination cleaning performance.
By above-mentioned composition, cleaning emulsion of the present invention is able to realize good clean effect under the prerequisite of clean environment firendly, and the experiment that the applicant carries out shows that clean effect is not less than 90%.
Because cleaning emulsion of the present invention has good soil removability and security, can be used for the daily processing of surperficial dirts such as kitchen range, cabinet, vent fan, sink, ceramic tile wall, kitchen glass, kitchen tools surface, dining table, and it is supporting for the dirty aftertreatment of removing of heavy oil with the dirty professional clean-out system of heavy oil, various surfaces such as stainless steel, ceramic tile, metal, urushoil woodwork can also be used for, corrosion can be do not caused.Easy to use, effect is remarkable.
Compare with existing industrial cleaners, cleaning emulsion of the present invention does not contain alkaline matters such as caustic soda, yellow soda ash, water glass, and it is neutral that pH is, non-stimulated to user's skin; The present invention simultaneously cleans that citrus solvent in the emulsion itself has acid and fresh aromatic odour not only can expel intense strain and pressure, improve the caused insomnia of anxiety, and has the effect of dispelling abnormal flavor.
On the basis of the above, the present invention further also provides the preparation method of described cleaning emulsion, comprise the steps: citrus solvent, vegetable oil derivatives, poly alkyl alcohol ether phosphate, aliphatic alcohol polyether and emulsifying agent, after stirring and dissolving is complete, adds quick stirring of deionized water again and carry out microemulsified.
In above-mentioned preparation method, the preparation method of the not concrete restriction citrus solvent of applicant, poly alkyl alcohol ether phosphate etc., no matter adopt which kind of preparation method, namely can be used for the present invention as long as can obtain described composition, preferably, the citrus solvent can prepare in the following way: with the mixture of citrus fruits through obtaining after the juice extractor, the oil-water mixture that the back pericarp of perhaps squeezing the juice obtains through mechanical process, after standing demix is removed most of water, more both must this extract through the refining centrifugation of two-stage; Wherein used poly alkyl alcohol ether phosphate, aliphatic alcohol polyether and emulsifying agent etc. all are the existing materials in this area, can use the conventional chemical prepared, also can directly buy from the market.
Adopt above-mentioned preparation method, preparation method's technology is simple, and is easy to operate, need not specific equipment and the supporting facility that decontaminates, and has remarkable practical value and economic and environmental benefit; And the citrus solvent comes from the reprocessing of peel of Citrus reticulata Blanco etc., has both solved the refuse pollution problem that citrus peel residue brings, and turns waste into wealth and has protected environment, has enlarged product category again, has increased added value, and effect is remarkable.
Embodiment
The following embodiment that provides only be used for the preferred realization of explanation technical solution of the present invention, and unrestricted the present invention only adopts following proposal.Those skilled in the art still belong to protection scope of the present invention at understand on the basis of essence of the present invention the raw materials used improvement of carrying out, substitute, equivalents etc.
In following example, the used vegetable oil derivatives of embodiment 1-3 is respectively the hydrogenated derivatives of soybean oil, Oleum Cocois, Viscotrol C, all can buy from the market, and its preparation method also is familiar with by those skilled in the art.
Embodiment 1:
A kind of described kitchen daily nursing preparation method of cleaning emulsion, step is as follows:
Add 5 parts of natural citrus solvents, 10 parts of vegetable oil derivatives, 5 parts of poly alkyl alcohol ether phosphates, 10 parts of aliphatic alcohol polyethers by weight successively, 3 parts of emulsifying agents, it is complete to carry out stirring and dissolving under 40-50 ℃, adds 67 parts of quick stirrings of deionized water again and carries out microemulsified.
The kitchen daily nursing of present embodiment preparation is with cleaning emulsion, and its clean effect is remarkable, and according to the examination criteria detection of detersive power in the QB/T4348-2012 kitchen oil scale washing agent, its detersive power reaches 94.9.
Embodiment 2:
A kind of described kitchen daily nursing preparation method of cleaning emulsion, step is as follows:
Add 10 parts of natural citrus solvents, 5 parts of vegetable oil derivatives, 3 parts of poly alkyl alcohol ether phosphates, 15 parts of aliphatic alcohol polyethers by weight successively, 5 parts of emulsifying agents, it is complete to carry out stirring and dissolving under 40-50 ℃, adds 62 parts of quick stirrings of deionized water again and carries out microemulsified.
The kitchen daily nursing of present embodiment preparation is with cleaning emulsion, and its clean effect is remarkable, and according to the examination criteria detection of detersive power in the QB/T4348-2012 kitchen oil scale washing agent, its detersive power reaches 96.2.
Embodiment 3
A kind of described kitchen daily nursing preparation method of cleaning emulsion, step is as follows:
Add 15 parts of natural citrus solvents, 10 parts of vegetable oil derivatives, 8 parts of poly alkyl alcohol ether phosphates, 7 parts of aliphatic alcohol polyethers by weight successively, 10 parts of emulsifying agents, it is complete to carry out stirring and dissolving under 40-50 ℃, adds 50 parts of quick stirrings of deionized water again and carries out microemulsified.
The kitchen daily nursing of present embodiment preparation is with cleaning emulsion, and its clean effect is remarkable, and according to the examination criteria detection of detersive power in the QB/T4348-2012 kitchen oil scale washing agent, its detersive power reaches 94.7.
Simultaneously, the applicant has also carried out the skin irritation test, experimental technique is divided into three groups for engaging 30 housewifves, every group of 10 people, try out the product of above-described embodiment 1-3 respectively, use every day cleaning emulsion of the present invention that the kitchen range top, cabinet, dining table, kitchen tools etc. in the kitchen are cleaned, be 30min average duration of contact every day, used for two weeks continuously.Two week back viewing test personnel's arm skin also records its subjective feeling, and experimental result is that testing crew is not all felt pungency, no sense of discomfort; Compare no change before observing its skin and testing, show that product of the present invention has good security.
Claims (9)
1. a kitchen daily nursing is characterized in that comprising following compositions: natural citrus solvent, vegetable oil derivatives, poly alkyl alcohol ether phosphate, aliphatic alcohol polyether, emulsifying agent, deionized water with the cleaning emulsion.
2. cleaning emulsion according to claim 1, it is characterized in that each composition consumption is, calculate with mass fraction: 5～15 parts of natural citrus solvents, 10～20 parts of vegetable oil derivatives, 1～10 part of poly alkyl alcohol ether phosphate, 5～15 parts of aliphatic alcohol polyethers, 50～80 parts of 2～10 parts of emulsifying agents and deionized waters.
3. cleaning emulsion according to claim 2 is characterized in that described particle size of emulsion is 300-800nm.
4. cleaning emulsion according to claim 1 is characterized in that described natural citrus solvent is the essential oil that is obtained through squeezing or distillation by the citrus fruit pericarp.
5. cleaning emulsion according to claim 1 is characterized in that described vegetable oil derivatives is the representative examples of saturated aliphatic polymkeric substance that is obtained through hydrogenation by natural plant grease.
6. cleaning emulsion according to claim 1 is characterized in that described aliphatic alcohol polyether comprises AEO-2, AEO-3, AEO-5, AEO-7, the mixture of two or more among the AEO-9.
7. cleaning emulsion according to claim 1 is characterized in that described poly alkyl alcohol ether phosphate is aliphatic alcohol polyether and P
2O
5Obtain through esterification at 70 ℃.
8. cleaning emulsion according to claim 1 is characterized in that described emulsifying agent is triethanolamine oleate.
9. the preparation method of the described cleaning emulsion of above-mentioned arbitrary claim, it is characterized in that comprising the steps: with citrus solvent, vegetable oil derivatives, poly alkyl alcohol ether phosphate, aliphatic alcohol polyether and emulsifying agent, after stirring and dissolving is complete, add deionized water again in high speed dispersor, with the speed stirring 5-8min of 400-900r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201310165628 CN103242972A (en) | 2013-05-08 | 2013-05-08 | Cleaning emulsion for daily kitchen care and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201310165628 CN103242972A (en) | 2013-05-08 | 2013-05-08 | Cleaning emulsion for daily kitchen care and preparation method thereof |
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| CN103242972A true CN103242972A (en) | 2013-08-14 |
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| CN 201310165628 Pending CN103242972A (en) | 2013-05-08 | 2013-05-08 | Cleaning emulsion for daily kitchen care and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987387A (en) * | 2017-03-19 | 2017-07-28 | 长沙协浩吉生物工程有限公司 | A kind of compound method of stainless steel ware ferment cleaning solution |
| CN107523437A (en) * | 2017-08-23 | 2017-12-29 | 杭州兰茜化妆品有限公司 | A kind of cabinet conditioning liquid |
| CN112980601A (en) * | 2019-12-17 | 2021-06-18 | 中国石油天然气股份有限公司 | Heavy oil pollution oil pipeline cleaning agent and application thereof |
-
2013
- 2013-05-08 CN CN 201310165628 patent/CN103242972A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987387A (en) * | 2017-03-19 | 2017-07-28 | 长沙协浩吉生物工程有限公司 | A kind of compound method of stainless steel ware ferment cleaning solution |
| CN107523437A (en) * | 2017-08-23 | 2017-12-29 | 杭州兰茜化妆品有限公司 | A kind of cabinet conditioning liquid |
| CN112980601A (en) * | 2019-12-17 | 2021-06-18 | 中国石油天然气股份有限公司 | Heavy oil pollution oil pipeline cleaning agent and application thereof |
| CN112980601B (en) * | 2019-12-17 | 2022-10-04 | 中国石油天然气股份有限公司 | Heavy oil pollution oil pipeline cleaning agent and application thereof |
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Application publication date: 20130814 |