CN108060030A - A kind of Closestool cleanser and preparation method thereof - Google Patents
A kind of Closestool cleanser and preparation method thereof Download PDFInfo
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- CN108060030A CN108060030A CN201711418068.1A CN201711418068A CN108060030A CN 108060030 A CN108060030 A CN 108060030A CN 201711418068 A CN201711418068 A CN 201711418068A CN 108060030 A CN108060030 A CN 108060030A
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- closestool
- essential oil
- fruits
- closestool cleanser
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/24—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- Chemical & Material Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of Closestool cleanser and preparation method thereof, the Closestool cleanser includes following substance：Methyl sodiosul foaliphatate, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether, fungicide, sodium acid carbonate, light-coloured vinegar, fruits and vegetables zymotic fluid, essential oil, 75% ethyl alcohol, distilled water.Detergent of closet agent prescription provided by the invention is mild, compared with prior art, can quickly remove toilet grime and play an important role of bacteriostat degerming, and one punching of a spray can purify closestool, and fast and easy is succinct.
Description
Technical field
The present invention relates to a kind of Closestool cleansers and preparation method thereof.
Background technology
Closestool is common daily necessities and the most easy place for growing dirt and bacterium, detergent of closet in people's life
Agent is to switch to the cleaning formulation of toilet designs.Presently commercially available the mostly of toilet bowl cleaning agent use are cheap, toxic and not degradable
Inorganic acid and surfactant based on ingredient be made, except pollute environment, the health of people can also be caused centainly
Influence.
The content of the invention
For above deficiency, the present invention provides a kind of Closestool cleanser and preparation method thereof, by adding in Chinese medicinal plant
Type bacteriostatic agent, and mild formula is used, the Closestool cleanser of antibacterial delicate fragrance type is prepared, to the cleaning effect of hand
Substantially, hand skin will not be stimulated, there is moisturizing moisturizing and antibacterial, and is easy to degrade, it is environmentally protective for environment.
The technical solution that the present invention takes is：
A kind of Closestool cleanser includes the raw material of following parts by weight：
Further, it is preferable to it is the raw material for including following parts by weight：
The methyl sodiosul foaliphatate is carbochain in C14/16Or C14Following methyl sodiosul foaliphatate, it is relatively more suitable
For being used as surfactant in liquid detergent.
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1：(0.3~0.6)：(0.8~
1.2) form.The effect of the fungicide sterilization of such proportioning is stronger, if proportioning can reduce the effect of sterilization outside this scope
Fruit.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight：5~10 parts of aloe, 10~30 parts of pomelo peel, orange peel
10~30 parts, 15~25 parts of lemon.
The preparation method of the fruits and vegetables zymotic fluid is：Each raw material of formula ratio is crushed, 5~10 times of water is added in and carries out anaerobism
Fermentation 7~10 days.Above each fruits and vegetables generate a variety of organic acids after anaerobic fermentation, can remove remaining urine on closestool
Alkali.
The essential oil includes Rosa Damascana, clove oil, Lavender, refined jasmine oil, chamomile essential oil, lemon extract
Oil, in one's early teens orange essential oil, one kind in essential oil.
The present invention also provides the preparation method of the Closestool cleanser, the preparation method comprises the following steps：
(1) distilled water of formula ratio and 75% ethyl alcohol are mixed and heated to 45~55 DEG C, added thereto while agitating
Enter methyl sodiosul foaliphatate, neopelex, lauramide third class amine oxide, the aliphatic alcohol polyethenoxy of formula ratio
Ether, heating stirring is to being completely dissolved, and natural cooling；
(2) sodium acid carbonate, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added in into step (1), is mixed evenly；
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that can obtain the closestool clear
Clean dose.
In the formula of Closestool cleanser provided by the invention, by the anion, cation, non-ionic surface of low irritant
Activating agent compounds, and has fabulous synergistic function, has stronger dirt-removing power, and with certain bacteriostasis.Fruit
Vegetable zymotic fluid, light-coloured vinegar, sodium acid carbonate mating reaction can depth remove closestool in tough stains.
The addition of essential oil improves the faint scent degree of Closestool cleanser, effectively purifies the air of toilet.
The formula of Closestool cleanser provided by the invention is mild, can be made respectively as solvent using 75% ethyl alcohol and distilled water
Raw material fully dissolves, and obtained product viscosity is suitable, and each raw material mutual cooperation can effectively play the work of antibacterial decontamination de-sludging
With, and it is easy to safety and environmental protection of degrading.
Compared with prior art, Closestool cleanser provided by the invention is with quick removal toilet grime and with suppression
The effect of bacterium degerming, one punching of a spray can purify closestool, and fast and easy is succinct.
Specific embodiment
With reference to embodiment, the present invention is described in detail.
Embodiment 1
A kind of Closestool cleanser includes the raw material of following parts by weight：
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1：0.5：1.0 composition.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight：8 parts of aloe, 15 parts of pomelo peel, 15 parts of orange peel, lemon
20 parts of lemon；Each raw material of formula ratio is crushed, 8 times of water progress anaerobic fermentations is added in and can obtain the fruits and vegetables zymotic fluid in 10 days.
The preparation method of the Closestool cleanser is：
(1) distilled water of formula ratio and 75% ethyl alcohol are mixed and heated to 50 DEG C, add in match somebody with somebody thereto while agitating
The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether,
Heating stirring is to being completely dissolved, and natural cooling；
(2) sodium acid carbonate, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added in into step (1), is mixed evenly；
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that can obtain the closestool clear
Clean dose.
Embodiment 2
A kind of Closestool cleanser includes the raw material of following parts by weight：
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1：0.3：1.2 composition.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight：5 parts of aloe, 10 parts of pomelo peel, 10 parts of orange peel, lemon
15 parts of lemon；Each raw material of formula ratio is crushed, 5 times of water progress anaerobic fermentations is added in and can obtain the fruits and vegetables zymotic fluid in 10 days.
The preparation method of the Closestool cleanser is：
(1) distilled water of formula ratio and 75% ethyl alcohol are mixed and heated to 55 DEG C, add in match somebody with somebody thereto while agitating
The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether,
Heating stirring is to being completely dissolved, and natural cooling；
(2) sodium acid carbonate, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added in into step (1), is mixed evenly；
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that can obtain the closestool clear
Clean dose.
Embodiment 3
A kind of Closestool cleanser includes the raw material of following parts by weight：
The fungicide is by trichlorine is non-, benzalkonium bromide, dimethyl oxazolidine are according to weight ratio 1：0.6：0.8 composition.
The fruits and vegetables zymotic fluid includes the raw material of following parts by weight：10 parts of aloe, 30 parts of pomelo peel, 30 parts of orange peel, lemon
25 parts of lemon；Each raw material of formula ratio is crushed, 10 times of water progress anaerobic fermentations is added in and can obtain the fruits and vegetables zymotic fluid in 7 days.
The preparation method of the Closestool cleanser is：
(1) distilled water of formula ratio and 75% ethyl alcohol are mixed and heated to 45 DEG C, add in match somebody with somebody thereto while agitating
The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether,
Heating stirring is to being completely dissolved, and natural cooling；
(2) sodium acid carbonate, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added in into step (1), is mixed evenly；
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly that can obtain the closestool clear
Clean dose.
Comparative example 1
Other simply wherein eliminate lauramide third class amine oxide, fatty alcohol polyoxyethylene ether ingredient with embodiment 1.
Comparative example 2
Other simply wherein eliminate fruits and vegetables zymotic fluid with embodiment 1.
Comparative example 3
Other are with embodiment 1, and simply the proportioning of fungicide therein is that trichlorine is non-：Benzalkonium bromide：Dimethyl dislikes=1：
0.1：1.4.
After the Closestool cleanser cleaning closestool obtained using Examples 1 to 3, comparative example 1~3, quickly surveyed using bacterium
Test paper detects toilet bowl interior, finds Examples 1 to 3 and the toilet bowl interior noresidue bacterium that comparative example 1~2 cleans, and compares
The toilet bowl interior cleaned compared with example 3 has slightly remaining bacteria.
Choose the stain removal and scale removal for the Closestool cleanser that 120 volunteers obtain various embodiments of the present invention and comparative example
Property evaluated, 10 points are best result, and evaluation result is as shown in table 1：
Table 1
The above-mentioned detailed description carried out to a kind of Closestool cleanser and preparation method thereof with reference to embodiment, be it is illustrative and
It is not limited, several embodiments can be included according to limited scope, therefore in the case where not departing from present general inventive concept
Change and modification, should belong within protection scope of the present invention.
Claims (8)
1. a kind of Closestool cleanser, which is characterized in that include the raw material of following parts by weight：
2~8 parts of methyl sodiosul foaliphatate；
4~9 parts of neopelex；
2~10 parts of lauramide third class amine oxide；
3~9 parts of fatty alcohol polyoxyethylene ether；
6~16 parts of fungicide；
5~10 parts of sodium acid carbonate；
10~15 parts of light-coloured vinegar；
15~30 parts of fruits and vegetables zymotic fluid；
0.5~3 part of essential oil；
75% 25~40 parts of ethyl alcohol；
38~65 parts of distilled water.
2. Closestool cleanser according to claim 1, which is characterized in that include the raw material of following parts by weight：
5 parts of methyl sodiosul foaliphatate；
6 parts of neopelex；
5 parts of lauramide third class amine oxide；
7 parts of fatty alcohol polyoxyethylene ether；
8 parts of fungicide；
7 parts of sodium acid carbonate；
12 parts of light-coloured vinegar；
22 parts of fruits and vegetables zymotic fluid；
2 parts of essential oil；
75% 30 parts of ethyl alcohol；
50 parts of distilled water.
3. Closestool cleanser according to claim 1 or 2, which is characterized in that the methyl sodiosul foaliphatate is carbochain
In C14/16Or C14Following methyl sodiosul foaliphatate.
4. Closestool cleanser according to claim 1 or 2, which is characterized in that the fungicide is by trichlorine is non-, benzene pricks bromine
Ammonium, dimethyl oxazolidine are according to weight ratio 1：(0.3~0.6)：(0.8~1.2) form.
5. Closestool cleanser according to claim 1 or 2, which is characterized in that the fruits and vegetables zymotic fluid includes following heavy
Measure the raw material of part：5~10 parts of aloe, 10~30 parts of pomelo peel, 10~30 parts of orange peel, 15~25 parts of lemon.
6. Closestool cleanser according to claim 4, which is characterized in that the preparation method of the fruits and vegetables zymotic fluid is：It will
Each raw material of formula ratio crushes, and adds in 5~10 times of water and carries out anaerobic fermentation 7~10 days.
7. Closestool cleanser according to claim 1 or 2, which is characterized in that the essential oil includes Rosa Damascana, cloves essence
Oil, Lavender, refined jasmine oil, chamomile essential oil, lemon, in one's early teens orange essential oil, one kind in essential oil.
8. the preparation method of Closestool cleanser according to claim 1 or 2, which is characterized in that the preparation method includes
Following steps：
(1) distilled water of formula ratio and 75% ethyl alcohol are mixed and heated to 45~55 DEG C, add in match somebody with somebody thereto while agitating
The methyl sodiosul foaliphatate just measured, neopelex, lauramide third class amine oxide, fatty alcohol polyoxyethylene ether,
Heating stirring is to being completely dissolved, and natural cooling；
(2) sodium acid carbonate, light-coloured vinegar, the fruits and vegetables zymotic fluid of formula ratio are added in into step (1), is mixed evenly；
(3) fungicide and essential oil of formula ratio will be added in step (2), is mixed evenly and can obtain the detergent of closet
Agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711418068.1A CN108060030A (en) | 2017-12-25 | 2017-12-25 | A kind of Closestool cleanser and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711418068.1A CN108060030A (en) | 2017-12-25 | 2017-12-25 | A kind of Closestool cleanser and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108060030A true CN108060030A (en) | 2018-05-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711418068.1A Withdrawn CN108060030A (en) | 2017-12-25 | 2017-12-25 | A kind of Closestool cleanser and preparation method thereof |
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| Country | Link |
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| CN (1) | CN108060030A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109456859A (en) * | 2018-11-16 | 2019-03-12 | 怀化学院 | A kind of natural cleaning agent and preparation method thereof |
| CN114736742A (en) * | 2022-05-10 | 2022-07-12 | 珠海市合顺兴日化股份有限公司 | Novel toilet bowl cleaning agent and preparation method thereof |
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2017
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109456859A (en) * | 2018-11-16 | 2019-03-12 | 怀化学院 | A kind of natural cleaning agent and preparation method thereof |
| CN114736742A (en) * | 2022-05-10 | 2022-07-12 | 珠海市合顺兴日化股份有限公司 | Novel toilet bowl cleaning agent and preparation method thereof |
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