KR20090111025A - Composition of cleaning agent - Google Patents

Abstract

PURPOSE: A composition of cleaning agent is provided to ensure anti-bacterial effect and offensive odor elimination and improve environment. CONSTITUTION: A composition of cleaning agent comprise: 2-13 weight% of extract selected from orange peel extract, mixture extract of cucumber and jujube, and mixture extract of jujube, Epimedium Koreanum Nakai and Poria cocas Wolf.; 2-13 weight% of vegetable oil; 4-20 weight% of anionic surfactant; 2-20 weight% of spirit; 0.1-8 weight% of poly(3,4- ethylenedioxy thiophene), 0.01-20 weight% of sterilizing agent; 0.1-10 weight% of antiseptic; and 26.5-62.5 weight% of water.

Description

Composition of cleaning agent

The present invention relates to a composition of the cleaning agent, and more particularly to a composition of the cleaning composition composed of a nature-friendly composition.

In general, when people live, they pollute things around them, or things around them are caused by natural phenomena. Various dusts, fats, oil pollution, oil contamination of protein, and oil pollution are the main pollutants. Most of the detergents used to remove them include organic solvents, which not only have an adverse effect on the environment, but also have a problem of degrading skin stability and surface and adversely affecting the natural environment and the human body.

Especially, cleaning agents for removing various pollutants in kitchens, home appliances, office equipment, and indoors do not use environmentally friendly solvents such as alcohol and water, causing human, air, and water pollution, and they are inferior in cleanability and masking. Most of them used irritating scents for).

Accordingly, an object of the present invention is to provide a composition of a detergent that is environmentally friendly and excellent in cleaning power, antistatic and anti-corrosion, antibacterial and deodorizing power.

In order to achieve the above object, the present invention is any one selected from the tangerine peel extract, a mixed extract of cucumber and jujube, a mixed extract of jujube and trichophyte and baekbokyeong, 2 to 13% by weight, vegetable oil 2 to 13% by weight, anion 4-20 wt% of surfactant, 2-20 wt% of alcohol, 0.1-8 wt% of poly (3,4-ethylenedioxythiophene), 0.01-20 wt% of antibacterial agent, 0.1-10 wt% of antiseptic, 0.05 ~ deodorant It provides a composition of the cleaning agent, characterized in that the composition is composed of 10% by weight and 26.5 to 62.5% by weight of water.

The present invention necessarily includes any one selected from a tangerine peel extract, a mixed extract of cucumber and jujube, a mixed extract of jujube and trigeminal vinegar and Baekbokryeong, which is harmless to the human body because it is faster to decompose than chemical solvents and has excellent cleaning power. Because I am. The present invention includes 2 to 13% by weight of any one selected from the tangerine peel extract, a mixed extract of cucumber and jujube, a mixed extract of jujube and trigeminal vinegar and Baekbokryeong, if less than 2% by weight, low cleaning power If it contains more than 13% by weight, problems arise in mixing the compositions of the detergent.

On the other hand, the present invention includes a vegetable oil, because the vegetable oil is hypoallergenic to the human body to remove oily contaminants and improve the micro-gap penetration. The present invention includes 2 to 13% by weight of vegetable oil, when containing less than 2% by weight, the effect of removing oily contaminants is low, when it contains more than 13% by weight, during the mixing of the composition of the cleaning agent A problem arises.

The vegetable oil used in the present invention is not limited to a specific kind, but preferably castor oil, camellia oil, olive oil, macadamia nut oil, coconut oil, jojoba oil, sweet almond oil, dew point oil, grape seed oil, avocado One of the oil and apricot seed oil is good, because it is harmless to the human body and excellent in cleaning of oily contaminants.

On the other hand, the present invention includes an anionic surfactant, the anionic surfactant improves the microgap penetration force of the cleaning agent of the present invention, lowers the interfacial tension and imparts stability. The present invention comprises 4 to 20% by weight of anionic surfactant, when it contains less than 4% by weight, the composition of the detergent is unstable because it does not mix well, when it contains more than 20% by weight, surfactant The rate is good but there is a problem that can not exhibit the efficacy of the detergent pursuant to the present invention because other components are used relatively less.

The anionic surfactant used in the present invention is not limited to a specific kind, but is preferably any one selected from lauryl ether sulfate salt or xylene sulfate salt. This is because the effect is large.

On the other hand, the present invention includes alcohol, alcohol is a fermented grain alcohol, excellent sterilization effect and cleaning effect, and help to mix the composition of the cleaning agent of the present invention, in particular, water and vegetable oil to help mix the stability of the cleaning agent To give. The present invention contains 2 to 20% by weight of alcohol, but less than 2% by weight, it is difficult to mix between the composition of the detergent, when containing more than 20% by weight, using the detergent as a strong smell of alcohol Difficulties arise.

On the other hand, the present invention includes a poly (3,4-ethylene dioxy thiophene), because it is harmless to the human body while preventing static and corrosion. The present invention comprises 0.1 to 8% by weight of poly (3,4-ethylene dioxythiophene), but when it contains less than 0.1% by weight, the antistatic and corrosion protection effect is low, when more than 8% by weight The cleaning power of the present invention can be reduced.

On the other hand, the present invention includes an antimicrobial agent, which serves to sterilize bacteria or bacteria when using the composition of the cleaning agent of the present invention. The present invention contains 0.1 to 20% by weight of the antimicrobial agent, when included in less than 0.1% by weight, the antimicrobial effect is insignificant, when it exceeds 20% by weight impairs the quality of the cleaning agent.

The antimicrobial agent used in the present invention is not limited to a specific kind, but preferably, any one selected from eochochocho extract, green tea extract, grapefruit extract, leek extract, mugwort extract, wood vinegar solution, bactericidal effect of bacteria or bacteria Is because it is excellent and harmless to the human body because it is derived from the plant.

On the other hand, the present invention includes a preservative, in order to solve the problem that the period of use is shortened due to the components derived from the plant contained in the composition of the cleaning agent of the present invention. The present invention includes 0.1 to 10% by weight of preservatives, when less than 0.1% by weight because the antiseptic effect is insignificant, when it contains more than 10% by weight, the efficiency is lowered.

Although the preservative used for this invention is not limited to a specific kind, Preferably it is any one chosen from the compound of methyl paraoxybenzoate, methylchloroisothiazolinone, and methylisothiazolinone.

On the other hand, this invention includes a deodorant, in order to remove odor when using the composition of the cleaning agent of this invention. Although the present invention contains 0.05 to 10% by weight of the deodorant, when contained in less than 0.05% by weight, the effect of removing the odor is insignificant, when it exceeds 10% by weight, the economic efficiency is lowered.

Deodorant used in the present invention is not limited to a specific kind, but preferably any one or a mixture thereof selected from persimmon leaf extract, dermis extract, octagonal extract, guchi extract, Jasomi extract, It is because it is harmless and has excellent deodorizing effect without generating pollution.

On the other hand, water imparts stability to the cleaning agent while cleaning the polar contaminants, and in the present invention contains 26.5 ~ 62.5% by weight, when containing less than 26.5% by weight, the cleaning power is lowered and contains 62.5% by weight The concentration of the cleaning agent of the present invention is lowered, causing a problem that the cleaning power is lowered.

As described above, the composition of the detergent of the present invention exhibits excellent cleaning power, antistatic and anti-corrosion, antibacterial and deodorizing power, and is harmless to the human body because it is environmentally friendly, and may improve the working environment.

In addition, the composition of the present cleaning agent is effective because it can be processed into various types of cleaning agents such as the cleaning agent used as the liquid itself or the cleaning agent used for spraying.

Hereinafter, the configuration and operation of the present invention will be described in more detail with reference to the following examples, but the scope of the present invention is not limited to the following examples, and includes modifications of equivalent technical spirit.

< Example  1> detergent cleaner

The composition of the detergent was prepared.

First, 10 g of apricot seed oil was slowly added to 43 g of water, and then 8 g of tangerine peel extract was added slowly with stirring. 10 g of alcohol was added to the solution to which the tangerine peel extract was added, 6 g of poly (3,4-ethylene dioxythiophene) was added and stirred, followed by addition and stirring of 10 g of lauryl ether sulfate salt (SLES), followed by grapefruit. 6 g of extract, 2 g of methyl paraoxyacetate and 5 g of persimmon leaf extract were added and stirred to prepare a detergent.

< Example  2> cleaning agent

First, 11 g of camellia oil was slowly added to 47 g of water, and then 9 g of a mixed extract of cucumber and jujube was added slowly with stirring. 10 g of alcohol was added to the solution containing the mixed extract of cucumber and jujube, 4 g of poly (3,4-ethylene dioxythiophene) was added and stirred, followed by 8 g of xylene sulfate salt, followed by stirring. 7g, 2 g of methylchloroisothiazolinone, and 2 g of dermis extract were added, and it stirred and prepared the washing | cleaning agent.

< Example  3> detergent manufacturing

First, 10 g of olive oil was slowly added to 47 g of water, and then 10 g of jujube, Trigeminal herb and mixed extract of Baekbokryeong were added slowly with stirring. 10 g of alcohol was added to the solution to which the jujube, trigeminal leaf vinegar and baekbok yeong mixed extract were added, 4 g of poly (3,4-ethylene dioxythiophene) was added and stirred, and then 10 g of xylene sulfate salt was added and stirred, 5 g of green tea extract, 2 g of methylchloroisothiazolinone, and 2 g of octagonal extract were added and stirred to prepare a detergent.

< Comparative example  1> Preparation of detergents (mandarin peel extract, mixed extract of cucumber and jujube, jujube and trilobite vinegar and Baekbokyeong  Does not contain any one selected from mixed extracts)

10 g of apricot seed oil was added to 48 g of water with gentle stirring, then 12 g of alcohol and 7 g of poly (3,4-ethylene dioxythiophene) were added and stirred, followed by 10 g of lauryl ether sulfate salt (SLES). After adding and stirring, 6 g of grapefruit extract, 2 g of methyl paraoxyacetic acid, and 5 g of persimmon leaf extract were added to the mixture, followed by stirring to prepare a detergent.

< Comparative example  2> Manufacture of detergent Poly (3,4-ethylenedioxythiophene))  Not included)

First, 13 g of camellia oil was slowly added to 47 g of water, and then 10 g of the mixed extract of cucumber and jujube were added slowly with stirring. 10 g of alcohol was added to the solution to which the mixed extract of cucumber and jujube was added and stirred. Then, 8 g of xylene sulfate salt was added and stirred, followed by 7 g of leek extract, 3 g of methylchloroisothiazolinone, and 2 g of dermis extract. Agitated to prepare a detergent.

< Comparative example  3> Cleaner preparation (does not contain antimicrobial)

First, 11 g of apricot seed oil was slowly added to 44 g of water, and then 10 g of tangerine peel extract was added slowly with stirring. 10 g of alcohol was added to the solution to which the tangerine peel extract was added, 6 g of poly (3,4-ethylene dioxy thiophene) was added and stirred, and then 10 g of lauryl ether sulfate salt (SLES) was added and stirred, followed by para 3 g of methyl oxia benzoate and 6 g of persimmon leaf extract were added, and the mixture was stirred to prepare a detergent.

< Comparative example  4> Manufacture of detergent Deodorant  Not included)

First, 11 g of camellia oil was slowly added to 49 g of water, and then 9 g of a mixed extract of cucumber and jujube was added slowly with stirring. 10 g of alcohol was added to the solution containing the mixed extract of cucumber and jujube, 4 g of poly (3,4-ethylene dioxythiophene) was added and stirred, followed by 8 g of xylene sulfate salt, followed by stirring. 7g and 2g of methylchloroisothiazolinones were added and stirred, and the washing | cleaning agent was prepared.

< Experimental Example  1> Detergent

The cleaning powers of Examples 1, 2 and 3 and Comparative Example 1 were measured.

To evaluate detergency, the composition stock solution was sprayed three times using a common spray gun onto a glass plate coated with a 30 cm long by 30 cm contaminant, and then wiped ten times with a dry tissue. A consumer survey (30 people surveyed) on the transparency of the glass surface was conducted according to the 5-point measurement method (1 point: no cleaning power, 3 points: a little cleaning power, 5 points: very good cleaning power). .

Example 1 Example 2 Example 3 Comparative Example 1 Detergency rating 4.6 4.5 4.7 3.4

As a result of measuring the cleaning power, Examples 1, 2, and 3 containing any one selected from a tangerine peel extract, a mixed extract of cucumber and jujube, a mixed extract of jujube and trigeminal leaf vinegar and Baekbokryeong showed high cleaning power, Comparative Example 1, which does not contain an extract, showed low cleaning power.

From the above results, the present invention was confirmed that the cleaning power must be included at least any one selected from the tangerine bark extract, the mixed extract of cucumber and jujube, the mixed extract of jujube and trigeminal vinegar and Baekbokryeong.

< Experimental Example  2> Static electricity and corrosion Prevention  Measure

The static electricity and corrosion protection of Examples 1, 2 and 3 and Comparative Example 2 were measured.

The antistatic power was sprayed 3g of the detergent stock solution to the surface of the computer monitor area about 50 × 50cm, then wiped with a towel and the surface resistance was measured after 1 minute. Humidity was 50 ± 5% and temperature was 25 ° C., and the surface resistance meter used was Surface Resistance Meter SRM 110 (manufactured by Wolfgang Warmbier) (3; surface resistance value 1010-1012; decay immediately after charging, 2; Surface resistance of 1012 to 1013; gradually decay after charging; 1; surface resistance of 1013 or more; static charge accumulates).

For corrosion protection, immerse the aluminum specimen in 150g of the detergent stock solution and leave it in a dry oven at 60 ° C for 1 day (24 hours), then take out the aluminum specimen, wash it with distilled water, dry it with a dryer, and visualize the corrosion state. Evaluated. A consumer survey (30 people surveyed) on the degree of corrosion was made according to the five-point measurement method. The measuring method was judged according to the five-point measuring method (one point: severe corrosion, three points: some corrosion, five points: no corrosion).

Example 1 Example 2 Example 3 Comparative Example 2 Antistatic power 3 3 3 One Corrosion protection 4.8 4.9 4.9 2.3

As a result of measuring the static electricity and the corrosion protection, Examples 1, 2, 3 showed excellent static and corrosion protection, while Comparative Example 2 was low.

From the above results, it can be seen that in the composition of the present invention, poly (3,4-ethylene dioxythiophene) should be included to prevent static electricity and corrosion. I could confirm it.

< Experimental Example  3> Antimicrobial measurement

The antimicrobial properties of Examples 1, 2 and 3 and Comparative Example 3 were measured.

As a standard strain, Bacillus sp. CK-1 was used. After nourishing juicy medium (Difco) was shaken for 18 hours at 37 ℃, 150rpm and used for the test by adjusting the number of bacteria by dilution if necessary. In order to evaluate the antimicrobial activity of the composition of each detergent was diluted 10 times, 50 times, 100 times (v / v) with purified water to evaluate the antimicrobial activity as follows. That is, Bacillus sp. 50 μl of CK-1 bacteria culture was evenly spread, and 20 μl of each of the diluted detergent compositions was quantitated and Bacillus sp. Antimicrobial activity was evaluated as follows by comparing the size of the bacterial growth inhibitory rings formed by incubating the CK-1 bacteria on a juicy nutrient solid medium at regular intervals and incubating at 37 ° C. for 24 hours. (Triangle | delta): When 50% or more die, x: 50% or less killing or antibacterial effect).

Example 1 Example 2 Example 3 Comparative Example 3 Antimicrobial activity 10 times ○ ○ ○ △ 50 times ○ ○ ○ × 100 times ○ ○ ○ ×

As a result of measuring the antimicrobial activity, Examples 1, 2, and 3 were excellent in antimicrobial activity, while Comparative Example 3 was low.

From the above results, it was found that in the composition of the present invention, the antimicrobial agent exhibited an excellent antimicrobial effect, and the excellent antimicrobial activity of the present invention was also confirmed.

< Experimental Example  4> Deodorant  Measure

The deodorizing powers of Examples 1, 2 and 3 and Comparative Example 4 were measured.

In this test example, ammonia (ammonia detection tube, 0.5 mL of 0.03% aqueous solution), amine (amine solution, 0.5 mL of 0.3% aqueous solution), mercaptan (using mercaptan detection tube, 0.1% benzene solution) were used as odor sources. , Using 0.1 mL).

After the cleaning agents prepared in Examples 1, 2, 3 and Comparative Example 4 were put in a sealed container, the same amount of odor source was put in, respectively, and after a certain time, the residual amount of odor which had not been deodorized was sucked into a detector (Gastec Detector) and remained. The gas concentration was measured and evaluated by the following evaluation criteria (×; no deodorizing power of 80 ppm or more, △; deodorizing power of 50 to 80 ppm, ○; 20 to 50 ppm deodorizing power, ◎; excellent deodorization of 20 ppm or less Force).

Example 1 Example 2 Example 3 Comparative Example 4 Deodorant ammonia ◎ ◎ ◎ × Amine ◎ ○ ○ × Mercaptan ○ ○ ○ ×

As a result of measuring the deodorizing power, Examples 1, 2 and 3 showed excellent deodorizing power, but Comparative Example 4 had a low deodorizing power.

From the above results, it was found that in the composition of the present invention, the deodorant exhibited excellent deodorizing power, and the excellent deodorizing power of the present invention was also confirmed.

Claims (6)

Tangerine peel extract, mixed extracts of cucumber and jujube, any one selected from the mixed extracts of jujube and trigeminal vinegar and Baekbokryeong, vegetable oil 2 ~ 13% by weight, anionic surfactant 4 ~ 20% by weight, alcohol 2 ~ 20 wt%, 0.1-8 wt% poly (3,4-ethylenedioxythiophene), 0.01-20 wt% antibacterial, 0.1-10 wt% preservative, 0.05-10 wt% deodorant, and 26.5-62.5 wt% water Composition of the cleaning agent, characterized in that The method of claim 1, Vegetable oils, The composition of the cleaning agent, characterized in that any one selected from castor oil, camellia oil, olive oil, macadamia nut oil, coconut oil, jojoba oil, sweet almond oil, dew point oil, grape seed oil, avocado oil, apricot seed oil The method of claim 1, Anionic surfactants, The composition of the cleaning agent, characterized in that any one selected from lauryl ether sulfate salt or xylene sulfate salt. The method of claim 1, Antibacterial agent, The composition of the cleaning agent, characterized in that any one selected from Eungchocho extract, green tea extract, grapefruit extract, leek extract, mugwort extract, wood vinegar solution The method of claim 1, Preservatives, A composition of the cleaning agent, characterized in that any one selected from compounds of methyl paraoxybenzoate, methylchloroisothiazolinone, methylisothiazolinone The method of claim 1, Deodorant, The composition of the cleaning agent, characterized in that any one selected from persimmon leaf extract, dermis extract, octagonal extract, machi extract, Jashyeon extract or a mixture thereof