CN101613640B - Natural surface active agent for cleaning fruits and vegetables and preparation method thereof - Google Patents
Natural surface active agent for cleaning fruits and vegetables and preparation method thereof Download PDFInfo
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- CN101613640B CN101613640B CN2009100123528A CN200910012352A CN101613640B CN 101613640 B CN101613640 B CN 101613640B CN 2009100123528 A CN2009100123528 A CN 2009100123528A CN 200910012352 A CN200910012352 A CN 200910012352A CN 101613640 B CN101613640 B CN 101613640B
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Abstract
The invention relates to a natural surface active agent for cleaning fruits and vegetables, which is designed for overcoming the defects that the prior cleaning agent has non-thorough secondary cleaning, is harm to a human body after long terms of use, is not easily degraded, can cause secondary pollution, and the like. The natural surface active agent is prepared from the following components by weight percent: 10-40 percent of active matter extract of Chinese soaphberry with the concentration of 30-40 percent, 10-40 percent of alkyl poly-glycosides (APG) with the concentration of 47 percent, 10-30 percent of ginger extract with the concentration of 5 percent, 0.1-0.5 percent of EDTA, 0.3-1 percent of sodium chloride, citric acid and appropriate water. The method comprises the following steps: adding 20 percent of deionized water in a reaction vessel; heating to 35-40 DEG C, then sequentially adding APG, the active matter extract of Chinese soaphberry, the ginger extract and the EDTA, and fully mixing and stirring evenly during addition; adding appropriate citric acid; cooling to room temperature; adding appropriate sodium chloride, fully stirring for 0.5 hour and aging for 1.5 hours to obtain finished product; and bottling for leaving factory. The main components of the natural surface active agent are natural products and derivatives thereof, and the invention has the advantages of good cleaning effect, no residual, easy degradation, no stimulation to skin, no side effects, no secondary pollution to environment and environmental protection.
Description
Technical field:
The present invention relates to a kind of washing composition and preparation method thereof, especially a kind of self-faced active fruit and vegetable clean-out system and preparation method thereof belongs to the household chemicals field.
Background technology:
Existing fruits and vegetables clean-out system mostly is chemosynthesis, though clean effect can, have secondary to clean halfway problem, life-time service damages human body easily, can make people's pachylosis; And be difficult for degraded, can cause second environmental pollution.
Summary of the invention:
The secondary cleaning that The present invention be directed to above-mentioned existing clean-out system existence is not thorough, life-time service damages human body easily, can make people's pachylosis, and be difficult for degrading, cause deficiencies such as second environmental pollution problems, and provide a kind of self-faced active fruit and vegetable clean-out system and preparation method thereof, this clean-out system is to get by following each composition weight centesimal system: the Seed of Chinese Soapberry actives extracting solution 10-40% of concentration 30-40%, the alkyl polyglycoside of concentration 47% (APG) 10-40%, the ginger extract 10-30% of concentration 5%, the EDTA 0.1-0.5% of concentration 100%, the sodium-chlor 0.3-1% of concentration 100%, the citric acid of concentration 100% is an amount of, and the water of concentration 100% is an amount of.
Its making method:
1, Seed of Chinese Soapberry actives extracting solution produces.In 1: 5 (wt%) ratio Seed of Chinese Soapberry kind skin is immersed in the water, stir, be heated to 90 ℃, 1 hour time, perhaps room temperature is following 6 hours, promptly obtains Seed of Chinese Soapberry actives extracting solution, and its effective concentration is 30%-40%.
2, ginger extract produces.Available steam distillation method, solvent extraction method, milling process, supersonic method, liquid CO 2 extraction and supercritical CO 2 extraction process etc. extract ginger extract, and its effective concentration is about 5%.
3, add 20% part of deionized water in the reactor, be heated to 35-40 ℃, add load weighted APG, concentration 47%, thorough mixing stirs; Add load weighted Seed of Chinese Soapberry actives extracting solution in reactor, thorough mixing stirs; Add load weighted ginger extract in reactor, thorough mixing stirs; Add EDTA, thorough mixing stirs;
4, adding citric acid transfers pH value at 7-7.5 in right amount;
5, be cooled to room temperature, add an amount of sodium-chlor, thorough mixing stirred 0.5 hour, and aging 1.5 hours again, make finished product, bottling is dispatched from the factory.
Beneficial effect of the present invention: this fruits and vegetables clean-out system main component is natural product and derivative thereof, and to human body toxicological harmless effect, clean effect is remarkable, and noresidue is easy to degraded, and is non-stimulated to skin, has no side effect.Avoided to second environmental pollution environmental protection.
Embodiment:
Each component of self-faced active fruit and vegetable clean-out system makes by following weight percent: the Seed of Chinese Soapberry actives extracting solution 10-40% of concentration 30-40%, the alkyl polyglycoside of concentration 47% (APG) 10-40%, the ginger extract 10-30% of concentration 5%, the EDTA 0.1-0.5% of concentration 100%, the sodium-chlor 0.3-1% of concentration 100%, the citric acid of concentration 100% is an amount of, and the water of concentration 100% is an amount of.
Its preparation method, realize by following step:
(1) Seed of Chinese Soapberry actives extracting solution produces; By 1: 5 weight ratio Seed of Chinese Soapberry kind skin is immersed in the water, stir, be heated to 90 ℃, following 6 hours of 1 hour time or room temperature promptly obtain Seed of Chinese Soapberry actives extracting solution, and its effective concentration is 30%-40%;
(2) produce ginger extract, its effective concentration is about 5%; Can adopt steam distillation method, solvent extraction method, milling process, supersonic method, liquid CO 2 extraction or supercritical CO 2 extraction process all can realize the extraction of ginger extract.
(3) deionized water of adding 20% in reactor is heated to 35-40 ℃, and adding load weighted concentration is 47%APG, and thorough mixing stirs; Add load weighted Seed of Chinese Soapberry actives extracting solution in reactor, thorough mixing stirs; Add load weighted ginger extract in reactor, thorough mixing stirs; Add EDTA again, thorough mixing stirs;
(4) adding citric acid is an amount of, transfers pH value at 7-7.5;
(5) be cooled to room temperature, add an amount of sodium-chlor, thorough mixing stirred 0.5 hour, and aging 1.5 hours again, make finished product, bottling is dispatched from the factory.
Sapindus Sapindaceae (Sapindaceae), formal name used at school: Seed of Chinese Soapberry (Sapindus mukurossiGaertn.), be commonly called as: oil is suffered from son, fertile pearl etc., mainly originate in China Yangtze valley and on the south wide geographic area, Seed of Chinese Soapberry contains many materials to the human body beneficial, as: reducing sugar, lipid acid, grease, oleic acid, carotenoid, Yan acid, riboflavin, protein, vitamins C, vitamin A, vitamins B and Methionin, phenylalanine, L-glutamic acid, 10 multiple amino acids such as glycine and Histidine, Feng Fu glucosides class material wherein, be mainly triterpene saponin and sesquiterpene glucosides class, have very strong surfactivity effect, be natural nonionic surface active agent.Simultaneously the Seed of Chinese Soapberry triterpene saponin has antibiotic, sterilization and anti-inflammatory effect, the usefulness of Chang Zuowei washing among the people for human body skin.Because Seed of Chinese Soapberry contains high-load natural mild non-ionic surface active material, decontamination, scourability are fine, and contain a large amount of natural nutrition conditioning materials simultaneously, and be non-stimulated to human body, is the ideal natural surface active agent.
Alkyl poly glucoside (APG): a kind of novel nonionogenic tenside, have the characteristics of nonionic and two kinds of tensio-active agents of negatively charged ion concurrently, have the surfactivity height, strong detergency, compatibility is good, foam is abundant fine and smooth and stable, nontoxic, non-stimulated etc. a bit.In addition, APG also has good biodegradability, and its raw material all derives from natural reproducible resource, is genuine green product, now uses on a large scale as the main raw material of articles for washing.
Bioactive ingredients in the ginger is various ethereal oils and gingerol.Its main component is zingiberene, zingiberol heerabolene, curcumene, Sulcatone etc.The gingerol main component is a ginger oil, can be decomposed into mixtures such as ginger ketenes, zingiberone, zingiberone.Also contain materials such as asparagine and L-glutamic acid, aspartic acid, Serine in addition in the ginger.The water logging agent of ginger has the obvious suppression effect to Corynebacterium diphtheriae, suis, Salmonellas, streptococcus pneumoniae, can be used for treating dysentery and diarrhoea.The aqueous extract of discovering ginger all has in various degree restraining effect to Corynebacterium diphtheriae, vibrio cholerae.Car lotus and Ma Yansong reported once that fresh ginger juice had significantly bacteriostatic action to intestinal bacteria, cereuisiae fermentum, Penicillium notatum.Once jade-like stone proof gingerade extract had certain anti-microbial effect to streptococcus aureus, intestinal bacteria, Hansenula anomala.The ether extract of ginger has the obvious suppression effect to multiple microorganism such as streptococcus aureus, Bacillus subtilus, aspergillus niger, mould, intestinal bacteria saccharomyces cerevisiae.
Alkyl polyglycoside of the composite use of the present invention (APG) and Seed of Chinese Soapberry actives extracting solution are natural surface active agent and derivative thereof, and ginger extract is a natural extract also, have sterilization, disinfectant effect.Pungency of the present invention is low, solvability good, have foam and enrich advantages such as fine and smooth, that detergency ability is good, degreasing power is moderate, resistance to hard water is strong, can remove the dirt of fruit and vegetable surfaces and residual agricultural chemicals, simultaneously because its main component is the water-soluble natural product, can not cause secondary pollution, be ideal fruits and vegetables cleaning product
Embodiment 1
Self-faced active fruit and vegetable clean-out system is to be made by following component, and the weight percent of each component is as follows:
Material concentration per-cent
Seed of Chinese Soapberry actives extracting solution 30-40% 20%
Alkyl polyglycoside (APG) 47% 30%
Ginger extract 5% 15%
EDTA 100％ 0.1％
Sodium-chlor 100% 0.3%
Citric acid 100% is an amount of
Water 100% surplus
Making method:
1, Seed of Chinese Soapberry actives extracting solution produces.In 1: 5 (wt%) ratio Seed of Chinese Soapberry kind skin is immersed in the water, stir, be heated to 90 ℃, 1 hour time, perhaps room temperature is following 6 hours, promptly obtains Seed of Chinese Soapberry actives extracting solution, and its effective concentration is 30%-40%.
2, ginger extract produces.Available steam distillation method, solvent extraction method, milling process, supersonic method, liquid CO 2 extraction and supercritical CO 2 extraction process etc. extract ginger extract, and its effective concentration is about 5%.
3, add 20% part of deionized water in the reactor, be heated to 35-40 ℃, add load weighted APG, concentration 47%, thorough mixing stirs; Add load weighted Seed of Chinese Soapberry actives extracting solution in reactor, thorough mixing stirs; Add load weighted ginger extract in reactor, thorough mixing stirs; Add EDTA, thorough mixing stirs;
4, adding citric acid transfers pH value at 7-7.5 in right amount;
5, be cooled to room temperature, add an amount of sodium-chlor, thorough mixing stirred 0.5 hour, and aging 1.5 hours again, make finished product, bottling is dispatched from the factory.
Embodiment 2
Self-faced active fruit and vegetable clean-out system, its preparation method is identical with embodiment 1, and difference is that this clean-out system is made by following component, and the weight percent of each component is as follows:
Material concentration per-cent
Seed of Chinese Soapberry actives extracting solution 30-40% 30%
Alkyl polyglycoside (APG) 47% 20%
Ginger extract 5% 20%
EDTA 100％ 0.2％
Sodium-chlor 100% 1%
Citric acid 100% is an amount of
Water 100% surplus
Embodiment 3
Self-faced active fruit and vegetable clean-out system, its preparation method is identical with embodiment 1, and difference is that this clean-out system is made by following component, and the weight percent of each component is as follows:
Material concentration per-cent
Seed of Chinese Soapberry actives extracting solution 30-40% 35%
Alkyl polyglycoside (APG) 47% 40%
Ginger extract 5% 20%
EDTA 100％ 0.2％
Sodium-chlor 100% 0.5%
Citric acid 100% is an amount of
Water 100% surplus
Embodiment 4
Self-faced active fruit and vegetable clean-out system, its preparation method is identical with embodiment 1, and difference is that this clean-out system is made by following component, and the weight percent of each component is as follows:
Material concentration per-cent
Seed of Chinese Soapberry actives extracting solution 30-40% 20%
Alkyl polyglycoside (APG) 47% 40%
Ginger extract 5% 30%
EDTA 100％ 0.3％
Sodium-chlor 100% 0.5%
Citric acid 100% is an amount of
Water 100% surplus
Claims (1)
1. fruits and vegetables clean-out system, it is made by following compositions in weight percentage: the Seed of Chinese Soapberry actives extracting solution 10-40% of concentration 30-40%, the alkyl polyglycoside 10-40% of concentration 47%, the ginger extract 10-30% of concentration 5%, the EDTA 0.1-0.5% of concentration 100%, the sodium-chlor 0.3-1% of concentration 100%, the citric acid of concentration 100% is an amount of, and the water of concentration 100% is an amount of;
Described Seed of Chinese Soapberry actives extracting solution is produced as follows and obtained: by 1: 5 weight ratio Seed of Chinese Soapberry kind skin is immersed in the water, stir, be heated to 90 ℃, 1 hour time, perhaps room temperature is following 6 hours, promptly obtains Seed of Chinese Soapberry actives extracting solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100123528A CN101613640B (en) | 2009-07-03 | 2009-07-03 | Natural surface active agent for cleaning fruits and vegetables and preparation method thereof |
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| CN2009100123528A CN101613640B (en) | 2009-07-03 | 2009-07-03 | Natural surface active agent for cleaning fruits and vegetables and preparation method thereof |
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| CN101613640A CN101613640A (en) | 2009-12-30 |
| CN101613640B true CN101613640B (en) | 2011-06-22 |
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| CN2009100123528A Expired - Fee Related CN101613640B (en) | 2009-07-03 | 2009-07-03 | Natural surface active agent for cleaning fruits and vegetables and preparation method thereof |
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| US8338347B2 (en) * | 2010-09-09 | 2012-12-25 | Mareya Shawki Ibrahim | System for reducing bacteria on unprocessed food surfaces while extending shelf life |
| CN102041204B (en) * | 2011-01-05 | 2013-01-23 | 中国林业科学研究院林产化学工业研究所 | Method for preparing tree-starch based natural biomass detergent |
| CN102304441B (en) * | 2011-08-08 | 2012-11-14 | 上海瑞涌食品有限公司 | Edible cleaning agent for fruits and vegetables |
| CN102429844B (en) * | 2011-12-07 | 2013-04-17 | 广州青能健日用品有限公司 | Biological environment-friendly antioxidant itching-relieving bath wash and preparation method thereof |
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| CN103961275A (en) * | 2013-02-03 | 2014-08-06 | 广州无患子生物科技有限公司 | Daily necessities containing all-natural source surfactant and preparation method thereof |
| CN103276023B (en) * | 2013-05-27 | 2015-01-14 | 南京理工大学 | Method for promoting anaerobic fermentation of surplus sludge to produce acid by using biosurfactant |
| CN103444809A (en) * | 2013-08-29 | 2013-12-18 | 严积芳 | Daily-use chemical Chinese herbal medicine antibacterial agent |
| CN103421621A (en) * | 2013-08-29 | 2013-12-04 | 严积芳 | Glucose monodecanoate Chinese herbal medicine washing agent |
| CN103695206A (en) * | 2013-12-16 | 2014-04-02 | 芜湖欣荣管业科技有限公司 | Fruit surface cleaner |
| CN104531399A (en) * | 2014-12-04 | 2015-04-22 | 成都顺发消洗科技有限公司 | Preparation method of plant-type fruit detergent |
| CN105132215A (en) * | 2015-08-25 | 2015-12-09 | 郎溪县睿智生产力促进中心有限公司 | Sausage casing cleaning agent |
| CN105087173A (en) * | 2015-09-11 | 2015-11-25 | 舟山赛莱特海洋科技有限公司 | Green sea fruit and vegetable antibacterial cleaning agent and preparation method thereof |
| CN105647710A (en) * | 2016-02-04 | 2016-06-08 | 王玉成 | Fruit and vegetable washing salt and preparing method |
| CN105647711A (en) * | 2016-02-04 | 2016-06-08 | 王玉成 | Fruit washing salt and preparation method |
| CN106221953A (en) * | 2016-07-29 | 2016-12-14 | 太仓新东方生物科技养殖有限公司 | A kind of environment-friendly type fruit surface detergent |
| CN106947610A (en) * | 2017-03-24 | 2017-07-14 | 福建师范大学泉港石化研究院 | A kind of antibacterial detergent of environment-friendly type and preparation method thereof |
| CN108822988A (en) * | 2018-06-06 | 2018-11-16 | 无限极（中国）有限公司 | A kind of composition and the daily chemical product containing the composition |
| CN112210445B (en) * | 2020-09-30 | 2022-01-11 | 山东华熙海御生物医药有限公司 | Hyaluronic acid cleaning solution and preparation method thereof |
| CN115477981A (en) * | 2022-09-23 | 2022-12-16 | 广西壮族自治区林业科学研究院 | Liquid green fruit and vegetable washing product and preparation method thereof |
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| CN1073203A (en) * | 1992-08-03 | 1993-06-16 | 黄其彬 | Cleaning agent for fruit and vegetable |
| CN101161806A (en) * | 2007-10-03 | 2008-04-16 | 胡银安 | Detergent for removing heavy metal pollution on surface of fruits and vegetables |
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2009
- 2009-07-03 CN CN2009100123528A patent/CN101613640B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1073203A (en) * | 1992-08-03 | 1993-06-16 | 黄其彬 | Cleaning agent for fruit and vegetable |
| CN101161806A (en) * | 2007-10-03 | 2008-04-16 | 胡银安 | Detergent for removing heavy metal pollution on surface of fruits and vegetables |
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| CN101613640A (en) | 2009-12-30 |
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