CN102041204B - Method for preparing tree-starch based natural biomass detergent - Google Patents
Method for preparing tree-starch based natural biomass detergent Download PDFInfo
- Publication number
- CN102041204B CN102041204B CN2011100007416A CN201110000741A CN102041204B CN 102041204 B CN102041204 B CN 102041204B CN 2011100007416 A CN2011100007416 A CN 2011100007416A CN 201110000741 A CN201110000741 A CN 201110000741A CN 102041204 B CN102041204 B CN 102041204B
- Authority
- CN
- China
- Prior art keywords
- starch
- tree
- starch based
- hydrolysis
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Abstract
The invention relates to a method for preparing tree-starch based natural biomass detergent from raw materials of starch based plant, comprising the processing steps of grinding, steaming, hydrolyzing, pulping, pulp refining, fine separating, or esterifying or aminating, refining and compounding. The tree-starch based natural biomass detergent can be liquid product and powdery product. The tree-starch based natural biomass detergent is mainly used for the environmentally-friendly washing and cleaning of the utensils, fruits, vegetables and body, has good oil stain removing effect and is all natural, non-toxic, safe and environmentally friendly.
Description
Technical field:
The present invention relates to a kind of preparation and method thereof of tree-starch based natural biomass detergent.This technology belongs to household chemicals.
Background technology:
The present invention relates to a kind of preparation and method thereof of tree-starch based natural biomass detergent, namely take the starch of tree-starch based fruit as raw material, prepare the tree-starch based biomass detergent through pulverizing, boiling, hydrolysis making beating, defibrination or esterification or ammonification, the complete processing such as refining, composite respectively.It can be liquiform product, also can be powder-like product.Trees starch-based bio matter washing composition is mainly used in green cleaning that tableware, fruits and vegetables clean, take a shower, keeps a public place clean, wash, and it is rather good that it cleans oil stain effect, pure natural, nontoxic, safety, environmental protection.
In the face of the severe challenge of food sanitation and safety, the food sanitation and safety problem is extremely urgent, has caused compatriots' very big concern.Food is not only the requisite that maintains people existence, also is simultaneously the consumer's goods closely bound up with people's quality of life and level.Progress along with expanding economy and science and technology, various food enriching constantly people's " vegetable basket " and " meal-table ", but more difficult food contamination of being perceiveed by the human consumer of one flourishing back at this, and the various harm consumer healths' that cause thus food poisonings.
The present invention is intended to make circulation, optimization, the effectively utilization of China's trees starch-based bio matter resource realization renewable resource.In China, the trees starch-based bio matter plant length and breadth of land, abundant, full, its preparation quality, resource that is used for natural biomass detergent is guaranteed, and not exclusively depends on the quality of soapless soap.Trees starch-based bio matter resource is wide, and the present invention preferentially selects trees starch-based bio matter resource to have: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris, Seed of Chinese Soapberry etc.
Acorn nut belongs to Fagaceae, it of a great variety, and such as chinquapin, white oak, thick fringe Ke, Delavay Evergreenchinkapin etc., the raw material name is referred to as acorn nut.It mainly is distributed in Liaoning, Jilin, Heilungkiang one band, can be made into a kind of novel protective foods one acorn starch through processing.The mode of appearance of acorn starch is light brown powder, have itself intrinsic smell, delicate mouthfeel, with the topmost difference of other starch be that this starch is rich in tannin, its main component is Ellagitannins, and Ellagitannins is divided into again rubber tannin, Ke's Chinese tannin, tannin, oak tannin.The astringent taste of Ellagitannins not only gives acorn starch special local flavor, and Ellagitannins and Protein formation complex compound make metabolism slack-off simultaneously, reduce in addition blood urea nitrogen effect in the blood; Antitoxin antiulcer action and anti-allergic effects, and step-down ends dysentery, treatment gastrointestinal hemorrhage, Ellagitannins can be with the complexings such as plumbous mercury, produce precipitation, have detoxification.Just because this medicinal health value, be subject to gradually the favor of users at home and abroad, the market requirement is very large, most products export Korea S, Japan, and economic benefit is very considerable.At present, domestic acorn starch production is also more rare, and the experience of moulding is also few.Acorn nut is starch-containing 46.4～62.88%, and reasonable and advanced technique is under the prerequisite of ensuring the quality of products, and improves as much as possible flour extraction rate.
Chinese chestnut has another name called chestnut, originates in China, and cultivation history, the iron crops in more than 3000 year, the laudatory titles such as king of dry fruit are arranged, and is one of famous in the world important dry fruit, is that the important exported product Chinese chestnut of China is nutritious, unique flavor.Chinese chestnut is effective in cure effect again, can cure mainly gastric disorder causing nausea, hematemesis hematochezia, pyogenic infections etc.Therefore, Chinese chestnut is popular in the international market.Chinese chestnut processing is paid attention to deeply such as the U.S., Japan, France etc. abroad, and Chinese chestnut is processed into series product.In China, except eating raw, multi-processing becomes the products such as marrons glaces, chestnut in syrup can, chestnut mash.
The root of kudzu vine is a kind of natural green food.Contain the flavonoid activeconstituents in the root of kudzu vine a lot, flavonoid compound can reach 0.5g/L, and flavonoid compound can be used as the cerebral anemia health food development.These physiologically active ingredients. have the function of removing free radical, vasodilation, reducing blood pressure and prevent arteriosclerosis, improve blood circulation, avoid the cell hypoxemia to injure.To senile dementia and delay body aging preferably effect is arranged, it is effective protective foods of the elderly.Therefore, exploitation and the production of flavonoid activeconstituents healthcare products for guaranteeing human health, improve the significant and wide market outlook of its life quality.The root of kudzu vine also can be used for producing drink, because containing the too starch component of amount, easily produces juice and separates, and makes beverage layering, precipitation.Employing double-enzyme method hydrolysis, the problem of compound and aspects such as decomposition reaction generation, saccharified liquid color, sugar degree and purity when basically having avoided hydrolysis.
Along with development and the progress of human society, the consumption of natural, environmental protection, the washing of green bio matter, sanitising agent increases day by day, the shortage of petroleum resources and the deterioration of environment serious threat to the human survival and development.With natural reproducible resource substitute that fossil resource synthetic environment close friend is natural, environmental protection, the washing of green bio matter, sanitising agent, be subject to domestic and international common concern always, become global development strategy.Utilize that the synthetic high added value of agricultural renewable resources and residuum thereof is natural, environmental protection, the washing of green bio matter, sanitising agent be one of developing direction of natural resource comprehensive utilization.
The family of languages row green ecological washing composition of " the natural biological washing " of domestic relevant department document announcement---bamboo, its zero pollution, degradable, safety is natural.Although be washing composition, pleasing to the eye harmless, entrance is nontoxic, and is drinkable washing composition.This product can directly be drunk, because it is directly to extract green bamboo and contained refining the forming of biological effective components of Endoconcha Sepiae, is different from the petrochemical industry washing composition fully.
The green natural biocleaner is not to environment.Utilize advanced biotechnology, just as cutting rubber, can directly in the live body mao bamboon, extract active bamboo juice composition, in 800 ℃ high temperature, extracted bamboo juice by modern high technology.The mao bamboon at three to six ages, every strain can be extracted six to nine kilograms of bamboo juices, have greatly brought into play the usefulness of mao bamboon, promote the economic worth of mao bamboon.
The peaceful grade of Wang Qing reported in " starch alkyl polyglycosides prepares the environment-friendly type washing composition " take attapulgite as inorganic assistant agent, optimized technique take starch alkyl polyglycosides (APG) as the composite liquid washing agent of major surfaces promoting agent with orthogonal experiment.Yuan Hao has reported that in " research of Starch-based Surfactants Alkyl Polyglycoside " alkyl glycoside (APG for short) is a kind of novel world-class nonionogenic tenside.Alkyl glycoside not only surface tension is low, and foam enriches fine and smooth and stablizes, and decontamination is good, and compatibility is splendid, and under the very high condition of electrolyte concentration, its solubleness is still very high.The advantages such as in addition, this tensio-active agent also has skin and eyes non-stimulated, and consistency is good, and product is nontoxic comparatively speaking, and biological degradability is good.Alkyl glycoside is of many uses, can be applied to the fields such as washing composition, makeup, food, medicine, agricultural chemicals.
Tree-starch based natural botanical extraction liquid used in the present invention mainly utilizes tree-starch based starch and hydrolyzate thereof and derivative production to be easy to biological degradation and excellent property, tensio-active agent numerous in variety.Just begun the development of starch tensio-active agent as far back as the thirties abroad, in recent years because oil and glyceride stock shortage and constantly appreciating, made cheapness and abundant starch resource just day by day comes into one's own as the new raw material of tensio-active agent and develops.
Summary of the invention:
1, a kind of preparation of tree-starch based natural biomass detergent and method is characterized in that may further comprise the steps:
The first step, the selection of tree-starch based plant variety: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris.
Second step, a kind of tree-starch based natural biomass detergent contain the tree-starch based biomass extract such as the tree-starch based Starch Hydrolysis purifies concentrated solution or its alkyl glucoside or glycosamine.It can be liquiform product, also can be powder-like product.
The 3rd step, the preparation of tree-starch based biomass hydrolysate or powder
Do constant weight with the tree-starch based fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried tree-starch based dry fruit to constant weight of gas carries out separation of hull from kernel, and the kernel that is separated can be through too high comminution ratio crushing material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready.Or produce fresh tree-starch based kernel as raw material for subsequent use.
With the tree-starch based kernel crushed material for preparing or get and add in the boiling hydrolytic decomposition pot after fresh tree-starch based kernel is pulverized, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time is controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8.The solution accent is weakly alkaline, makes the pH value of solution be about 9～10.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after being hydrolyzed, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain the tree-starch based Starch Hydrolysis, in and scavenging solution.Carry out concentrating under reduced pressure with scavenging solution in the tree-starch based Starch Hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density tree-starch based Starch Hydrolysis and purify concentrated solution, require solids content 20～50%.
It is tasteless little Huang that the tree-starch based Starch Hydrolysis purifies concentrated solution, connects diaphanous viscous liquid.Can be with tree-starch based Starch Hydrolysis concentrated solution with the high pressure steam sterilization tank 10～15min that under 120 ℃ of conditions, sterilizes, for subsequent use.
The tree-starch based Starch Hydrolysis purifies concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery tree-starch based starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Or get in the tree-starch based Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, the corresponding aqueous or powdered product that makes its alkyl glucoside or glycosamine
Tree-starch based starch alkyl-glucoside is the general name of a series of products.It can be generated through the glycosyl shift reaction under protonic acid catalysis by tree-starch based starch and alcohols material, temperature of reaction, time are looked the difference of catalyzer and difference, the alcohols glucoside that generates, generate the alkoxide glucoside with the reaction of epoxy alkyl compound again, and then with the reaction of lipid acid or higher aliphatic acid, make various alcohols glucoside esters or ethers nonionogenic tenside.
The 4th step, product configuration
Liquiform product: take by weighing tree-starch based Starch Hydrolysis purification concentrated solution or its alkyl glucoside or glycosamine liquid by proportioning and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
The deionized water quality requires to meet standard GB/T 6682-2000.
Powder-like product: take by weighing tree-starch based Starch Hydrolysis purification concentrated dry thing or its alkyl glucoside or glycosamine meal by proportioning and put into stirred vessel, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling or pack.
Description of drawings:
Fig. 1 is the schema of the embodiment of the invention.
Embodiment:
Preparation and the method for 1 one kinds of tree-starch based natural biomass detergents of embodiment is characterized in that may further comprise the steps:
The first step, the selection of tree-starch based plant variety: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris.
Second step, a kind of tree-starch based natural biomass detergent contain the tree-starch based biomass extract such as the tree-starch based Starch Hydrolysis purifies concentrated solution or its alkyl glucoside or glycosamine.It can be liquiform product, also can be powder-like product.
The 3rd step, the preparation of tree-starch based biomass hydrolysate or powder
Do constant weight with the tree-starch based fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried tree-starch based dry fruit to constant weight of gas carries out separation of hull from kernel, and the kernel that is separated can be through too high comminution ratio crushing material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready.Or produce fresh tree-starch based kernel as raw material for subsequent use.
With the tree-starch based kernel crushed material for preparing or get and add in the boiling hydrolytic decomposition pot after fresh tree-starch based kernel is pulverized, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time is controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8.The solution accent is weakly alkaline, makes the pH value of solution be about 9～10.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after being hydrolyzed, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain the tree-starch based Starch Hydrolysis, in and scavenging solution.Carry out concentrating under reduced pressure with scavenging solution in the tree-starch based Starch Hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density tree-starch based Starch Hydrolysis and purify concentrated solution, require solids content 20～50%.
It is tasteless little Huang that the tree-starch based Starch Hydrolysis purifies concentrated solution, connects diaphanous viscous liquid.Can be with tree-starch based Starch Hydrolysis concentrated solution with the high pressure steam sterilization tank 10～15min that under 120 ℃ of conditions, sterilizes, for subsequent use.
The tree-starch based Starch Hydrolysis purifies concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery tree-starch based starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Or get in the tree-starch based Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, the corresponding aqueous or powdered product that makes its alkyl glucoside or glycosamine.
Tree-starch based starch alkyl-glucoside is the general name of a series of products.It can be generated through the glycosyl shift reaction under protonic acid catalysis by tree-starch based starch and alcohols material, temperature of reaction, time are looked the difference of catalyzer and difference, the alcohols glucoside that generates, generate the alkoxide glucoside with the reaction of epoxy alkyl compound again, and then with the reaction of lipid acid or higher aliphatic acid, make various alcohols glucoside esters or ethers nonionogenic tenside.
The 4th step, product configuration
Liquiform product: take by weighing tree-starch based Starch Hydrolysis purification concentrated solution or its alkyl glucoside or glycosamine liquid by proportioning and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
The deionized water quality requires to meet standard GB/T 6682-2000.
Powder-like product: take by weighing tree-starch based Starch Hydrolysis purification concentrated dry thing or its alkyl glucoside or glycosamine meal by proportioning and put into stirred vessel, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling or pack.
Embodiment 2:
Do constant weight with the tree-starch based acorn nut fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried tree-starch based acorn nut dry fruit to constant weight of gas carries out the separation of hull from kernel operation, and the acorn nut kernel that is separated can through too high comminution ratio crushing material, be got the raw materials ready.Or produce fresh acorn nut kernel as raw material for subsequent use.
In 5 kilograms of adding hydrolysis of fresh acorn nut kernel after getting the crushed material tree-starch based acorn nut kernel for preparing or getting pulverizing digester, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100-105 ℃, and extraction time is controlled at 2～3 hours.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after being hydrolyzed, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain forest acorn starch base Starch Hydrolysis scavenging solution.The forest acorn starch base Starch Hydrolysis scavenging solution that obtains carries out concentrating under reduced pressure, steam unnecessary water, 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest acorn starch base Starch Hydrolysis and purify concentrated solution, require solids content 20～50%.
Concentrated forest acorn starch base Starch Hydrolysis concentrated solution is with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use.Or get in the tree-starch based acorn starch hydrolytic purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, corresponding acorn starch alkyl glucoside or the glycosamine of making.
Maybe concentrated forest acorn starch base Starch Hydrolysis concentrated solution is carried out press atomization or centrifugal spray drying after with high pressure steam sterilization, further make powdery tree-starch based acorn starch hydrolyzate.Or get in the tree-starch based acorn starch hydrolytic purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, correspondingly make the acorn starch alkyl glucoside or glycosamine carries out press atomization or centrifugal spray drying, further make powdery forest acorn starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Liquiform product: take by weighing forest acorn starch base Starch Hydrolysis and purify concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest acorn starch base Starch Hydrolysis by said ratio and purify concentrated solution or alkyl glucoside or glycosamine liquid, and squeeze in the stirred vessel, add the deionized water of surplus, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest acorn starch base Starch Hydrolysis and purify concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.
Embodiment 3:
Do constant weight with the tree-starch based seven leaf fruit Exposures to Sunlight of collection or with drier (60～65 ℃) to gas.The dried tree-starch based seven leaf dry fruits to constant weight of gas carry out the separation of hull from kernel operation, and the seven leaf kernels that are separated can through too high comminution ratio crushing material, be got the raw materials ready.Or produce seven fresh leaf kernels as raw material for subsequent use.
In 5 kilograms of adding hydrolysis of fresh seven leaf kernels after getting the crushed material tree-starch based seven leaf kernels that prepare or getting pulverizing digester, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, and extraction time is controlled at 2～3 hours.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after being hydrolyzed, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain forest seven leaf kernel starch base Starch Hydrolysis scavenging solutions.The forest seven leaf kernel starch base Starch Hydrolysis scavenging solutions that obtain carry out concentrating under reduced pressure, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density tree-starch based seven leaf kernel Starch Hydrolysis and purify concentrated solution, require solids content 20～50%.Concentrated tree-starch based seven leaf kernel Starch Hydrolysis concentrated solutions are with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use.Or get in the forest seven leaf kernel starch base Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, corresponding seven leaf kernel starch alkyl glucoside or the glycosamines that make.
Concentrated forest seven leaves fruit starch base Starch Hydrolysis concentrated solution is with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use.Or get in the forest seven leaves fruit starch base Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, corresponding acorn starch alkyl glucoside or the glycosamine of making.
Maybe concentrated forest seven leaves fruit starch base Starch Hydrolysis concentrated solution is carried out press atomization or centrifugal spray drying after with high pressure steam sterilization, further make powdery forest seven leaves fruit starch base starch hydrolyzates.Or get in the forest seven leaves fruit starch base Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, correspondingly make seven leaves fruits starch alkyl glucoside or glycosamine carries out press atomization or centrifugal spray drying, further make powdery forest seven leaves fruit starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Liquiform product: take by weighing forest seven leaves fruit starch base Starch Hydrolysis and purify concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest seven leaves fruit starch base Starch Hydrolysis by said ratio and purify concentrated solution or alkyl glucoside or glycosamine liquid, and squeeze in the stirred vessel, add the deionized water of surplus, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest seven leaves fruit starch base Starch Hydrolysis and purify concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.
Embodiment 4:
Do constant weight with the forest chestnut starch base fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest chestnut starch backbone to constant weight of gas really carries out the separation of hull from kernel operation, and the chestnut kernel that is separated can through too high comminution ratio crushing material, be got the raw materials ready.Or produce fresh chestnut kernel as raw material for subsequent use.
The crushed material forest chestnut starch base kernel that feeding is got ready or get pulverizing after 5 kilograms of fresh chestnut kernels add in the hydrolysis digester, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, and extraction time is controlled at 2～3 hours.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after being hydrolyzed, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain forest chestnut starch base Starch Hydrolysis scavenging solution.The forest chestnut starch base Starch Hydrolysis scavenging solution that obtains carries out concentrating under reduced pressure, steam unnecessary water, 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest chestnut starch base Starch Hydrolysis and purify concentrated solution, require solids content 20～50%.
Concentrated forest chestnut starch base Starch Hydrolysis concentrated solution is with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use.Or get in the forest chestnut starch base Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, corresponding chestnut starch alkyl glucoside or the glycosamine of making.
Maybe concentrated forest chestnut starch base Starch Hydrolysis concentrated solution is carried out press atomization or centrifugal spray drying after with high pressure steam sterilization, further make powdery forest chestnut starch base starch hydrolyzates.Or get in the forest chestnut starch base Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, correspondingly make the chestnut starch alkyl glucoside or glycosamine carries out press atomization or centrifugal spray drying, further make powdery forest chestnut starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Liquiform product: take by weighing forest chestnut starch base Starch Hydrolysis and purify concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest chestnut starch base Starch Hydrolysis by said ratio and purify concentrated solution or alkyl glucoside or glycosamine liquid, and squeeze in the stirred vessel, add the deionized water of surplus, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest chestnut starch base Starch Hydrolysis and purify concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.Tree-starch based biomass detergent detection method:
(1) mensuration of pH: measure pH with PHS-3C type acidometer;
(2) mensuration of proportion: adopt pycnometric method;
(3) winter hardiness: after in-10 ℃ refrigerator, placing 24h, recover room temperature, observe phenomena;
(4) thermotolerance: in 40 ± 1 ℃ water-bath, behind the heating 24h, recover room temperature, observe phenomena;
(5) mensuration of fat content: adopt the Soxhlet method;
(6) mensuration of viscosity: adopt the method for GB GB9985-2000 to measure;
(7) mensuration of foam height: adopt the method for GB GB/T1974-2002 to measure;
(8) mensuration of alcohol-insoluble substance content: adopt the method for GB GB/T9986-1988 to measure;
(9) mensuration of toxic metal constituent content: adopt mass spectroscopy.Get the tree-starch based Starch Hydrolysis and purify concentrated solution or its alkyl glucoside or glycosamine 25ml and put into MARS5 microwave nitre solution instrument and carry out nitratedly, take out the mensuration of carrying out arsenic, cadmium, mercury, lead ion with the 7500A Inductively coupled plasma mass spectrometry behind the 6h;
(10) soil removability: adopt GB GB9985-2000 method to measure.
Claims (2)
1. the preparation method of a tree-starch based natural biomass washings is characterized in that may further comprise the steps:
Be dried to the dried constant weight of gas with the tree-starch based fruit Exposure to Sunlight that is selected from acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris of collection or with dryer at 60～65 ℃; The dried tree-starch based dry fruit to constant weight of gas carries out shell, benevolence is separated, and the kernel that is separated is through too high comminution ratio crushing material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready; Or produce the fresh tree-starch based kernel that is selected from acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris as raw material for subsequent use;
With the tree-starch based kernel crushed material for preparing or get and add in the boiling hydrolytic decomposition pot after fresh tree-starch based kernel is pulverized, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time is controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8; The solution accent is weakly alkaline, makes the pH value of solution be about 9～10; Neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid carried out in hydrolysis after finishing, and crosses 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain the tree-starch based Starch Hydrolysis, in and scavenging solution; Carry out concentrating under reduced pressure with scavenging solution in the tree-starch based Starch Hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density tree-starch based Starch Hydrolysis and purify concentrated solution, require solids content 20～50%;
The tree-starch based Starch Hydrolysis is purified concentrated solution with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use; Or get in the tree-starch based Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, the corresponding aqueous product that makes its alkyl glucoside or glycosamine;
Take by weighing according to a certain ratio the aqueous product that above-mentioned tree-starch based Starch Hydrolysis purifies concentrated solution or its alkyl glucoside or glycosamine, put into stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling; Wherein said proportioning is: the tree-starch based Starch Hydrolysis purifies the aqueous product of concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus, wherein the deionized water quality requires to meet standard GB/T 6682-2000.
2. the preparation method of a tree-starch based natural biomass washing powder is characterized in that may further comprise the steps:
Be dried to the dried constant weight of gas with the tree-starch based fruit Exposure to Sunlight that is selected from acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris of collection or with dryer at 60～65 ℃; The dried tree-starch based dry fruit to constant weight of gas carries out shell, benevolence is separated, and the kernel that is separated is through too high comminution ratio crushing material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready; Or produce the fresh tree-starch based kernel that is selected from acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris as raw material for subsequent use;
With the tree-starch based kernel crushed material for preparing or get and add in the boiling hydrolytic decomposition pot after fresh tree-starch based kernel is pulverized, acid adding, deionized water to solid-to-liquid ratio be controlled at 1: 6～12 scope in, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time is controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8; The solution accent is weakly alkaline, makes the pH value of solution be about 9～10; Neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid carried out in hydrolysis after finishing, and crosses 100 mesh sieves, elimination part insolubles and lixiviate material residue namely obtain the tree-starch based Starch Hydrolysis, in and scavenging solution; Carry out concentrating under reduced pressure with scavenging solution in the tree-starch based Starch Hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density tree-starch based Starch Hydrolysis and purify concentrated solution, require solids content 20～50%;
Tree-starch based Starch Hydrolysis concentrated solution is with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use;
The tree-starch based Starch Hydrolysis is purified concentrated solution carry out press atomization or centrifugal spray drying, further make the tree-starch based Starch Hydrolysis and purify concentrated dry thing, wherein press atomization or centrifugal spray drying inlet air temperature are controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures; Or get in the tree-starch based Starch Hydrolysis purification concentrated solution adding retort, add respectively Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia and carry out esterification or aminating reaction, the corresponding powdered product that makes its alkyl glucoside or glycosamine;
Take by weighing according to a certain ratio the powdered product that the tree-starch based Starch Hydrolysis purifies concentrated dry thing or its alkyl glucoside or glycosamine, put into stirred vessel, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling or pack; Wherein said proportioning is: the tree-starch based Starch Hydrolysis purifies the powdered product of concentrated dry thing or its alkyl glucoside or glycosamine, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100007416A CN102041204B (en) | 2011-01-05 | 2011-01-05 | Method for preparing tree-starch based natural biomass detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100007416A CN102041204B (en) | 2011-01-05 | 2011-01-05 | Method for preparing tree-starch based natural biomass detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102041204A CN102041204A (en) | 2011-05-04 |
| CN102041204B true CN102041204B (en) | 2013-01-23 |
Family
ID=43907753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100007416A Expired - Fee Related CN102041204B (en) | 2011-01-05 | 2011-01-05 | Method for preparing tree-starch based natural biomass detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102041204B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604750A (en) * | 2012-01-12 | 2012-07-25 | 中国林业科学研究院林产化学工业研究所 | Method for preparing forest herbaceous plant biomass detergent |
| CN106978281A (en) * | 2017-03-30 | 2017-07-25 | 柳州立洁科技有限公司 | A kind of acidic cleaner and preparation method thereof |
| CN108250307B (en) * | 2018-01-22 | 2020-12-15 | 安徽师范大学 | Preparation method of modified lycoris starch |
| CN110499219A (en) * | 2018-05-17 | 2019-11-26 | 陈广龙 | Tableware, fruits and vegetables cleaning agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613640A (en) * | 2009-07-03 | 2009-12-30 | 沈阳师范大学 | Self-faced active fruit and vegetable clean-out system and preparation method thereof |
| CN101659909A (en) * | 2009-06-09 | 2010-03-03 | 深圳市成为工贸有限公司 | Natural washing particle and preparation method thereof |
-
2011
- 2011-01-05 CN CN2011100007416A patent/CN102041204B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659909A (en) * | 2009-06-09 | 2010-03-03 | 深圳市成为工贸有限公司 | Natural washing particle and preparation method thereof |
| CN101613640A (en) * | 2009-07-03 | 2009-12-30 | 沈阳师范大学 | Self-faced active fruit and vegetable clean-out system and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102041204A (en) | 2011-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102551028B (en) | Method for preparing suaeda salsa biogenetic salt | |
| CN101812111B (en) | Comprehensive deep processing method for oil tea fruits | |
| CN103843970B (en) | Production method for preparing ossein oligopeptide meal, bone oil and bone meal | |
| CN105410873B (en) | A kind of functional kelp sauce rich in dietary fiber and preparation method thereof | |
| CN101628925B (en) | Application of microwave technology in processing oil-tea camellia seeds | |
| CN101356963B (en) | Banana peel full-powder and production method thereof | |
| CN103859243B (en) | A kind of preparation method of seaweeds fishy-smell removing agent | |
| CN102793120A (en) | Preparation method for whole-banana powder | |
| CN106343410A (en) | Production method of kelp extract | |
| CN102041204B (en) | Method for preparing tree-starch based natural biomass detergent | |
| CN102080028A (en) | Dryopteris erythrosora/soapberry natural biomass detergent and preparation method thereof | |
| CN103314788A (en) | Practical seafood mushroom culture medium and manufacturing method thereof | |
| CN102669406A (en) | Process for preparing edible protein powder by modifying corn protein powder | |
| CN106281638B (en) | A kind of method that camellia seed oil and oil tea saponin and camellia seed meal feed are extracted from camellia seed kernel | |
| CN102224960B (en) | Cyperus esculentus beverage and preparation method thereof | |
| CN102349863A (en) | Preparation method of algal polysaccharides toner | |
| CN104171095A (en) | Selenium-rich tea and production process thereof | |
| CN104719970A (en) | Production process of sea cucumber oral liquid | |
| CN102533436A (en) | Method for processing health-care camellia oil | |
| CN102219932B (en) | Preparation method of edible soup bases packaging film containing tremellan | |
| CN109619581A (en) | A kind of tree peony salt and preparation method thereof | |
| CN101791104B (en) | Method for preparing sweet agent by utilizing bananas | |
| CN101756295A (en) | Method for preparing kelp dietary fiber by ultrasonic enzymolysis | |
| KR20100076094A (en) | Seaweeds sauce | |
| CN102232561A (en) | Chinese wolfberry cellulose capsule and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130123 Termination date: 20150105 |
|
| EXPY | Termination of patent right or utility model |