CN102041204A - Method for preparing tree-starch based natural biomass detergent - Google Patents
Method for preparing tree-starch based natural biomass detergent Download PDFInfo
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Abstract
The invention relates to a method for preparing tree-starch based natural biomass detergent from raw materials of starch based plant, comprising the processing steps of grinding, steaming, hydrolyzing, pulping, pulp refining, fine separating, or esterifying or aminating, refining and compounding. The tree-starch based natural biomass detergent can be liquid product and powdery product. The tree-starch based natural biomass detergent is mainly used for the environmentally-friendly washing and cleaning of the utensils, fruits, vegetables and body, has good oil stain removing effect and is all natural, non-toxic, safe and environmentally friendly.
Description
Technical field:
The present invention relates to a kind of preparation and method thereof of forest starch base natural biomass washing composition.This technology belongs to household chemicals.
Background technology:
The present invention relates to a kind of preparation and method thereof of forest starch base natural biomass washing composition, promptly the starch with forest starch base fruit is raw material, prepares forest starch-based bio matter washing composition through pulverizing, boiling, hydrolysis making beating, defibrination or esterification or ammonification, complete processing such as refining, composite respectively.It can be a liquiform product, also can be powder-like product.Trees starch-based bio matter washing composition is mainly used in the green that tableware, fruits and vegetables clean, take a shower and cleans, keeps a public place clean, washs, and it is rather good that it cleans oil stain effect, pure natural, nontoxic, safety, environmental protection.
In the face of the severe challenge of food sanitation with safety, food sanitation and safety problem are extremely urgent, have caused compatriots' very big concern.Food is not only the requisite that maintains people's existence, also is and the people's quality of life and the closely bound up consumer's goods of level simultaneously.Progress along with expanding economy and science and technology, various food enriching constantly people's " vegetable basket " and " meal-table ", but more difficult food contamination of being perceiveed by the human consumer in one flourishing back at this, and the various harm consumer healths' that cause thus food poisonings.
The present invention is intended to make circulation, optimization, the effectively utilization of China's trees starch-based bio matter resource realization renewable resource.In China, the trees starch-based bio matter plant length and breadth of land, abundant, full, its preparation quality, resource that is used for the natural biomass washing composition is guaranteed, and not exclusively depends on the quality of soapless soap.Trees starch-based bio matter resource is wide, and the present invention preferentially selects trees starch-based bio matter resource to have: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris, Seed of Chinese Soapberry etc.
Acorn nut belongs to Fagaceae, it of a great variety, and as chinquapin, white oak, thick fringe Ke, Delavay Evergreenchinkapin etc., the raw material name is referred to as acorn nut.It mainly is distributed in Liaoning, Jilin, Heilungkiang one band, can be made into a kind of novel health food one acorn starch through processing.The mode of appearance of acorn starch is a light brown powder, have itself inherent smell, delicate mouthfeel, with other starch major different be that this starch is rich in tannin, its main component is an Ellagitannins, and Ellagitannins is divided into rubber tannin, Ke's Chinese tannin, tannin, oak tannin again.The astringent taste of Ellagitannins not only gives acorn starch special local flavor, and Ellagitannins and protein form complex compound simultaneously, make metabolism slack-off, reduce blood urea nitrogen effect in the blood in addition; Antitoxin antiulcer action and anti-allergic effects, and step-down ends dysentery, treatment gastrointestinal hemorrhage, Ellagitannins can be with complexings such as plumbous mercury, produce precipitation, have detoxification.Just because this medicinal health value, be subjected to the favor of users at home and abroad gradually, the market requirement is very big, most products export Korea S, Japan, and economic benefit is very considerable.At present, domestic acorn starch production is also relatively more rare, and the experience of moulding is also few.Acorn nut is starch-containing 46.4～62.88%, and reasonable and advanced technology is under the prerequisite of ensuring the quality of products, and improves flour extraction rate as much as possible.
Chinese chestnut has another name called chestnut, originates in China, and cultivation history, the iron crops in more than 3000 year, the laudatory titles such as king of dry fruit are arranged, and is one of famous in the world important dry fruit, is that the important exported product Chinese chestnut of China is nutritious, unique flavor.The effective in cure again effect of Chinese chestnut can cure mainly gastric disorder causing nausea, hematemesis hematochezia, pyogenic infections etc.Therefore, Chinese chestnut is popular in the international market.Chinese chestnut processing is paid attention to deeply as the U.S., Japan, France etc. abroad, and Chinese chestnut is processed into series product.In China, except that eating raw, multi-processing becomes products such as marrons glaces, chestnut in syrup can, chestnut custard.
The root of kudzu vine is a kind of natural green food.It is a lot of to contain the flavonoid activeconstituents in the root of kudzu vine, and the total flavones material can reach 0.5g/L, and flavonoid compound can be used as the exploitation of cerebral anemia protective foods.These physiologically active ingredients. have the function of removing free radical, vasodilation, bringing high blood pressure down and prevent arteriosclerosis, improve blood circulation, avoid the cell hypoxemia to injure.To senile dementia and delay body aging effect is preferably arranged, be effective protective foods of the elderly.Therefore, the exploitation and the production of flavonoid activeconstituents healthcare products for guaranteeing human health, improve the significant and vast market prospect of its life quality.The root of kudzu vine also can be used for producing drink, because of containing the too starch component of amount, easily produces juice and separates, and makes beverage layering, precipitation.Adopt the double-enzyme method hydrolysis, the problem of compound and aspects such as decomposition reaction generation, saccharification liquid color, sugar degree and purity when having avoided hydrolysis basically.
Along with development of human society and progress, the consumption of natural, environmental protection, the washing of green bio matter, sanitising agent increases day by day, the shortage of petroleum resources and the deterioration of environment serious threat to human existence and development.With natural reproducible resource substitute that fossil resource synthetic environment close friend is natural, environmental protection, the washing of green bio matter, sanitising agent, be subjected to domestic and international common concern always, become global development strategy.Utilize that the synthetic high added value of agricultural renewable resources and residuum thereof is natural, environmental protection, the washing of green bio matter, sanitising agent be one of developing direction of natural resource comprehensive utilization.
The family of languages row green ecological washing composition of " the natural biological washing " of domestic relevant department document announcement---bamboo, its zero pollution, high-fall separating, safety is natural.Although be washing composition, pleasing to the eye harmless, it is nontoxic to enter the mouth, and is drinkable washing composition.This product can directly be drunk, because it is directly to extract green bamboo and contained refining the forming of biological effective components of Endoconcha Sepiae, is different from the petrochemical industry washing composition fully.
The green natural biocleaner does not pollute environment.Utilized advanced biotechnology,, can directly in the live body mao bamboon, extract active bamboo juice composition, in 800 ℃ high temperature, extracted bamboo juice by modern high technology just as cutting rubber.The mao bamboon at three to six ages, every strain can be extracted six to nine kilograms of bamboo juices, have brought into play the usefulness of mao bamboon greatly, promote the economic worth of mao bamboon.
Wang Qing is peaceful to wait to have reported with the attapulgite to be inorganic assistant agent in " the starch base alkyl glycoside prepares the environment-friendly type washing composition ", and having optimized with starch base alkyl glycoside (APG) with orthogonal experiment is the technology of the composite liquid washing agent of major surfaces promoting agent.Yuan Hao has reported that in " research of starch base tensio-active agent alkyl glycoside " alkyl glycoside (APG for short) is a kind of novel world-class nonionogenic tenside.Alkyl glycoside not only surface tension is low, and foam enriches fine and smooth and stablizes, and decontamination is good, and compatibility is splendid, and under the very high condition of electrolyte concentration, its solubleness is still very high.Advantages such as in addition, this tensio-active agent also has skin and eyes non-stimulated, and consistency is good, and product is nontoxic comparatively speaking, and biological degradability is good.Alkyl glycoside is of many uses, can be applied to fields such as washing composition, makeup, food, medicine, agricultural chemicals.
Forest starch base natural botanical extraction liquid used in the present invention mainly utilizes forest starch base starch and hydrolyzate thereof and derivative production to be easy to biological degradation and excellent property, tensio-active agent numerous in variety.Just begun the development of starch tensio-active agent as far back as the thirties abroad,, made cheapness and the abundant starch resource comes into one's own just day by day as the new raw material of tensio-active agent and develops in recent years because oil and glyceride stock shortage and constantly appreciating.
Summary of the invention:
1, a kind of preparation and method of forest starch base natural biomass washing composition is characterized in that may further comprise the steps:
The first step, the selection of forest starch base plant variety: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris.
In second step, a kind of forest starch base natural biomass washing composition contains forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine.It can be a liquiform product, also can be powder-like product.
The 3rd step, the preparation of forest starch-based bio matter hydrolyzed solution or powder
Do constant weight with the forest starch base fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest starch base dry fruit to constant weight of gas carries out shell benevolence to be separated, and the kernel that is separated can be pulverized through too high comminution ratio material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready.Or produce fresh forest starch base kernel as standby raw material.
The forest starch base kernel pulverizing for preparing is expected or gets to add in the boiling hydrolytic decomposition pot after fresh forest starch base kernel is pulverized, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time was controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8.The solution accent is weakly alkaline, makes the pH value of solution be about 9～10.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain the hydrolysis of forest starch base starch, in and scavenging solution.Carry out concentrating under reduced pressure with scavenging solution in the forest starch base starch hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest starch base starch hydrolytic purification concentrated solution, require solids content 20～50%.
Forest starch base starch hydrolytic purification concentrated solution is tasteless little Huang, near transparent viscous liquid.Can be with forest starch base starch hydrolysis concentrated solution with the high pressure steam sterilization jar 10～15min that under 120 ℃ of conditions, sterilizes, standby.
Forest starch base starch hydrolytic purification concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery forest starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Or get in the forest starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, the corresponding aqueous or powdered product that makes its alkyl glucoside or glycosamine
Forest starch base starch alkyl-glucoside is the general name of a series of products.It can be generated through the glycosyl shift reaction under protonic acid catalysis by forest starch base starch and alcohols material, temperature of reaction, time are looked the difference of catalyzer and difference, the alcohols glucoside that generates, generate the alkoxide glucoside with the reaction of epoxy alkyl compound again, and then with the reaction of lipid acid or higher aliphatic acid, make various alcohols glucoside esters or ethers nonionogenic tenside.
The 4th step, the product preparation
Liquiform product: take by weighing forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine liquid by proportioning and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
The deionized water quality requires to meet standard GB 6682-2000.
Powder-like product: take by weighing forest starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine meal by proportioning and put into stirred vessel, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling or pack.
Description of drawings:
Fig. 1 is the schema of the embodiment of the invention.
Embodiment:
The preparation and the method for 1 one kinds of forest starch base of embodiment natural biomass washing composition is characterized in that may further comprise the steps:
The first step, the selection of forest starch base plant variety: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris.
In second step, a kind of forest starch base natural biomass washing composition contains forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine.It can be a liquiform product, also can be powder-like product.
The 3rd step, the preparation of forest starch-based bio matter hydrolyzed solution or powder
Do constant weight with the forest starch base fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest starch base dry fruit to constant weight of gas carries out shell benevolence to be separated, and the kernel that is separated can be pulverized through too high comminution ratio material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready.Or produce fresh forest starch base kernel as standby raw material.
The forest starch base kernel pulverizing for preparing is expected or gets to add in the boiling hydrolytic decomposition pot after fresh forest starch base kernel is pulverized, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time was controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8.The solution accent is weakly alkaline, makes the pH value of solution be about 9～10.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain the hydrolysis of forest starch base starch, in and scavenging solution.Carry out concentrating under reduced pressure with scavenging solution in the forest starch base starch hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest starch base starch hydrolytic purification concentrated solution, require solids content 20～50%.
Forest starch base starch hydrolytic purification concentrated solution is tasteless little Huang, near transparent viscous liquid.Can be with forest starch base starch hydrolysis concentrated solution with the high pressure steam sterilization jar 10～15min that under 120 ℃ of conditions, sterilizes, standby.
Forest starch base starch hydrolytic purification concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery forest starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Or get in the forest starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, the corresponding aqueous or powdered product that makes its alkyl glucoside or glycosamine.
Forest starch base starch alkyl-glucoside is the general name of a series of products.It can be generated through the glycosyl shift reaction under protonic acid catalysis by forest starch base starch and alcohols material, temperature of reaction, time are looked the difference of catalyzer and difference, the alcohols glucoside that generates, generate the alkoxide glucoside with the reaction of epoxy alkyl compound again, and then with the reaction of lipid acid or higher aliphatic acid, make various alcohols glucoside esters or ethers nonionogenic tenside.
The 4th step, the product preparation
Liquiform product: take by weighing forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine liquid by proportioning and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
The deionized water quality requires to meet standard GB 6682-2000.
Powder-like product: take by weighing forest starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine meal by proportioning and put into stirred vessel, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling or pack.
Embodiment 2:
Do constant weight with the forest starch base acorn nut fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest starch base acorn nut dry fruit to constant weight of gas carries out shell benevolence lock out operation, and the acorn nut kernel that is separated can be pulverized through too high comminution ratio material, gets the raw materials ready.Or produce fresh acorn nut kernel as standby raw material.
Fresh acorn nut kernel after getting the pulverizing material forest starch base acorn nut kernel for preparing or getting pulverizing adds in the hydrolysis digester for 5 kilograms, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100-105 ℃, and extraction time was controlled at 2～3 hours.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain forest acorn starch base starch hydrolytic purification liquid.The forest acorn starch base starch hydrolytic purification liquid that obtains carries out concentrating under reduced pressure, steam unnecessary water, 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest acorn starch base starch hydrolytic purification concentrated solution, require solids content 20～50%.
Spissated forest acorn starch base starch hydrolysis concentrated solution is with the high pressure steam sterilization jar 10～15min that sterilizes under 120 ℃ of conditions, standby.Or get in the forest starch base acorn starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, corresponding acorn starch alkyl glucoside or the glycosamine of making.
Or spissated forest acorn starch base starch hydrolysis concentrated solution carried out press atomization or centrifugal spray drying after with high pressure steam sterilization, further make powdery forest starch base acorn starch hydrolyzate.Or get in the forest starch base acorn starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, correspondingly make the acorn starch alkyl glucoside or glycosamine carries out press atomization or centrifugal spray drying, further make powdery forest acorn starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Liquiform product: take by weighing forest acorn starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest acorn starch base starch hydrolytic purification concentrated solution or alkyl glucoside or glycosamine liquid by said ratio, and squeeze in the stirred vessel, add balance of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest acorn starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.
Embodiment 3:
Do constant weight with the forest starch base seven leaf fruit Exposures to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest starch base seven leaf dry fruits to constant weight of gas carry out shell benevolence lock out operation, and the seven leaf kernels that are separated can be pulverized through too high comminution ratio material, get the raw materials ready.Or produce seven fresh leaf kernels as standby raw material.
Fresh seven leaf kernels after getting the pulverizing material forest starch base seven leaf kernels that prepare or getting pulverizing add in the hydrolysis digester for 5 kilograms, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, and extraction time was controlled at 2～3 hours.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain forest seven leaf kernel starch base starch hydrolytic purification liquid.The forest seven leaf kernel starch base starch hydrolytic purification liquid that obtain carry out concentrating under reduced pressure, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest starch base seven leaf kernel starch hydrolytic purification concentrated solutions, require solids content 20～50%.Spissated forest starch base seven leaf kernel starch hydrolysis concentrated solutions are with the high pressure steam sterilization jar 10～15min that sterilizes under 120 ℃ of conditions, standby.Or get in the forest seven leaf kernel starch base starch hydrolytic purification concentrated solutions adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, corresponding seven leaf kernel starch alkyl glucoside or the glycosamines that make.
Spissated forest seven leaves fruit starch base starch hydrolysis concentrated solution is with the high pressure steam sterilization jar 10～15min that sterilizes under 120 ℃ of conditions, standby.Or get in the forest seven leaves fruit starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, corresponding acorn starch alkyl glucoside or the glycosamine of making.
Or spissated forest seven leaves fruit starch base starch hydrolysis concentrated solution carried out press atomization or centrifugal spray drying after with high pressure steam sterilization, further make powdery forest seven leaves fruit starch base starch hydrolyzates.Or get in the forest seven leaves fruit starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, correspondingly make seven leaves fruits starch alkyl glucoside or glycosamine carries out press atomization or centrifugal spray drying, further make powdery forest seven leaves fruit starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Liquiform product: take by weighing forest seven leaves fruit starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest seven leaves fruit starch base starch hydrolytic purification concentrated solution or alkyl glucoside or glycosamine liquid by said ratio, and squeeze in the stirred vessel, add balance of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest seven leaves fruit starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.
Embodiment 4:
Do constant weight with the forest chestnut starch base fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest chestnut starch backbone to constant weight of gas really carries out shell benevolence lock out operation, and the chestnut kernel that is separated can be pulverized through too high comminution ratio material, gets the raw materials ready.Or produce fresh chestnut kernel as standby raw material.
The fresh chestnut kernel of getting after expecting the pulverizing material forest chestnut starch base kernel of getting ready or getting pulverizing adds in the hydrolysis digester for 5 kilograms, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, and extraction time was controlled at 2～3 hours.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain forest chestnut starch base starch hydrolytic purification liquid.The forest chestnut starch base starch hydrolytic purification liquid that obtains carries out concentrating under reduced pressure, steam unnecessary water, 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest chestnut starch base starch hydrolytic purification concentrated solution, require solids content 20～50%.
Spissated forest chestnut starch base starch hydrolysis concentrated solution is with the high pressure steam sterilization jar 10～15min that sterilizes under 120 ℃ of conditions, standby.Or get in the forest chestnut starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, corresponding chestnut starch alkyl glucoside or the glycosamine of making.
Or spissated forest chestnut starch base starch hydrolysis concentrated solution carried out press atomization or centrifugal spray drying after with high pressure steam sterilization, further make powdery forest chestnut starch base starch hydrolyzates.Or get in the forest chestnut starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, correspondingly make the chestnut starch alkyl glucoside or glycosamine carries out press atomization or centrifugal spray drying, further make powdery forest chestnut starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Liquiform product: take by weighing forest chestnut starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest chestnut starch base starch hydrolytic purification concentrated solution or alkyl glucoside or glycosamine liquid by said ratio, and squeeze in the stirred vessel, add balance of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest chestnut starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.Forest starch-based bio matter washing composition detection method:
(1) mensuration of pH: measure pH with PHS-3C type acidometer;
(2) mensuration of proportion: adopt pycnometric method;
(3) winter hardiness: after in-10 ℃ refrigerator, placing 24h, recover room temperature, observe phenomena;
(4) thermotolerance: in 40 ± 1 ℃ water-bath, behind the heating 24h, recover room temperature, observe phenomena;
(5) mensuration of fat content: adopt the Soxhlet method;
(6) mensuration of viscosity: adopt the method for GB GB9985-2000 to measure;
(7) mensuration of foam height: adopt the method for GB GB/T1974-2002 to measure;
(8) alcohol-insoluble substance Determination on content: adopt the method for GB GB/T9986-1988 to measure;
(9) mensuration of toxic metal constituent content: adopt mass spectroscopy.Get forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine 25ml and put into MARS5 microwave nitre and separate instrument and carry out nitratedly, take out the mensuration of carrying out arsenic, cadmium, mercury, lead ion with 7500A inductively coupled plasma mass spectrograph behind the 6h;
(10) soil removability: adopt GB GB9985-2000 method to measure.
Claims (5)
1. the preparation and the method for a forest starch base natural biomass washing composition is characterized in that may further comprise the steps:
The first step, the selection of forest starch base plant variety: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris.
In second step, a kind of forest starch base natural biomass washing composition contains forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine.It can be a liquiform product, also can be powder-like product.
The 3rd step, the preparation of forest starch-based bio matter hydrolyzed solution or powder
Do constant weight with the forest starch base fruit order solarization of collection or with drier (60～65 ℃) to gas.The dried forest starch base dry fruit to constant weight of gas carries out shell benevolence to be separated, and the kernel that is separated can be pulverized through too high comminution ratio material, and the degree of grinding after the pulverizing is 50～100 orders, gets the raw materials ready.Or produce fresh forest starch base kernel as standby raw material.
The forest starch base kernel pulverizing for preparing is expected or gets to add in the boiling hydrolytic decomposition pot after fresh forest starch base kernel is pulverized, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time was controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8.The solution accent is weakly alkaline, makes the pH value of solution be about 9～10.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain the hydrolysis of forest starch base starch, in and scavenging solution.Carry out concentrating under reduced pressure with scavenging solution in the forest starch base starch hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest starch base starch hydrolytic purification concentrated solution, require solids content 20～50%.
Forest starch base starch hydrolytic purification concentrated solution is tasteless little Huang, near transparent viscous liquid.Can be with forest starch base starch hydrolysis concentrated solution with the high pressure steam sterilization jar 10～15min that under 120 ℃ of conditions, sterilizes, standby.
Forest starch base starch hydrolytic purification concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery forest starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Or get in the forest starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, the corresponding aqueous or powdered product that makes its alkyl glucoside or glycosamine.
Forest starch base starch alkyl-glucoside is the general name of a series of products.It can be generated through the glycosyl shift reaction under protonic acid catalysis by forest starch base starch and alcohols material, temperature of reaction, time are looked the difference of catalyzer and difference, the alcohols glucoside that generates, generate the alkoxide glucoside with the reaction of epoxy alkyl compound again, and then with the reaction of lipid acid or higher aliphatic acid, make various alcohols glucoside esters or ethers nonionogenic tenside.
The 4th step, the product preparation
Liquiform product: take by weighing forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine liquid by proportioning and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
The deionized water quality requires to meet standard GB 6682-2000.
Powder-like product: take by weighing forest starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine meal by proportioning and put into stirred vessel, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling or pack.
2. the preparation and the method for a kind of forest starch base natural biomass washing composition according to claim 1 is characterized in that the forest tree breed selection: acorn nut, seven leaves fruit, Chinese chestnut, the root of kudzu vine, Seed of Chinese Soapberry, Rhizome of Glabrous Greenbrier, fern root, short-tube lycoris.
3. the preparation and the method for a kind of forest starch base natural biomass washing composition according to claim 1 is characterized in that this forest starch base natural biomass washing composition contains forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated solution or its alkyl glucoside or glycosamine liquid.It can be a liquiform product, also can be powder-like product.
4. the preparation and the method for a kind of forest starch base natural biomass washing composition according to claim 1 is characterized in that the preparation of forest starch-based bio matter extracting solution or powder:
Do constant weight with the forest starch base fruit Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried forest starch base dry fruit to constant weight of gas carries out shell benevolence lock out operation, and the kernel that is separated can be pulverized through too high comminution ratio material, and degree of grinding is controlled at 50～100 orders, gets the raw materials ready.Or produce fresh forest starch base kernel as standby raw material.
The forest starch base kernel pulverizing for preparing is expected or gets to add in the boiling hydrolytic decomposition pot after fresh forest starch base kernel is pulverized, adding acid, deionized water to solid-to-liquid ratio is controlled in 1: 6～12 the scope, the boiling that is hydrolyzed operation, hydrolysis temperature is controlled at 100～105 ℃, hydrolysis time was controlled at 0.5～3 hour, starch: water: 20% sulfuric acid=0.5g: 4ml: 4ml=1: 8: 8.The solution accent is weakly alkaline, makes the pH value of solution be about 9～10.Carry out neutralization, making beating, defibrination, the lock out operation of hydrolyzation material liquid after hydrolysis is intact, cross 100 mesh sieves, elimination part insolubles and lixiviate material residue promptly obtain the hydrolysis of forest starch base starch, in and scavenging solution.Carry out concentrating under reduced pressure with scavenging solution in the forest starch base starch hydrolysis that obtains, steam unnecessary water, 60～65 ℃ are evaporated to 1/2～1/5 of original volume, make certain density forest starch base starch hydrolytic purification concentrated solution, require solids content 20～50%.
Forest starch base starch hydrolytic purification concentrated solution is tasteless little Huang, near transparent viscous liquid.Can be with forest starch base starch hydrolysis concentrated solution with the high pressure steam sterilization jar 10～15min that under 120 ℃ of conditions, sterilizes, standby.
Forest starch base starch hydrolytic purification concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery forest starch base starch hydrolyzates.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
Or get in the forest starch base starch hydrolytic purification concentrated solution adding retort, add Fatty Alcohol(C12-C14 and C12-C18) or amine or liquefied ammonia respectively and carry out esterification or aminating reaction, the corresponding aqueous or powdered product that makes its alkyl glucoside or glycosamine.
Forest starch base starch alkyl-glucoside is the general name of a series of products.It can be generated through the glycosyl shift reaction under protonic acid catalysis by forest starch base starch and alcohols material, temperature of reaction, time are looked the difference of catalyzer and difference, the alcohols glucoside that generates, generate the alkoxide glucoside with the reaction of oxirane meter compound again, and then with the reaction of lipid acid or higher aliphatic acid, make various alcohols glucoside esters or ethers nonionogenic tenside.
5. the preparation and the method for a kind of forest starch base natural biomass washing composition according to claim 1 is characterized in that by following composition preparation.
Liquiform product: take by weighing forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated solution or alkyl glucoside or glycosamine, solids content 20～50%, consumption 20～40%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; Deionized water: surplus.Take by weighing forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated solution or alkyl glucoside or glycosamine liquid by said ratio, and squeeze in the stirred vessel, add balance of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
Powder-like product: take by weighing forest starch-based bio matter extract such as forest starch base starch hydrolytic purification concentrated dry thing or its alkyl glucoside or glycosamine solid substance, solids content 〉=90%, consumption 90～95%; Add an amount of plant auxiliary agent and natural essence, consumption 5～10%; In the lump mixture is added in the stirred vessel, after the mixing and stirring, detect discharging, packing.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102604750A (en) * | 2012-01-12 | 2012-07-25 | 中国林业科学研究院林产化学工业研究所 | Method for preparing forest herbaceous plant biomass detergent |
| CN106978281A (en) * | 2017-03-30 | 2017-07-25 | 柳州立洁科技有限公司 | A kind of acidic cleaner and preparation method thereof |
| CN108250307A (en) * | 2018-01-22 | 2018-07-06 | 安徽师范大学 | A kind of preparation method for being denaturalized short-tube lycoris starch |
| CN110499219A (en) * | 2018-05-17 | 2019-11-26 | 陈广龙 | Tableware, fruits and vegetables cleaning agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613640A (en) * | 2009-07-03 | 2009-12-30 | 沈阳师范大学 | Self-faced active fruit and vegetable clean-out system and preparation method thereof |
| CN101659909A (en) * | 2009-06-09 | 2010-03-03 | 深圳市成为工贸有限公司 | Natural washing particle and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101659909A (en) * | 2009-06-09 | 2010-03-03 | 深圳市成为工贸有限公司 | Natural washing particle and preparation method thereof |
| CN101613640A (en) * | 2009-07-03 | 2009-12-30 | 沈阳师范大学 | Self-faced active fruit and vegetable clean-out system and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604750A (en) * | 2012-01-12 | 2012-07-25 | 中国林业科学研究院林产化学工业研究所 | Method for preparing forest herbaceous plant biomass detergent |
| CN106978281A (en) * | 2017-03-30 | 2017-07-25 | 柳州立洁科技有限公司 | A kind of acidic cleaner and preparation method thereof |
| CN108250307A (en) * | 2018-01-22 | 2018-07-06 | 安徽师范大学 | A kind of preparation method for being denaturalized short-tube lycoris starch |
| CN110499219A (en) * | 2018-05-17 | 2019-11-26 | 陈广龙 | Tableware, fruits and vegetables cleaning agent |
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