CN102349863A - Preparation method of algal polysaccharides toner - Google Patents
Preparation method of algal polysaccharides toner Download PDFInfo
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- CN102349863A CN102349863A CN 201110338566 CN201110338566A CN102349863A CN 102349863 A CN102349863 A CN 102349863A CN 201110338566 CN201110338566 CN 201110338566 CN 201110338566 A CN201110338566 A CN 201110338566A CN 102349863 A CN102349863 A CN 102349863A
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- sargassum polysaccharides
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- algal polysaccharides
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Abstract
The invention relates to a preparation method of an algal polysaccharides toner, comprising the following steps of: putting cleaned grateloupia filicina into an oven for baking, pulverizing by a universal pulverizer, sieving; then adding double distilled water according to a solid-to-liquid ratio, putting into a water bath of 100 DEG C, staying for a period of time in the boiled water bath; centrifuging by a high-speed centrifuge, taking the supernatant, performing rotary evaporation by a rotary evaporator until the supernatant is 1/4 of the original volume, adding absolute ethyl alcohol, standing in a refrigerator of 4 DEG C; then centrifuging by the high-speed centrifuge again, taking the precipitate, adding a proper amount of water for dissolving, evaporating by the rotary evaporator to remove the ethyl alcohol to obtain the algal polysaccharides extracting solution; and stirring the algal polysaccharides extracting solution, double distilled water, rose essence and a preservative imidazolidinyl urea uniformly to obtain the natural algal polysaccharides toner. The algal polysaccharides toner has the advantages of simple process, easiness of control, stable system, no toxic side effect, efficacies of moistening, anti-wrinkling, whitening, diminishing inflammation, promoting tissue regeneration, resisting aging and the like, and broad market prospect.
Description
Technical field
The present invention relates to a kind of method for preparing of surfactant, be specifically related to a kind of method for preparing of Sargassum polysaccharides surfactant, belong to the cosmetics of everyday use technical field.
Background technology
Polysaccharide is the general name of the family macromolecule that connects and composes through glycosidic bond with monosaccharide.Polysaccharose substance is the indispensable macromole reactive compound of human life metabolism.The various vital movements of these polysaccharide wide participation cells and produce the various biological function are like functions such as enhance immunity characteristic, antitumor, antiviral, anticoagulation, radioprotective and slow down aging.In addition, the existence of a large amount of hydrophilic hydroxyls makes many polysaccharide show some good physicochemical properties, like strong absorptive, emulsibility, high viscosity and good film property.Since the sixties in 20th century, people begin polysaccharide is applied in the cosmetics, satisfy the requirement of natural, nutrition that people propose cosmetics, nonirritant etc.
China's marine algae resource is very abundant, has thousands of kinds approximately, and wherein most important product is a polysaccharide, accounts for more than 50% of Sargassum dry weight.Grateloupia filicina (Wulf.) (
Grateloupia filicina) be Rhodophyta, Grateloupia filicina (Wulf.) section, the Grateloupia filicina (Wulf.) platymiscium is the common macro in marine site, China southeast, is grown in subtidal line, China's Coastal Areas all has distribution, can carry out the artificial cultivation of scale.The Grateloupia filicina (Wulf.) polysaccharide is the important composition composition of Grateloupia filicina (Wulf.), is a kind of sulfated polysaccharides, has multiple efficacies such as human body immunity improving, antiviral, antitumor, mutation.The present suitable growth conditions of domestic and international more research Grateloupia filicina (Wulf.) like influence, artificial culture and the health food exploitation etc. to its growth such as salinity, temperature, radiation, but does not have the report and the patent application of polysaccharide surfactant as yet.
Summary of the invention
The object of the present invention is to provide a kind of method for preparing of Sargassum polysaccharides surfactant, advantage such as this method technology is easy, be easy to control, system is stable; Have no side effect, can produce preserves moisture wrinkle resistant, moistly whitens, dephlogistication and promoting nuscle growth and the anti-ageing function of waiting for a long time, and has vast market prospect.
In order to address the above problem, the technical scheme that the present invention adopted is:
A kind of method for preparing of Sargassum polysaccharides surfactant comprises the steps:
(1) preparation of Sargassum polysaccharides extracting solution:
A, the Grateloupia filicina (Wulf.) that cleans up is put into baking oven, under 40 ~ 60 ℃ of conditions, toast 4 ~ 8 h;
B, pulverize, cross 60 ~ 80 eye mesh screens with Universalpulverizer;
C, the Grateloupia filicina (Wulf.) after will pulverizing add distilled water in the ratio of solid-liquid mass ratio 1:40 ~ 60, place 100 ℃ water-bath, boiling water bath 2 ~ 4h;
D, solidliquid mixture that step C water bath processing is good are centrifugal under 3000 ~ 5000rmp/min condition with high speed centrifuge, get supernatant behind 15 ~ 25min, supernatant with rotary evaporator at 50 ~ 70 ℃ of rotary evaporations to 1/4 of original volume;
E, step D is added the dehydrated alcohol of 2 ~ 4 times of its volumes through the spissated supernatant of rotary evaporator, in 4 ℃ of refrigerators, leave standstill 10 ~ 14h;
F, with high speed centrifuge that the liquid that step e obtains is centrifugal under 3000 ~ 5000rmp/min condition once more gets deposition behind 15 ~ 25min, add the suitable quantity of water dissolving;
Liquid rotary evaporation under 50 ~ 70 ℃ of conditions after G, the dissolving that step F obtained with rotary evaporator is removed ethanol, obtains the Sargassum polysaccharides extracting solution;
(2) method for preparing of Sargassum polysaccharides surfactant: with mass ratio is that 15 ~ 25% Sargassum polysaccharides extracting solution, 0.1 ~ 0.2% rose essence, antiseptic-two imidazolidinyl urea of 0.1 ~ 0.3% and the distilled water of surplus mix, and stirring to obtain natural seaweed polysaccharide surfactant.
A kind of Sargassum polysaccharides surfactant with method for preparing.
The present invention optimizes the extraction process that the hot water extraction extracts the Grateloupia filicina (Wulf.) polysaccharide through single factor and orthogonal test; And carried out proportioning and the test of effect property repeatedly with distilled water, essence and antiseptic etc., a kind of method for preparing of natural seaweed polysaccharide surfactant has been proposed.The essence that is adopted is rose essence, and antiseptic is two imidazolidinyl urea (English names: Germall A), all be the typical additives of producing cosmetics, obtain easy purchase of Chemical market.
The present invention with respect to the beneficial effect of prior art is: the Grateloupia filicina (Wulf.) polysaccharide is a kind of natural product; The patent medicine that is involutory has little, the active strong advantage of toxic and side effects; The advantage that have aboundresources, gather easily, cost is low, the present invention have technology easy, be easy to control, advantage that system is stable; And macromolecule polysaccharide has no side effect; Can produce preserves moisture wrinkle resistant, moistly whitens, dephlogistication and promoting nuscle growth and the anti-ageing function of waiting for a long time; Satisfied the requirement of natural, nutrition that people propose cosmetics, nonirritant etc., the development and use Grateloupia filicina (Wulf.) prepares the polysaccharide surfactant and has vast market prospect.The present invention have technology easy, be easy to advantages such as control, system is stable; Have no side effect, can produce preserves moisture wrinkle resistant, moistly whitens, dephlogistication and promoting nuscle growth and the anti-ageing function of waiting for a long time, and has vast market prospect.
The specific embodiment
Through embodiment the present invention is explained further details below, these embodiment only are used for explaining the present invention, do not limit the scope of the invention.
Embodiment 1
A kind of method for preparing of Sargassum polysaccharides surfactant comprises the steps:
(1) preparation of Sargassum polysaccharides extracting solution:
A, the Grateloupia filicina (Wulf.) that cleans up is put into baking oven, baking 4 h under 40 ℃ of conditions;
B, exsiccant Grateloupia filicina (Wulf.) is pulverized, crossed 60 eye mesh screens with Universalpulverizer;
C, with the ratio adding distilled water of the Grateloupia filicina (Wulf.) of pulverizing by solid-liquid mass ratio 1:40, place 100 ℃ water-bath, boiling water bath 2h;
D, liquid that water-bath is good are centrifugal under the 3000rmp/min condition with high speed centrifuge, get supernatant behind the 15min, with rotary evaporator supernatant are rotated to be evaporated to 1/4 of original volume under 50 ℃ of conditions;
E, the supernatant after will concentrating add the dehydrated alcohol of its 2 times of volumes, in 4 ℃ of refrigerators, leave standstill 10h;
F, will to have added alcoholic acid supernatant with high speed centrifuge once more centrifugal under the 3000rmp/min condition, gets deposition behind the 15min, adds the suitable quantity of water dissolving;
G, liquid rotary evaporation under 50 ℃ of conditions that step F obtains is removed ethanol, obtain the Sargassum polysaccharides extracting solution with rotary evaporator;
(2) method for preparing of Sargassum polysaccharides surfactant: with mass ratio is 15% Sargassum polysaccharides extracting solution, 0.1% rose essence, 0.1% antiseptic-two imidazolidinyl urea and the mixing of surplus distilled water, and stirring to obtain natural seaweed polysaccharide surfactant.
Embodiment 2
A kind of method for preparing of Sargassum polysaccharides surfactant comprises the steps:
(1) preparation of Sargassum polysaccharides extracting solution:
A, the Grateloupia filicina (Wulf.) that cleans up is put into baking oven, baking 8 h under 60 ℃ of conditions;
B, exsiccant Grateloupia filicina (Wulf.) is pulverized, crossed 80 eye mesh screens with Universalpulverizer;
C, with the ratio adding distilled water of the Grateloupia filicina (Wulf.) of pulverizing by solid-liquid mass ratio 1:60, place 100 ℃ water-bath, boiling water bath 4h;
D, the liquid that water-bath obtains is centrifugal under the 5000rmp/min condition with high speed centrifuge gets supernatant behind the 25min, with rotary evaporator the supernatant that obtains is rotated to be evaporated to 1/4 of original volume under 70 ℃ of conditions;
E, the supernatant after will concentrating add the dehydrated alcohol of its 4 times of volumes, in 4 ℃ of refrigerators, leave standstill 14h;
F, with high speed centrifuge that the liquid that step e obtains is centrifugal under the 5000rmp/min condition once more gets deposition behind the 25min, add the suitable quantity of water dissolving;
G, the liquid that step F obtains is removed ethanol at 70 ℃ of rotary evaporations, obtain the Sargassum polysaccharides extracting solution with rotary evaporator;
(2) method for preparing of Sargassum polysaccharides surfactant: with mass ratio is 25% Sargassum polysaccharides extracting solution, 0.2% rose essence, 0.2% antiseptic-two imidazolidinyl urea and the mixing of surplus distilled water, and stirring to obtain natural seaweed polysaccharide surfactant.
Embodiment 3
A kind of method for preparing of Sargassum polysaccharides surfactant is characterized in that: comprise the steps:
(1) preparation of Sargassum polysaccharides extracting solution:
A, the Grateloupia filicina (Wulf.) that cleans up is put into baking oven, baking 6 h under 50 ℃ of conditions;
B, exsiccant Grateloupia filicina (Wulf.) is pulverized, crossed 70 eye mesh screens with Universalpulverizer;
C, the Grateloupia filicina (Wulf.) that crushes is added distilled water in the ratio of solid-liquid mass ratio 1:50, place 100 ℃ water-bath, boiling water bath 3h;
D, centrifugal under the 4000rmp/min condition with the high speed centrifuge liquid that water-bath is good gets supernatant behind the 20min, with rotary evaporator supernatant is rotated to be evaporated to 1/4 of original volume under 60 ℃ of conditions;
E, the supernatant that will concentrate add the dehydrated alcohol like its 3 times of volumes, in 4 ℃ of refrigerators, leave standstill 12h;
F, with high speed centrifuge that the liquid that step e obtains is centrifugal under the 4000rmp/min condition once more gets deposition behind the 20min, add the suitable quantity of water dissolving;
G, liquid rotary evaporation under 60 ℃ of conditions that step F obtains is removed ethanol, obtain the Sargassum polysaccharides extracting solution with rotary evaporator;
(2) method for preparing of Sargassum polysaccharides surfactant: with mass ratio is 20% Sargassum polysaccharides extracting solution, 0.15% rose essence, 0.3% antiseptic--two imidazolidinyl urea and surplus distilled water mix, and stirring to obtain natural seaweed polysaccharide surfactant.
Claims (2)
1. the method for preparing of a Sargassum polysaccharides surfactant is characterized in that: comprise the steps:
(1) preparation of Sargassum polysaccharides extracting solution:
A, the Grateloupia filicina (Wulf.) that cleans up is put into baking oven, under 40 ~ 60 ℃ of conditions, toast 4 ~ 8 h;
B, exsiccant Grateloupia filicina (Wulf.) is pulverized, crossed 60 ~ 80 eye mesh screens with Universalpulverizer;
C, the Grateloupia filicina (Wulf.) after will pulverizing add distilled water in the ratio of solid-liquid mass ratio 1:40 ~ 60, place 100 ℃ water-bath, and the boiling water bath time is 2 ~ 4h;
D, solidliquid mixture that step C water bath processing is good are centrifugal under 3000 ~ 5000rmp/min condition with high speed centrifuge, get supernatant behind 15 ~ 25min, supernatant with rotary evaporator at 50 ~ 70 ℃ of rotary evaporations to 1/4 of original volume;
E, step D is added the dehydrated alcohol of 2 ~ 4 times of its volumes through the spissated supernatant of rotary evaporator, in 4 ℃ of refrigerators, leave standstill 10 ~ 14h;
F, with high speed centrifuge that the liquid that step e obtains is centrifugal under 3000 ~ 5000rmp/min condition once more gets deposition behind 15 ~ 25min, add the suitable quantity of water dissolving;
Liquid rotary evaporation under 50 ~ 70 ℃ of conditions after G, the dissolving that step F obtained with rotary evaporator is removed ethanol, obtains the Sargassum polysaccharides extracting solution;
(2) method for preparing of Sargassum polysaccharides surfactant: with mass ratio is that 15 ~ 25% Sargassum polysaccharides extracting solution, 0.1 ~ 0.2% rose essence, antiseptic-two imidazolidinyl urea of 0.1 ~ 0.3% and the distilled water of surplus mix, and stirring to obtain natural seaweed polysaccharide surfactant.
2. Sargassum polysaccharides surfactant with the preparation of the said method of claim 1.
Priority Applications (1)
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| CN 201110338566 CN102349863A (en) | 2011-11-01 | 2011-11-01 | Preparation method of algal polysaccharides toner |
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| CN 201110338566 CN102349863A (en) | 2011-11-01 | 2011-11-01 | Preparation method of algal polysaccharides toner |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103301054A (en) * | 2013-06-27 | 2013-09-18 | 安婕妤化妆品科技股份有限公司 | Collagen gel capable of moisturizing, revitalizing and nourishing as well as preparation method and application thereof |
| CN103655308A (en) * | 2013-12-04 | 2014-03-26 | 青岛安信医疗器械有限公司 | Moisturizing skin care water |
| CN104721068A (en) * | 2015-01-29 | 2015-06-24 | 广州暨南生物医药研究开发基地有限公司 | Application of eucheuma gelatinae polysaccharide in preparation of antioxidant skin care products |
| CN104940109A (en) * | 2015-07-01 | 2015-09-30 | 浙江海洋学院 | Natural marine facial mask based on shell and preparation method of natural marine facial mask |
| CN105175563A (en) * | 2015-08-18 | 2015-12-23 | 浙江中烟工业有限责任公司 | Extraction method and application of Grateloupia turuturu Yamada polysaccharide |
| CN105581950A (en) * | 2016-03-30 | 2016-05-18 | 吴美燕 | Method for utilizing seaweed extract for preparing whitening and freckle removing seaweed paste |
| CN105687058A (en) * | 2016-03-30 | 2016-06-22 | 吴美燕 | Method for preparing water-soluble scar repairing seaweed cream by utilizing seaweed extract |
| CN105708766A (en) * | 2016-03-30 | 2016-06-29 | 吴美燕 | Method for preparing water-soluble seaweed mask from seaweed extract |
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| CN1389476A (en) * | 2002-07-09 | 2003-01-08 | 暨南大学 | Algae extracting process |
| CN1810842A (en) * | 2005-01-25 | 2006-08-02 | 上海中医药大学 | Longleaf Grateloupia acuminata polysaccharide extract and its prepn and use |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1389476A (en) * | 2002-07-09 | 2003-01-08 | 暨南大学 | Algae extracting process |
| CN1810842A (en) * | 2005-01-25 | 2006-08-02 | 上海中医药大学 | Longleaf Grateloupia acuminata polysaccharide extract and its prepn and use |
Non-Patent Citations (2)
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| 《食品科技》 20051231 盛建春等 《海藻多糖生物活性研究》 第262-264页 1-2 第26卷, 第3期 * |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103301054A (en) * | 2013-06-27 | 2013-09-18 | 安婕妤化妆品科技股份有限公司 | Collagen gel capable of moisturizing, revitalizing and nourishing as well as preparation method and application thereof |
| CN103301054B (en) * | 2013-06-27 | 2014-03-26 | 安婕妤化妆品科技股份有限公司 | Collagen gel capable of moisturizing, revitalizing and nourishing as well as preparation method and application thereof |
| CN103655308A (en) * | 2013-12-04 | 2014-03-26 | 青岛安信医疗器械有限公司 | Moisturizing skin care water |
| CN104721068A (en) * | 2015-01-29 | 2015-06-24 | 广州暨南生物医药研究开发基地有限公司 | Application of eucheuma gelatinae polysaccharide in preparation of antioxidant skin care products |
| CN104940109A (en) * | 2015-07-01 | 2015-09-30 | 浙江海洋学院 | Natural marine facial mask based on shell and preparation method of natural marine facial mask |
| CN105175563A (en) * | 2015-08-18 | 2015-12-23 | 浙江中烟工业有限责任公司 | Extraction method and application of Grateloupia turuturu Yamada polysaccharide |
| CN105581950A (en) * | 2016-03-30 | 2016-05-18 | 吴美燕 | Method for utilizing seaweed extract for preparing whitening and freckle removing seaweed paste |
| CN105687058A (en) * | 2016-03-30 | 2016-06-22 | 吴美燕 | Method for preparing water-soluble scar repairing seaweed cream by utilizing seaweed extract |
| CN105708766A (en) * | 2016-03-30 | 2016-06-29 | 吴美燕 | Method for preparing water-soluble seaweed mask from seaweed extract |
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Application publication date: 20120215 |